Adhesives in general and structural adhesives in particular are the subjects of much academic interest as well as commercial importance. Structural bonding, as a method of joining, offers a number of advantages over mechanical fastening. However, in order to achieve satisfactory results, the proper adhesive must be selected and the appropriate bonding procedures followed. The purpose of Structural Adhesives: Chemistry and Technology is to review the major classes of structural adhesives and the principles of adhesion and bonding as these relate to structural joints. Each chapter provides an overview of the topic under discussion with a list of references to the relevant literature. In addition to describing the chemistry involved, other aspects of structural adhesive technology are covered, such as formula tion, testing, and end uses. Some structural adhesives, especially epoxies and phenolics, have a long history of successful use and are now widely employed. Others, such as the structural acrylics and cyanoacrylates, are beginning to gain industrial acceptance. Urethanes and anaerobics have limited but important uses, while high-temperature adhesives are still largely in the research and development stage."

More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100 DegreesC, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

In The New Superconductors, Frank J. Owens and Charles P. Poole, Jr., offer a descriptive, non-mathematical presentation of the latest superconductors and their properties for the non-specialist. Highlights of this up-to-date text include chapters on superfluidity, the latest copper oxide types, fullerenes, and prospects for future research. The book also features many examples of commercial applications; an extensive glossary that defines superconductivity terms in clear language; and a supplementary list of readings for the interested lay reader.

These volumes, 3 and 4, of Fracture Mechanics of Ceramics con stitute the proceedings of an international symposium on the frac ture mechanics of ceramics held at the Pennsylvania State Univer sity, University Park, PA on July 27, 28, and 29, 1977. Volumes 1 and 2 were published previously as the proceedings of a sympo sium of the same name held July 11, 12, and 13, 1973, also at Penn State. All four volumes published to date concentrate on the fracture aspects of the mechanical behavior of brittle'ceramics in terms of the characteristics of cracks. The program chairmen gratefully acknowledge the financial as sistance for the symposium provided by the Office of Naval Re search, the Energy Research and Development Administration, and the Army Research Office. Without their support the quality and mag nitude of this conference simply would not have been possible. Numerous individuals contributedto the success of the con ference, but unfortunately they cannot all be listed here. However the program chairmen would especially like to recognize the contri butions of Penn State Conference Coordinator, Mr. Ronald Avillion, whose expertise in planning and organization was indispensable; Dr. Fred R. Matson for his interesting after dinner speech; and Drs. A. M. Diness, J. C. Hurt, and D. W. Readey for their en couragement and valuable suggestions regarding the program. Finally, we wish to also thank our joint secretaries for the patience and help in bringing these proceedings to press."

To the biochemist, water is, of course, the only solvent worthy of consideration, because natural macromolecules exhibit their remarkable conformational properties only in aqueous media. Probably because of these remarkable properties, biochemists do not tend to regard proteins, nucleotides and polysaccharides as polymers in the way that real polymer scientists regard methyl methacrylate and polyethylene. The laws of polymer statistics hardly apply to native biopolymers. Between these two powerful camps, lies the No-man's land of water soluble synthetic polymers: here, we must also include natural polymers which have been chemically modified. The scientific literature of these compounds is characterized by a large number of patents, which is usually a sign of little basic understanding, of 'know-how' rather than of 'know-why'. Many of the physical properties of such aqueous solutions are intriguing: the polymer may be completely miscible with water, and yet water is a 'poor' solvent, in terms of polymer parlance. ~kiny of the polymers form thermorever sible gels on heating or cooling. The phenomena of exothermic mixing and salting-in are common features of such systems: neither can be fully explained by the available theories. Finally, the eccentric behaviour of polyelectrolytes is well documented. Despite the lack of a sound physico-chemical foundation there is a general awareness of the importance of water soluble vinyl, acrylic, polyether, starch and cellulose derivatives, as witnessed again by ~he vast patent literature.

The IUTAM-Symposium on "Finite Inelastic Deformations - Theory and Applications" took place from August 19 to 23, 1991, at the University of Hannover, Germany, with 75 participants from 14 countries. Scope of the symposium was a fundamental treatment of new developments in plasticity and visco-plasticity at finite strains. This covered the phenomenological material theory based on continuum mechanics as well as the treatment of microstructural phenomena detected by precise experimental datas. In a restricted number, lectures on new experi mental facilities for measuring finite strains were also implemented into the symposium. Another important topic of the symposium was the treatment of reliable and effective computational methods for solving engineering problems with finite inelastic strains. Wi thin this context it was an essential feature that theory, numerical and computational analysis were be seen in an integrated way. In total 9 sessions with 37 lectures, many of them given by well known keynote-lecturers, and a poster session with 10 contributions met fully our expectations of a high ranking up-to-date forum for the interaction of four topics, namely the physical and mathematical modelling of finite strain inelastic deformations including localizations and damage as well as the achievements in the numerical analysis and implementation and the solution of complicated engineering systems. Special and important features were reliable material datas from macroscopic and microscopic tests as well as test results of complex engineering problems, like deep drawing and extrusion."

