The idea of this monograph is to present the latest results related to design and computation of engineering materials and structures. The contributions cover the classical fields of mechanical, civil and materials engineering up to biomechanics and advanced materials processing and optimization. The materials and structures covered can be categorized into modern steels and titanium alloys, composite materials, biological and natural materials, material hybrids and modern joining technologies. Analytical modelling, numerical simulation, the application of state-of-the-art design tools and sophisticated experimental techniques are applied to characterize the performance of materials and to design and optimize structures in different fields of engineering applications.

The idea of this monograph is to present the latest results related to experimental and numerical investigations of advanced materials and structures. The contributions cover the field of mechanical, civil and materials engineering, ranging from new modelling and simulation techniques, advanced analysis techniques, optimization of structures and materials and constitutive modelling. Well known experts present their research on damage and fracture of material and structures, materials modelling and evaluation up to image processing and visualization for advanced analyses and evaluation.

This thesis introduces a series of novel, non-conjugated polyarylether hosts that are not subject to the triplet-energy limitations of traditional conjugated polymer hosts. As a result of this major breakthrough, the long-standing problem of triplet energy back transfer has now been overcome, making it possible to design high-efficiency electrophosphorescent polymers (PhPs), especially the blue and all-phosphorescent white ones. In addition, the author proposes a spiro-linked hyperbranched architecture for PhPs to inhibit the undesired triplet energy back transfer process in low triplet-energy hosts. The work in this thesis provides vital new insights into the design of PhPs and has led to several publications in high-profile journals.

This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.

This book presents, in a self-contained fashion, a series of studies on flow and heat transfer in porous media, in which distinct energy balances are considered for the porous matrix and for the permeating fluid. Detailed mathematical modeling is presented considering both volume and time averaging operators simultaneously applied to the governing equations. System involving combustion in the gaseous phase, moving bed and double-diffusion mechanism are analyzed. Numerical results are presented for each case. In the end, this book contains the description of a tool that might benefit engineers in developing and designing more efficient thermal equipment.

This book is about the pattern formation and the evolution of crack propagation in engineering materials and structures, bridging mathematical analyses of cracks based on singular integral equations, to computational simulation of engineering design. The first two parts of this book focus on elasticity and fracture and provide the basis for discussions on fracture morphology and its numerical simulation, which may lead to a simulation-based fracture control in engineering structures. Several design concepts are discussed for the prevention of fatigue and fracture in engineering structures, including safe-life design, fail-safe design, damage tolerant design. After starting with basic elasticity and fracture theories in parts one and two, this book focuses on the fracture morphology that develops due to the propagation of brittle cracks or fatigue cracks. In part three, the mathematical analysis of a curved crack is precisely described, based on the perturbation method. The stability theory of interactive cracks propagating in brittle solids may help readers to understand the formation of a fractal-like cracking patterns in brittle solids, while the stability theory of crack paths helps to identify the straight versus sharply curved or sometimes wavy crack paths observed in brittle solids. In part four, the numerical simulation method of a system of multiple cracks is introduced by means of the finite element method, which may be used for the better implementation of fracture control in engineering structures. This book is part of a series on "Mathematics for Industry" and will appeal to structural engineers seeking to understand the basic backgrounds of analyses, but also to mathematicians with an interest in how such mathematical solutions are evaluated in industrial applications.

The book is about calorimetry and thermal analysis methods, alone or linked to other techniques, as applied to the characterization of catalysts, supports and adsorbents, and to the study of catalytic reactions in various domains: air and wastewater treatment, clean and renewable energies, refining of hydrocarbons, green chemistry, hydrogen production and storage. The book is intended to fill the gap between the basic thermodynamic and kinetics concepts acquired by students during their academic formation, and the use of experimental techniques such as thermal analysis and calorimetry to answer practical questions. Moreover, it supplies insights into the various thermal and calorimetric methods which can be employed in studies aimed at characterizing the physico-chemical properties of solid adsorbents, supports and catalysts, and the processes related to the adsorption desorption phenomena of the reactants and/or products of catalytic reactions. The book also covers the basic concepts for physico-chemical comprehension of the relevant phenomena. Thermodynamic and kinetic aspects of the catalytic reactions can be fruitfully investigated by means of thermal analysis and calorimetric methods, in order to better understand the sequence of the elemental steps in the catalysed reaction. So the fundamental theory behind the various thermal analysis and calorimetric techniques and methods also are illustrated.

