High performance liquid chromatography (HPLC) is one of the most widespread analytical and preparative scale separation techniques used for both scientific investigations and industrial and biomedical analysis. Now in its second edition, this revised and updated version of the Handbook of HPLC examines the new advances made in this field since the publication of the benchmark first edition twelve years ago. It reports detailed information on fundamental and practical aspects of HPLC related to conventional format and sophisticated novel approaches which have been developed to address a variety of separation problems in different fields. The latest concepts New concepts presented in this edition include monolithic columns, bonded stationary phases, micro-HPLC, two-dimensional comprehensive liquid chromatography, gradient elution mode, and capillary electromigration techniques. The book also discusses LC-MS interfaces, nonlinear chromatography, displacement chromatography of peptides and proteins, field-flow fractionation, retention models for ions, and polymer HPLC. Fundamentals and applications The first section of the book explores emerging novel aspects of HPLC and related separation methods based on the differential velocity of analytes in a liquid medium under the action of either an electric field (capillary electromigration techniques) or a gravitational field (field-flow fractionation). The section focusing on applications highlights four significant areas in which HPLC is successfully employed: chiral pharmaceutical, environmental analysis, food analysis, and forensic science. Ideal for a widespread audience Explanatory figures and tables supplement the text and clarify difficult concepts. Extensive references provide gateways to more focused study. Suitable for undergraduates or new practitioners interested in improving their knowledge on the current status and future trends of HPLC, the book is also a critical resource for researchers looking for solutions to complex separation problems or those who currently use HPLC either as an analytical or a preparative scale tool.

Process engineering can potentially provide the means to develop economically viable and environmentally friendly technologies for the production of fuel ethanol. Focusing on a key tool of process engineering, Process Synthesis for Fuel Ethanol Production is a comprehensive guide to the design and analysis of the most advanced technologies for fuel ethanol production from feedstocks. It describes how process systems engineering can be applied to fuel ethanol production to achieve new levels of efficiency according to technical, economic, and environmental criteria. Drawing on the authors' more than 15 years of process engineering and ethanol research, the book first focuses on liquid biofuels, before examining the role of process synthesis in the rapid and high-tech analysis and design of complex biotechnological processes. It then describes various types of feedstocks, including sugars, starchy crops, lignocellulosic biomass, and microorganisms, as well as hydrolysis technologies, such as saccharification. The authors cover the fuel ethanol production technologies for different feedstocks, the new technological innovations based on process integration to reduce energy consumption, and the environmental issues of bioethanol production. They also discuss the technological configurations for fuel ethanol production in the industry and the possible factors affecting food security with fuel ethanol production and consumption. Supported by case studies that include calculations and discussions of results, this book uses a process engineering approach to explore the analysis and development of fuel ethanol production from different feedstocks. It shows how accurate analysis and precise design, along with responsible government policies, can lead to fair and sustainable development of energy crops worldwide.

Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Catalysis explores the recent developments in Fischer-Tropsch technology, which holds great promise in the area of renewable resources. Expert contributors explore a range of issues The book focuses on three main themes: catalyst preparation and activation, reaction mechanism, and process-related topics. A panel of expert contributors discusses synthesis of catalysts, carbon nanomaterials, nitric oxide calcinations, the influence of carbon, catalytic performance issues, chelating agents, and Cu and alkali promoters. They also explore Co/silica catalysts, thermodynamic control, the Two Alpha model, co-feeding experiments, internal diffusion limitations, Fe-LTFT selectivity, and the effect of co-fed water. Lastly, the book examines cross-flow filtration, kinetic studies, reduction of CO2 emissions, syncrude, and low-temperature water-gas shift. Attaining the maximum catalytic activity and catalyst life The themes explored in the book demonstrate that while the Fischer-Tropsch synthesis (FTS) has advanced in maturity, many issues remain concerning the preparation of increasingly active catalysts and the method of activation to attain the maximum catalytic activity and catalyst life. The book includes coverage of the structural features, their changes, and the application of increasingly sophisticated characterization techniques, shedding light on the reaction mechanism and providing a glimpse into the processes and reaction rates under realistic commercial process conditions.

