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Stereoselective Polymerization with Single-Site Catalysts (Paperback)
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Stereoselective Polymerization with Single-Site Catalysts (Paperback)
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New synthetic techniques allow chemists to modify polymer
microstructures more precisely than ever, making it possible to
design materials that meet increasingly demanding performance
requirements. Written and edited by experts in the field,
Stereoselective Polymerization with Single-Site Catalysts reviews
how the relative stereochemistry of polymer chains affects polymer
properties and presents the latest strategies for developing tactic
polymers using single-site catalysis. This unified volume explains
the mechanistic basics of tactic polymerizations, beginning with an
extensive survey of the most important classes of metallocene and
post-metallocene catalysts used to make polypropylenes. It also
focuses on tactic stereoblock and ethylene/propylene copolymers and
catalyst active site models, followed by chapters discussing the
structure of more stereochemically complex polymers and
polymerizations that proceed via non-vinyl-addition mechanisms.
Individual chapters thoroughly describe tactic polymerizations of
-olefins, styrene, dienes, acetylenes, lactides, epoxides,
acrylates, and cyclic monomers, as well as cyclopolymerizations and
ditactic structures, olefin/CO polymers, and metathesis
polyalkenamers. An ideal reference and supplementary text,
Stereoselective Polymerization with Single-Site Catalysts enables
both new and experienced chemists to better understand tactic
polymers and select appropriate catalyst systems for their
preparation.
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