The occurrence of superconductivity among the d- and f-band metals remains one of the unsolved problems of physics. The first Rochester conference on this subject in October 1971 brought together approximately 100 experimentalists and theorists, and that conference was considered successful; the published proceedings well-represented the current research at that time and has served as a "handbook" to many. In the four and one half years since the first conference, impressive progress has been made in many areas (although Berndt Matthias would be one of the first to point out that raising the m"aximum transition temperature by a significant amount was not one of them). For a variety of reasons, I decided that it was time for a Second Rochester Conference on Superconductivity in d- and f-Band Metals and it was held on April 30 and May 1, 1976. It would appear that this conference was even more successful judging from the quality of the talks and various comments made to me. I believe that this was due to the fact that the subject matter is exciting and that the timing was particularly appropriate for several areas of research that were discussed. However, I cannot rule out other factors such as the one advanced humorously by J.

Minsk, Belarus was the site of the NATO ARW on Wide Band-Gap electronic Materials May 3 through 6,1994; 143 participants and observers from 15 countries met for the NATO Advanced Research Workshop on Wide Band-Gap Electronic Materials (NATO ARW). The meeting was marked by a remarkable free exchange between east and west on these topics by revealing technical achievements not widely known or available in the west because ofpast political climate or present economic realities in the Newly IndependentStates. The topics ranged from electron doping of diamond, n-type diamond, negative electron affinity ofdiamond, applications of aluminum nitride, doping ofboron nitride, wideband gap electronic applications, to nanophase diamond. Of the many high-lights during the scientific meetings, an energy sub band due to defects in the diamond lattice was described. These defects areresponsible for the light emission from a diamond Light Emitting Diode (LED) which was demonstrated at the NATO ARW. This diamond LED can emitred, green, and blue light. The potential for "high tech" nanostructure electronic devices such as quantum transistors was described which mightsome day revolutionize electronics. The prospectsofaluminum nitride for acusto devices, piezodevices, and electroluminescencedevices were discussed.

All significant studies agree that aqueous corrosion continues to cost nations dearly in almost every area of technological endeavour. Over the past ten years, microcomputers have facilitated an explosion in the power of modelling as a technique in science and engineering. In corrosion they have enabled better understanding of polarization curves, they have transformed the scope of electrochemical impedance measurements and they have placed a large range of electrochemistry at the fingertips of the corrosion scientist. This book focuses on the models, rather than the computing, which have been made possible during the past decade. Aimed at all those with an interest in corrosion and its control, the book draws together the range of new modelling strands, suggests new avenues of approach and generates further momentum for improvements to corrosion management, whether by increased understanding of atomistic processes or by control of large plant.

The first edition of this book (1958) described an analytical situation which had existed for a number of years for maintaining quality control on vulcanizates of natural rubber although the situation had recently been disturbed by the introduction of a range of synthetic rubbers which required identification and quantitative estimation. For the former purpose 'wet' chemistry, based on various imperfectly understood organic reactions, was pressed into service. Alongside this was the first introduction of instrumental analysis, using the infrared spectra of either the polymers or, more usually, their pyrolytic products to 'fingerprint' the material. The identification of a range of organic accelerators, antioxidants and their derivatives which had been intro duced during the 1920s and 30s was, in the first edition, dealt with by a combination of column chromatography and infrared spectroscopy or by paper chromatography. Quantitative procedures were, however, still classical in the tradition of gravimetric or volumetric assays with an initially weighed sample yielding, after chemical manipulation, a carefully precipitated, dried and weighed end product, or a solution of known composition whose weight or titre, as a percentage of the initial sample, quantified the function being determined. The second edition of this work (1968) consolidated the newer techni ques which had been introduced in the first without adding to them although, in other applications of analytical chemistry, instrumental analysis had already brought about a transformation in laboratory practice."

