The liquid crystalline state may be identified as a distinct and unique state of matter which is characterised by properties which resembles those of both solids and liquids. It was first recognised in the middle of the last century through the study of nerve myelin and derivatives of cholesterol. The research in the area really gathered momentum, however, when as a result of the pioneering work of Gray in the early 1970's organic compounds showing liquid crystalline properties were shown to be suitable to form the basis of display devices in the electronic products. The study of liquid crystals is truly multidisciplinary and has attached the attention of physicists, biologists, chemists, mathematicians and electronics engineers. It is therefore impossible to cover all these aspects fully in two small volumes and therefore it was decided in view of the overall title of the series to concentrate on the structural and bonding aspects of the subject. The Chapters presented in these two volumes have been organised to cover the following fundamental aspects of the subject. The calculation of the structures of liquid crystals, an account of their dynamical properties and a discussion of computer simulations of liquid crystalline phases formed by Gay Berne mesogens. The relationships between molecular conformation and packing are analysed in some detail. The crystal structures of liquid crystal mesogens and the importance of their X ray scattering properties for characterisational purposes are discussed.

It was seven years ago this month when I had the pleasure of writing the Foreword to the Proceedings of the Eighth Conference on Thermal Conductivity hosted by TPRC/ Purdue University in 1968. Since then this Conference has developed to the point where one can say it has just entered a new phase. At its meeting in June 1975, the Board of Governors of the International Thermal Conductivity Conferences passed a resolution which formalizes two main policies that were felt to be desirable for a number of years, A key item of the resolution was for CINDAS/Purdue University to become the permanent Sponsor of the Conferences and in this capacity assist the Conferences in all matters which will result in the effective implementation of its goals and mission. In short, CINDAS will serve as a home base for the Conferences thus providing continuity and a permanent point of contact. CINDAS/Purdue University is pleased to accept this respons ibility as it is well within its mission to promote the advancement and dissemination of knowledge on thermophysica properties of matter. A second important aspect of the Conference resolution was the establishment of a policy to publish the Proceedings of future conferences on a continuing and uniform basis effective with this, the Fourteenth Conference."

Over 100 scientists met at the IBM Research Laboratory in San Jose. California for a symposium on the Physics and Chemistry of Liquid Crystal Devices. The two-day meeting was intellectually stimulating with excellent oral presentations and with person-to-person discussions. The applications of liquid crystals have developed dramatically in the past ten years. In these few years, they have moved from being a laboratory curiosity to products in the market place. The first commercial application (1940's) of liquid crystals was the preparation of a light polarizer. The second commercial application was their use as temperature sensors. The third major application of liquid crystals dealt with commercial displays. Other current applications include polymeric and graphitic fibers and light attenuators. The future of liquid crystals looks very promising indeed. One can expect to see new fibers of qualities which will be superior to those presently known. Graphitic fibers or other physical forms of graphitic materials will be used as catalytic surfaces for chemical synthesis. In the display area. one can expect to see television screens using liquid crystals. Larger displays than are now used in wrist watches and pocket calculators will become available. Liquid crystals using color displays will become commercially practical. Watches. calculators and television screens will have color.

In Number 20 of Modern Aspects of Electrochemistry, we present chapters whose organization is typical for the series: They start with the most fundamental aspects and then work to the more complex. Thus, Jerry Goodisman gives us an interesting contribution on a subject in which he is one of the pioneers, the electron overlap contribution to the double layer potential difference. Closely related to this theme, but not always imbued with knowledge ofit, is the electron transfertheory, treated in this volume by the experienced author A. M. Kuznetsov ofthe Frumkin Institute. H. P. Agarwal is a well-known figure in the field of faradaic rectification, which he originated, and he now teils us about the more recent thinking in the field. On the other hand, Hector D. Abruna comes relatively new to us, and his field, that of X-ray interactions with electrodes, is new, too, but probably augers the trend for the future. The photoelectrochemical reduction of CO2 , described here by Isao Taniguchi from Kumamoto University, is a subject which will have much practical importance as the greenhouse effect continues. Finally, alu mi nu m in aqueous solutions and the physics of its anodic oxide is a subject which seems ever with us, and is described in its latest guise by Aleksandar Despie and Vitaly P. Parkhutik.

