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Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry
Technology and Development of Self-Reinforced Polymer Composites,
by Ben Alcock und Ton Peijs; Recent Advances in High-Temperature
Fractionation of Polyolefins, by Harald Pasch, Muhammad Imran Malik
und Tibor Macko ; Antibacterial Peptidomimetics: Polymeric
Synthetic Mimics of Antimicrobial Peptides, by Karen Lienkamp,
Ahmad E. Madkour und Gregory N. Tew; Collagen in Human Tissues:
Structure, Function, and Biomedical Implications from a Tissue
Engineering Perspective, by Molamma P. Prabhakaran;
Iptycenes Chemistry: From Synthesis to Applications provides a
comprehensive overview of the development of iptycene chemistry in
the past seventy years. This book covers: (1) the basic
nomenclature and general properties of iptycenes and their
derivatives; (2) the synthesis and functionalization reactions of
triptycenes, pentiptycenes, higher iptycenes, heterotriptycenes,
and homotriptycenes; (3) the methods for the preparation of
iptycene-based polymers with different types; and (4) the
applications of iptycenes and their derivatives in molecular
machines, materials science, host-guest chemistry, self-assembly,
coordination chemistry, physical organic chemistry, medicinal
chemistry, and so on. Consequently, such a book is not only helpful
to researchers working in iptycene chemistry, but can also
facilitate future research in wide areas.
The Ninth Biennial Polymer Symposium, sponsored by the Division of
Polymer Chemistry of the American Chemical Society, was convened
during November 18-22, 1978 at Key Biscayne, Florida. The symposium
also marks the occasion when the Second Division of Polymer
Chemistry Award was presented to Professor C. S. Marvel for his
outstanding achievements in polymer chemistry. The proceedings of
this Symposium are recorded in this volume. Carl Shipp Marvel, more
popularly known as Speed Marvel, was born in Waynesville, Illinois
in 1894. He received his A.B. and M.S. degrees at Illinois Wesleyan
University, and M.A. and Ph.D. degrees at the University of
Illinois. After having completed his graduate education, Professor
Harvel remained at the University as a member of the Chem istry
faculty. He "retired" from Illinois in 1961, and moved to the
University of Arizona where he continued his research in polymer
chemistry. Out of the more than 500 publications, over 100 were
from Arizona during his active retirement. Speed has so far trained
176 Ph.D. students and 128 postdoctoral fellows, and inspired
countless young chemists to the science of macromolecules. No doubt
these numbers will increase along with his scientific productivity.
Professor Harvel has been honored on numerous ocasions prior to
receiving the Division of Polymer Chemistry Award."
This volume chronicles the proceedings of the Third Symposium on
Particles on Surfaces : Detection, Adhesion and Removal held as a
part of the 21st Annual Meeting of the Fine Particle Society in San
Diego , California, August 21 - 25 , 1990 . The first two symposia
i n t h i s series were held in 1986 and 1988 , respectively, and
have been properly l documented ,2. Li ke its antecedent s the
Third symposium was very well received, and the continuing success
of these symposia reinforced our earlier belief that regular
symposia on the topic of particles on surfaces were very much
needed. Concomitantly, the fourth symposium in this series is
planned in Las Vegas , July 13-17 , 199 2 . l As pointed out in the
Preface to the earlier two volumes ,2, the topic of particles on
surfaces is of tremendous interest and concern in a wide spectrum
of technological areas . The objectives of the Third symposium were
es s ent i a l ly the same as those of the earlier two and our
intent her e was to provide an update on the research and
development activities in the world of particles on surfaces .
Apropos , there has been a deliberate attempt every time to s eek
out new people to present their research results and we have been
very succes s f ul in this mission.
This volume contains the proceedings of the Europhysics Conference
on Gels, held in Balatonszeplak, Hungary, in September 1995.
Topics of the contributions cover fundamentals and applications of
gels formed from inorganic and organic polymers, colloidal
particles and surfactant systems, new powerful methods such as
scattering techniques, rheology, atomic microscopy, swelling
pressure and mechanical measurements, gels with sensitivity to
changes in chemical and physical environment, novel technical and
biomedical applications, computer simulation and new theoretical
approaches.
Thisbook continuesthe tradition ofproviding the scientificcommunity
with infonnation on some ofthe most important advances reported at
aseries ofconferences on Frontiers ofPolymers and Advanced
Materials. The particular meeting covered in this proceedings
volume was held in KualaLumpur, Malaysia, from January 16th through
the 20th, 1995. It follows earlier proceedings, also published by
Plenum, for a conference in New Delhi in 1991, and another in
Jakarta in 1993. All of these conferences focused on the most
recent and important advances in a wide range of carefully chosen
subject areas dealing with advanced materials and new technologies.