Particulate products make up around 80% of chemical products, from all industry sectors. Examples given in this book include the construction materials, fine ceramics and concrete; the delicacies, chocolate and ice cream; pharmaceutical, powders, medical inhalers and sun screen; liquid and powder paints. Size distribution and the shape of the particles provide for different functionalities in these products. Some functions are general, others specific. General functions are powder flow and require - at the typical particulate concentrations of these products - that the particles cause adequate rheological behavior during processing and/or for product performance. Therefore, this book addresses particle packing as well as its relation to powder flow and rheological behavior. Moreover, general relationships to particle size are discussed for e.g. color and sensorial aspects of particulate products. Product-specific functionalities are often relevant for comparable product groups. Particle size distribution and shape provide, for example, the following functionalities: - dense particle packing in relation to sufficient strength is required in concrete construction, ceramic objects and pharmaceutical tablets - good sensorial properties (mouthfeel) to chocolate and ice cream - effective dissolution, flow and compression properties for pharmaceutical powders - adequate hiding power and effective coloring of paints for protection and the desired esthetical appeal of the objects - adequate protection of our body against sun light by sunscreen - effective particle transport and deposition to desired locations for medical inhalers and powder paints. Adequate particle size distribution, shape and porosity of particulate products have to be achieved in order to reach optimum product performance. This requires adequate management of design and development as well as sufficient knowledge of the underlying principles of physics and chemistry. Moreover, flammability, explosivity and other health hazards from powders, during handling, are taken into account. This is necessary, since great risks may be involved. In all aspects, the most relevant parameters of the size distribution (and particle shape) have to be selected. In this book, experts in the different product fields have contributed to the product chapters. This provides optimum information on what particulate aspects are most relevant for behavior and performance within specified industrial products and how optimum results can be obtained. It differs from other books in the way that the critical aspects of different products are reported, so that similarities and differences can be identified. We trust that this approach will lead to improved optimization in design, development and quality of many particulate products.

Composites are widely used in marine applications. There is considerable experience of glass reinforced resins in boats and ships but these are usually not highly loaded. However, for new areas such as offshore and ocean energy there is a need for highly loaded structures to survive harsh conditions for 20 years or more. High performance composites are therefore being proposed. This book provides an overview of the state of the art in predicting the long term durability of composite marine structures. The following points are covered: •       Modelling water diffusion •       Damage induced by water •       Accelerated testing •       Including durability in design •       In-service experience. This is essential reading for all those involved with composites in the marine industry, from initial design and calculation through to manufacture and service exploitation. It also provides information unavailable elsewhere on the mechanisms involved in degradation and how to take account of them. Ensuring long term durability is not only necessary for safety reasons, but will also determine the economic viability of future marine structures.

This review book is concerned with the synthesis, charge transport properties and practical applications of poly (o-aminophenol) (POAP) film electrodes. It is divided into three parts. The first one has a particular emphasis on problems of synthesis and structure of POAP. The second part deals with the mechanism of charge transfer and charge transport processes occurring in the course of the redox reactions of POAP. The third part describes the promising applications of POAP in the different fields of sensors, electrocatalysis, bioelectrochemistry, corrosion protection, among others. This review covers the literature on POAP in the time period comprised between 1987 and 2013.

This book presents the important analytical technique of magnetic microscopy. This method is applied to analyze layered structures with high resolution. This book presents a number of layer-resolving magnetic imaging techniques that have evolved recently. Many exciting new developments in magnetism rely on the ability to independently control the magnetization in two or more magnetic layers in micro- or nanostructures. This in turn requires techniques with the appropriate spatial resolution and magnetic sensitivity. The book begins with an introductory overview, explains then the principles of the various techniques and gives guidance to their use. Selected examples demonstrate the specific strengths of each method. Thus the book is a valuable resource for all scientists and practitioners investigating and applying magnetic layered structures.

This book highlights the basics of crystal optics methods and refractive index (RI) measurement techniques in various solids, as well as their scientific and technological applications. In addition to new techniques for cases when traditional techniques are impractical, such as for highly refracting powders, anomalous dispersion of light in the studied solid, or for colloids, it also describes conventional methods of RI measurement.

This book presents an extensive review of literature on the properties of carbon nanofibers (CNF) reinforced polymer composites in conjunction with advances in the production and properties of CNFs. It further provides readers a view into the development of lightweight composites whose properties are tailored and enhanced with micro- and nano-reinforcement, along with results from data comparisons from several published investigations.

The elucidation of the effects of structurally extended defects on electronic properties of materials is especially important in view of the current advances in electronic device development that involve defect control and engineering at the nanometer level. This book surveys the properties, effects, roles and characterization of extended defects in semiconductors. The basic properties of extended defects (dislocations, stacking faults, grain boundaries, and precipitates) are outlined, and their effect on the electronic properties of semiconductors, their role in semiconductor devices, and techniques for their characterization are discussed. These topics are among the central issues in the investigation and applications of semiconductors and in the operation of semiconductor devices. The authors preface their treatment with an introduction to semiconductor materials and conclude with a chapter on point defect maldistributions. This text is suitable for advanced undergraduate and graduate students in materials science and engineering, and for those studying semiconductor physics.