J.-P. CALISTE, A. TRUYOL AND J. WESTBROOK The Series, "Data and Knowledge in a Changing World", exemplifies CODATA's primary purpose of collecting, from widely different fields, a wealth of information on efficient exploitation of data for progress in science and technology and making that information available to scientists and engineers. A separate and complementary CODATA Reference Series will present Directories of compiled and evaluated data and Glossaries of data-related terms. The present book "Thermodynamic Modeling and Materials Data Engineering" discusses thermodynamic, structural, systemic and heuristic approaches to the modeling of complex materials behavior in condensed phases, both fluids and solids, in order to evaluate their potential applications. Itwas inspired by the Symposium on "Materials and Structural Properties" held during the 14th International CODATA Conference in Chambery, France. The quality of the contributions to this Symposium motivated us to present" a coherent book of interest to the field. Updated contributions inspired by Symposium discussions and selections from other CODATA workshops concerning material properties data and Computer Aided Design combine to highlight the complexity of material data issues on experimental, theoretical and simulation levels Articles were selected for their pertinence in three areas. Complex data leading to interesting developments and tools such as: * new developments in state equations and their applications, * prediction and validation of physical and energy data by group correlations for pure compounds, * modeling and prediction of mixture properties.

The beneficial impact of the European communities involvement in scientific research and technology is wide-ranging and pervasive. There are high hopes of major advances in scientific knowledge and technological processes, while the emergence of a genuine tradition of collaborative research holds out great and continuing promise for the future. Close, frequent and long-term cooperation between universities, research centres and industry is already generating new synergies, forging a truly European scientific community. Many of tomorrows industrial developments, destined to be determinant for our economic success and prosperity, will spring from this research. The Concerted European Action on Magnets - CEAM - project is a prime example of collaborative research and development. Financed from the Communities STIMULATION action and implemented with the help of EURAM, the advanced materials programme, CEAM will bestow great benefits on European industrial competitiveness, providing a channel for high quality basic research to find its way into commercial products. This remarkable cooperative enterprise brought t gether 58 laboratories and more than 120 scientists and englneers in a sustained thirty month effort. It spanned every aspect of new iron-based high performance magnets from theoretical modelling of their intrinsic magnetic properties to the design and construction of novel electrical devices and machines. Besides adding a new European dimension to advanced magnetic technology, CEAM also ensured that a whole new generation of young researchers and technicians have been trained in applied magnetism.

Optical measurement techniques have been stimulated in recent years by the advent of lasers and also by modern electro-optical devices. Despite the considerable research and developments in this field, these techniques are not widely appreciated by engineers, who are often unaware of their versatility. This book provides a single comprehensive source giving the basic science and technology involved in the implementation of these latest methods, for use by industrial and research engineers, in the solution of measurement problems and the design of measurement systems. The book covers the most recent and useful innovations and emphasises applications to practical problems. The emphasis in each chapter has been placed on the transducer aspect, i.e. on the instrumentation necessary to perform specific tasks, so that all the necessary components-basic theory, practical details and devices, application to actual problems. are included, as well as information concerning probable sensitivity, accuracy, etc. Simple explanations of complex physical phenomena have been used instead of rigorous treatments, the latter usually being available from the references associated with each chapter. Engineers and applied scientists are often faced with the measurement of a wide range of parameters, e.g. dimension, displacement, strain, force, pressure, torque, fluid flow, fluid level, time dependent effects, etc., and optical methods may seem inappropriate at first glance, but all those mentioned are capable of evaluation using optics and most physical parameters are susceptible to this type of measurement."

Only in the past decade, has the scientific and industrial community come to realize the potential utility offered by inorganic and organometallic polymers (lOPs) for a wide variety of applications. This potential is especially important for applications requiring multifunctional polymers, e.g. for smart materials, nanotechnology, biomimetic systems (neural networks), photonics, etc; lOPs with special properties. The breadth of perfor- mance requirements for the individual areas of application is enormous as are the problems pertaining to generating low cost, high performance, processable lOPs. This book represents the third in a series of books we have edited on inorganic and organometallic polymer chemistry (1. Transfonnation of Organometallics into Common and Exotic Materials, NATO ASI Series Vol 141. 2. Inorganic and Organometallic Oligo- mers and Polymers, Kluwer publications). In this series, we have attempted to identify important trends that help to define for the reader; the potential scope of lOP science as well as the problems that must be surmounted to realize this potential. The focus of the work presented in the following chapters is primarily on the relationships between lOPs and solid state materials with special properties, e.g. conducting, magnetic, photonic and structural materials.