Although there is a shortage of light petroleum, there is plenty of heavy petroleum rich in macromolecules available, creating an increasing interest for processes that can convert heavy oils to light oils. Process Chemistry of Petroleum Macromolecules provides the scientific basis for such processes, presenting methods to determine improvement potential. Topics include characterization, thermal kinetics, phase behavior, and separation. Revealing that the science of petroleum macromolecules is simpler and more exciting than imagined, it also discusses macromolecules that self-associate, liquid crystalline phases, reactions triggered by phase separation, and both dispersed and dissolved solutes.

Many oil refineries employ hydroprocessing for removing sulfur and other impurities from petroleum feedstocks. Capable of handling heavier feedstocks than other refining techniques, hydroprocessing enables refineries to produce higher quality products from unconventional - and formerly wasted - sources. Hydroprocessing of Heavy Oils and Residua illustrates how to obtain maximum yields of high-value products from heavy oils and residue using hydroprocessing technologies. While most resources on hydroprocessing concentrate ongas oil and lower boiling products, this book details the chemistry involved and the process modifications required for the hydroprocessing of heavy crude oils and residua. Emphasizing the use of effective catalysts to ensure cleaner and more efficient industrial fuel processes, the book presents key principles of heterogeneous catalyst preparation, catalyst loading, and reactor systems. It explains how to evaluate and account for catalysts, reactor type, process variables, feedstock type, and feedstock composition in the design of hydroprocessing operations. The text concludes with examples of commercial processes and discusses methods of hydrogen production. To meet the growing demand for transportation fuels and fuel oil, modern oil refineries must find ways to produce high quality fuel products from increasingly heavy feedstocks. Hydroprocessing of Heavy Oils and Residua contains the fundamental concepts, technologies, and process modifications refineries need to adapt current hydroprocessing technologies for processing heavier feedstocks.

Predictive and Optimised Life-Cycle Management sets out methodologies to meet the demands of the current trend towards sustainable civil engineering and building. Encompassing all aspects of construction practice, from design through to demolition and the recycling of materials, Sarja provides tools for optimal property-value protection, including a description of an integrated and predictive Life-Cycle Maintenance and Management Planning System (LMS), which employs a wide range of techniques. Clear and practical, this guide provides effective methodology required to change a reactive system of management to a predictive one, which will benefit practitioners and students involved in construction, from the architect to local and government authorities; from design engineers to facility managers.

In the past two decades, new modeling efforts have gradually incorporated more molecular and structural detail in response to environmental and technical interests. Molecular Modeling in Heavy Hydrocarbon Conversions introduces a systematic molecule-based modeling approach with a system of chemical engineering software tools that can automate the entire model building, solution, and optimization process. Part I shows how chemical engineering principles provide a rigorous framework for the building, solution, and optimization of detailed kinetic models for delivery to process chemists and engineers. Part II presents illustrative examples that apply this approach to the development of kinetic models for complex process chemistries, such as heavy naphtha reforming and gas oil hydroprocessing. Molecular Modeling in Heavy Hydrocarbon Conversions develops the key tools and best possible approaches that process chemists and engineers can use to focus on the process chemistry and reaction kinetics for performing work that is repetitive or prone to human-error accurately and quickly.

Catalytic Naphtha Reforming, Second Edition presents modern, crystal-clear explanations of every aspect of this critical process for generating high-octane reformate products for gasoline blending and production of benzene, toluene, and xylene (BTX) aromatics. The book details the chemistry of naphtha reforming, the preparation and characterization of catalysts, and the very latest commercial technologies and industrial applications. With more than 300 tables and figures, it addresses the development of new catalysts and revamp process improvements propelled by regulations on sulfur, benzene, and oxygenate content in gasoline and refinery pressure to maximize utilization of existing assets.

