Fibre reinforced polymer (FRP) composites are used in almost every type of advanced engineering structure, with their usage ranging from aircraft, helicopters and spacecraft through to boats, ships and offshore platforms and to automobiles, sports goods, chemical processing equipment and civil infrastructure such as bridges and buildlings. The usage of FRP composites continues to grow at an impessive rate as these materials are used more in their existing markets and become established in relatively new markets such as biomedical devices and civil structures. A key factor driving the increased applications of composites over the recent years is the development of new advanced forms of FRP materials. This includes developments in high performance resin systems and new styles of reinforcement, such as carbon nanotubes and nanoparticles. This book provides an up-to-date account of the fabrication, mechanical properties, delamination resistance, impact tolerance and applications of 3D FRP composites. The book focuses on 3D composites made using the textile technologies of weaving, braiding, knitting and stiching as well as by z-pinning.

Experts in rheology and polymer processing present up-to-date, fundamental and applied information on the rheological properties of polymers, in particular those relevant to processing, contributing to the physical understanding and the mathematical modelling of polymer processing sequences. Basic concepts of non-Newtonian fluid mechanics, micro-rheological modelling and constitutive modelling are reviewed, and rheological measurements are described. Topics with practical relevance are debated, such as linear viscoelasticity, converging and diverging flows, and the rheology of multiphase systems. Approximation methods are discussed for the computer modelling of polymer melt flow. Subsequently, polymer processing technologies are studied from both simulation and engineering perspectives. Mixing, crystallization and reactive processing aspects are also included. Audience: An integrated and complete view of polymer processing and rheology, important to institutions and individuals engaged in the characterisation, testing, compounding, modification and processing of polymeric materials. Can also support academic polymer processing engineering programs.

This book is intended to fill a gap between the theoretical studies and the practical experience of the processor in the extrusion of thermoplastic polymers. The former have provided a basis for numerical design of extruders and their components, but generally give scant attention to the practical performance, especially to the conflict between production rate and product quality. In practice extruders are frequently purchased to perform a range of duties; even so, the operator may have to use a machine designed for another purpose and not necessarily suitable for the polymer, process or product in hand. The operator's experience enables him to make good product in unpromising circumstances, but a large number of variables and interactions often give apparently contradictory results. The hope is that this book will provide a logical background, based on both theory and experience, which will help the industrial processor to obtain the best performance from his equipment, to recognize its limitations, and to face new problems with confidence. Mathematics is used only to the extent that it clarifies effects which cannot easily be expressed in words; ifit is passed over, at least a qualitative understanding should remain. The approximate theory will not satisfy the purist, but this seems to the authors less important than a clear representation of the physical mechanisms on which so much of the polymer processing industry depends. M. J. STEVENS J. A.

Over the past 40 years, Rotational Isomeric State (RIS) models for hundreds of polymer structures have been developed. The RIS approach is now available in several software packages. The user is often faced with the time-consuming task of finding appropriate RIS parameters from the literature. This book aims at easing this step by providing a comprehensive overview of the models available. It reviews the literature from the first applications of RIS models to the end of 1994, comprises synthetic as well as naturally orccuring macromolecules, and tabulates all the pertinent features of published models. It will help readers, even when not very familiar with the method, to take advantage of this computationally efficient way of assessing the conformational properties of macromolecular systems.

The subject of liquid crystals and their use in electronic displays and in non-linear optical systems has become of tremendous importance during the last decade; and the incorporation of liquid crystal units into polymeric materials has led to a group of new materials with diverse properties. Some of these properties have been utilized in new products and some have yet to be used. Much published work has appeared that deals with specific materials or particular applications, and it was felt that a book was needed to examine and explain the underlying principles governing the diverse properties of these liquid crystal polymers, LCPs. The current work describes the diverse nature of LCPs, their synthesis, characterization, properties and finally their applications. It describes the manner in which liquid crystallinity or mesomorphism occurs in small molecules, monomer liquid crystals and polymer liquid crystals. Chapter 1 gives a classification of the various ways in which the meso gens may be connected to the polymer chains. Currently, the bulk of LCP material is based on main chain or longitudinal LCPs for use in engineering applications. The side chain or comb polymers are intended for use in electronics and opto-electronic systems and as surfactants. Many other variants and possibilities exist but their properties have not yet been fully studied or used. In this respect it is hoped that the current work will indicate future possibilities as well as discussing current opinion. v Preface vi Chapters 2 and 3 describe methods of characterizing the mesophases.