This volume constitutes the proceedings of the Fourth International Workshop on Materials Processing at High Gravity, held at Clarkson University, May 29 to June 2, 2000. There were 73 attendees from 16 countries. Since the topics extended well beyond materials processing, it was felt appropriate to name this proceedings "Centrifugal Processing." Processing by Centrifugation includes the traditional bench-scale centrifuges, as well as all rotating systems utilizing the centrifugal and Coriolis forces to provide unique performance. Centrifugation led to the formation of sticky porous Teflon membranes, as well as improved polymeric solar cells. Centrifugation on large equipment improved the chemical vapor deposition of diamond films, influenced the growth and dissolution of semiconductor crystals, and elucidated the influence of gravity on coagulation of colloidal Teflon. A million g centrifuge was constructed and used to study sedimentation in solids and to prepare compositionally graded materials and new phases. Rotation of a pipe about its axis allowed the casting of large-diameter metal alloy pipes as well as coating the interior of pipes with a cermet utilizing self-propagating high-temperature synthesis. Such coatings are highly corrosion and erosion resistant. Flow on a rotating disk was shown to be useful for process intensification, such as large-scale manufacturing of nano-particles, polymerization reactions, and heat & mass transfer. Several theoretical studies dealt with the influence of rotation on fluid convection on surfaces and in pipes, tubes, and porous media. These have applications to integrated-circuit chip manufacturing, alloy casting, oil production, crystal growth, and the operation of rotating machinery.

In view of its extreme complexity the mathematical description of the mechanical behaviour of granular materials is an extremely difficult task. Today many different models compete with each other. However, the complexity of the models hinders their comparison, and the potential users are confused and, often, disencouraged. This book is expected to serve as a milestone in the present situation, to evaluate the present methodes, to clear up the situation, to focus and encourage for further research activities.

There are numerous technological materials - such as metals, polymers, ceramics, concrete, and many others - that vary in properties and serviceability. However, the almost universal common theme to most real materials is that their properties depend on the scale at which the analysis or observation takes place and at each scale "probabilities" play an important role. Here the word "probabilities" is used in a wider than the classical sense. In order to increase the efficiency and serviceability of these materials, researchers from NATO, CP and other countries were brought together to exchange knowledge and develop avenues for progress and applications in the st 21 century. The workshop began by reviewing progress in the subject area over the past few years and by identifying key questions that remain open. One point was how to observe/measure material properties at different scales and whether a probabilistic approach, at each scale, was always applicable and advantageous. The wide range of materials, from wood to advanced metals and from concrete to complex advanced composites, and the diversity of applications, e.g. fatigue, fracture, deformation, etc., were recognized as "obstacles" in identifying a "universal" approach.

This book starts with an extended introductory treatise on the fundamentals before moving on to a detailed description of the new methods of purification of transition metals and rare earth metals.

Number 25 of this acclaimed series breaks new ground with articles on charge transfer across liquid-liquid interfaces, electrochemical techniques to study hydrogen ingress in metals, and electrical breakdown of liquids. Also included are articles on the measurement of corrosion and ellipsometry, bringing these older subjects up to date.

Crystal pulling is an industrial process and provides the bulk of semiconductor crystals for the semiconductor industry. Initially a purely empirical process, the increase in importance and size of the industry has led to basic research into the fundamentals of the process - particularly the modelling of heat and mass transfer. The book has been written by the recognized authority on Czochralski crystal-growth techniques. It is an attempt to strengthen the interface between the practical crystal grower and the applied mathematician involved in analytical and computer modelling. Its focus is on the physics, chemistry and metallurgy of the process. From reviews: "... There is a need for a modern, non-trivial text on Czochralski growth ... and Dr. Hurle is eminently suited to write such a text."; "Dr. Hurle is probably uniquely qualified to write a book on ... (the Czochralski) growth process. ... He has published a great deal of very substantial as well as innovative work in this area."

This volume contains nearly all of the papers presented at the Symposium on "Defects and Qualities of Semiconductors" which was held in Tokyo on May 17-18, 1984, under the sponsorship of the SOCIETY OF NON-TRADITIONAL TECHNOLOGY. The Symposium was organized by the promoting committee of the research project "Quality Developement of Semiconductors by Utilization of Crystal Defects" sponsored by the Science and Technology Agency of Japan. Defect study in semiconductor engineering started originally with seeking methods how to suppress generation of harmful defects during device processing in order to achieve a high yield of device fabrication. Recently, a new trend has appeared in which crystal defects are positively utilized to improve the device performance and reliability. A typical example is the intrinsic gettering technique for Czochralski silicon. Thus, a new term "DEFECT ENGINEERING" was born. It is becoming more important to control density and distribution of defects than to eliminate all the defects. Very precise and deep knowledge on defects is required to establish such techniques as generation and development of defects desired depending on type of devices and degree of integration. Electrical, optical and mechanical effects of defects should be also understood correctly. Such knowledge is essential even for eliminating defects from some specified device regions. It is the time now to investigate defect properties and defect kinetics in an energetic way. From this point of view, all the speakers in this symposium were invited among the most active investigators in the field of defect engineering in Japan.

