The Army Materials and Mechanics Research Center of Water town, Massachusetts in cooperation with the Materials Science Group of the Department of Chemical Engineering and Materials Science of Syracuse University has conducted the Sagamore Army Materials Research Conference since 1954. The main purpose of these conferences has been to gather together over 150 scientists and engineers from academic institutions, industry and government who are uniquely qualified to explore in depth a subject of importance to the Department of Defense, the Army and the scientific community. This volume, RISK AND FAILURE ANALYSIS FOR IMPROVED PERFORMANCE AND RELIABILITY, addresses the areas of Techniques of Failure Analysis, Risk and Failure Analysis for Design Against Fracture, Risk and Failure Analysis for Design Against Fatigue, Elevated Temperature Effects, Environmental Effects, Systems Approach to Production Reliability Integration and Outlook - Emerging Needs and Techniques. We wish to acknowledge the dedicated assistance of Joseph M. Bernier of the Army Materials and Mechanics Research Center and Helen Brown DeMascio of Syracuse University throughout the stages of the conference planning and finally the publication of this book is deeply appreciated."

This volume, the proceedings of a 1998 international workshop, provides experimental evidence of the effects of correlation on the physical, chemical, and mechanical properties of materials, as well as the theoretical/computational methodology that has been developed for their study.

The synergism of the mechanics of nondestructive testing and the mechanics of materials response has great potential value in an era of rapid development of new materials and new applications for con ventional materials. The two areas are closely related and an advance in one area often leads to an advance in the other. As our understanding of basic principles increases, nondestructive testing is outgrowing the image of "black box techniques" and is rapidly becoming a legitimate technical area of science and engineering. At the present time, however, an understanding of the mechanics of nondestructive testing is lagging behind other advances in the field. The key to further development in the mechanics of nondestructive testing lies in the mechanics of the phenomena or response being investigated - a better understanding of materials response suggests better nondestructive test methods to investigate the response which, in turn, advances our understanding of materials response, and so on. With this approach in mind, the Materials Response Group of the Engineering Science and Mechanics Department at Virginia Polytechnic Institute and State University hosted a Conference on the Mechanics of Nondestructive Testing on September 10 through 12, 1980. Sponsors of the conference were the Army Research Office, the National Science Foundation, and the Engineering Science and Mechanics Department."

This volume constitutes the Proceedings of the November 7-9, 1977 Conference on PROCESSING OF CRYSTALLINE CERAMICS, held at North Carolina State University in Raleigh. It was the Fourteenth in a series of "University Conferences on Ceramic Science" initiated in 1964 and still coordinated by a founding group of four ceramic related institutions, of which North Carolina State University is a charter member, along with the University of California at Berkeley, Notre Dame University, and the New York State College of Ceramics at Alfred University. In addition, two other ceramic-oriented schools, the University of Florida and Case-Western Reserve University, have also hosted Conferences in the series. These research-oriented conferences, each uniquely concerned with a timely ceramic theme, have been well attended by audiences which typically were both inter national and interdisciplinary in character; their published Proceedings have been well received and are frequently cited. This three day conference was concerned with (a) scientific aspects of all process steps which must be combined and controlled effectively and sequentially in producing crystalline ceramics (both oxides and nonoxides), and (b) utilization of these principles in developing processes for several classes of advanced ceramics critical to present and future technology."

This book reviews recent advances in polymer swelling resulting from the use of novel microporous composite films. It offers a new approach to understanding sorption processes in polymer-liquid systems based on the molecular structures of the sorbed molecules and the repeat unit of the sorbent polymer. It is shown how the adsorption parameters obtained in these studies relate meaningfully with the Flory-Huggins interaction parameters. This implies that these adsorption parameters have relevance not only for swelling and drying of polymers, but also for other phenomena in which molecular sorption plays an important role, such as in chromatography and in membrane permeation.

Nanoindentation, Third Edition gives a detailed account of the most up-to-date research in this important field of materials testing. As in previous editions, extensive theoretical treatments are provided and explained in a clear and consistent manner that will satisfy both experienced and novice scientists and engineers. Additionally, numerous examples of the applications of the technique are provided directly from manufacturers of nanoindentation instruments. A helpful series of appendices provides essential reference information that includes a list of frequently asked questions. The new edition has been restructured to provide results of the latest research and developments in the field of mechanical testing while retaining the essential background and introductory, but authoritative nature, of the previous editions. The new edition also expands on the instrumentation and applications chapters by including material sourced direct from the instrument manufacturers in this field. Aimed at graduate student level, this book is designed to fill a need associated with the use of nanoindentation as a quantitative test method for mechanical properties of small volumes of materials.

