an integrated approach to electron transfer phenomena
This two-part stand-alone volume in the prestigious Advances in Chemical Physics series provides the most comprehensive overview of electron transfer science today. It draws on cutting-edge research from diverse areas of chemistry, physics, and biology-covering the most recent developments in the field, and pointing to important future trends. This second volume offers the following sections:
* Solvent control, including ultrafast solvation dynamics and related topics
* Ultrafast electron transfer and coherence effects
* Molecular electronics
* Electron transfer and exciplex chemistry
* Biomolecules-from electron transfer tubes to kinetics in a DNA environment
Part One addresses the historical perspective, electron transfer phenomena in isolated molecules and clusters, general theory, and electron transfer kinetics in bridged compounds.
Electron transfer science has seen tremendous progress in recent years. Technological innovations, most notably the advent of femtosecond lasers, now permit the real-time investigation of intramolecular and intermolecular electron transfer processes on a time scale of nuclear motion. New scientific information abounds, illuminating the processes of energy acquisition, storage, and disposal in large molecules, clusters, condensed phase, and biophysical systems.
Electron Transfer: From Isolated Molecules to Biomolecules is the first book devoted to the exciting work being done in nonradiative electron transfer dynamics today. This two-part edited volume emphasizes the interdisciplinary nature of the field, bringing together the contributions of pioneers inchemistry, physics, and biology. Both theoretical and experimental topics are featured. The authors describe modern approaches to the exploration of different systems, including supersonic beam techniques, femtosecond laser spectroscopy, chemical syntheses, and methods in genetic and chemical engineering. They examine applications in such areas as supersonic jets, solvents, electrodes, semi- conductors, respiratory and enzymatic protein systems, photosynthesis, and more. They also relate electron transfer and radiationless transitions theory to pertinent physical phenomena, and provide a conceptual framework for the different processes.
Complete with over two hundred illustrations, Part Two opens with solvent control issues, including electron transfer reactions and ultrafast solvation dynamics. Other topics include ultrafast electron transfer and coherence effects, molecular electronics, and electron transfer in exciplex chemistry. This volume concludes with a section on biomolecules-from electron transfer tubes to experimental electron transfer and transport in DNA.
Timely, comprehensive, and authoritative, Electron Transfer: From Isolated Molecules to Biomolecules is an essential resource for physical chemists, molecular physicists, and researchers working in nonradiative dynamics today.

This work introduces heavy ion beam probe diagnostics and presents an overview of its applications. The heavy ion beam probe is a unique tool for the measurement of potential in the plasma core in order to understand the role of the electric field in plasma confinement, including the mechanism of transition from low to high confinement regimes (L-H transition). This allows measurement of the steady-state profile of the plasma potential, and its use has been extended to include the measurement of quasi-monochromatic and broadband oscillating components, the turbulent-particle flux and oscillations of the electron density and poloidal magnetic field. Special emphasis is placed on the study of Geodesic Acoustic Modes and Alfven Eigenmodes excited by energetic particles with experimental data sets. These experimental studies help to understand the link between broadband turbulent physics and quasi-coherent oscillations in devices with a rather different magnetic configuration. The book also compares spontaneous and biased transitions from low to high confinement regimes on both classes of closed magnetic traps (tokamak and stellarator) and highlights the common features in the behavior of electric potential and turbulence of magnetized plasmas. A valuable resource for physicists, postgraduates and students specializing in plasma physics and controlled fusion.

The two decades between the first and second world wars saw the emergence of nuclear physics as the dominant field of experimental and theoretical physics, owing to the work of an international cast of gifted physicists. Prominent among them were Ernest Rutherford, George Gamow, the husband and wife team of Frederic and Irene Joliot-Curie, John Cockcroft and Ernest Walton, Gregory Breit and Eugene Wigner, Lise Meitner and Otto Robert Frisch, the brash Ernest Lawrence, the prodigious Enrico Fermi, and the incomparable Niels Bohr. Their experimental and theoretical work arose from a quest to understand nuclear phenomena; it was not motivated by a desire to find a practical application for nuclear energy. In this sense, these physicists lived in an 'Age of Innocence'. They did not, however, live in isolation. Their research reflected their idiosyncratic personalities; it was shaped by the physical and intellectual environments of the countries and institutions in which they worked. It was also buffeted by the political upheavals after the Great War: the punitive postwar treaties, the runaway inflation in Germany and Austria, the Great Depression, and the intellectual migration from Germany and later from Austria and Italy. Their pioneering experimental and theoretical achievements in the interwar period therefore are set within their personal, institutional, and political contexts. Both domains and their mutual influences are conveyed by quotations from autobiographies, biographies, recollections, interviews, correspondence, and other writings of physicists and historians.