Incorporates Worked-Out Real-World Problems Steam Generators and Waste Heat Boilers: For Process and Plant Engineers focuses on the thermal design and performance aspects of steam generators, HRSGs and fire tube, water tube waste heat boilers including air heaters, and condensing economizers. Over 120 real-life problems are fully worked out which will help plant engineers in evaluating new boilers or making modifications to existing boiler components without assistance from boiler suppliers. The book examines recent trends and developments in boiler design and technology and presents novel ideas for improving boiler efficiency and lowering gas pressure drop. It helps plant engineers understand and evaluate the performance of steam generators and waste heat boilers at any load. Learn How to Independently Evaluate the Thermal Performance of Boilers and Their Components This book begins with basic combustion and boiler efficiency calculations. It then moves on to estimation of furnace exit gas temperature (FEGT), furnace duty, view factors, heat flux, and boiler circulation calculations. It also describes trends in large steam generator designs such as multiple-module; elevated drum design types of boilers such as D, O, and A; and forced circulation steam generators. It illustrates various options to improve boiler efficiency and lower operating costs. The author addresses the importance of flue gas analysis, fire tube versus water tube boilers used in chemical plants, and refineries. In addition, he describes cogeneration systems; heat recovery in sulfur plants, hydrogen plants, and cement plants; and the effect of fouling factor on performance. The book also explains HRSG simulation process and illustrates calculations for complete performance evaluation of boilers and their components. Helps plant engineers make independent evaluations of thermal performance of boilers before purchasing them Provides numerous examples on boiler thermal performance calculations that help plant engineers develop programming codes with ease Follows the metric and SI system, and British units are shown in parentheses wherever possible Includes calculation procedures for the basic sizing and performance evaluation of a complete steam generator or waste heat boiler system and their components with appendices outlining simplified procedures for estimation of heat transfer coefficients Steam Generators and Waste Heat Boilers: For Process and Plant Engineers serves as a source book for plant engineers, consultants, and boiler designers.

Fuel Production with Heterogeneous Catalysis presents the groundbreaking discoveries, recent developments, and future perspectives of one of the most important areas of renewable energy research-the heterogeneous catalytic production of fuels. Comprised of chapters authored by leading experts in the field, this authoritative text: Focuses primarily on the state-of-the-art catalysts and catalytic processes anticipated to play a pivotal role in the production of fuels Describes production of fuels from renewable sources using environmentally friendly technologies Exposes the advantages and disadvantages of each production process Suggests solutions to minimize the impact of fuel transportation Conveys the importance of catalysis for the sustainable production of fuels Fuel Production with Heterogeneous Catalysis delivers a comprehensive overview of the current state of the art of the heterogeneous catalytic production of fuels, providing reaction mechanism schemes, engineering solutions, valuable industry insights, and more.

This book mainly investigates the cooperative optimal control of hybrid energy system, it presents security control, multi-objective optimization, distributed optimization and distributed control approaches for tackling with security, economic and stability problem of the hybrid energy system. It aims to solve some challenging problems including security issue, economic cost or benefits from both power generation side and load demand side, and coordination among different power generators. The methods proposed in this book is novel and attractive, it consists of the hierarchical optimal control strategy for the security issue, multi-objective optimization for both economic and emission issue, and distributed optimal control for coordination among power generators. Readers can learn novel methods or technique for tackling with the security issue, multiple-objective problem, and distributed coordination problem. It also may inspire readers to improve some drawbacks of existing alternatives. Some fundamental knowledge prepared to read this book includes basic principles of the multi-agents system, robust optimization, Pareto-dominance optimization, and background of electrical engineering and renewable energy.

