This book reviews various aspects of molecular spectroscopy and its application in materials science, chemistry, physics, medicine, the arts and the earth sciences. Written by an international group of recognized experts, it examines how complementary applications of diverse spectroscopic methods can be used to study the structure and properties of different materials. The chapters cover the whole spectrum of topics related to theoretical and computational methods, as well as the practical application of spectroscopic techniques to study the structure and dynamics of molecular systems, solid-state crystalline and amorphous materials, surfaces and interfaces, and biological systems. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in the latest developments in the theory, experimentation, measurement and application of various advanced spectroscopic methods for the study of materials.

This monograph presents fundamental aspects of modern spectral and other computational methods, which are not generally taught in traditional courses. It emphasizes concepts as errors, convergence, stability, order and efficiency applied to the solution of physical problems. The spectral methods consist in expanding the function to be calculated into a set of appropriate basis functions (generally orthogonal polynomials) and the respective expansion coefficients are obtained via collocation equations. The main advantage of these methods is that they simultaneously take into account all available information, rather only the information available at a limited number of mesh points. They require more complicated matrix equations than those obtained in finite difference methods. However, the elegance, speed, and accuracy of the spectral methods more than compensates for any such drawbacks. During the course of the monograph, the authors examine the usually rapid convergence of the spectral expansions and the improved accuracy that results when nonequispaced support points are used, in contrast to the equispaced points used in finite difference methods. In particular, they demonstrate the enhanced accuracy obtained in the solutionof integral equations. The monograph includes an informative introduction to old and new computational methods with numerous practical examples, while at the same time pointing out the errors that each of the available algorithms introduces into the specific solution. It is a valuable resource for undergraduate students as an introduction to the field and for graduate students wishing to compare the available computational methods. In addition, the work develops the criteria required for students to select the most suitable method to solve the particular scientific problem that they are confronting.

This thesis identifies the turning point in chain length, after which alkanes self-solvate into a folded structure instead of an extended stretched conformation. After this turning point, London dispersion forces rearrange isolated n-alkanes into a particular hairpin-structure, while for shorter chain lengths, a simple stretched conformation is energetically preferred. This thesis can locate the experimental turning point for the first time in an interaction-free manner from measurements of unbranched alkanes at low temperatures in supersonic jet expansions. It contains a detailed analysis of the vibrational Raman spectra of the chain molecules, which is supported by comprehensive quantum chemical simulations. In this way, the detailed balance between inter-chain attraction and conformational flexibility can be quantified. The investigations are complemented by measurements of perfluoroalkanes and similarities and differences between the compounds are discussed. Furthermore, Nils Luttschwager determines the stiffnesses (elastic moduli) of two of the most common industrial polymers: polyethylene and polytetrafluorethylene. He uses in this thesis a sophisticated extrapolation to calculate this value from quantities of their building blocks, showing that the single polymer molecules can be as stiff as a rod of steel.

This thesis investigates the behavior of two candidate materials (a-SiO2 and MgO) for applications in fusion (e.g., the International Thermonuclear Experimental Reactor ITER) and Generation IV fission reactors. Both parts of the thesis - the development of the ionoluminescence technique and the study of the ion-irradiation effects on both materials - are highly relevant for the fields of the ion-beam analysis techniques and irradiation damage in materials. The research presented determines the microstructural changes at different length scales in these materials under ion irradiation. In particular, it studies the effect of the irradiation temperature using several advanced characterization techniques. It also provides much-needed insights into the use of these materials at elevated temperatures. Further, it discusses the development of the ion-beam-induced luminescence technique in different research facilities around the globe, a powerful in situ spectroscopic characterization method that until now was little known. Thanks to its relevance, rigorosity and quality, this thesis has received twoprestigious awards in Spain and France.

Electrostatic Accelerators have been at the forefront of modern technology since the development by Sir John Cockroft and Ernest Walton in 1932 of the first accelerator, which was the first to achieve nuclear transmutation and earned them the Nobel Prize in Physics in 1951. The applications of Cockroft and Walton's development have been far reaching, even into our kitchens where it is employed to generate the high voltage needed for the magnetron in microwave ovens. Other electrostatic accelerator related Nobel prize winning developments that have had a major socio-economic impact are; the electron microscope where the beams of electrons are produced by an electrostatic accelerator, X-rays and computer tomography (CT) scanners where the X-rays are produced using an electron accelerator and microelectronic technology where ion implantation is used to dope the semiconductor chips which form the basis of our computers, mobile phones and entertainment systems. Although the Electrostatic Accelerator field is over 90 years old, and only a handful of accelerators are used for their original purpose in nuclear physics, the field and the number of accelerators is growing more rapidly than ever. The objective of this book is to collect together the basic science and technology that underlies the Electrostatic Accelerator field so it can serve as a handbook, reference guide and textbook for accelerator engineers as well as students and researchers who work with Electrostatic Accelerators.

