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Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry
Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Gunter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya
A molecular view on the fundamental issues in polymer physics is provided with an aim at students in chemistry, chemical engineering, condensed matter physics and material science courses. An updated translation by the author, a renowned Chinese chemist, it has been proven to be an effective source of learning for many years. Up-to-date developments are reflected throughout the work in this concise presentation of the topic. The author aims at presenting the subject in an efficient manner, which makes this particularly suitable for teaching polymer physics in settings where time is limited, without having to sacrifice the extensive scope that this topic demands.
1 V.O. Aseyev, H. Tenhu, F. Winnik: Temperature Dependence of the Colloidal Stability of Neutral Amphiphilic Polymers in Water.- 2 V.I. Lozinsky: Approaches to Chemical Synthesis of Protein-Like Copolymers.- 3 S.I. Kuchanov, A.R. Khokhlov: Role of Physical Factors in the Processes of Obtaining of Copolymers.- 4 A.Y. Grosberg, A.R. Khokhlov: After-Action of the Ideas of I.M. Lifshitz in Polymer and Biopolymer Physics.-
The effects of various space environment factors like atomic oxygen, vacuum ultraviolet radiation, charging, micrometeoroids, meteoroid showers, etc. on materials and structures in various orbits are discussed. In addition the ways to prevent these effects or reduce them through protection by coatings or modification of affected surfaces are considered in the book. The discussions on development of predictive models of material erosion that will allow the materials engineers and designers of future spacecraft to evaluate materials' behaviour is continued from the past meetings.
This is a book for people who love mechanics of composite materials and ? MATLAB . We will use the popular computer package MATLAB as a matrix calculator for doing the numerical calculations needed in mechanics of c- posite materials. In particular, the steps of the mechanical calculations will be emphasized in this book. The reader will not ?nd ready-made MATLAB programs for use as black boxes. Instead step-by-step solutions of composite material mechanics problems are examined in detail using MATLAB. All the problems in the book assume linear elastic behavior in structural mechanics. The emphasis is not on mass computations or programming, but rather on learning the composite material mechanics computations and understanding of the underlying concepts. The basic aspects of the mechanics of ?ber-reinforced composite materials are covered in this book. This includes lamina analysis in both the local and global coordinate systems, laminate analysis, and failure theories of a lamina.
The text features experimental investigations which use a variety of modern methods and theoretical modeling of surface structures and physicochemical processes which occur at solid surfaces. Nanomaterials and Supramolecular Structures: Physics, Chemistry, and Applications is intended for specialists experienced in the fields of Nanochemistry, Nanophysics, Surface Chemistry (and Physics), synthesis of new nanostructural functional materials and their practical applications. It will also prove useful to students, post-graduates, researchers, and lecturers.
This is the second edition of Melt Rheology and its Role in Plastics Processing, although the title has changed to reflect its broadened scope. Advances in the recent years in rheometer technology and polymer science have greatly enhanced the usefulness of rheology in the plastics industry. It is now possible to design polymers having specific molecular structures and to predict the flow properties of melts having those structures. In addition, rheological properties now provide more precise information about molecular structure. This book provides all the information that is needed for the intelligent application of rheology in the development of new polymers, the determination of molecular structure and the correlation of processability with laboratory test data. Theory and equations are limited to what is essential for the use of rheology in the characterization of polymers, the development of new plastics materials and the prediction of plastics processing behavior. The emphasis is on information that will be of direct use to practitioners. Extensive references are provided for those wishing to pursue certain issues in greater depth. While the primary audience is applied polymer scientists and plastics engineers, the book will also be of use to postgraduate students in polymer science and engineering and as a text for a graduate course.
This thesis focuses on porous monolithic materials that are not in the forms of particles, fibers, or films. In particular, the synthetic strategy of porous monolithic materials via the sol-gel method accompanied by phase separation, which is characterized as the non-templating method for tailoring well-defined macropores, is described from the basics to actual synthesis. Porous materials are attracting more and more attention in various fields such as electronics, energy storage, catalysis, sensing, adsorbents, biomedical science, and separation science. To date, many efforts have been made to synthesize porous materials in various chemical compositions-organics, inorganics including metals, glasses and ceramics, and organic-inorganic hybrids. Also demonstrated in this thesis are the potential applications of synthesized porous monolithic materials to separation media as well as to electrodes for electric double-layer capacitors (EDLCs) and Li-ion batteries (LIBs). This work is ideal for graduate students in materials science and is also useful to engineers or scientists seeking basic knowledge of porous monolithic materials.
