This book presents a detailed look at experimental and computational techniques for accurate structure determination of free molecules. The most fundamental property of a molecule is its structure - it is a prerequisite for determining and understanding most other important properties of molecules. The determination of accurate structures is hampered by a myriad of factors, subjecting the collected data to non-negligible systematic errors. This book explains the origin of these errors and how to mitigate and even avoid them altogether. It features a detailed comparison of the different experimental and computation methods, explaining their interplay and the advantages of their combined use. Armed with this information, the reader will be able to choose the appropriate methods to determine - to a great degree of accuracy - the relevant molecular structure.

This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride-water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.

The search for examples of proton radioactivity has resulted in the discovery of a large number of proton emitters in the region 50 < Z < 84 [1]. Many of these proton emitters and their daughters are also a-emitters, and in some cases the a-decay chain from the daughter terminates on a nuclide closer to stability whose mass excess is known. This opens up the possibility of using a-and proton-decay Q-values to determine the mass excesses of a large group of nuclei connected by particle decay. The Q-values are derived from the measured kinetic energies of the emitted protons or a-particles. Where the decay chains are not connected to nuclei with known mass excesses, proton separation energies can be measured in some cases and derived in others. For the a-decay ofthe parent nucleus (Z, A) to the daughter (Z - 2, A - 4), the energy and momentum relations used to convert between Q-value, mass (M) and mass excess (ME) are: M(4He)E", (1) M(Z - 2, A - 4)Erecoil, (2) Q", E", + Erecoi\, ME(Z, A) Q", + ME(Z - 2, A - 4) + ME(4He). (3) In practice, one uses M(4He) ~ 4 and M(Z - 2, A - 4) (A - 4), so that Equation (3) becomes ME(Z, A) = E", (_A_) + ME(Z - 2, A - 4) + ME(4He). (4) A -4 Similarly, for protons, we have ME(Z, A) = Ep(_A_) +ME(Z - 1, A-I) +ME(lH).

This book focuses on the modern development of techniques for analysis of the hierarchical structure of polymers from both the experimental and theoretical points of view. Starting with molecular and crystal symmetry, the author explains fundamental and professional methods, such as wide- and small-angle X-ray scattering, neutron diffraction, electron diffraction, FTIR and Raman spectroscopy, NMR, and synchrotron radiation. In addition, the author explains another indispensable method, computer simulation, which includes energy calculation, lattice dynamics, molecular dynamics, and quantum chemistry. These various methods are described in a systematic way so that the reader can utilize them for the purpose of 3D structure analysis of polymers. Not only such analytical knowledge but also the preparation techniques of samples necessary for these measurements and the methods of analyzing the experimental data collected in this way are given in a concrete manner. Examples are offered to help master the principles of how to clarify the static structures and dynamic structural changes in the phase transitions of various kinds of crystalline polymers that are revealed by these novel methods. The examples are quite useful for readers who want to apply these techniques in finding practical solutions to concrete problems that are encountered in their own research. The principal audience for this book is made up of young professional researchers including those working in industry, but it can also be used as an excellent reference for graduate-level students. This book is the first volume of a two-volume set with Structural Science of Crystalline Polymers: A Microscopically Viewed Structure-Property Relationship being the second volume by the same author.

This book provides a rounded biography of Franz (later Sir Francis) Simon, his early life in Germany, his move to Oxford in 1933, and his experimental contributions to low temperature physics approximating absolute zero. After 1939 he switched his research to nuclear physics, and is credited with solving the problem of uranium isotope separation by gaseous diffusion for the British nuclear programme Tube Alloys. The volume is distinctive for its inclusion of source materials not available to previous researchers, such as Simon's diary and his correspondence with his wife, and for a fresh, well-informed insider voice on the five-power nuclear rivalry of the war years. The work also draws on a relatively mature nuclear literature to attempt a comparison and evaluation of the five nuclear rivals in wider political and military context, and to identify the factors, or groups of factors, that can explain the results.