The international seminar "Material Behavior and Physical Chemistry in Liquid Metal Systems" was organized by the Institute of Materials and Solid State Research of the Karlsruhe Nuclear Research Center (Karlsruhe, Federal Republic of Germany). The seminar was held at the Nuclear Engineering School of the center on March 24-26, 1981. The aim of the seminar was to give metallurgists, chemists,. and physicists working in different areas of the science and technology of liquid metals an opportunity to discuss the basic work and the need for further work in this field. Since the seminar was held near one of the laboratories which for the last few years has been engaged in liquid alkali metal studies, partic ipants also had an opportunity to observe modern equipment for liquid alkali metal research. Interest in the application of liquid metals as working fluids in energy production, conversion, and storage is increasing. The technology has already demonstrated its high standards, which make possible the operation of large sodium-cooled fast reactors. Past conferences have shown, however, that there is still a lack of basic knowledge and understanding. Therefore, the aim of the present seminar was to discuss basic work in detail, and most of the papers contributed to this objective.

Natural products like wool, leather or cotton are permeable to water vapor. Their complex fibrous structure makes it difficult to imitate this natural phenomenon by synthesis. This book discusses ways to obtain water vapor permeability by microporosity or through a hydrophilic structure. Various areas of application include the medical sector for implants and dialysis, the industrial sector for filtration or for processes requiring the slow release of substances, and the consumer sector for leather substitutes or performance textiles.

Awarenes s of the great significance of surface consti- tution in understanding the behavior and perforITlance of ITlaterials has been growing in proportion to the ITleans which have becoITle available for surface study. Recent years have seen iITlportant advances in analytical tools and ITlethods; their applications to date will certainly suggest ITlany other fruitful lines of investigation. The Conference "Surfaces and Interfaces of Glass and CeraITlics" held at the New York State College of CeraITlics at Alfred University under the sponsorship of the U. S. ArITly Research Office, DurhaITl, and the National Aeronautics and Space AdITlinistration, in August 1973, was tenth in the Uni- versity Series in CeraITlic Science, held in rotation aITlong North Carolina State University, the University of California at Berkeley, the University of Notre DaITle and Alfred Uni- versity. The chapters are arranged in order of their particular eITlphasis beginning with those principally concerned with analytical ITlethods. Chapters dealing with friction and wear follow, highly topical in the present-day concern with effi- cient use of energy in finishing processes, on the one hand, and the avoidance of preITlature failure by frictional daITlage to ITloving parts on the other. Surface reactions are then considered, including the iITlportant questions of physiological interactions with ceraITlic candidates for prosthetic applica- tions. Material-ITlaterial interfaces and transition zones are discussed through exaITlples which include grain bound- aries in ceraITlics as well as interfaces aITlong various solid, liquid and gaseous phases.

The Army Materials and Mechanics Research Center has conducted the Sagamore Army Materials Research Conferences, in cooperation with the Metallurgical Research Laboratories of the Department of Chemical Engineering and Metallurgy of Syracuse University, since 1954. The purpose of the conferences has been to gather together scientists and engineers from academic institutions, industry, and government who are uniquely qualified to explore in depth a subject of importance to the Army, the Department of Defense and the scientific corr.munity. This volume, Surfaces and Interfaces ll: Physical and Mechanical Properties, can be considered a continuation, or perhaps an extension, of the information contained in Surfaces and Interfaces I: Chemical and Physical Characteristics. The emphasis in this volume is focused on: the technological significance of surfaces and interfaces; surface sensitive mechanical properties; environment-sensitive properties; control of grain structure; and composite materials. It is felt that the rather ambitious undertaking of the program committee to place the role of "surfaces and interfaces" in its proper context has been achieved. The balance between basic research findings and more applied research allows the reader a certain degree of latitude in the use of the two volumes. The continued active interest and support of these conferences by Col. C. T. Riordan, Commanding Officer, Dr. E. Scala, Technical Di rector, and J. F. Sullivan, Deputy Technical Director, of the Army Materials and Mechanics Research Center is appreciated."

Included is a presentation of configurational forces within a classical context and a discussion of their use in areas as diverse as phase transitions and fracture.