This edited, multi-author volume contains selected, peer-reviewed contributions based on the presentations given at the 21th International Workshop on Quantum Systems in Chemistry, Physics, and Biology (QSCP-XXI), held in Vancouver, Canada, in July 2016. This book is primarily aimed at scholars, researchers and graduate students working at universities and scientific laboratories and interested in the structure, properties, dynamics and spectroscopy of atoms, molecules, biological systems and condensed matter.

This book describes advanced research on the structures and photochemical properties of polyatomic molecules and molecular clusters having various functionalities under cold gas-phase conditions. Target molecules are crown ethers, polypeptides, large size protonated clusters, metal clusters, and other complex polyatomic molecules of special interest. A variety of advanced frequency and time-domain laser spectroscopic methods are applied. The book begins with the principle of an experimental setup for cold gas-phase molecules and various laser spectroscopic methods, followed by chapters on investigation of specific molecular systems. Through a molecular-level approach and analysis by quantum chemical calculation, it is possible to learn how atomic and molecular-level interactions (van der Waals, hydrogen-bonding, and others) control the specific properties of molecules and clusters. Those properties include molecular recognition, induced fitting, chirality, proton and hydrogen transfer, isomerization, and catalytic reaction. The information will be applicable to the design of new types of functional molecules and nanoparticles in the broad area that includes applied chemistry, drug delivery systems, and catalysts.

This book looks at the early history of nuclear power, at what happened next, and at its longer-term prospects. The main question is: can nuclear power overcome the problems that have emerged? It was once touted as the ultimate energy source, freeing mankind from reliance on dirty, expensive fossil energy. Sixty years on, nuclear only supplies around 11.5% of global energy and is being challenged by cheaper energy options. While the costs of renewable sources, like wind and solar, are falling rapidly, nuclear costs have remained stubbornly high. Its development has also been slowed by a range of other problems, including a spate of major accidents, security concerns and the as yet unresolved issue of what to do with the wastes that it produces. In response, a new generation of nuclear reactors is being developed, many of them actually revised versions of the ideas first looked at in the earlier phase. Will this new generation of reactors bring nuclear energy to the forefront of energy production in the future?

This book focuses on the study of the interfacial water using molecular dynamics simulation and experimental sum frequency generation spectroscopy. It proposes a new definition of the free O-H groups at water-air interface and presents research on the structure and dynamics of these groups. Furthermore, it discusses the exponential decay nature of the orientation distribution of the free O-H groups of interfacial water and ascribes the origin of the down pointing free O-H groups to the presence of capillary waves on the surface. It also describes how, based on this new definition, a maximum surface H-bond density of around 200 K at ice surface was found, as the maximum results from two competing effects. Lastly, the book discusses the absorption of water molecules at the water-TiO2 interface. Providing insights into the combination of molecular dynamics simulation and experimental sum frequency generation spectroscopy, it is a valuable resource for researchers in the field.

A recipient of the PROSE 2017 Honorable Mention in Chemistry & Physics, Radioactivity: Introduction and History, From the Quantum to Quarks, Second Edition provides a greatly expanded overview of radioactivity from natural and artificial sources on earth, radiation of cosmic origins, and an introduction to the atom and its nucleus. The book also includes historical accounts of the lives, works, and major achievements of many famous pioneers and Nobel Laureates from 1895 to the present. These leaders in the field have contributed to our knowledge of the science of the atom, its nucleus, nuclear decay, and subatomic particles that are part of our current knowledge of the structure of matter, including the role of quarks, leptons, and the bosons (force carriers). Users will find a completely revised and greatly expanded text that includes all new material that further describes the significant historical events on the topic dating from the 1950s to the present.

The work describes the production technology of standard medical radionuclides using reactors and cyclotrons for patient diagnosis and therapy. A special focus lies on the science and technology involved in the development of novel radionuclides for positron emission tomography (PET) and internal targeted radiotherapy. The availability of those radionuclides is opening up new potential in clinical research, especially in neurology, cardiology and oncology. The future perspectives of the developing technology are also discussed.

This textbook, now in its third edition, provides a formative introduction to the structure of matter that will serve as a sound basis for students proceeding to more complex courses, thus bridging the gap between elementary physics and topics pertaining to research activities. The focus is deliberately limited to key concepts of atoms, molecules and solids, examining the basic structural aspects without paying detailed attention to the related properties. For many topics the aim has been to start from the beginning and to guide the reader to the threshold of advanced research. This edition includes four new chapters dealing with relevant phases of solid matter (magnetic, electric and superconductive) and the related phase transitions. The book is based on a mixture of theory and solved problems that are integrated into the formal presentation of the arguments. Readers will find it invaluable in enabling them to acquire basic knowledge in the wide and wonderful field of condensed matter and to understand how phenomenological properties originate from the microscopic, quantum features of nature.