Natural products like wool, leather or cotton are permeable to water vapor. Their complex fibrous structure makes it difficult to imitate this natural phenomenon by synthesis. This book discusses ways to obtain water vapor permeability by microporosity or through a hydrophilic structure. Various areas of application include the medical sector for implants and dialysis, the industrial sector for filtration or for processes requiring the slow release of substances, and the consumer sector for leather substitutes or performance textiles.

Dynamic Behavior of Materials represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials, MEMS and Nanotechnology; Optical Measurements, Modeling and, Metrology; Experimental and Applied Mechanics, Thermomechanics and Infra-Red Imaging, and Engineering Applications of Residual Stress.

Optical Measurements, Modeling, and Metrology represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials; MEMS and Nanotechnology; Experimental and Applied Mechanics, Thermomechanics and Infra-Red Imaging, and Engineering Applications of Residual Stress.

vi on geometric probability is included, students can be expected to create a few simple programs like those shown, but for other geometries. I am indebted to Tom Hare for critical reviews of the material and an endless enthusiasm to debate and derive stereological relationships; to John Matzka at Plenum Press for patiently instructing me in the intricacies of typesetting; to Chris Russ for helping to program many of these measurement techniques; and especially to Helen Adams, both for her patience with my creative fever to write yet another book, and for pointing out that the title, which I had intended to contrast to "theoretical stereology," can also be understood as the antonym of "impractical stereology." John C. Russ Raleigh,NC July, 1986 Chapter 1: Statistics 1 Accuracy and precision 1 The mean and standard deviation 5 Distributions 7 Comparison 13 Correlation 18 Nonlinear fitting 19 Chapter 2: Image Types 23 Planar sections 23 Projected images 25 Finite sections 28 Space-filling structures and dispersed phases 29 Types of images and contrast mechanisms 31 Sampling 32 Chapter 3: Manual Methods 35 Volume fraction 35 Surface density 38 Contiguity 41 Mean intercept length 42 Line density 43 Grain size determination 55 Curvature 48 Reticles to aid counting 49 Magnification and units 51 Chapter4: Size Distributions 53 Intercept length in spheres 53 Nonspherical shapes 57 Corrections for finite section thickness 59 Lamellae 61 Measurement of profile size 62 Nonspherical particles 69 vii Contents viii Chapter 5: Computer Metlwds 73

This is a book about mathematical modelling. It focuses on the modelling of the preparation of materials. Materials are important, of course, in an economic sense: the "goods" of goods-and-services are made of materials. This provides a strong incentive to produce good materials and to improve existing materials. Mathematical modelling can help in this regard. Without a doubt, modelling a materials processing operation is not strictly necessary. Materials synthesis and fabrication processes certainly existed before the invention of mathematics and computers, and well before the combined use of mathematics and computers. Modelling can, however, be of assistance--if done properly--and if used properly. The mathematical modelling described in this book is, at its root, a rather formal, structured way of thinking about materials synthesis and fabrication processes. It requires looking at a process as a whole. It requires considering everything that is or might be important. It requires translating the details of a given physical process into one or more mathematical equations. It requires knowing how to simplify the equations without over-simplifying them.