In the 1950s the direct observation of dislocations became possible, stimulat ing the interest of many research workers in the dynamics of dislocations. This led to major contributions to the understanding of the plasticity of various crys talline materials. During this time the study of metals and alloys of fcc and hcp structures developed remarkably. In particular, the discovery of the so-called in ertial effect caused by the electron and phonon frictional forces greatly influenced the quantitative understanding of the strength of these metallic materials. Statis tical studies of dislocations moving through random arrays of point obstacles played an important role in the above advances. These topics are described in Chaps. 2-4. Metals and alloys with bcc structure have large Peierls forces compared to those with fcc structure. The reasons for the delay in studying substances with bcc structure were mostly difficulties connected with the purification techniques and with microscopic studies of the dislocation core. In the 1970s, these difficulties were largely overcome by developments in experimental techniques and computer physics. Studies of dislocations in ionic and covalent bonding materials with large Peierls forces provided infonnation about the core structures of dislocations and their electronic interactions with charged particles. These are the main subjects in Chaps. 5-7."

It was a great honor for us to organize ChiCat, a symposium devoted to Chiral Reactions in Heterogeneous Catalysis and to be the hostsofmore than 120 scientists coming from everywhere in the industrialized world, to celebrate together one century of existence ofInstitut Meurice. This school was established in 1892when an industrial chemist, named Albert Meurice, decided to educate practical chemists according to the perceived needs ofthe industry ofthat time. This is exactly what we are still trying to do. It is the reason why, thirty years ago, we started a research activity in catalysis, and why we progressively devote this research to the applications of catalysis in the field of fine chemicals. In this respect, we are very close to another initiative of Albert Meurice, who started the first production of synthetic pharmaceuticals in Belgium during World War I. This business later on became a part ofthe Belgian corporation DCB, still very active in pharmaceuticals today. The school created by Albert Meurice merged in the fifties with another school that had been created to meet the same needs in the field of the food industries, mainly distilleries and breweries. This merger was done in the frame of the establishment of CERIA. For people in catalysis, ceria stands for cerium oxide, but for those who engineered the concept, CERIA stood for Center of Education and Research for the Food and Chemical Industries.

Larry L. Hench June Wilson OBJECTIVE Millions of people presently enjoy an improved quality of life due to prostheses which repair, augment or replace parts of their skeletal system: bones, joints, teeth, etc. However, all replacement parts have a finite probability of survival. The goal of this book is to compare the survivability data for various skeletal prosthesis systems. All data derive from previously published clinical studies. Where possible statistical comparisons are made and the reasons for failure are discussed. THE NEED FOR SKELETAL PROSTHESES We are an aging population with more than 100 million people in the U. S. and Europe over the age of 50 years. An unfortunate consequence of aging is a progressive deterioration of the quality of skeletal tissues. From the age of 30 years there is a decrease in bone mass for both men and women (Fig. 1. 1). However, for women it is much greater and between 40 and 60 years of age the rate of deterioration of long bones and vertebrae of women is especially severe due to hormonal changes. By the age of 70 most women will have lost from 35 to 60% of their bone mass. The loss of volume of cancellous or trabecular bone leads to a large decrease in mechanical compressive strength (Fig. 1. 2). The clinical consequence is an increasing incidence of vertebral collapse. Cortical bone decreases in tensile strength with age (Fig. 1.

Zeolites, with their crystalline microporous structures, are cordial hosts to a wide variety of guests. However, it was the abrupt and unexpected departure of one of these guests (water) from a host (stilbite) on heating which led Cronstedt, in 1756, to coin the term "zeolite" (from the Greek meaning "boiling stone") to describe this material. Since that time, approximately 40 different naturally-occurring zeolites have been discovered on earth. Recent studies of meteorite compositions have shown that these guest-host materials (e. g. , sodalite) occur in other parts of the universe as well. However, it wasn't until the twentieth century that synthetic routes to zeolites and other non-aluminosilicate molecular sieves were discovered. In addition, with the development of X-ray diffraction and the various spectroscopies, better understanding of the nature of the cavities, cages, and channels of these materials has led to the industrial exploitation of their guest-host properties. The world of zeolites has now expanded into a greater than 2 billion pound per year business, with major applications in detergent formulations, catalysis, and as adsorbents and desiccants. Their economic impact is difficult to determine; however, the improvement in gasoline yields alone (from catalytic cracking) must account for hundreds ofbillions ofdollars in increased GDP. In this volume, we have brought together a sampling of recent developments in various areas of guest-host or inclusion chemistry in zeolites.