TheMalaysiaConference was organized by the Malaysian
MinistryofScience, Technology and Environment; Malaysian
Industry-Government Group for Higher Technology; Standards and
Industrial Research Institute ofMalaysia; State University ofNew
York at Buffalo; and Malaysian Plastic Manufacturers Association.
The stated goals ofthe conference were: To highlight advances and
new findings in Polymers and Advanced Materials To bring together
leading international scientists, engineers and top level
industrial managementfor discussionsonthe CUTTent status ofadvanced
materials, new technologies and industrial opportunities To foster
global communication in polymers and advanced materials technology.
Tbe
Malaysianconferencecoveredbytheseproceedingsemphasized"composites
and blends," ''high-performance materials," ''materials for
photonics," ''materials for electronics," ''biomaterials'',
"recycling of materials," "sol-gel and processed materials,"
"advanced materials from natural products," and ''multifunctional
and smart materials." There was also a separate symposium on
''business opportunities.""
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II:
State-of-the-art and Perspectives provides a critical review of the
state-of-the-art developments in industrially relevant processes
connected to efficient and selective olefin upgrading. Specific
attention is devoted to catalysts containing imine- and amine-based
ligands.
All the chapters in this book have been designed to provide a
systematic account of the vast amount of information available for
this type of catalyst as well as to highlight the factors that
ultimately control the catalyst's performance and productivity. A
comprehensive panorama of catalyst precursors is presented,
spanning from group 10 -diimine complexes and iron and cobalt
2,6-bis(imino)pyridine derivatives, to vanadium, chromium,
titanium, zirconium and lanthanide complexes supported by
nitrogen-containing ligands. The authors of this collective work
are currently involved in the development of imine-based catalysts
for efficient and selective olefin upgrading and the majority of
them have dedicated most of their scientific career to this
important field. In writing this book, their major goal is to
transfer as many ideas and experiences as possible to the global
audience of scientists engaged in this area of research."
Multiscale Fibrous Scaffolds in Regenerative Medicine, by Sowmya
Srinivasan, R. Jayakumar, K. P. Chennazhi, Erica J. Levorson,
Antonios G. Mikos and Shantikumar V. Nair; Stem Cells and
Nanostructures for Advanced Tissue Regeneration, by Molamma P.
Prabhakaran, J. Venugopal, Laleh Ghasemi-Mobarakeh, Dan Kai Guorui
Jin and Seeram Ramakrishna; Creating Electrospun Nanofiber-Based
Biomimetic Scaffolds for Bone Regeneration, by Eleni Katsanevakis,
Xuejun Wen and Ning Zhang; Synthetic/Biopolymer Nanofibrous
Composites as Dynamic Tissue Engineering Scaffolds, by J. A. Kluge
and R. L. Mauck; Electrospun Fibers as Substrates for Peripheral
Nerve Regeneration, by Jorg Mey, Gary Brook, Dorothee Hodde and
Andreas Kriebel; Highly Aligned Polymer Nanofiber Structures:
Fabrication and Applications in Tissue Engineering, by Vince
Beachley, Eleni Katsanevakis, Ning Zhang, Xuejun Wen;
Electrospinning of Biocompatible Polymers and Their Potentials in
Biomedical Applications, by Pitt Supaphol, Orawan Suwantong,
Pakakrong Sangsanoh, Sowmya Srinivasan, Rangasamy Jayakumar and
Shantikumar V. Nair; Electrospun Nanofibrous Scaffolds-Current
Status and Prospects in Drug Delivery, by M. Prabaharan, R.
Jayakumar and S. V. Nair.; Biomedical Applications of
Polymer/Silver Composite Nanofibers, by R. Jayakumar, M.
Prabaharan, K. T. Shalumon, K. P. Chennazhi and S. V. Nair.-"
This volume includes a number of selected papers of the
international conference "Colloidal Aspects of Lipids," held in
June 1997 at Lund, Sweden. In conjunction with the conference
Professor Kare Larsson, well-known and respected as a leading
scientist in this field of food technology during the recent
decades, was honored.
I used the opportunity of this edition to correct some minor
mistakes and clarify, wherever it possible, exposition of the
theory in comparison with the previous edition of this book
(Kluwer, Dordrechtet cet, 2000). It provokes - largement of the
book, though I tried to present the modern theory of thermic motion
of long macromolecules in compact form. I have tried to accumulate
the common heritage and to take into account di?erent approaches in
the theory of dynamics of linear polymers, at least, to understand
and make clear the importance of various ideas for explanation of
relaxation phenomena in linear polymers, to present recent
development in the ?eld. The theory of non-equilibrium phenomena in
polymer systems is based on the fundamental principles of
statistical physics. However, the peculiarities of
thestructureandthebehaviourofthesystemsnecessitatetheimplementation
of special methods and heuristic models that are di?erent from
those for gases and solids, so that polymer dynamics has appeared
to be a special branch of physicsnow.