This book provides a comprehensive look at the state of the art of externally driven and self-generated rotation as well as momentum transport in tokamak plasmas. In addition to recent developments, the book includes a review of rotation measurement techniques, measurements of directly and indirectly driven rotation, momentum sinks, self-generated flow, and momentum transport. These results are presented alongside summaries of prevailing theory and are compared to predictions, bringing together both experimental and theoretical perspectives for a broad look at the field. Both researchers and graduate students in the field of plasma physics will find this book to be a useful reference. Although there is an emphasis on tokamaks, a number of the concepts are also relevant to other configurations.

In this thesis, the author develops new high-power millimeter wave techniques for measuring the hyperfine structure of positronium (Ps-HFS) directly for the first time in the world. Indirect measurement of Ps-HFS in the literature might have systematic uncertainties related to the use of a static magnetic field. Development of the millimeter wave devices supports the precise determination of Ps-HFS by directly measuring the Breit-Wigner resonant transition from o-Ps to p-Ps without the magnetic field. At the same time, the width of the measured Breit-Wigner resonance directly provides the lifetime of p-Ps. This measurement is the first precise spectroscopic experiment involving the magnetic dipole transition and high-power millimeter waves. The development of a gyrotron and a Fabry-Perot cavity is described as providing an effective power of over 20 kW, which is required to cause the direct transition from o-Ps to p-Ps. Those values measured by the newly developed millimeter wave device pave the way for examining the discrepancy observed between conventional indirect experiments on Ps-HFS and the theoretical predictions of Quantum Electrodynamics.

To all four of us, Carsten was the best possible friend and colleague. To Finn, he was a fellow student in the history of science for several years at the Niels Bohr Institute; to Relge, he was a welcome resource for personal and intellectual interac tion in an otherwise less than fertile environment for the history of science; Roger was Carsten's friend and advisor, not least in the development of the dissertation on which the present book is based; and as director of the Niels Bohr Archive, Erik was his main advisor in his historical work. Because he was the person closest to Carsten's work on his Ph. D. dissertation on the history of beta decay, on which the present book is based, it is only fitting that Erik stands as single author of the words in Carsten's memory at the very beginning of this book. Before his untimely death shortly after the completion of the Ph. D. disser tation, Carsten had himself plans to develop the dissertation into a book. Being a true perfectionist, he wanted to rework the manuscript substantively, especially with regard to relating it to the broader discussion among historians of science."

Taking the reader through the underlying principles of molecular translational dynamics, Translational Dynamics and Magnetic Resonance outlines the ways in which magnetic resonance, through the use of magnetic field gradients, can reveal those dynamics. The measurement of diffusion and flow, over different length and time scales, provides unique insight regarding fluid interactions with porous materials, as well as molecular organization in soft matter and complex fluids.
The book covers both time and frequency domain methodologies, as well as advances in scattering and diffraction methods, multidimensional exchange and correlation experiments and orientational correlation methods ideal for studying anisotropic environments. At the heart of these new methods resides the ubiquitous spin echo, a phenomenon whose discovery underpins nearly every major development in magnetic resonance methodology. Measuring molecular translational motion does not require high spectral resolution and so finds application in new NMR technologies concerned with 'outside the laboratory' applications, in geophysics and petroleum physics, in horticulture, in food technology, in security screening and in environmental monitoring.

Volume 1 of this three-part series introduces the fundamental concepts of quantum field theory using the formalism of canonical quantization. This volume is intended for use as a text for an introductory quantum field theory course that can include both particle and condensed matter physics students. Dr. Strickland starts with a brief review of classical field theory and uses this as a jumping off point for the quantization of classical field, thereby promoting them to proper quantum fields. He then presents the formalism for real and complex scalar field theories, fermion field quantization, gauge field quantization, toy models of the nuclear interaction, and finally the full Lagrangian for QED and its renormalization. Part of IOP Series in Nuclear Medicine.