This new text looks at Quantum Chromodynamics, the theory of the strong force between quarks, which form the fundamental building blocks of nuclear matter. With a primary focus on experiments, the authors also include an extensive theoretical introduction to the field, as well as many exercises with solutions explained in detail.

This is a comprehensive text for a course on non-relativistic nuclear reactions. The main formalisms used to describe nuclear reactions are explained clearly and coherently, and the reader is led from basic laws to the final formulae used to calculate measurable quantities. Combining a thorough theoretical approach with applications to recent experimental results, this text covers all main topics including potential scattering, formal reaction theory, the theory of the optical model, direct and compound reactions, fusion, deep inelastic collisions, and induced fission. Lecturers, graduate students, and researchers in nuclear and atomic physics will find this a useful textbook and reference work.

This monograph takes stock of the situation in higher spin gauge theories for the first time. Besides a thorough recapitulation of the field's history, it reviews the progress that has been made and offers a pedagogical introduction to the subject. Abstract approaches to the theory are offered to facilitate a conceptual rethinking of the main problems and to help see patterns hidden by heavy formalism.

This thesis covers several important topics relevant to our understanding of quark-gluon plasma. It describes measurement of the third-order harmonic flow using two-particle correlations and isolation of flow and non-flow contributions to particle correlations in gold-gold collisions. The work also investigates long-range longitudinal correlations in small systems of deuteron-gold collisions. The former is related to the hydrodynamic transport properties of the quark-gluon plasma created in gold-gold collisions. The latter pertains to the question whether hydrodynamics is applicable to small systems, such as deuteron-gold collisions, and whether the quark-gluon plasma can be formed in those small-system collisions. The work presented in this thesis was conducted with the STAR experiment at the Relativistic Heavy Ion Collider at Brookhaven National Laboratory, where the center-of-mass energy of both collision systems was a factor of 100 larger than the rest mass of the colliding nuclei. The results contained in this thesis are highly relevant to our quest for deeper understanding of quantum chromodynamics. The results obtained challenge the interpretation of previous works from several other experiments on small systems, and provoke a fresh look at the physics of hydrodynamics and particle correlations pertinent to high energy nuclear collisions.

This book covers the principles and practices behind the Magnetic Confinement Fusion (MCF) approach to driven new source of energy. All possible technical methods, including well established theoretical research, as well as findings tested in an experimental tokamak reactor, are examined in order to determine how to best achieve breakeven via this pathway to plasma-driven fusion. The author undertakes a life cycle analysis to compare and contrast the efficiency, environmental impacts, and operating costs of plasma-driven MCF fusion against other forms of energy generation currently in widespread use. The associated computer code and numerical analysis are included in the book. No prior knowledge of MCF and no more than basic background in plasma physics is required.

Optics has become one of the most dynamic fields of science since the first volume of Progress in Optics was published, forty years ago. At the time of inception of this series, the first lasers were only just becoming operational, holography was in its infancy, subjects such as fiber optics, integrated optics and optoelectronics did not exist and quantum optics was the domain of only a few physicists. The term photonics had not yet been coined. Today these fields are flourishing and have become areas of specialisation for many science and engineering students and numerous research workers and engineers throughout the world. Some of the advances in these fields have been recognized by awarding Nobel prizes to seven physicists in the last twenty years. The volumes in this series which have appeared up to now contain 240 review articles by distinguished research workers, which have become permanent records for many important developments. They have helped optical scientists and optical engineers to stay abreast of their fields. There is no sign that developments in optics are slowing down or becoming less interesting. We confidently expect that, just like their predecessors, future volumes of Progress in Optics will faithfully record the most important advances that are being made in optics and related fields.

An authoritative review of the state of the art in the Nuclear Overhauser Effect—essential information for organic chemists, biochemists, biophysicists, and NMR spectroscopists

The field of NMR spectroscopy has seen tremendous growth in the last twenty years, particularly advances relating to Nuclear Overhauser Effect (NOE) spectroscopy—the most powerful technique for obtaining structural information on molecules in solution. Extensive and engaging, the Second Edition of the leading reference on the NOE is significantly updated to reflect the latest changes and new approaches in the field.