"Polymeric and Nanostructured Macromolecules" presents the recent advances made in the synthesis, characterization, and applications of polymeric macromolecules. This book provides an excellent overview of the recent breakthroughs in the science of macromolecules, with an emphasis on nanostructured macromolecules and the perspectives that these versatile materials offer to different fields such as optoelectronics and biotechnology. Advanced undergraduate, graduate students and researchers alike will find the topics concerning physical and chemical properties of advanced macromolecular materials of great interest.
This book is divided into chapters covering instrumentation, sedimentation velocity runs, density gradient runs, application examples and future developments. In particular, the detailed application chapter demonstrates the versatility and power of AUC by means of many interesting and important industrial examples. Thus the book concentrates on practical aspects rather than details of centrifugation theory.
Dielectric Polymer Nanocomposites provides the first in-depth discussion of nano-dielectrics, an emerging and fast moving topic in electrical insulation. The text begins with an overview of the background, principles and promise of nanodielectrics, followed by a discussion of the processing of nanocomposites and then proceeds with special considerations of clay based processes, mechanical, thermal and electric properties and surface properties as well as erosion resistance. Carbon nanotubes are discussed as a means of creation of non linear conductivity, the text concludes with a industrial applications perspective.
This book describes the design of the first functioning single-sided tomograph, the related measurement methods, and a number of applications in medicine, materials science, and chemical engineering. It will be the first comprehensive account of this new device and its applications. Among the key advances of this method is that images can be obtained in much shorter times than originally anticipated, and that even vector maps of flow fields can be measured although the magnetic fields are highly inhomogeneous. Furthermore, the equipment is small, mobile and affordable to small and medium enterprises and can be located in doctors' offices.
This book covers fundamental principles and numerical methods relevant to the modeling of the injection molding process. As injection molding processing is related to rheology, mechanical and chemical engineering, polymer science and computational methods, and is a rapidly growing field, the book provides a multidisciplinary and comprehensive introduction to the subjects required for an understanding of the complex process. It addresses the up-to-date status of fundamental understanding and simulation technologies, without losing sight of still useful classical approaches. The main chapters of the book are devoted to the currently active fields of flow-induced crystallization and orientation evolution of fiber suspensions, respectively, followed by detailed discussion of their effects on mechanical property, shrinkage and warpage of injection-molded products. The level of the proposed book will be suitable for interested scientists, R&D engineers, application engineers, and graduate students in engineering.
This monograph is a follow-up material to the first FRRPP book by Gerard Caneba in 2009. It includes additional conceptual results, implementation of the FRRPP process in emulsion media to produce various block copolymers, and other FRRPP-related supplementary topics. Conceptual topics include the application of the quantitative analysis presented in the first FRRPP monograph for the occurrence of the FRRPP process to the polysterene-styrene-ether (PS-S-Ether) and poly(methacrylic acid)-methacrylic acid-water (PMAA-MAA-Water) systems, as well as extensions through unsteady state analysis of the occurrence of flat temperature profiles. Also, the generalization of the quantitative analysis is done to consider molecular weight effects, especially based on changes of the phase envelope to an hourglass type. Topics in implementation of the FRRPP process from pre-emulsions of monomers and the solvent/precipitant are highlighted. Additional FRRPP topics are included in this monograph that pertain to more recent efforts of Gerard Caneba, such as oil spill control, oil dispersant system, and caustic sludge remediation from emulsion-based FRRPP materials, hydrolysis of vinyl acetate-acrylic acid-based copolymers, and other polymer modification studies from FRRPP-based emulsions.
This is the second edition of the book "Thermodynamics of Fluids under Flow," which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vazquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vazquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer blends, laminar and turbulent superfluids, phonon hydrodynamics and heat transport in nanosystems, nuclear collisions, far-from-equilibrium ideal gases, and molecular solutions. It also deals with a variety of situations, emphasizing the non-equilibrium flow contribution: temperature and entropy in flowing ideal gases, shear-induced effects on phase transitions in real gases and on polymer solutions, stress-induced migration and its application to flow chromatography, Taylor dispersion, anomalous diffusion in flowing systems, the influence of the flow on chemical reactions, and polymer degradation. The new edition is not only broader in scope, but more educational in character, and with more emphasis on applications, in keeping with our times. It provides many examples of how a deeper theoretical understanding may bring new and more efficient applications, forging links between theoretical progress and practical aims. This updated version expands on the trusted content of its predecessor, making it more interesting and useful for a larger audience.
