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Crystallization Modalities in Polymer Melt Processing - Fundamental Aspects of Structure Formation (Hardcover, 2010 ed.)
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Crystallization Modalities in Polymer Melt Processing - Fundamental Aspects of Structure Formation (Hardcover, 2010 ed.)
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Structure formation in crystallizing polymers, as occurring during
processing, has not been treated so far in a coherent form. This
fact explains, why this monograph is written as the ?rst book
devoted to this subject. A quarter of a century ago the
underdevelopment of this subject was obvious. Trial and error
dominated. In fact, other apposite subjects as polymer melt
rheology or heat transfer, had reached high levels. A great number
of books has been devoted to them. Mold ?lling of amorphous
polymers and the solidi?cation of these polymers by vitri?cation
can nowadays be simulated numerically with a high degree of
accuracy. In the solidi?ed sample even residual stresses and
corresponding birefringence effects can accurately be 1 calculated
. However, semicrystalline polymers, which form the majority of
industrial po- mers, have been excluded from these considerations
for good reasons. In fact, great uncertainties existed about the
formation of quality determining crystalline str- tures. In
particular, polyole?ns suffered from this shortcoming. In 1983 this
fact instigated the polymer research group at the Johannes Kepler
University in Linz to start with pertinent activities. The urgency
of this kind of studies becomes evident, if advantages and hitches
of these polymers are considered. 1. Versatility of processing:
Injection molding into a great variety of shapes and sizes, from
thin walled beakers to garden chairs, not to forget pipe and pro?le
extrusion, cable coating, ?ber spinning, ?lm blowing. 2. Product
qualities: Ductility, low density, good electric insulation,
corrosion resistance, surface quality.
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