This volume constitutes the written proceedings of the Third International Conference on Materials SCience, held under the sponsorship of the Accademia Nazionale dei Lincei as the XIII summer course of the G. Donegani Foundation at Tremezzo, Italy, on September 4-15, 1972. The course of lectures was designed for scientists and engineers "d th a, wrking knowledge of electronic materials, who sought to extend their knowledge of the newest developments in the field. The rapid pace of research and exploratory development in electronic materials has led to a preSSing need for continuing awareness and assessment of new electronic materials, as well as renewal of information in the more traditional areas. Three classes of electronic materials were selected for the course. Semiconductors provide the foundation for solid state electronics and semiconductor devices represent the most sophisti cated and advanced application of materials science and engineering known to modern technology. Yet, the march of progress in semi conductors continues, unabated - new semiconductor materials are in the research stage, new process technology is being developed, and new devices are being conceived. The second class of materials dealt with in the course, magnetic alloys and insulators, also has a firm application base; for example, computer performance is often measured in terms of the size of the magnetic memory. The tailoring of materials to provide particular combinations of desired magnetic properties is an integral part of the development of the electronics, just as in the case of semiconductors."

Everything flows, so rheology is a universal science. Even if we set aside claims of such width, there can be no doubt of its importance in polymers. It joins with chemistry in the polymerisation step but polymer engineering is supreme in all the succeeding steps. This is the area concerned with the fabrication of the polymer into articles or components, with their design to meet the needs in service, and with the long and short term performance of the article or component. This is a typical area of professional engineering activity, but one as yet without its proper complement of professional engineers. An understanding of polymer rheology is the key to effective design and material plus process selection, to efficient fabrication, and to satisfactory service, yet few engineers make adequate use of what is known and understood in polymer rheology. Its importance in the flow processes of fabrication is obvious. Less obvious, but equally important, are the rheological phenomena which determine the in-service performance. There is a gap between the polymer rheologist and the polymer engineer which is damaging to both parties and which contributes to a less than satisfactory use of polymers in our society. It is important that this gap be filled and this book makes an attempt to do so. It presents an outline of what is known in a concise and logical fashion. It does this starting from first principles and with the minimum use of complex mathematics.

A number of significant changes have occurred in Advances in Solar Energy since Volume 1 appeared in 1982. The delays in publication of the second volume are the result of reorganization of the American Solar Energy Society, and the negotiation of a new publishing arrangement. Beginning with this volume, Advances is now published jointly by the Society and Plenum Press. The Editorial Board has been enlarged to be more representative of the different fields of solar energy conversion. Production of Advances is being expedited through the use of modern word processing equipment and the 'lEX typesetting-editing program. We have gone to a single-column format to ease the problems of presenting long equations, and we expect that the user of the volume will find it easy to read. The use of 'lEX will make last minute updates possible. The external appearance of the volume matches that of Volume 1. We expect that future volumes of this annual will be proceeding on schedule. We invite comments from users and correspondence from prospective authors of critical reviews. Karl W. Boer John A. Duffie CONTENTS CHAPTER 1 The Measurement of Solar Radiation Ronald Stewart, Daniel W. Spencer and Richard Perez 1.1 Abstract 1 1.2 Characteristics of Pyranometers ....................................... . 2 1.3 General Features of a Pyranometer ................................... . 3 1.3.1 Instrument Sensitivity 4 1.3.2 Response with Time 4 1.3.3 Sensitivity 4 1.3.4 Responsivity ................................................. .

The International Thermal Expansion Symposium was started in 1968 with the initiative of Messrs. R. K. Kirby and P. S. Gaa1. These Symposia cover the deve10pments and advances in theoretica1 and experimental studies of the thermal expansion of so lids and its relation to other re1ated properties, and provide a broad1y based forum for researchers active1y working in this fie1d to convene on a regular basis to exchange their ideas and experiences and report their findings and resu1ts. The Symposia have been se1f-perpetuating and are an examp1e of how a technica1 community with a common purpose can transcend the invisible artificia1 barriers between discip1ines and gather togeth- er in increasing numbers without the need of national publicity and continuing funding support, when they see something worthwhi1e going on. Of the first five Symposia on1y three pub1ished formal Pro- ceedings. However, effective with the Sixth Symposium in 1977 when our Center for Information and Numerica1 Data Analysis and Synthesis (CINDAS) of Purdue University became the permanent Spon- sor of the Symposia, a po1icy of pub1ishing formal Proceedings on a continuipg and uniform basis has been estab1ished. Thus, inc1ud- ing the present vo1ume, the fo110wing formal Proceedings have been pub1ished: Publisher Symposium Tit1e of Vo1ume and Year and Year 2nd SYMPOSIUM ON THERMAL EXPANSION OF American Institute SOLIDS, Journal of App1ied Physics, of Physics (1970) (1970) 41 (13), pp. 5043-5154 American Institute 3rd THERMAL EXPANSION - 1971 of Physics (1972) (1971) AlP Conference Proceedings No.