This comprehensive text presents not only a detailed exposition of the basic principles of nuclear physics but also provides a contemporary flavour by covering the recent developments in the field. Starting with a synoptic view of the subject, the book explains various physical phenomena in nuclear physics along with experimental methods of measurement. Nuclear forces as encountered in two body problems are detailed next followed by the problems of radioactive decay. Nuclear reactions are then comprehensively explained along with the various models of reaction mechanism. This is followed by recent developments like the pre-equilibrium model and heavy ions induced reaction.

SESSION 1- DESIGN ASPECTS - 1.1 Single Focusing Magnetic Deflection Mass Spectrometers - 1.2 The Design of Double Focusing Magnetic Deflection Instruments - 1.3 A New Cycloidal Mass Spectrometer - 1.4 A Time of Flight Mass Spectrometer - 1.5 Recent Developments in the Quadrupole Mass Filter - SESSION 2 - PHYSICAL AND CHROMATOGRAPHIC APPLICATIONS - 2.1 A Fast-scan Mass Spectrometer for Residual Gas Analysis and the Examination of Effluents from Gas Chromatography Columns - 2.2 Flavour Research with a Low Cost Fast-scan Mass Spectrometer - 2.3 A Gas Chromatograph-Mass Spectrometer Linkup Recent Developments - 2.4 A Small 1800 Deflection Partial Pressure-Total Pressure Gauge for Vacuum System Diagnosis - 2.5 A Cycloidal Mass Spectrometer Applied to the Measurement of the Speed of Sputter Ion Pumps - 2.6 The Sorption of Gases by Thin Films - SESSION 3 - CHEMICAL APPLICATIONS I - 3.1 The Use of a Quadrupole Mass Filter in the Study of a Reacting Surface - 3.2 Mass-spectrometric Investigation of the Formation of Di-imide by the Catalytic Decomposition of Hydrazine at Low Pressures on Platinum - 3.3 Rearrangement Processes in the Fragmentation of Organic Ions - 3.4 A Novel Ion in the Mass Spectra of Arylureas and Related Compounds - 3.5 Mass Spectra of Some Substituted Cyclotetrazenoboranes - 3.6 The Decomposition of 9,1O-Diphenylanthracene Under Electron Impact - SESSION 4 - CHEMICAL APPLICATIONS II - 4.1 Use of Multiplet Peaks in the Examination of High Molecular Weight Petroleum Fractions - 4.2 Inorganic Analysis of Spark Source Mass Spectrometry - 4.3 An Examination of Metal Chelates by Mass Spectrometry - 4.4 Data Handling and Instrumentation in the A.W.R.E. Mass Spectrometers - SYMPOSIUM IMPRESSIONS - INDEX

On the night of March 26, 1938, nuclear physicist Ettore Majorana boarded a ship, cash and passport in hand. He was never seen again. In "A Brilliant Darkness," theoretical physicist Joao Magueijo tells the story of Majorana and his research group, "the Via Panisperna Boys," who discovered atomic fission in 1934. As Majorana, the most brilliant of the group, began to realize the implications of what they had found, he became increasingly unstable. Did he commit suicide that night in Palermo? Was he kidnapped? Did he stage his own death?

"A Brilliant Darkness" chronicles Majorana's invaluable contributions to science--including his major discovery, the Majorana neutrino--while revealing the truth behind his fascinating and tragic life.

This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

This book reviews recent progress in our understanding of tokamak physics related to steady state operation, and addresses the scientific feasibility of a steady state tokamak fusion power system. It covers the physical principles behind continuous tokamak operation and details the challenges remaining and new lines of research towards the realization of such a system. Following a short introduction to tokamak physics and the fundamentals of steady state operation, later chapters cover parallel and perpendicular transport in tokamaks, MHD instabilities in advanced tokamak regimes, control issues, and SOL and divertor plasmas. A final chapter reviews key enabling technologies for steady state reactors, including negative ion source and NBI systems, Gyrotron and ECRF systems, superconductor and magnet systems, and structural materials for reactors. The tokamak has demonstrated an excellent plasma confinement capability with its symmetry, but has an intrinsic drawback with its pulsed operation with inductive operation. Efforts have been made over the last 20 years to realize steady state operation, most promisingly utilizing bootstrap current. Frontiers in Fusion Research II: Introduction to Modern Tokamak Physics will be of interest to graduate students and researchers involved in all aspects of tokamak science and technology.