The 6th International Conference on Laser Probing (LAP2012) had been held in Paris at the Institut Henri Poincare. It highlighted the state of the art in Laser Probing and reinforced the common ground and synergies among the different actors in the field. The Institut de Physique Nucleaire d'Orsay and the Grand Accelerateur National d'Ions Lourds in Caen had been in charge of the organization of this event, co-sponsored by the Institut National de Physique Nucleaire et de Physique des Particules (IN2P3) and the Laboratory Physique des 2 Infinis et des Origines (P2IO). Previously published as special issue of Hyperfine Interactions, vol. 216, 1-3.

Thermomechanics and Infra-Red Imaging represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials, MEMS and Nanotechnology; Optical Measurements, Modeling and, Metrology; Experimental and Applied Mechanics, and Engineering Applications of Residual Stress.

This volume will define the direction of eddy-current technology in nondestructive evaluation (NDE) in the twenty-first century. It describes the natural marriage of the computer to eddy-current NDE, and its publication was encouraged by favorable responses from workers in the nuclear-power and aerospace industries. It will be used by advanced students and practitioners in the fields of computational electromagnetics, electromagnetic inverse-scattering theory, nondestructive evaluation, materials evaluation and biomedical imaging, among others, and will be based on our experience in applying the subject of computational electromagnetics to these areas, as manifested by our recent research and publications. Finally, it will be a reference to future monographs on advanced NDE that are being contemplated by our colleagues and others. Its importance lies in the fact that it will be the first book to show that advanced computational methods can be used to solve practical, but difficult, problems in eddy-current NDE. In fact, in many cases these methods are the only things available for solving the problems. The book will cover the topic of computational electromagnetics in eddy-current nondestructive evaluation (NDE) by emphasizing three distinct topics: (a) fundamental mathematical principles of volume-integral equations as a subset of computational electromagnetics, (b) mathematical algorithms applied to signal-processing and inverse scattering problems, and (c) applications of these two topics to problems in which real and model data are used. This will make the book more than an academic exercise; we expect it to be valuable to users of eddy-current NDE technology in industries as varied as nuclear power, aerospace, materials characterization and biomedical imaging. We know of no other book on the market that covers this material in the manner in which we will present it, nor are there any books, to our knowledge, that apply this material to actual test situations that are of importance to the industries cited. It will be the first book to actually define the modern technology of eddy-current NDE, by showing how mathematics and the computer will solve problems more effectively than current analog practice.

Research for the development of more efficient photocatalysts has experienced an almost exponential growth since its popularization in early 1970's. Despite the advantages of the widely used TiO2, the yield of the conversion of sun power into chemical energy that can be achieved with this material is limited prompting the research and development of a number of structural, morphological and chemical modifications of TiO2 , as well as a number of novel photocatalysts with very different composition. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a systematic account of the current understanding of the relationships between the physicochemical properties of the catalysts and photoactivity. The already long list of photocatalysts phases and their modifications is increasing day by day. By approaching this field from a material sciences angle, an integrated view allows readers to consider the diversity of photocatalysts globally and in connection with other technologies. Design of Advanced Photocatalytic Materials for Energy and Environmental Applications provides a valuable road-map, outlining the common principles lying behind the diversity of materials, but also delimiting the imprecise border between the contrasted results and the most speculative studies. This broad approach makes it ideal for specialist but also for engineers, researchers and students in related fields.

This book provides essential information on metal forming, utilizing a practical distinction between bulk and sheet metal forming. In the field of bulk forming, it examines processes of cold, warm and hot bulk forming, as well as rolling and a new addition, the process of thixoforming. As for the field of sheet metal working, on the one hand it deals with sheet metal forming processes (deep drawing, flange forming, stretch drawing, metal spinning and bending). In terms of special processes, the chapters on internal high-pressure forming and high rate forming have been revised and refined. On the other, the book elucidates and presents the state of the art in sheet metal separation processes (shearing and fineblanking). Furthermore, joining by forming has been added to the new edition as a new chapter describing mechanical methods for joining sheet metals. The new chapter "Basic Principles" addresses both sheet metal and bulk forming, in addition to metal physics, plastomechanics and computational basics; these points are complemented by the newly added topics of metallography and analysis, materials and processes for testing, and tribology and lubrication techniques. The chapters are supplemented by an in-depth description of modern numeric methods such as the finite element method. All chapters have been updated and revised for the new edition, and many practical examples from modern manufacturing processes have been added.