The 1989 Cryogenic Engineering Conference, meeting jointly with the International Cryogenic Materials Conference, was held on the campus of the University of California, Los Angeles from July 24 to 28. Professor T.H.K. Frederking was the conference chairman. The Conference had previously met at U.C.L.A. in 1962 and 1969. A special symposium, "A Half Century of Superfluid Helium," was a significant part of the program of CEC-89. We were especially fortunate to have Professor Jack Allen of the University of St. Andrews, Scotland present at the Conference; his paper, "Early Superfluidity in Cambridge, 1936 to 1939," was a delightful, often humorous account of the early experimental work with superfluid helium. Professors V.L. Ginzburg and J.L. Olesen could not be present for the Symposium, but provided papers which are published in these proceedings. The late Bill Fairbank, responding graciously to a last-minute invitation from Professor Frederking, presented a wonderful account of superfluid research in the United States in the post-war years.

This book is a product of the understanding I developed of stress analysis applied to plastics, while at work at L. J. Broutman and Associates (UBA) and as a lecturer in the seminars on this topic co-sponsored by UBA and Society of Plastics Engineers. I believe that by its extent and level of treatment, this book would serve as an easy-to-read desktop reference for professionals, as well as a text book at the junior or senior level in undergraduate programs. The main theme of this book is what to do with computed stress. To approach the theme effectively, I have taken the "stress category ap proach" to stress analysis. Such an approach is being successfully used in the nuclear power field. In plastics, this approach helps in the prediction of long term behavior of structures. To maintain interest I have limited derivations and proofs to a minimum, and provided them, if at all, as flow charts. In this way, I believe that one can see better the connection between the variables, assumptions, and mathematics.

Knowledge of the refractive indices and absorption coefficients of semiconductors is especially import in the design and analysis of optical and optoelectronic devices. The determination of the optical constants of semiconductors at energies beyond the fundamental absorption edge is also known to be a powerful way of studying the electronic energy-band structures of the semiconductors. The purpose of this book is to give tabulated values and graphical information on the optical constants of the most popular semiconductors over the entire spectral range. This book presents data on the optical constants of crystalline and amorphous semiconductors. A complete set of the optical constants are presented in this book. They are: the complex dielectric constant (E=e.+ieJ, complex refractive index (n*=n+ik), absorption coefficient (a.), and normal-incidence reflectivity (R). The semiconductor materials considered in this book are the group-IV elemental and binary, llI-V, IT-VI, IV-VI binary semiconductors, and their alloys. The reader will fmd the companion book "Optical Properties of Crystalline and Amorphous Semiconductors: Materials and Fundamental Principles" useful since it emphasizes the basic material properties and fundamental prinCiples.

The Conference on the Science and Technology of Thin Film Superconductors was conceived in the early part of 1988 as a forum for the specialist in thin film superconductivity. The conference was held on November 14-18, 1988, in Co lorado Springs, Co lorado. Al though many excellent superconductivity conferences had been convened in the wake of the 1986-1987 discoveries in high temperature superconductivity, thin film topics were often dispersed among the sessions of a more general conference agenda. The response to the Conference on the Science and Technology of Thin Film Superconductors confirmed the need for an extended conference devoted to thin film superconductors. These proceedings are a major contribution to the technnology of thin film superconductivity because of the breadth and quality of the articles provided by leaders in the field. The proceedings are divided into articles on laser deposition, sputtering, evaporation, metal organic chemical vapor deposition, thick film, substrate studies, characterization, patterning and applications, and general properties. Most of the articles discuss scientific issues for high temperature thin film superconductors, although the conference was to be a forum for technology and scientific questions for both low and high temperature superconductivity. For the first day of the 5 day conference, Lawrence Berkeley Laboratory had organized an excellent set of short courses in superconduc t ing thin film devices.