The development of photosensitive materials in general and photoreactive polymers in particular is responsible for major advances in the information, imaging, and electronic industries. Computer parts manufacturing, information storage, and book and magazine publishing all depend on photoreactive polymer systems. The photo-and radiation-induced processes in polymers are also active areas of research. New information on the preparation and properties of com mercially available photosensitive systems is constantly being acquired. The recent demand for environmentally safe solvent-free and water-soluble materials also motivated changes in the composition of photopolymers and photoresists. The interest in holographic recording media for head-up displays, light scanners, and data recording stimulated development of reconfigurable and visible light sensitive materials. Photoconductive polymerizable coatings are being tested in electrostatic proofing and color printing. The list of available initiators, poly meric binders, and other coating ingredients is continually evolving to respond to the requirements of low component loss (low diffusivity) and the high rate of photochemical reactions."

A survey of the role of plastics materials in the motor industry. It discusses progress in the different sectors of automotive engineering, and the possible effect of economic and environmental pressures on the growth of the plastics contribution. Emphasis is given to materials selection and the author explains how a material can be 'right' or 'wrong' for a particular job – and what extraneous factors could change things.

The behavior of polymer solutions in simple shear flows has been the subject of considerable research in the past. On the other hand, reports on polymers in elongational flow have appeared comparatively recently in the literature. Elongational flow with an inherent low vorticity is known to be more effective in extending polymer chains than simple shear flow and thus is more interesting from the point of view of basic (molecular chain dynamics at high deformation) and applied polymer science (rheology, fiber extrusion, drag reduction, flow through porous media). Undoubtly, one landmark in the field of polymer dynamics in elongational flow was the notion of critical strain-rate for chain extension, initially put forward by A. Peterlin (1966) and later refined into the "coil-stretching" transition by P. G. de Gennes and H. Hinch (1974). In the two decades which followed, significant progress in the understanding of chain conformation in "strong" flow has been accomplished through a combination of advances in instrumentation, computation techniques and theoretical studies. As a result of the multidisciplinary nature of the field, information on polymer chains in "strong" flow is accessible only from reviews and research papers scattered in disparate scientific journals. An important objective of this book is to remedy that situation by providing the reader with up-to-date knowledge in a single volume. The editors therefore invited leading specialists to provide both fundamental and applied information on the multiple facets of chain deformation in elongational flow.

Chitin, Chitosan and Derivatives for Wound Healing and Tissue Engineering, by Antonio Francesko and Tzanko Tzanov Polyhydroxyalkanoates (PHA) and their Applications, by Guo-Qiang Chen.- Enzymatic Polymer Functionalisation: Advances in Laccase and Peroxidase Derived Lignocellulose Functional Polymers, by Gibson S. Nyanhongo, Tukayi Kudanga, Endry Nugroho Prasetyo and Georg M. Guebitz.- Lipases in Polymer Chemistry, by Bahar Yeniad, Hemantkumar Naik and Andreas Heise.- Enzymes for the Biofunctionalization of Poly(Ethylene Terephthalate), by Wolfgang Zimmermann and Susan Billig.- Biology of Human Hair: Know Your Hair to Control It, by Rita Araujo, Margarida Fernandes, Artur Cavaco-Paulo and Andreia Gomes.- Recombinamers: Combining Molecular Complexity with Diverse Bioactivities for Advanced Biomedical and Biotechnological Applications, by Jose Carlos Rodriguez-Cabello, Maria Pierna, Alicia Fernandez-Colino, Carmen Garcia-Arevalo and Francisco Javier Arias.- Biomimetic Materials for Medical Application Through Enzymatic Modification, by Piergiorgio Gentile, Valeria Chiono, Chiara Tonda-Turo, Susanna Sartori and Gianluca Ciardelli.- Supramolecular Polymers Based on Cyclodextrins for Drug and Gene Carrier Delivery, by Jia Jing Li, Feng Zhao and Jun Li.- Engineering Liposomes and Nanoparticles for Biological Targeting, by Rasmus I. Jolck, Lise N. Feldborg, Simon Andersen, S. Moein Moghimi and Thomas L. Andresen.-"