The development of nuclear weapons during the Manhattan Project is one of the most significant scientific events of the twentieth century. This revised and updated 4th edition explores the challenges that faced the scientists and engineers of the Manhattan Project. It gives a clear introduction to fission weapons at the level of an upper-year undergraduate physics student by examining the details of nuclear reactions, their energy release, analytic and numerical models of the fission process, how critical masses can be estimated, how fissile materials are produced, and what factors complicate bomb design. An extensive list of references and a number of exercises for self-study are included. Revisions to this fourth edition include many upgrades and new sections. Improvements are made to, among other things, the analysis of the physics of the fission barrier, the time-dependent simulation of the explosion of a nuclear weapon, and the discussion of tamped bomb cores. New sections cover, for example, composite bomb cores, approximate methods for various of the calculations presented, and the physics of the polonium-beryllium "neutron initiators" used to trigger the bombs. The author delivers in this book an unparalleled, clear and comprehensive treatment of the physics behind the Manhattan project.

This Open Access book gives a comprehensive account of both the history and current achievements of molecular beam research. In 1919, Otto Stern launched the revolutionary molecular beam technique. This technique made it possible to send atoms and molecules with well-defined momentum through vacuum and to measure with high accuracy the deflections they underwent when acted upon by transversal forces. These measurements revealed unforeseen quantum properties of nuclei, atoms, and molecules that became the basis for our current understanding of quantum matter. This volume shows that many key areas of modern physics and chemistry owe their beginnings to the seminal molecular beam work of Otto Stern and his school. Written by internationally recognized experts, the contributions in this volume will help experienced researchers and incoming graduate students alike to keep abreast of current developments in molecular beam research as well as to appreciate the history and evolution of this powerful method and the knowledge it reveals.

This book is about the drift, diffusion, and reaction of ions moving through gases under the influence of an external electric field, the gas temperature, and the number density. While this field was established late in the 19th century, experimental and theoretical studies of ion and electron swarms continue to be important in such varied fields as atomic and molecular physics, aeronomy and atmospheric chemistry, gaseous electronics, plasma processing, and laser physics. This book follows in the rigorous tradition of well-known older books on the subject, while at the same time providing a much-needed overview of modern developments with a focus on theory. Graduate students and researchers new to this field will find this book an indispensable guide, particularly those involved with ion mobility spectrometry and the use of ion transport coefficients to test and improve ab initio ion-neutral interaction potentials. Established researchers and academics will find in this book a modern companion to the classic references.

This book analyzes the effect of hydrogen on the atomic-level interactions in metals, detailing the corresponding changes in the physical properties of crystal lattice defects, diffusion, and phase transformations in metallic materials as a result of hydrogen loading. It presents a novel derivation of the structure of stacking faults, the mobility of dislocations, and short-range atomic order in hydrogen-infused metallic alloys based on the change in the concentration of free electrons. It reviews the current hypotheses behind hydrogen embrittlement of iron-, nickel, and titanium-based alloys, focusing on the phenomenon of hydrogen-enhanced localized plasticity and taking into account inherent atomic states in the alloys and other effects due to hydrogen loading. Finally, the book analyzes the use of hydrogen as an interim alloying element in the technological processing of titanium alloys, discussing the necessary preconditions for hydrogen-enhanced plasticity of metals. This book is an excellent resource for graduate students, academic researchers, and practicing engineers involved in the development of advanced hydrogen-resistant metallic materials.

