Fractal and Trans-scale Nature of Entropy: Towards a Geometrization of Thermodynamics develops a new vision for entropy in thermodynamics by proposing a new method to geometrize. It investigates how this approach can accommodate a large number of very different physical systems, going from combustion and turbulence towards cosmology. As an example, a simple interpretation of the Hawking entropy in black-hole physics is provided. In the life sciences, entropy appears as the driving element for the organization of systems. This book demonstrates this fact using simple pedagogical tools, thus showing that entropy cannot be interpreted as a basic measure of disorder.

This book covers emerging energy storage technologies and material characterization methods along with various systems and applications in building, power generation systems and thermal management. The authors present options available for reducing the net energy consumption for heating/cooling, improving the thermal properties of the phase change materials and optimization methods for heat storage embedded multi-generation systems. An in-depth discussion on the natural convection-driven phase change is included. The book also discusses main energy storage options for thermal management practices in photovoltaics and phase change material applications that aim passive thermal control. This book will appeal to researchers and professionals in the fields of mechanical engineering, chemical engineering, electrical engineering, renewable energy, and thermodynamics. It can also be used as an ancillary text in upper-level undergraduate courses and graduate courses in these fields.

In a comprehensive treatment of Statistical Mechanics from thermodynamics through the renormalization group, this book serves as the core text for a full-year graduate course in statistical mechanics at either the Masters or Ph.D. level. Each chapter contains numerous exercises, and several chapters treat special topics which can be used as the basis for student projects. The concept of scaling is introduced early and used extensively throughout the text. At the heart of the book is an extensive treatment of mean field theory, from the simplest decoupling approach, through the density matrix formalism, to self-consistent classical and quantum field theory as well as exact solutions on the Cayley tree. Proceeding beyond mean field theory, the book discusses exact mappings involving Potts models, percolation, self-avoiding walks and quenched randomness, connecting various athermal and thermal models. Computational methods such as series expansions and Monte Carlo simulations are discussed, along with exact solutions to the 1D quantum and 2D classical Ising models. The renormalization group formalism is developed, starting from real-space RG and proceeding through a detailed treatment of Wilson's epsilon expansion. Finally the subject of Kosterlitz-Thouless systems is introduced from a historical perspective and then treated by methods due to Anderson, Kosterlitz, Thouless and Young. Altogether, this comprehensive, up-to-date, and engaging text offers an ideal package for advanced undergraduate or graduate courses or for use in self study.

This book investigates a wide range of phase equilibrium modelling and calculation problems for compositional thermal simulation. Further, it provides an effective solution for multiphase isenthalpic flash under the classical framework, and it also presents a new flash calculation framework for multiphase systems, which can handle phase equilibrium and chemical reaction equilibrium simultaneously. The framework is particularly suitable for systems with many phases and reactions. In this book, the author shows how the new framework can be generalised for different flash specifications and different independent variables. Since the flash calculation is at the heart of various types of compositional simulation, the findings presented here will promote the combination of phase equilibrium and chemical equilibrium calculations in future simulators, aiming at improving their robustness and efficiency.

This book is intended for undergraduate students in mechanical engineering. It covers the fundamentals of applied thermodynamics, including heat transfer and environmental control. A collection of more than 50 carefully tailored problems to promote greater understanding of the subject, supported by relevant property tables and diagrams are included along with a solutions manual.

This book offers a comprehensive overview of thermodynamics. It is divided into four parts, the first of which equips readers with a deeper understanding of the fundamental principles of thermodynamics of equilibrium states and of their evolution. The second part applies these principles to a series of generalized situations, presenting applications that are of interest both in their own right and in terms of demonstrating how thermodynamics, as a theory of principle, relates to different fields. In turn, the third part focuses on non-equilibrium configurations and the dynamics of natural processes. It discusses both discontinuous and continuous systems, highlighting the interference among non-equilibrium processes, and the nature of stationary states and of fluctuations in isolated systems. Lastly, part four introduces the relation between physics and information theory, which constitutes a new frontier in fundamental research. The book includes step-by-step exercises, with solutions, to help readers to gain a fuller understanding of the subjects, and also features a series of appendices providing useful mathematical formulae. Reflecting the content of modern university courses on thermodynamics, it is a valuable resource for students and young scientists in the fields of physics, chemistry, and engineering.