The last decade or so has seen a dramatic increase in the amount of detailed structural information available from a range of experimental techniques. Exciting new techniques such as atomic force microscopy have become widely available, while the potential of established methods like X-ray diffraction and electron microscopy has been greatly enhanced by powerful new sources and analytical methods. Progress in computing has also had a widespread impact: in areas such as neutron scattering, large data sets can now be manipulated more readily. The software supplied with commercial instruments generally provides more sophisti cated analytical facilities, while time-resolved X-ray studies rely on rapid data handling capabilities. The polymer scientist is faced with an expanding array of experimental tools for addressing both fundamental science and industrial problems. This work reviews some recent developments in structural techniques, with the aim of presenting the current 'state of the art' in a selection of areas."

The two volumes "New Developments in Polymer Analytics" deal with recent progress in the characterization of polymers, mostly in solution but also at s- faces. Despite the fact that almost all of the described techniques are getting on in years, the contributions are expected to meet the readers interest because either the methods are newly applied to polymers or the instrumentation has achieved a major breakthrough leading to an enhanced utilizaton by polymer scientists. The first volume concentrates on separation techniques. H. Pasch summarizes the recent successes of multi-dimensional chromatography in the characteri- tion of copolymers. Both, chain length distribution and the compositional h- erogeneity of copolymers are accessible. Capillary electrophoresis is widely and successfully utilized for the characterization of biopolymers, particular of DNA. It is only recently that the technique has been applied to the characterization of water soluble synthetic macromolecules. This contributrion of Grosche and Engelhardt focuses on the analysis of polyelectrolytes by capillary electopho- sis. The last contribution of the first volume by Coelfen and Antonietti sum- rizes the achievements and pitfalls of field flow fractionation techniques. The major drawbacks in the instrumentation have been overcome in recent years and the"triple F techniques" are currently advancing to a powerful competitor to size exclusion chromatography.

This book contains contributions from a workshop on topology and geometry of polymers, held at the IMA in June 1996, which brought together topologists, combinatorialists, theoretical physicists and polymer scientists, with a common interest in polymer topology. Polymers can be highly self-entangled even in dilute solution. In the melt the inter- and intra-chain entanglements can dominate the rheological properties of these phenomena. Although the possibility of knotting in ring polymers has been recognized for more than thirty years it is only recently that the powerful methods of algebraic topology have been used in treating models of polymers. This book contains a series of chapters which review the current state of the field and give an up to date account of what is known and perhaps more importantly, what is still unknown. The field abounds with open problems. The book is of interest to workers in polymer statistical mechanics but will also be useful as an introduction to topological methods for polymer scientists, and will introduce mathematicians to an area of science where topological approaches are making a substantial contribution.

The two volumes "New Developments in Polymer Analytics" deal with recent progress in the characterization of polymers, mostly in solution but also at sur faces. Despite the fact that almost all of the described techniques are getting on in years, the contributions are expected to meet the readers interest because either the methods are newly applied to polymers or the instrumentation has achieved a major breakthrough leading to an enhanced utilization by polymer scientists. The first volume concentrates on separation techniques. H. Pasch summarizes the recent successes of multi dimensional chromatography in the characteriza tion of copolymers. Both, chain length distribution and the compositional het erogeneity of copolymers are accessible. Capillary electrophoresis is widely and successfully utilized for the characterization of biopolymers, particular of DNA . It is only recently that the technique has been applied to the characterization of water soluble synthetic macromolecules. This contribution of Grosche and Engelhardt focuses on the analysis of polyelectrolytes by capillary electophore sis. The last contribution of the first volume by Coelfen and Antonietti summa rizes the achievements and pitfalls of field flow fractionation techniques .The major drawbacks in the instrumentation have been overcome in recent years and the "triple F techniques" are currently advancing to a powerful competitor to size exclusion chromatography.