The International Conference on Fracture Mechanics Technology Applied to Material Evaluation and Structure Design was held in Melbourne, Australia, from August 10 to 13, 1982. It was sponsored jointly by the Australian Fracture Group and Institute of Fracture and Solid Mechanics at Lehigh University. Pro fessor G. C. Sih of Lehigh University, Drs. N. E. Ryan and R. Jones of Aeronau tical Research Laboratories served as Co-Chairmen. They initiated the organiza tion of this international event to provide an opportunity for the practitioners, engineers and interested individuals to present and discuss recent advances in the evaluation of material and structure damage originating from defects or cracks. Particular emphases were placed on applying the fracture mechanics tech nology for assessing interactions between material properties, design and opera tional requirements. It is timely to hold such a Conference in Australia as she embarks on technology extensive industries where safeguarding structures from pre mature and unexpected failure is essential from both the technical and economical points. view The application of system-type approach to failure control owes much of its success to fracture mechanics. It is now generally accepted that the discipline, when properly implemented, provides a sound engineering basis for accounting in teractions between material properties, design, fabrication, inspection and op erational requirements. The approach offers effective solutions for design and maintenance of large-scale energy generation plants, mining machineries, oil ex ploration and retrieval equipments, land, sea and air transport vehicles."

The investigation of scattering phenomena is a major theme of modern physics. A scattered particle provides a dynamical probe of the target system. The practical problem of interest here is the scattering of a low energy electron by an N-electron atom. It has been difficult in this area of study to achieve theoretical results that are even qualitatively correct, yet quantitative accuracy is often needed as an adjunct to experiment. The present book describes a quantitative theoretical method, or class of methods, that has been applied effectively to this problem. Quantum mechanical theory relevant to the scattering of an electron by an N-electron atom, which may gain or lose energy in the process, is summarized in Chapter 1. The variational theory itself is presented in Chapter 2, both as currently used and in forms that may facilitate future applications. The theory of multichannel resonance and threshold effects, which provide a rich structure to observed electron-atom scattering data, is presented in Chapter 3. Practical details of the computational implementation of the variational theory are given in Chapter 4. Chapters 5 and 6 summarize recent appli cations of the variational theory to problems of experimental interest, with many examples of the successful interpretation of complex structural fea tures observed in scattering experiments, and of the quantitative prediction of details of electron-atom scattering phenomena."

The need for reliable data on thermophysical and thermal optical properties of solid materials grows continually and increasingly. Existing property data, except for selected pure elements and for some simple alloys and compounds, are often not reliable, so in many cases the need for correct and acceptably accurate information can only be met through the measurement of a given property. The measurement-that is, the selection of the measurement method, building or purchase of the apparatus, and the measurement procedure itself carries many hidden hazards because methods and their variants are numerous and not appropriate for all materials and temperature ranges, and have many subtle sources of systematic errors, known only to those who have thoroughly studied them. The need for a concise yet complete reference work describing thermo physical and thermal optical property measurement techniques, and ultimately, reliable and detailed directions for property measurement discussed at the Sixth European Thermophysical Properties Conference in Dubrovnik, Yugoslavia in 1978, led its International Organizing Committee to launch an international cooperative project with these objectives. This reference work, the Compendium of Thermophysical Property Measurement Methods, is the result of the first phase of work on this program. It is a summary of the state-of-the-art methods for the measurement of thermal and electrical conductivity, thermal diffusivity, specific heat, thermal expansion, and thermal radiative properties of solid materials, from room temperature to very high temperatures."