The atomic arrangements in condensed matter play an ever increasing role in many areas of science and technology - Materials Science and Engineering, Chemistry, Physics, Geology, Biology and Electrical, Civil, Mechanidtl and Chemical Engineering. Exciting discoveries in these fields in this century often stemmed from studies of these arrangements using diffraction: the structure and functions of DNA and other biological molecules, the configuration of polymer chains, the crystalline nature of metals and their imperfections, semiconductors and insulators, and -the links between their structures, their defects and material properties, and the interaction between materials and the environment. The broad, interdisciplinary character of diffraction studies makes them particularly exciting. With new tools such as the high-resolution electron microscope, new detectors, new techniques (such as EXAFS and glancing angle diffraction) and the new sources, the horizons of this field greatly expanded in the 1950's and 60's. Pulsed neutron sources and high intensity storage rings that came on the scene in the late 70's have opened up possibilities for new study to such vast horizons that it is hard to sit here writing this - there's so much to be done! Within the walls bounding each field of science or engineering, diffraction and structure is only one specialty. It is too easy for this topic to be developed in such a narrow way that sight is lost of the basic principles and broad possibilities.

Thermomechanics and Infra-Red Imaging represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials, MEMS and Nanotechnology; Optical Measurements, Modeling and, Metrology; Experimental and Applied Mechanics, and Engineering Applications of Residual Stress.

Scalar diffraction from a circular aperture is a ubiquitous problem that arises in a variety of disciplines, such as optics (lenses), acoustics (speakers), electromagnetics (dish antennas), and ultrasonics (piston transducers). The problem endures despite centuries of research because each new generation of researchers rediscovers it and adds some novel insight or new result to the existing literature. Scalar Diffraction from a Circular Aperture promises a few new results and several novel insights, particularly with regard to spatial averaging. Although the text emphasizes ultrasonic diffraction, the results and insights developed are general and may be applied to the many practical problems involving scalar diffraction from a circular aperture. Included are novel insights on mirror-image diffraction, autoconvolution diffraction, and coherent and incoherent averaging. Examples from ultrasonic imaging, a coherent imaging modality, are used to develop a fairly general theory that connects over a century of research on scalar diffraction from a circular aperture. The material is based on a synthesis of mathematics, physical optics, linear systems theory, and scalar diffraction theory. Thus, engineers, scientists, mathematicians, and students working in optics, acoustics, antenna design, biomedical engineering, non-destructive testing, and astronomy will find Scalar Diffraction from a Circular Aperture interesting, provocative, and useful.

This book represents a compilation and correlation of pertinent information currently available on polypropylene fibers and films. Specifically. the information presented con siders the effects of fiber and film processing conditions upon polypropylene fiber properties as well as the engineering properties of polypropylene relative to other commercial fibers. The data on polypropylene fibers were obtained almost entirely from recent technical periodicals. reports. and technical literature of various polypropylene manufacturers. Since much of the originalworkonpolypropylenewas conducted by the Montecatini Company in Italy. several pertinent trade journals were foreign-based and required translation. Ref erence is made to sources of information indicated in the appended list of references for the tables and figures; many figures were reproduced as they appeared in the original articles. When available, the origin of a fiber used in a specific analysis is presented by indicating the manufacturer's trade mark; a list of thesetrademarks as wellas several definitions are given in the appended section "Definitions and Fiber Trademarks." The more general term "fiber" is used in the work to include both monofilaments which are relatively coarse fibers approximately 40-1000 den, and textile fibers which have a denier between 1-15. Multifilament yarns consist of a group of textile fibers assembled together to form a single thread. Since fibers are Widely utilized in theform of yarns. consider able information on the properties of various yarns relative to polypropylene yarn is presented.