Themonographcontainsdiscussionsofthemainprinciplesofthe theoryof
slowrelaxationphenomena in linearpolymers, elaborated inthe last
decades. The basic model of a macromolecule, which allows us a
consistent explanation of di?erent relaxation phenomena (di?usion,
neutron scattering, viscoelasticity, optical birefringence),
remains to be a coarse-grained or be- spring model, considered in
di?erent environments: viscous, to describe the
behaviourofdilutesolutions,orviscoelastic,todescribethebehaviourofboth
weakly and strongly entangled systems.
The role of high pressure experiments in the discovery of supercon
ducting materials with a T. above liquid nitrogen temperature has
demon strated the importance of such experiments. The same role
holds true in the tailoring of materials for optoelectronic
devices. In addition, much progress has been made recently in the
search for metallic hydro gen, and the application of high pressure
in polymer research has brought forth interesting results. These
facts together with the suc cess of previous small size meetings
(such as the "First International Conference on the Physics of
Solids at High Pressure", held in 1965 in Tucson, Arizona, U. S. A.
; "High Pressure and Low Temperature Physics", held in 1977 in
Cleveland, Ohio, U. S. A. ; and "Physics of Solids Under High
Pressure", held in 1981 in bad Honnef, Germany), motivated us to
organize a workshop with emphasis on the newest results and trends
in these fields of high pressure research. Furthermore, it was
intended to mix experienced and young scien tists to realize an
idea best expressed in a letter by Prof. Weinstein: "I think it is
an excellent idea. I have often felt that the number of excellent
young researchers in the high pressure field need an opportu nity
to put forward their work with due recognition. " Thanks to the
support of the key speakers, we were able to achieve this goal and
had more than 50\ young participants.
The art and science of macromolecular architecture is based on
synthesis, analysis, processing, and evaluation of physical
properties of polymers. The growing specificity of available
synthetic methods and the increasing refinement of analytical and
physical analysis are gradually providing a deeper insight into
structure-property relationships of polymers, upon which many
applications can be based. This book deals with recent methods for
polymer synthesis. Those that lead to specific structures have been
selected especially. Background, mechanism scope and limitations,
and illustrative procedures are given for each method. With this
layout the editor hopes that the book will provide a practical
guideline, for the synthetic polymer chemist in industry or at a
university graduate school, on how to apply the methods in the
design of new polymer structures. The editor is grateful to the
authors not only for their contributions containing interesting new
developments in polymer synthesis, but also for the way they have
fitted their text into the general framework of the book. The
elegant chemistry described in the following chapters will, it is
hoped, inspire more organic chemists to apply their skills to
polymer synthesis, where the beauty of organic chemistry in terms
of structural control and reactivity may be even more apparent than
in the low molecular field.
Many chemical processes that are important to society take place at
boundaries between phases. Understanding these processes is
critical in order for them to be subject to human control. The
building of theoretical or computational models of them puts them
into a theoretical framework in terms of which the behavior of the
system can be understood on a detailed level. Theoretical and
computational models are often capable of giving descriptions of
interfacial phenomena that are more detailed, on a molecular level,
than can be obtained through experimental observation. Advances in
computer hardware have also made possible the treatment of larger
and chemically more interesting systems. The study of interfacial
phenomena is a multi-disciplinary endeavor which requires
collaboration and communication among researchers in different
fields and across different types of institutions. Because there
are many important problems in this field much effort is being
expended to understand these processes by industrial laboratories
as well as by groups at universities. Our conference titled
"Theoretical and Computational Approaches to Interface Phenomena"
held at South Dakota State University, August 2-4, 1993 brought
together over thirty scientists from industry and academia and
three countries in the western hemisphere to discuss the modeling
of interfacial phenomena.
The idea for this book came from discussions among participants in
a symposium on biotechnical applications at the "Pacifichem 89"
meeting in Honolulu. It was the majority opinion of this group that
a volume dedicated to biotechnical and biomedical applications of
PEG chemistry would enhance research and development in this area.
Though the book was conceived at the Honolulu meeting, it is not a
proceedings of this symposium. Several groups who did not
participate in this meeting are repre sented in the book, and the
book incorporates much work done after the meeting. The book does
not include contributions in all related areas to which PEG
chemistry has been applied. Several invited researchers declined to
parti.:ipate, and there is not enough space in this single volume
to properly cover all submissions. Chapter I-an overview of the
topic-discusses in brief applications not given detailed coverage
in specifically devoted chapters. The following topics are covered:
introduction to and fundamental properties of PEG and derivatives
in Chapters 1-3; separations using aqueous polymer two-phase
partitioning in Chapters 4-6; PEG-proteins as catalysts in
biotechnical applications in Chapters 7 and 8; biomedical
applications of PEG-proteins in Chapters 9-13; PEG modified
surfaces for a variety of biomedical and biotechnical applications
in Chapters 14-20; and synthesis of new PEG derivatives in Chapters
21 and 22.