Beautifully illustrated and engagingly written, Twelve Lectures in Quantum Mechanics presents theoretical physics with a breathtaking array of examples and anecdotes. Basdevant's style is clear and stimulating, in the manner of a brisk lecture that can be followed with ease and enjoyment. Here is a sample of the book's style, from the opening of Chapter 1: "If one were to ask a passer-by to quote a great formula of physics, chances are that the answer would be 'E = mc2'.... There is no way around it: all physics is quantum, from elementary particles, to stellar physics and the Big Bang, not to mention semiconductors and solar cells."

Terahertz (THz) radiation with frequencies between 100 GHz and 30 THz has developed into an important tool of science and technology, with numerous applications in materials characterization, imaging, sensor technologies, and telecommunications. Recent progress in THz generation has provided ultrashort THz pulses with electric field amplitudes of up to several megavolts/cm. This development opens the new research field of nonlinear THz spectroscopy in which strong light-matter interactions are exploited to induce quantum excitations and/or charge transport and follow their nonequilibrium dynamics in time-resolved experiments. This book introduces methods of THz generation and nonlinear THz spectroscopy in a tutorial way, discusses the relevant theoretical concepts, and presents prototypical, experimental, and theoretical results in condensed matter physics. The potential of nonlinear THz spectroscopy is illustrated by recent research, including an overview of the relevant literature.

Thermal processes are ubiquitous and an understanding of thermal phenomena is essential for a complete description of the physics of nanoparticles, both for the purpose of modeling the dynamics of the particles and for the correct interpretation of experimental data. The second edition of this book follows the logic of first edition, with an emphasis on presentation of literature results and to guide the reader through derivations. Several topics have been added to the repertoire, notably magnetism, a fuller exposition of aggregation and the related area of nucleation theory. Also a new chapter has been added on the transient hot electron phenomenon. The book remains focused on the fundamental properties of nanosystems in the gas phase. Each chapter is enriched with additional new exercises and three Appendices provide additional useful material.

This book collates past and current research on one of the most promising emerging modalities for breast cancer detection. Readers will discover how, as a standalone technology or in conjunction with another modality, microwave imaging has the potential to provide reliable, safe and comfortable breast exams at low cost. Current breast imaging modalities include X- ray, Ultrasound, Magnetic Resonance Imaging, and Positron Emission Tomography. Each of these methods suffers from limitations, including poor sensitivity or specificity, high cost, patient discomfort, and exposure to potentially harmful ionising radiation. Microwave breast imaging is based on a contrast in the dielectric properties of breast tissue that exists at microwave frequencies. The book begins by considering the anatomy and dielectric properties of the breast, contrasting historical and recent studies. Next, radar-based breast imaging algorithms are discussed, encompassing both early-stage artefact removal, and data independent and adaptive beamforming algorithms. In a similar fashion, microwave tomographic reconstruction algorithms are reviewed in the following chapter, introducing the reader to both the fundamental and more advanced algorithms. Apart from imaging, the book also reviews research efforts in extracting clinically useful information from the Radar Target Signature of breast tumours, which is used to classify tumours as either benign or malignant. Finally, the book concludes by describing the current state of the art in terms of prototype microwave breast imaging systems, with a particular emphasis on those which have progressed to the clinical evaluation stage. This work is motivated by the fact that breast cancer is one of the leading causes of death amongst women in Europe and the US, and the second most common cancer in the world today. Such an important area of research will appeal to many scholars and practitioners.p>

This book presents the method of ion beam modification of solids in realization, theory and applications in a comprehensive way. It provides a review of the physical basics of ion-solid interaction and on ion-beam induced structural modifications of solids. Ion beams are widely used to modify the physical properties of materials. A complete theory of ion stopping in matter and the calculation of the energy loss due to nuclear and electronic interactions are presented including the effect of ion channeling. To explain structural modifications due to high electronic excitations, different concepts are presented with special emphasis on the thermal spike model. Furthermore, general concepts of damage evolution as a function of ion mass, ion fluence, ion flux and temperature are described in detail and their limits and applicability are discussed. The effect of nuclear and electronic energy loss on structural modifications of solids such as damage formation, phase transitions and amorphization is reviewed for insulators and semiconductors. Finally some selected applications of ion beams are given.