Non-Newtonian properties on bubble dynamics and cavitation are fundamentally different from those of Newtonian fluids. The most significant effect arises from the dramatic increase in viscosity of polymer solutions in an extensional flow, such as that generated about a spherical bubble during its growth or collapse phase. In addition, many biological fluids, such as blood, synovial fluid, and saliva, have non-Newtonian properties and can display significant viscoelastic behaviour. This monograph elucidates general aspects of bubble dynamics and cavitation in non-Newtonian fluids and applies them to the fields of biomedicine and bioengineering. In addition it presents many examples from the process industries. The field is strongly interdisciplinary and the numerous disciplines involve have and will continue to overlook and reinvent each others' work. This book helps researchers to think intuitively about the diverse physics of these systems, to attempt to bridge the various communities involved, and to convey the interest, elegance, and variety of physical phenomena that manifest themselves on the micrometer and microsecond scales.
Preparation of Liquid Crystalline Elastomers, by F. Broemmel, D. Kramer, H. Finkelmann Applications of Liquid Crystalline Elastomers, by C. Ohm, M. Brehmer und R. Zentel Liquid Crystal Elastomers and Light, by Peter Palffy-Muhoray Electro-Opto-Mechanical Effects in Swollen Nematic Elastomers, by Kenji Urayama The Isotropic-to-Nematic Conversion in Liquid Crystalline Elastomers, by Andrija Lebar, George Cordoyiannis, Zdravko Kutnjak und Bostjan Zalar Order and Disorder in Liquid-Crystalline Elastomers, by Wim H. de Jeu und Boris I. Ostrovskii
Chemical sensors are in high demand for applications as varied as water pollution detection, medical diagnostics, and battlefield air analysis. Designing the next generation of sensors requires an interdisciplinary approach. The book provides a critical analysis of new opportunities in sensor materials research that have been opened up with the use of combinatorial and high-throughput technologies, with emphasis on experimental techniques. For a view of component selection with a more computational perspective, readers may refer to the complementary volume of Integrated Analytical Systems edited by M. Ryan et al., entitled "Computational Methods for Sensor Material Selection".
The contributors to this volume study macroscopic flow properties and molecular mobility in complex liquids with high internal mobility and a highly anisotropic molecular shape. Particular attention is paid to the wide variety of experimental approaches, in theory as well as in computer simulation of these difficult but very important problems. The contributions are of interest to researchers in physics as well as in engineering and chemistry.
The last twenty years or so have seen a flurry of activity in the synthesis of new polymer systems. This interest has developed largely as a result of the increased need for advanced materials. Despite the emergence of a number of outstanding polymers, it is the polyimides that have captured the imagination of scientists and engineers alike as materials that offer outstanding promise for the high technology applic ations of the future. The reputation of the polyimide has been established on the bases of outstanding thermal stability, excellent mechanical properties and the ability to be fabricated into useful articles. Polyimides offer a versatility unparalleled in most other classes of macromolecules. Polymers can be prepared from a variety of starting materials, by a variety of synthetic routes. They can be tailor-made to suit specific applications. By judicious choice of starting materials, polymers can be made that offer variations in such properties as glass transition tempera ture, oxidative stability, toughness, adhesion, and permeability. It is this versatility that has led to the use of polyimides in a wide variety of applications. The electronics industry makes extensive use of poly imide films in, ior example, semiconductor applications. The leading polymer matrices for high temperature advanced composites are polyimides. High temperature adhesive systems for the bonding of metals or composites are often based on polyimides. In addition, polyimides are now finding use as fibres, foams, sealents and even membranes for the low energy separation of industrial gases.
New Antisense Strategies: Chemical Synthesis of RNA Oligomers, by Junichi Yano und Gerald E. Smyth Development and Modification of Decoy Oligodeoxynucleotides for Clinical Application, by Mariana Kiomy Osako, Hironori Nakagami und Ryuichi Morishita Modulation of Endosomal Toll-Like Receptor-Mediated Immune Responses by Synthetic Oligonucleotides, by Ekambar R. Kandimalla und Sudhir Agrawal Delivery of Nucleic Acid Drugs, by Yan Lee und Kazunori Kataoka Aptamer: Biology to Applications, by Yoshikazu Nakamura Development and Clinical Applications of Nucleic Acid Therapeutics, by Veenu Aishwarya, Anna Kalota und Alan M. Gewirtz |
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