Polymers in Solution was written for scientists and engineers who
have serious research interests in newer methods for
characterization of polymer solutions, but who are not seasoned
experts in the theoretical and experimental aspects of polymer
science. In particular, it is assumed that the reader is not
familiar with the development of theoretical notions in
conformational statistics and the dynamics of chainlike molecules;
how these two seemingly diverse theoretical topics are related; and
the role played by polymer-solvent interactions. Chapter 1 thus
presents background material that introduces most of the essential
concepts, including some of the mathematical apparatus most
commonly used in these areas of theory. This introduction is
followed by five chapters that are more closely related to
particular experimental techniques. These chapters introduce
further theoretical notions as needed. Three of the chapters
present con siderable detail on the experimental methods, while two
other chapters deal more with the interpretation of experimental
results in terms of current theories. Although neutron scattering
has become an almost standard technique for the study of
conformational properties of macromolecules in the solid state,
there has been less emphasis on its application for
characterization of polymer molecules in solution. Chapter 4 covers
this growing area of application."
The chapters in this collection are from papers which were
presented at a symposium on solid-state NMR of polymers. A two-part
program on available NMR techniques applicable to solid polymer
analysis was presented at the 3rd Chemical Congress of North
American held in Toronto, Ontario, June 5-10,1988. The program was
sponsored by the Division of Polymer Chemistry with support
provided by the Division, its Industrial Sponsors, and the Donors
of the Petroleum Research Fund administered by the American
Chemical Society. Co-organizers included Professor Colin Fyfe of
the University of British Columbia (Vancouver, Canada), Professor
Hans Spiess of the Max Planck Institut fur Polymerforschung (Mainz,
West Germany), and myself. The full-day tutorial, which was free to
registered attendees, covered the range of topics. The purpose of
the tutorial was to provide a basic introduction to the field so
that newcomers to its present and future applications could develop
sufficient understanding to learn effectively from the subsequent
symposium. The first talk attempted to give listeners a feel for
the way a novice spectroscopist can learn to use the various NMR
techniques to explore his own areas of interest. Simple experiments
can provide unique information about solid polymers that can be
useful in interpreting synthetic results and in relating
solid-state conformation, morphology and molecular motion to
physical properties.
This book brings together selected contributions both on the
fundamental information on the physics and chemistry of these
materials, new physical ideas and decisive experiments. It
constitutes both an insightful treatise and a handy reference for
specialists and graduate students working in solid state physics
and chemistry, material science and related fields.
This volume includes 35 contributions to the 24th Conference of the
European Colloid and Interface Society which took place in
September 2010 in Prague. The contributions from leading scientists
cover a broad spectrum of the following topics: * Self-assembling,
Stimuli-responsive and Hierarchically Organized Systems * Colloid,
Polymer and Polyelectrolyte Solutions; Concentrated Systems and
Gels * Thin Films, Interfaces and Surfaces; Wetting Phenomena *
Novel Nano-to-Mesostructured Functional Materials * Biologically
Important and Bioinspired Systems; Pharmaceutical and Medical
Applications
The development of "tailormade" electrode surfaces using
electroactive polymer films has been one of the most active and
exciting areas of electrochemistry over the last 15 years. The
properties of these materials have been examined by a wide range of
scientists from a variety of perspectives, and now electroactive
polymer research is considered to be a reasonably mature area of
research endeavor. Much is now understood about the fundamental
mechanism of conduction in these materials. A wide range of
electrochemical techniques may be used to probe the conductivity
processes in these materials, and more recently, a number of in
situ spectroscopic techniques have been used to further elucidate
the structure of these materials. The in situ spectroscopies and
allied techniques have also been used to obtain correlations
between structure and redox activity. The applications found for
electroactive polymers are many and varied, and range from thin
film amperometric chemical and biological sensors, electrocatalytic
systems, drug delivery devices, and advanced battery systems
through to molecular electronic devices. The research literature on
electroactive polymers is truly enormous and can daunt even the
most hardened researcher. The vast quantity of material reported in
the literature can also intimidate beginning graduate students.
Hence the present book. The original idea for this book arose as a
result of a series of lectures on chemically modified eiectrodes
and electroactive polymers given by the writer to final-year
undergraduates at Trinity College Dublin.
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