This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes' combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

This book is intended as a text for upper undergraduate and graduate courses on kinetics of metallurgical processes for students of materials science, metallurgical engineering, and chemical engineering. Focusing on basic and essential topics, selected from the authors' teaching and research, it serves as a comprehensive guide to metallurgical kinetics. Chapters 1-10 discuss the "logic" of various kinetics processes, while Chapter 11 explores the systematic analysis of raw rate data generated from controlled experiments. The final chapters illustrate how the fundamental concept of thermal activation is used to describe the kinetics of rate-dependent plastic deformation and creep fracture. With numerous examples, illustrations, and step-by-step tutorials, it is ideally suited for both self-study and classroom use. The examples were selected from research papers to highlight how the topics discussed can be, and are, used to solve real-world technological problems. Providing a comprehensive list of resources for further study, and end-of-chapter review questions to help students test their knowledge, it can be used for university coursework or as a text for professional development courses.

Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure explores the thermodynamics of non-equilibrium processes in materials. The book develops a general technique created in order to construct nonlinear evolution equations describing non-equilibrium processes, while also developing a geometric context for non-equilibrium thermodynamics. Solid materials are the main focus in this volume, but the construction is shown to also apply to fluids. This volume also: * Explains the theory behind thermodynamically-consistent construction of non-linear evolution equations for non-equilibrium processes * Provides a geometric setting for non-equilibrium thermodynamics through several standard models, which are defined as maximum dissipation processes * Emphasizes applications to the time-dependent modeling of soft biological tissue Maximum Dissipation: Non-Equilibrium Thermodynamics and its Geometric Structure will be valuable for researchers, engineers and graduate students in non-equilibrium thermodynamics and the mathematical modeling of material behavior.

This book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment has been streamlined by placing some background material in appendices. Chemical Activity is of interest not only to those in chemical thermodynamics, but also to chemical engineers working with mass transfer and its applications - for example, separation methods.

This volume looks afresh at the life and works of Lord Kelvin including his standing and relationships with Charles Darwin, T. S Huxley and the X-club, thereby throwing new light on the nineteenth-century conflict between the British energy and biology specialists. It focuses on two principal issues. Firstly, there is the contribution made by Kelvin to the formulation of the Laws of Thermodynamics, both personal and in the content of the scientific communications exchanged with other workers, such as Joule and Clausius. Secondly, there is Kelvin's impact on the wider field of science such as thermoelectricity and geology (determination of the age of the earth). Of late a number of studies and initiatives, including the Centenary celebrations of Kelvin's death and exhibits such as that of the 'Revolutionary Scientist' in the Hunterian Museum, Glasgow, have been undertaken aiding the redefinition of Kelvin's greatness and achievements. The book also raises awareness to 'improve our approach to the teaching of elementary thermodynamics by attempting to empathise with Kelvin's perspective'.It is completed by a full biography, overviews of various monuments to his memory, and short 'Stories in Pictures' on the Atlantic cable, Maxwell's Demon, the universities associated with the development of thermodynamics and the Royal Society of Edinburgh. Scientists and engineers with an interest in thermodynamics and anyone interested in the work of Lord Kelvin will find benefit in Kelvin, Thermodynamics and the Natural World.

This book concerns the most up-to-date advances in computational transport phenomena (CTP), an emerging tool for the design of gas-solid processes such as fluidized bed systems. The authors examine recent work in kinetic theory and CTP and illustrate gas-solid processes' many applications in the energy, chemical, pharmaceutical, and food industries. They also discuss the kinetic theory approach in developing constitutive equations for gas-solid flow systems and how it has advanced over the last decade as well as the possibility of obtaining innovative designs for multiphase reactors, such as those needed to capture CO2 from flue gases. Suitable as a concise reference and a textbook supplement for graduate courses, Computational Transport Phenomena of Gas-Solid Systems is ideal for practitioners in industries involved with the design and operation of processes based on fluid/particle mixtures, such as the energy, chemicals, pharmaceuticals, and food processing.

This expanded special issue of the Journal of Thermal Spray Technology features peer-reviewed and edited contributions based on papers presented at ITSC 2010.

Developments in Surface Contamination and Cleaning: Methods for Surface Cleaning, Volume 9, part of the Developments in Surface Contamination and Cleaning series provide a state-of-the-art guide to the current knowledge on the behavior of film-type and particulate surface contaminants and their associated cleaning methods. This newest volume in the series discusses methods of surface cleaning of contaminants and the resources that are needed to deal with them. Taken as a whole, the series forms a unique reference for professionals and academics working in the area of surface contamination and cleaning. A strong theme running through the series is that of surface contamination and cleaning at the micro and nano scales.