This book is written for those who would like to advance their knowledge beyond an introductory level of biomaterials or materials science and engineering. This requires one to understand more fully the science of materials, which is, of course, the foundation of biomaterials. The subject matter of this book may be divided into three parts: (1) fundamental structure-property relationships of man-made materials (Chapters 2-5) and natural biological materials, including biocompatibility (Chapters 6 and 7); (2) metallic, ceramic, and polymeric implant materials (Chapters 8-10); and (3) actual prostheses (Chapters 11 and 12). This manuscript was initially organized at Clemson University as classnotes for an introductory graduate course on biomaterials. Since then it has been revised and corrected many times based on experience with graduate students at Clemson and at Tulane University, where I taught for two years, 1981-1983, before joining the University of Iowa. I would like to thank the many people who helped me to finish this book; my son Y oon Ho, who typed all of the manuscript into the Apple Pie word processor; my former graduate students, M. Ackley Loony, W. Barb, D. N. Bingham, D. R. Clarke, J. P. Davies, M. F. DeMane, B. J. Kelly, K. W. Markgraf, N. N. Salman, W. J. Whatley, and S. o. Young; and my colleagues, Drs. W. Cooke, D. D. Moyle (Clemson G. H. Kenner (University of Utah), F. University), W. C. Van Buskirk (Tulane University), and Y.

This was the third meeting in the series of special topical conferences on Non-Metallic materials at low temperatures. The first meeting was in Munich in 1978, the second in Geneva (1980) and so Heidelberg 1984 seemed an obvious time to review some of the hopes and objectives of the earlier meetings. It is also appropriate to consider the changing needs of the cryogenic community and how best the theory and practice of Non-metallic materials can be applied to suit this dynamic young science. The aims and objectives of the International Cryogenic Materials Board in sponsoring this meeting remain the same. Namely, to provide a forum where practicing Engineers can meet with materials suppliers and researchers in an attempt to ensure that a real understanding exists between the two sides of the Cryogenic Materials Community. In this atmosphere, real problems can be addressed together with full discussions of tried and tested practical solutions. It is in this way that knowledge and confidence may grow hand in hand with the logical growth of the industry.

During August 24-27, 1993, approximately 60 scientists from the Americas, Europe and Japan, gathered in the city of Guanajuato, in the state of Guanajuato, Mexico, at the II Latin American Workshop on Magnetism, Magnetic Materials and their Applications. The group of scientists converging into the beautiful city of Guanajuato had come from Argentina, Chile, Brazil, Venezuela, Cuba, several places in Mexico, U. S. A. , Japan, Spain, France, Italy, Germany, Austria, Switzerland, and Denmark. The event attested to the success of the previous Workshop on Magnetism, Magnetic Materials and their Applications, held in Havana, Cuba, in 1991, as well as to the interest, level of activity and quality of the work being carried out in Latin America in the area of magnetism and magnetic materials. Equally important to everyone present was the fact that we had come to honor a friend, Professor L. M. Falicov, on his sixtieth birthday. The choice of a Latin American Workshop on magnetism as a Festschrift for Leo Falicov was, in our opinion, quite appropriate not only because of Leo's strong ties to Latin America, but also because of his superb contributions to science, and in particular, to magnetism. Professor Falicov was born in Buenos Aires, Argentina, where he spent a good part of his formative years.

The first U. S. Army Natick Research, Development and Engineering Center Atomic Force/Scanning Tunneling Microscopy (AFM/STM) Symposium was held on lune 8-10, 1993 in Natick, Massachusetts. This book represents the compilation of the papers presented at the meeting. The purpose ofthis symposium was to provide a forum where scientists from a number of diverse fields could interact with one another and exchange ideas. The various topics inc1uded application of AFM/STM in material sciences, polymers, physics, biology and biotechnology, along with recent developments inc1uding new probe microscopies and frontiers in this exciting area. The meeting's format was designed to encourage communication between members of the general scientific community and those individuals who are at the cutting edge of AFM, STM and other probe microscopies. It immediately became clear that this conference enabled interdisciplinary interactions among researchers from academia, industry and government, and set the tone for future collaborations. Expert scientists from diverse scientific areas including physics, chemistry, biology, materials science and electronics were invited to participate in the symposium. The agenda of the meeting was divided into three major sessions. In the first session, Biological Nanostructure, topics ranged from AFM ofDNA to STM imagmg ofthe biomoleeule tubulin and bacterialluciferase to the AFM of starch polymer double helices to AFM imaging of food surfaces.