This book presents the latest advances and future trends in electron and phonon spectrometrics, focusing on combined techniques using electron emissions, electron diffraction, and phonon absorption and reflection spectrometrics from a substance under various perturbations to obtain new information on bond-electron-phonon dynamics. Discussing the principles of the bond order-length-strength (BOLS) correlation, nonbonding electron polarization (NEP), local bond average (LBA), and multi-field lattice oscillation dynamics for systems under perturbation, the book covers topics like differential photoelectron/phonon spectrometrics (DPS), which distils transition of the length, energy, stiffness and the fraction of bonds upon chemical or physical conditioning; and the derived performance of electrons in various bands in terms of quantum entrapment and polarization. This book appeals to researchers, scientists and engineers in the fields of chemistry, physics, surface and interface science, and materials science and engineering who are interested in electron and phonon spectrometrics.

analyzing the experimental data and constructing math.ematical models of the processes under study, one has to rely rather on the physical intuition than on the strict calculations. Now let us go one step higher and explain the main title of the book. The concepts of "laminary" and "turbulent" motions were first introduced in hydrodynamics. Since the old days these concepts have considerably broadened; now the laminar and the turbulent motions have been discovered and investigated at all levels of description of nonequilibrium processes in the open systems, from kinetics to reaction diffusion. In any case, one of the principal characteristics of the turbulent motion is the existence of a large number of well-developed macroscopic degrees of freedom. For this reason the turbulent motion is extremely complicated and to a large extent unpredictable. As the laminar and the turbulent flows play an important role in the processes of evolution in the open systems, and in particular, in the processes of self-organization, the need arises for assessing the relative degree of order of laminar and turbulent motions, and also for comparing the degree of order of various turbulent motions. Without being able to make such estimates it will be impossible to determine whether the evolution is going towards higher or towards lower organization when one turbulent state is replaced by another.

This book serves as an introduction to boundary plasma physics, providing an accessible entry point to the topic of plasma exhaust in magnetic confinement devices. While it delivers a concise, rigorous, and comprehensive account of all the major scientific topics relevant to those working on the subject, it also remains accessible and easy to consult due to its modular and compact structure. Beginning with the basic kinetic and fluid descriptions of plasma, and advancing through plasma-surface interactions, filamentary transport and plasma detachment, to conclude with a discussion of divertor configurations, this book represents a necessary and timely addition to the literature on the fast-growing field of boundary plasma physics. It will appeal to experienced theoreticians or experimentalists looking to enter the field as well as graduate students wishing to learn about it.

This volume comprises select peer-reviewed papers from the Indo-French Workshop on Multifragmentation, Collective Flow, and Sub-Threshold Particle Production in Heavy-Ion Reactions held at the Department of Physics, Panjab University, Chandigarh, India in February, 2019. The contents highlight latest research trends in intermediate energy nuclear physics and emphasize on the various reaction mechanisms which take place in heavy-ion collisions. The chapters contribute to the understanding of interactions that govern the dynamics at sub-nucleonic level. The book includes contributions from global experts hailing from major research facilities of nuclear physics, and provides a good balance between experimental and theoretical model based studies. Given the range of topics covered, this book can be a useful reference for students and researchers interested in the field of heavy-ion reactions.

A pioneering treatise presenting how the new mathematical techniques of holographic duality unify seemingly unrelated fields of physics. This innovative development morphs quantum field theory, general relativity and the renormalisation group into a single computational framework and this book is the first to bring together a wide range of research in this rapidly developing field. Set within the context of condensed matter physics and using boxes highlighting the specific techniques required, it examines the holographic description of thermal properties of matter, Fermi liquids and superconductors, and hitherto unknown forms of macroscopically entangled quantum matter in terms of general relativity, stars and black holes. Showing that holographic duality can succeed where classic mathematical approaches fail, this text provides a thorough overview of this major breakthrough at the heart of modern physics. The inclusion of extensive introductory material using non-technical language and online Mathematica notebooks ensures the appeal to students and researchers alike.