Neuhaus and Williamson provide an essential guide to the complexities and use of the NOE in a readily accessible, straightforward manner. Their practical handbook features a new chapter addressing the use of NOE data to calculate biomolecular structures. Chapters dealing with the kinetics of the NOE, the effects of exchange and internal motion, and applications of the NOE, are also extensively revised. Cross-referenced in remarkable depth, The Nuclear Overhauser Effect is organized into three main parts:

• Part I describes the theory of the Nuclear Overhauser Effect in a clear, comprehensive fashion
• Part II discusses the considerations involved in implementing NOE experiments, including full coverage of all necessary details for both new and established techniques
• Part III offers examples of how the NOE is used, including applications to defining molecular geometry, stereochemistry, conformation, and biomolecular structure and interactions

This book introduces the current understanding of the fundamentals of nuclear physics by referring to key experimental data and by providing a theoretical understanding of principal nuclear properties. It primarily covers the structure of nuclei at low excitation in detail. It also examines nuclear forces and decay properties. In addition to fundamentals, the book treats several new research areas such as non-relativistic as well as relativistic Hartree-Fock calculations, the synthesis of super-heavy elements, the quantum chromodynamics phase diagram, and nucleosynthesis in stars, to convey to readers the flavor of current research frontiers in nuclear physics. The authors explain semi-classical arguments and derivation of its formulae. In these ways an intuitive understanding of complex nuclear phenomena is provided. The book is aimed at graduate school students as well as junior and senior undergraduate students and postdoctoral fellows. It is also useful for researchers to update their knowledge of diverse fields of nuclear structure. The book explains how basic physics such as quantum mechanics and statistical physics, as well as basic physical mathematics, is used to describe nuclear phenomena. A number of questions are given from place to place as supplements to the text.

This thesis presents the first isotope-shift measurement of bound-electron g-factors of highly charged ions and determines the most precise value of the electron mass in atomic mass units, which exceeds the value in the literature by a factor of 13. As the lightest fundamental massive particle, the electron is one of nature's few central building blocks. A precise knowledge of its intrinsic properties, such as its mass, is mandatory for the most accurate tests in physics - the Quantum Electrodynamics tests that describe one of the four established fundamental interactions in the universe. The underlying measurement principle combines a high-precision measurement of the Larmor-to-cyclotron frequency ratio on a single hydrogen-like carbon ion studied in a Penning trap with very accurate calculations of the so-called bound-electron g-factor. For the isotope-shift measurement, the bound-electron g-factors of two lithium-like calcium isotopes have been measured with relative uncertainties of a few 10^{-10}, constituting an as yet unrivaled level of precision for lithium-like ions.

"Physics and Engineering of Radiation Detection "presents an overview of the physics of radiation detection and its applications. It covers the origins and properties of different kinds of ionizing radiation, their detection and measurement, and the procedures used to protect people and the environment from their potentially harmful effects.

The second edition isfully revised and provides the latest developments in detector technology and analyses software. Also, more material related to measurements in particle physics and a complete solutions manual have been added.
Discussesthe experimental techniques and instrumentation used in different detection systems in a very practical way without sacrificing the physics contentProvides useful formulae and explains methodologies to solve problems related to radiation measurementsContains many worked-out examples and end-of-chapter problemsDetailed discussions on different detection media, such as gases, liquids, liquefied gases, semiconductors, and scintillatorsChapters on statistics, data analysis techniques, software for data analysis, and data acquisition systems"

The present research studies the fundamental physics occurring during the magnetic flux and magnetized plasma compression by plasma implosion. This subject is relevant to numerous studies in laboratory and space plasmas. Recently, it has attracted particular interest due to the advances in producing high-energy-density plasmas in fusion-oriented experiments, based on the approach of magnetized plasma compression. The studied configuration consists of a cylindrical gas-puff shell with pre-embedded axial magnetic field that pre-fills the anode-cathode gap. Subsequently, axial pulsed current is driven through the plasma generating an azimuthal magnetic field that compresses the plasma and the axial magnetic field embedded in it. A key parameter for the understanding of the physics occurring during the magnetized plasma compression is the evolution and distribution of the axial and azimuthal magnetic fields. Here, for the first time ever, both fields are measured simultaneously employing non-invasive spectroscopic methods that are based on the polarization properties of the Zeeman effect. These measurements reveal unexpected results of the current distribution and the nature of the equilibrium between the axial and azimuthal fields. These observations show that a large part of the current does not flow in the imploding plasma, rather it flows through a low-density plasma residing at large radii. The development of a force-free current configuration is suggested to explain this phenomenon. Previously unpredicted observations in higher-power imploding-magnetized-plasma experiments, including recent unexplained structures observed in the Magnetized Liner Inertial Fusion experiment, may be connected to the present discovery.