The book provides highly specialized researchers and practitioners with a major contribution to mathematical models' developments for energy systems. First, dynamic process simulation models based on mixture flow and two-fluid models are developed for combined-cycle power plants, pulverised coal-fired power plants, concentrated solar power plant and municipal waste incineration. Operation data, obtained from different power stations, are used to investigate the capability of dynamic models to predict the behaviour of real processes and to analyse the influence of modeling assumptions on simulation results. Then, a computational fluid dynamics (CFD) simulation programme, so-called DEMEST, is developed. Here, the fluid-solid, particle-particle and particle-wall interactions are modeled by tracking all individual particles. To this purpose, the deterministic Euler-Lagrange/Discrete Element Method (DEM) is applied and further improved. An emphasis is given to the determination of inter-phase values, such as volumetric void fraction, momentum and heat transfers, using a new procedure known as the offset-method and to the particle-grid method allowing the refinement of the grid resolution independently from particle size. Model validation is described in detail. Moreover, thermochemical reaction models for solid fuel combustion are developed based on quasi-single-phase, two-fluid and Euler-Lagrange/MP-PIC models. Measurements obtained from actual power plants are used for validation and comparison of the developed numerical models.

This text examines the thermal and catalytic processes involved in the refining of petroleum including visbreaking, coking, pyrolysis, catalytic cracking, oligomerization, alkylation, hydrofining, hydroisomerization, hydrocracking, and catalytic reforming. It analyzes the thermodynamics, reaction mechanisms, and kinetics of each process, as well as the effects of operating conditions and reactor design on process performance and product quality. This is a valuable resource for chemists who wish to improve their knowledge of some of the real world issues that must be addressed in hydrocarbon conversion. Topics include processes on metallic catalysts, processes using bifunctional catalysts, and catalytic reforming.

This book provides a wealth of information and a critically required framework for sustainable automobile policy development in major Asian countries. It also gives wide-ranging policy options, ranging from technological to institutional solutions to automobile emission problems, based on empirical case studies and comparative policy and regulatory analysis. It is a useful reference with valuable insights on how rapidly changing economies are adopting their policy and regulatory structures to cope with the progressively severe environmental impacts of automobile increase.

This book provides a comprehensive discussion of the public policy and management issues that are encountered in the regulation of infrastructure and utilities. Drawing from theoretical arguments and several case studies, the book is divided into three parts, namely devising regulation, installing regulation, and making regulation work. The first part covers theories of regulation, regulatory policies, strategies and tools, and regulatory reforms. The second part deals with the politics of regulation and regulatory capacity. The third part discusses regulatory commitment and investments, the performance of regulated industries, and the design of regulatory systems. Case studies pay attention to various sectors (including water, electricity, telecommunications, highways, railways, district heating, and airports) from countries in every region of the world. ; ;

Managing a successful transition of the current energy supply system to less carbon emitting options, ensuring a safe and secure supply during the whole process and in the long term, is one of the largest challenges of our time. Various approaches and first implementations show that it is not only technological issue, but also a matter of societal acceptance and acceptability, considering basic ethic values of the society. The main foci of the book are, thus, to develop an understanding about the specific challenges of the scientific policy advice in the area, to explore typical current approaches for the analysis of future energy systems and to develop criteria for the quality assessment and guidelines for the improvement of such studies. The book provides assistance to the interpretation of existing studies and guidelines for setting up and carrying out new analyses as well as for communicating and applying the results. Thereby, it aims to support the involved actors such as the respective scientific experts and researchers as well as decision makers, energy suppliers, stakeholders and the interested public in designing procedures for a successful transition process. The study elaborates consistent interdisciplinary advice as contribution for realising a continuously safe and secure, long-term viable energy supply in spite of diverse interests, multi-level responsibilities, multi-dimensional processes, large uncertainties and lack of knowledge about future developments.

This volume covers the fundamentals of boiler systems and gathers hard-to-find facts and observations for designing, constructing and operating industrial power plants in the United States and overseas. It contains formulas and spreadsheets outlining combustion points of natural gas, oil and solid fuel beds. It also includes a boiler operator's training guide, maintenance examples, and a checklist for troubleshooting.