The first edition was produced at a time when the advantages of studying oriented polymers were just becoming apparent. From a sci entific stand point it had been demonstrated that greater insight into both structure and properties could be obtained if an oriented polymer was prepared. From a technological viewpoint, major advances were under way, especially in high modulus and high strength fibres. Twenty years later, it is possible to review the scientific advances which have been made in this area and to provide much wider perspectives for the technology. As in the case of the first edition, the emphasis is on the methodologies available for characterizing oriented polymers and their mechanical behaviour. It is a particular pleasure to thank the contributing authors for their cooperation and Dr Philip Hastings of Chapman & Hall for his support and encouragement. I am also indebted to Professors A. H. Windle and D. C. Bassett for their respective contributions to sections 1. 3. 1 and 1. 3. 4. Although this chapter has been extensively revised, the contribution of the late Leslie Holliday to the first edition of this book is also acknowledged. Introduction 1 I. M. Ward 1. 1 THE PHENOMENON OF ORIENTATION Orientation in polymers is a phenomenon of great technical and theo retical importance. The word orientation itself conveys a number of ideas."

Polymer Latices, Second Edition is a comprehensive update of the previous edition, High Polymer Latices, taking into account the many developments since it was first published in 1966. It is the only publication to provide such an outstanding and extensive review of latex science and technology, from background theory and principles, to modern day applications. It will prove an invaluable reference source for all those working in the area of latex science and technology, such as colloid chemists, polymer scientists, and materials processors.

Experimental details that will be of use to the increasing number of researchers who find themselves faced with making rheological measurements, possibly for the first time.

This is a review of the broad spectrum of research activities currently being undertaken in the field of functionalized polymers and their significant application requirements in health, nutrition, environmental pollution control and economic developments. The book is structured in four parts. The first part is a general review of the chemistry of functionalized polymers, divided into sections on their synthesis and physical properties. The first section aims to give a background knowledge of the techniques necessary for designing reactive polymers through polymerization and the second considers pertinent physical properties which must be considered during the design of a new reactive polymer. Part two describes the contribution of functionalized polymers in solving problems associated with conventional procedures of chemical reactions, and considers a broad range of chemical applications, including the various types of functionalized polymers and in particular those used as reagents, catalysts and carriers in separation and synthesis. The third part aims to provide the basic principles necessary for the practical aspects of functionalized polymers with respect to a variety of biological fields such as the pharmaceutical, agriculture and food industries. This discussion includes a consideration of controlled release formulations of drugs and agrochemicals and the potential use of functionalized polymers in food additives and other related fields. The last part focuses on the applications of reactive functionalized polymers in various technological processes, including polymer stabilization, the conversion and storage of energy, conductive polymers and other processes.

During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40 60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. The photochemical instability of most polymers limits their outdoor application as they are photodegraded quickly over periods from months to a few years. To the despair of technologists and consumers alike, photodegradation and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In order to improve polymer photostability there has been a very big effort during the last 30 years to understand the mechanisms involved in photodegradation and environmental ageing. This book represents the author's attempt, based on his 25 years' experience in research on photodegradation and photo stabilization, to collect and generalize a number of available data on the photodegradation of polymers. The space limitation and the tremendous number of publications in the past two decades have made a detailed presentation of all important results and data difficult. The author apologizes to those whose work has not been quoted or widely presented in this book. Because many published results are very often contradictory, it has been difficult to present a fully critical review of collected knowledge, without antagonizing authors. For that reason, all available theories, mechanisms and different suggestions have been presented together, and only practice can evaluate which of them are valid.

Dynamics of Polymeric Liquids, Second Edition Volume 2: Kinetic Theory R. Byron Bird, Charles F. Curtiss, Robert C. Armstrong and Ole Hassager Volume Two deals with the molecular aspects of polymer rheology and fluid dynamics. It is the only book currently available dealing with kinetic theory and its relation to nonlinear rheological properties. Considerable emphasis is given to the connection between kinetic theory results and experimental data. The second edition contains new material on the basis for molecular modeling, the application of phase--space theory to dilute solutions, kinetic theory of melts and melt mixtures, and network theories. 1987 (0 471--80244--1) 450 pp.

This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.

Green Sustainable Process for Chemical and Environmental Engineering and Science: Carbon Dioxide Capture and Utilization explores advanced technologies based on CO2 utilization. The book provides an overview on the conversion and utilization of CO2, extraction techniques, heterogeneous catalysis, green solvent, industrial approaches, and commodity products through energy-intensive processes. In addition, it highlights lifecycle assessment and biological and engineering strategies for CO2 utilization. Each chapter presents challenges in the processes and future perspectives for the application of CO2 conversion and utilization.