In two parts, the book focusses on materials science developments in the area of 1) Materials Data and Informatics: - Materials data quality and infrastructure - Materials databases - Materials data mining, image analysis, data driven materials discovery, data visualization. 2) Materials for Tomorrow's Energy Infrastructure: - Pipeline, transport and storage materials for future fuels: biofuels, hydrogen, natural gas, ethanol, etc. -Materials for renewable energy technologies This book presents selected contributions of exceptional young postdoctoral scientists to the 4th WMRIF Workshop for Young Scientists, hosted by the National Institute of Standards and Technology, at the NIST site in Boulder, Colorado, USA, September 8 to September 10, 2014.

Catalysis and catalyst is a key technology to solve the problems in energy and environment issues to sustain our human society. We believe that comprehensive understanding of the catalysis and catalyst provides us a chance to develop a new catalyst and contributes greatly to our society. However, the ?eld of heterogeneous catalyst is dif?cultto study andstill stays behindmoredeveloped?elds ofchemistry such as organic and physical chemistries. This is a dilemma to the chemists who study the catalysis and catalyst. While we can accomplish the progress in the - dustrial application, the scienti?c understandingis not complete yet. A gap between the useful application and incomplete scienti?c understanding, however, becomes smaller and smaller in recent years. Because zeolites are ?ne crystals, and the structure is clearly known, the study on the catalysis using the zeolites is easier than those encountered in other catalysts such as metals and metal oxides. Very fortunately, zeolites provide us the strong acidity with the ?ne distribution which enables various useful catalytic reactions. When some metals and cations are loaded in close to the acid sites, these loadede- ments show extraordinarycharacters, and many catalytic reactions proceed thereon.

This volume contains the proceedings of the 5th International Symposium on Symmetries in Subatomic Physics (SSP2012), that was held in Groningen, The Netherlands from 18 till 22 June 2012. This sequence of symposia is now firmly connected with one of the main branches in fundamental nuclear and particle physics, i.e. in searches for physics beyond the Standard Model, focused on the (violation of) the discrete symmetries of Parity, Charge conjugation and Time reversal invariance. This field comes in various disguises: With large experimental facilities and large collaborations, as in LHC physics or in neutrino experiments, but also as table top experiments by small groups in the field of nuclear, atomic and molecular physics, such as in searches for a permanent electric dipole moments and atomic parity violation.

Bringing the practitioners of these divergent fields together gives a coherent overview and see the complementarities of the various approaches to the same question: why is the Standard Model what it is and what lies beyond it.

Steels and computer-based modelling are fast growing fields in materials science as well as structural engineering, demonstrated by the large amount of recent literature. Steels: From Materials Science to Structural Engineering combines steels research and model development, including the application of modelling techniques in steels. The latest research includes structural engineering modelling, and novel, prototype alloy steels such as heat-resistant steel, nitride-strengthened ferritic/martensitic steel and low nickel maraging steel. Researchers studying steels will find the topics vital to their work. Materials experts will be able to learn about steels used in structural engineering as well as modelling and apply this increasingly important technique in their steel materials research and development.

This volume presents contributions describing the micro- and macro-behaviours, new existence and uniqueness theorems, the formulation of multi-scale problems, etc. and now it is time to ponder again the state of matter and to discuss new trends and applications. The main focus is directed on the following items - Modelling and simulation of materials with significant microstructure, - Generalized continua as a result of multi-scale models, - Multi-field actions on materials resulting in generalized material models, and - Comparison with discrete modelling approaches

This book exposes a number of mathematical models for fracture of growing difficulty. All models are treated in a unified way, based on incremental energy minimization. They differ from each other by the assumptions made on the inelastic part of the total energy, here called the "cohesive energy". Each model describes a specific aspect of material response, and particular care is devoted to underline the correspondence of each model to the experiments. The content of the book is a re-elaboration of the lectures delivered at the First Sperlonga Summer School on Mechanics and Engineering Sciences in September 2011. In the year and a half elapsed after the course, the material has been revised and enriched with new and partially unpublished results. Significant additions have been introduced in the occasion of the course "The variational approach to fracture and other inelastic phenomena", delivered at SISSA, Trieste, in March 2013. The Notes reflect a research line carried on by the writer over the years, addressed to a comprehensive description of the many aspects of the phenomenon of fracture, and to its relations with other phenomena, such as the formation of microstructure and the changes in the material's strength induced by plasticity and damage. Reprinted from the Journal of Elasticity, volume 112, issue 1, 2013.