This edited monograph presents a selection of research contributions on eco-factories of the future. The topical focus lies on cutting-edge solutions from academia and industry that enable and support companies in their efforts towards sustainable manufacturing. The authors provide an overview over recent developments, aiming at a comprehensive understanding of eco- and cost-efficient manufacturing from machine to factory level. The solutions contributed by leading research institutions and companies have been mostly implemented and evaluated in industrial pilot projects across Europe. The methodological approaches cover topics such as factory planning, manufacturing simulation, energy management as well as life cycle evaluation. The target audience comprises industry experts and decision makers as well as researchers in the field of sustainable manufacturing.

Biomass and Carbon Fuels in Metallurgy presents contemporary and new insights into the use of carbonaceous (Biomass) fuels in the metallurgical sector. The authors describe application of these fuels in different technological processes to produce pig iron, steel and ferroalloys. Emphasis is placed on biomass and its metallurgical utilization. Coverage includes the specification of fuels, their classification and the characteristics of their basic properties. The use of carbonaceous fuels in the production of various kinds of agglomerates (ferriferous, manganese and metalized) is also covered. Key Features: Provides a comprehensive view of carbonaceous fuels in various metallurgy processes Details experiments conducted on the use of traditional and alternative (biomass) carbonaceous fuels for the production of agglomerates. Demonstrates that the energy potential of biomass can also be successfully used in pyrometallurgical processes Describes applications of biomass-based fuels in different technological processes for the production of pig iron, steel and ferroalloys. Coverage includes the specification of fuels, their classification and the characteristics of their basic properties.

The first English-language book which reviews and summarizes worldwide research advances in alkali-activated cements and concrete. Essential topics include: raw materials and their properties for the production of the two new types of binder the hydration and microstructure development of alkali-activated slag cements the mechanical properties and durability of alkali-activated slag cement and concrete other various cementing systems and their applications related standards and specifications. This respected team of authors has produced an important piece of research that will be of great interest to professionals and academics alike, enabling the production of more durable and environmentally sensitive materials.

This handbook presents the outlook for future production and consumption of MTBE and other oxygenates worldwide and studies new catalytic systems and modern methods for the synthesis and commercial production of methyl tertiary-butyl ether (MTBE) and related ethers. The scope of this sophisticated guide extends from process chemistry fundamentals and reaction kinetics to environmental remediation technologies and industry responses to conflicting calls for MTBE phase-out and higher-octane products. Well-illustrated with over 200 figures and tables, this authoritative Handbook details bioremediation, air stripping, and oxidation and adsorption processes for MTBE removal.

Discusses all the major aspects of automotive and engine lubrication - presenting state-of-the-art advances in the field from both research and industrial perspectives. This book should be of interest to mechanical, lubrication and automotive engineers, automotive and machinery designers as well as undergraduate and graduate students in these fields.

"With the appearance and fast evolution of high performance materials, mechanical, chemical and process engineers cannot perform effectively without fluid processing knowledge. The purpose of this book is to explore the systematic application of basic engineering principles to fluid flows that may occur in fluid processing and related activities. In Viscous Fluid Flow, the authors develop and rationalize the mathematics behind the study of fluid mechanics and examine the flows of Newtonian fluids. Although the material deals with Newtonian fluids, the concepts can be easily generalized to non-Newtonian fluid mechanics. The book contains many examples. Each chapter is accompanied by problems where the chapter theory can be applied to produce characteristic results. Fluid mechanics is a fundamental and essential element of advanced research, even for those working in different areas, because the principles, the equations, the analytical, computational and experimental means, and the purpose are common.

As concern grows over environmental issues and light pollution, this book satisfies a need for a straightforward and accessible guide to the use, design and installation of outdoor lighting. This all-inclusive guide to exterior lighting from the Institution of Lighting Engineers, recognized as the pre-eminent professional source in the UK for authoritative guidance on exterior lighting, provides a comprehensive source of information and advice on all forms of exterior lighting, from floodlighting, buildings and road lighting to elaborate Christmas decorations. Useful to practitioners and non-experts alike, specialists will value the dependable detail on standards and related design, installation and maintenance problems, whilst general professionals can find extensive practical guidance on safety issues, the lighting of hazardous areas and avoiding potential difficulties.