This book describes and systemizes analytical and numerical solutions for a broad range of instantaneous and continuous, stationary and moving, concentrated and distributed, 1D, 2D and 3D heat sources in semi-infinite bodies, thick plane layers, thin plates and cylinders under various boundary conditions. The analytical solutions were mainly obtained by the superimposing principle for various parts of the proposed 1D, 2D and 3D heat sources and based on the assumption that only heat conduction plays a major role in the thermal analysis of welds. Other complex effects of heat transfer in weld phenomena are incorporated in the solutions by means of various geometrical and energetic parameters of the heat source. The book is divided into 13 chapters. Chapter 1 briefly reviews various welding processes and the energy characteristics of welding heat sources, while Chapter 2 covers the main thermophysical properties of the most commonly used alloys. Chapter 3 describes the physical fundamentals of heat conduction during welding, and Chapter 4 introduces several useful methods for solving the problem of heat conduction in welding. Chapters 5 and 6 focus on the derivation of analytical solutions for many types of heat sources in semi-infinite bodies, thick plane layers, thin plates and cylinders under various boundary conditions. The heat sources can be instantaneous or continuous, stationary or moving, concentrated or distributed (1D, 2D or 3D). In Chapter 7 the temperature field under programmed heat input (pulsed power sources and weaving sources) is analyzed. In turn, Chapters 8 and 9 cover the thermal cycle, melting and solidification of the base metal. Heating and melting of filler metal are considered in Chapter 10. Chapter 11 addresses the formulation and solution of inverse heat conduction problems using zero-, first- and second-order algorithms, while Chapter 12 focuses on applying the solutions developed here to the optimization of welding conditions. In addition, case studies confirm the usefulness and feasibility of the respective solutions. Lastly, Chapter 13 demonstrates the prediction of local microstructure and mechanical properties of welded joint metals, while taking into account their thermal cycle. The book is intended for all researches, welding engineers, mechanical design engineers, research engineers and postgraduate students who deal with problems such as microstructure modeling of welds, analysis of the mechanical properties of welded metals, weldability, residual stresses and distortions, optimization of welding and allied processes (prewelding heating, cladding, thermal cutting, additive technologies, etc.). It also offers a useful reference guide for software engineers who are interested in writing application software for simulating welding processes, microstructure modeling, residual stress analysis of welds, and for robotic-welding control systems.

Thermal Stress Analysis of Composite Beams, Plates and Shells: Computational Modelling and Applications presents classic and advanced thermal stress topics in a cutting-edge review of this critical area, tackling subjects that have little coverage in existing resources. It includes discussions of complex problems, such as multi-layered cases using modern advanced computational and vibrational methods. Authors Carrera and Fazzolari begin with a review of the fundamentals of thermoelasticity and thermal stress analysis relating to advanced structures and the basic mechanics of beams, plates, and shells, making the book a self-contained reference. More challenging topics are then addressed, including anisotropic thermal stress structures, static and dynamic responses of coupled and uncoupled thermoelastic problems, thermal buckling, and post-buckling behavior of thermally loaded structures, and thermal effects on panel flutter phenomena, amongst others.

In a world of increasing population, this book explores the ways in which technological progress can provide smart energy management strategies to maximize resources. Energy is essential to the survival and development of mankind. Increased pressure on existing resources now requires wiser energy management, in addition to the discovery of new resources. Challenges such as the global trend of "cheaper", exponentially increasing demand in new geographies, and current climate change policies now call for new approaches and ways of thinking about energy use which consider the impact on all involved actors, and on nature. Energy generation and management can be made more efficient by making use of technological progress and sharing global experience in the smart use of this resource. This book presents a knowledge-based review of the past, present and future of energy usage, with mathematical, modeling, economic, technological and environmental perspectives. The ideas and experiences shared here propose wiser energy management as a system component of natural ecosystems.

This book provides detailed calculated values for the thermal radiative and thermodynamic functions of black-body radiation in finite spectral ranges. The results are presented in tabular form. The areas of thermal power generation, infrared medical diagnostics, solar power and nuclear generation, and astrophysics are included. A range of the thermal radiative and thermodynamic functions are calculated by the authors in the finite frequency/wavenumber/wavelength intervals at different temperatures. This book also contains the tables of the chromaticity coordinates and RGB parameters calculated for different color spaces (Rec.709 (HDTV), sRGB, Adobe RGB). A number of the optimization problems is formulated and solved for various thermal black-body radiative and thermodynamic functions in a finite range of frequencies.

This book presents the latest findings on the subject of combustion optimization based on computational intelligence. It covers a broad range of topics, including the modeling of coal combustion characteristics based on artificial neural networks and support vector machines. It also describes the optimization of combustion parameters using genetic algorithms or ant colony algorithms, an online coal optimization system, etc. Accordingly, the book offers a unique guide for researchers in the areas of combustion optimization, NOx emission control, energy and power engineering, and chemical engineering.

This book provides state-of-the-art computational approaches for accelerating materials discovery, synthesis, and processing using thermodynamics and kinetics. The authors deliver an overview of current practical computational tools for materials design in the field. They describe ways to integrate thermodynamics and kinetics and how the two can supplement each other.