While neutron halos were discovered 30 years ago, this is the first book written on the subject of this exotic form of nuclei that typically contain many more neutrons than stable isotopes of those elements. It provides an introductory description of the halo and outlines the discovery and evidence for its existence. It also discusses different theoretical models of the halo's structure as well as models and techniques in reaction theory that have allowed us to study the halo. This is written at a level accessible to graduate students starting a PhD in nuclear physics. Halo nuclei are an exotic form of atomic nuclei that contain typically many more neutrons than stable isotopes of those elements. To give you a famous example, an atom of the element lithium has three electrons orbiting a nucleus with three protons and, usually, either 3 or 4 neutrons. The difference in the number of neutrons gives us two different isotopes of lithium, Li6 and Li7. But if you keep adding neutrons to the nucleus you will eventually reach Li11, with still 3 protons (that means it's lithium) but with 8 neutrons. This nucleus is so neutron-rich that the last two are very weakly bound to the rest of the nucleus (a Li9 core). What happens is a quantum mechanical effect: the two outer neutrons float around beyond the rest of the nuclear core at a distance that is beyond the range of the force that is holding them to the core. This is utterly counterintuitive. It means the nucleus looks like a core plus extended diffuse cloud of neutron probability: the halo. The author of the book, Jim Al-Khalili, is a theoretician who published some of the key papers on the structure of the halo in the mid and late 90s and was the first to determine its true size. This monograph is based on review articles he has written on the mathematical models used to determine the halo structure and the reactions used to model that structure.

The new experiments underway at the Large Hadron Collider at CERN in Switzerland may significantly change our understanding of elementary particle physics and, indeed, the universe. This textbook provides a cutting-edge introduction to the field, preparing first-year graduate students and advanced undergraduates to understand and work in LHC physics at the dawn of what promises to be an era of experimental and theoretical breakthroughs.

Christopher Tully, an active participant in the work at the LHC, explains some of the most recent experiments in the field. But this book, which emerged from a course at Princeton University, also provides a comprehensive understanding of the subject. It explains every elementary particle physics process--whether it concerns nonaccelerator experiments, particle astrophysics, or the description of the early universe--as a gauge interaction coupled to the known building blocks of matter. Designed for a one-semester course that is complementary to a course in quantum field theory, the book gives special attention to high-energy collider physics, and includes a detailed discussion of the state of the search for the Higgs boson.Introduces elementary particle processes relevant to astrophysics, collider physics, and the physics of the early universe Covers experimental methods, detectors, and measurements Features a detailed discussion of the Higgs boson search Includes many challenging exercises

Professors: A supplementary Instructor's Manual which provides solutions for Chapters 1-3 of the textbook, is available as a PDF. It is restricted to teachers using the text in courses. To obtain a copy, please email your request to: Ingrid_Gnerlich "at" press.princeton.edu

This thesis reports the measurement of muon neutrino and antineutrino disappearance and electron neutrino and antineutrino appearance in a muon neutrino and antineutrino beam using the T2K experiment. It describes a result in neutrino physics that is a pioneering indication of charge-parity (CP) violation in neutrino oscillation; the first to be obtained from a single experiment. Neutrinos are some of the most abundant-but elusive-particles in the universe, and may provide a promising place to look for a potential solution to the puzzle of matter/antimatter imbalance in the observable universe. It has been firmly established that neutrinos can change flavour (or 'oscillate'), as recognised by the 2015 Nobel Prize. The theory of neutrino oscillation allows for neutrinos and antineutrinos to oscillate differently (CP violation), and may provide insights into why our universe is matter-dominated. Bayesian statistical methods, including the Markov Chain Monte Carlo fitting technique, are used to simultaneously optimise several hundred systematic parameters describing detector, beam, and neutrino interaction uncertainties as well as the six oscillation parameters.

Combining incisive experiments with the latest theoretical advances, this book presents an extensive study of transfer-triggered breakup, the dominant process by which breakup occurs in reactions involving light, weakly bound nuclei. It demonstrates not only that lifetimes of resonant states shorter than a zeptosecond are crucially important for these reactions to suppress complete fusion, but also that such short lifetimes are experimentally accessible. By making quantitative predictions of the effect of breakup from short-lived resonant states on incomplete fusion at above-barrier energies, the book suggests that the extent to which near-target breakup can suppress complete fusion is much more limited than previously thought. With an impressive amount of complex data and state-of-the-art models, which were developed, modified, and tested over course of the Ph.D., it examines all aspects of nuclear reactions - nuclear models, modern detectors and spectrometers, as well as data analysis, and offers a detailed discussion of experimental results and technical developments like new radioactive beams. This excellent and beautifully written book presents outstanding quality experimental work that establishes a cornerstone in our understanding of the reaction dynamics of light weakly bound nuclei at energies around the Coulomb barrier.

This book covers the principles and practices behind the Magnetic Confinement Fusion (MCF) approach to driven new source of energy. All possible technical methods, including well established theoretical research, as well as findings tested in an experimental tokamak reactor, are examined in order to determine how to best achieve breakeven via this pathway to plasma-driven fusion. The author undertakes a life cycle analysis to compare and contrast the efficiency, environmental impacts, and operating costs of plasma-driven MCF fusion against other forms of energy generation currently in widespread use. The associated computer code and numerical analysis are included in the book. No prior knowledge of MCF and no more than basic background in plasma physics is required.