The idea of a NATO Science Committee Institute on "Materials for Advanced Batteries" was suggested to JB and DWM by Dr. A. G. Chynoweth. His idea was to bring together experts in the field over the entire spectrum of pure research to applied research in order to familiarize everyone with potentially interesting new systems and the problems involved in their development. Dr. M. C. B. Hotz and Professor M. N. Ozdas were instrumental in helping organize this meeting as a NATO Advanced Science Institute. An organlzlng committee consisting of the three of us along with W. A. Adams, U. v Alpen, J. Casey and J. Rouxel organized the program. The program consisted of plenary talks and poster papers which are included in this volume. Nearly half the time of the conference was spent in study groups. The aim of these groups was to assess the status of several key aspects of batteries and prospects for research opportunities in each. The study groups and their chairmen were: Current status and new systems J. Broadhead High temperature systems W. A. Adams Interface problems B. C. H. Steele Electrolytes U. v Alpen Electrode materials J. Rouxel These discussions are summarized in this volume. We and all the conference participants are most grateful to Professor J. Rouxel for suggesting the Aussois conference site, and to both he and Dr. M. Armand for handling local arrangements.

The third International Symposium on the Scientific Basis for Nuclear Waste Management was held in Boston, Massachusetts, on November 17-20, 1980, as part of the Annual Meeting of the Materials Research Society. The purpose of this Symposium was to provide an interdisciplinary forum for the discussion of scientific research dealing with all levels and types of radioactive wastes and their management. Since its inception in 1978, this annual Symposium has provided a unique opportunity for scientists of widely differing backgrounds to share in such discussions. The proceedings of the first two meetings were published as Volumes 1 and 2 in this series. The fourth Symposium is scheduled to be held in the autumn of 1981. The efforts of many people went into making this meeting a success. The scope of the 1980 Symposium was guided by the follow ing Steering Committee: K. J. Notz (Chairman), Oak Ridge National Laboratory, USA G. H. Daly, Department of Energy, USA D. E. Ferguson, Oak Ridge National Laboratory, USA R. H. Flowers, Atomic Energy Research Establishment, UK F. Girardi, Ispra Establishment, Italy T. Ishihara, Radioactive Waste Management Center, Japan R. W. Lynch, Sandia Laboratories, USA S. A. Mayman, Atomic Energy of Canada Ltd., Canada G. J. McCarthy, North Dakota State University, USA E. Merz, Kernforschunganlage Jillich, FRG L. Nilsson, KBS Project, Sweden D. M. Rohrer, Nuclear Regulatory Commission, USA R. Roy, Pennsylvania State University, USA T. "E. Scott, Ames Laboratory, USA C."

The title of this volume implies a progression of sorts from species of molecular size to a product described on the basis of continuum prop erties. The difference in approach from the standpoint of molecular be havior, on the one hand-more the forte of chemists-and from the standpoint of large-scale properties, on the other-more the province of chemical engineers and materials scientists-represents a severe cultural divide, but one with much potential for creative input from both sides. Chapter 1 of this volume attempts a broad survey of trends toward the synthesis of large, well-defined molecular systems with interesting physical, chemical, or material properties. Review articles with more de tailed treatments are emphasized. In Chapter 2, Newkome and Moore field summarize work on synthesis of /I cascade" molecules. Next, Denti, Campagna, and Balzani describe the synthesis of assemblies with con nected metal-containing chromophore units which transmit electrons or electronic energy in defined ways. In Chapter 4 Wuest describes the con struction of hydrogen-bonded organic networks, and in Chapter 5 Michl defines a molecular-level construction set. Finally, Jaszczak points out how nature's attempts over geological time spans are emulated by recent human synthetic activity in the fullerene arena, through the appearance of various morphologies of natural graphite. The book concludes with a method for describing fractal-like mole cules, and an index based on the method for appropriate compounds described in the text."

The challenges of space exploration are a great stimulus to our technologies today. Development of successful aerospace programs has required the best efforts of the scientist and engineer in almost every discipline. Not so long ago, it truly could be said that designers are trying to develop tomorrow's vehicles with yesterday's materials. Unfortunately, we find that the situation remains nearly the same today. The purpose of this conference was to identify materials, proces ses, and methods that show the greatest potential in future space technology and to define the gap between mission requirements and materials application. Of the many properties of materials, the one in which the largest gap between fundamental understanding and practical application appears to exist is the mechanical property, particularly of crystalline materials. The emphasis on crystalline materials is a natural one. It is these materials which are used primarily when demands are placed on mechanical strength, especially at elevated temperatures. The advent of space exploration requires the utilization of materials in environments and under conditions that are a challenge to the resourcefulness and ingenuity of the scientist and engineer. The scientist can, as a result of the past thirty years' work, relate mechanical properties to the formation, motion, and interaction of individual crystalline defects, such as vacancies, interstitials, and dislocations. Furthermore, he can, by controlled preparation of his materials, confine his studies to those cases in which the concentration of crystal defects is conveniently low.