MTDSC provides a step-change increase in the power of calorimetry to characterize virtually all polymer systems including curing systems, blends and semicrystalline polymers. It enables hidden transitions to be revealed, miscibility to be accurately assessed, and phases and interfaces in complex blends to be quantified. It also enables crystallinity in complex systems to be measured and provides new insights into melting behaviour. All of this is achieved by a simple modification of conventional DSC.

In 1992 a new calorimetric technique was introduced that superimposed a small modulation on top of the conventional linear temperature program typically used in differential scanning calorimetry. This was combined with a method of data analysis that enabled the samplea (TM)s response to the linear component of the temperature program to be separated from its response to the periodic component. In this way, for the first time, a signal equivalent to that of conventional DSC was obtained simultaneously with a measure of the samplea (TM)s heat capacity from the modulation. The new information this provided sparked a revolution in scanning calorimetry by enabling new insights to be gained into almost all aspects of polymer characteristics.

This book provides both a basic and advanced treatment of the theory of the technique followed by a detailed exposition of its application to reacting systems, blends and semicrystalline polymers by the leaders in all of these fields. It is an essential text for anybody interested in calorimetry or polymer characterization, especially if they have found that conventional DSC cannot help them with their problems.

This book presents an exhaustive analysis of the trends in the development and use of natural and synthetic polymer systems aimed at sustainable agricultural production. The polymers have allowed the development of controlled and released systems of agrochemicals such as pesticides, fertilizers and phytohormones through micro and nanoencapsulated systems, which protect and stimulate the growth of crops at low costs and without damage to the environment. Hydrogel systems from natural and synthetic polymers have also had their place in the agricultural industry, since they allow to maintain the humidity conditions of the crops for their correct development in drought times. Mulch films made of polymers have also become important in the control of weeds and pests in crops, as well as the use of edible coatings applied to fruits and vegetables during post-harvest, which reduce the losses of these perishable foods. Currently, the systems indicated, as well as others, are already used on a large scale. However, research studies in this area have been limited compared to other polymer applications. This book collects useful information for researchers, students and technologies related to the polymer technology and agri-food production. In this book, world-renowned researchers have participated, including associate editors of important journals, as well as researchers working in the area of research and development (R&D) of leading agri-food industries in the manufacture of agricultural inputs.

A complete and timely overview of the topic, this Encyclopedia imparts knowledge of fundamental principles and their applications for academicians, scientists and researchers, while informing engineers, industrialists and entrepreneurs of the current state of the technology and its utilization.
Each article is uniformly structured for easy navigation, containing the latest research & development and its basic principles and applications, examples of case studies, laboratory and pilot plant experiments, as well as due reference to the published and patented literature.

This book summarizes recent progress in cellulose chemistry. The last 10 years have witnessed important developments, because sustainability is a major concern. Biodegradable cellulose derivatives, in particular esters and ethers, are employed on a large scale. The recent developments in cellulose chemistry include unconventional methods for the synthesis of derivatives, introduction of novel solvents, e.g. ionic liquids, novel approaches to regioselective derivatization of cellulose, preparation of nano-particles and nano-composites for specific applications. These new developments are discussed comprehensively. This book is aimed at researchers and professionals working on cellulose and its derivatives. It fills an important gap in teaching, because most organic chemistry textbooks concentrate on the relatively simple chemistry of mono- and disaccharides. The chemistry and, more importantly, the applications of cellulose are only concisely mentioned.

This book comprehensively summarizes important aspects of research in the active field of lignocellulosic (polymer) composites, including polymer materials from or containing cellulose, hemicellulose and lignin. It describes how these materials can be produced from forest products and natural fibers from sources such as jute, flax, sisal, and many more, and even from agricultural residues (like wheat straw, corn stover, or sugarcane bagasse). In times of high demand for renewable green materials, lignocellulosic materials from organic matter produced by trees, shrubs and agricultural crops present a highly attractive feedstock. The international authors explain different treatment and fabrication methods for the production of lignocellulosic materials. Other chapters address the properties of these green materials or illustrate specific applications, ranging from food packaging and household products to adsorbents and even conductive polymer composites. In this way, this book offers a broad and comprehensive overview over the entire field of lignocellulosic composite materials.

This book discusses the tribological, rheological and optical properties of liquid-crystal nanomaterials as well as lubricant media. It also describes the formation of liquid-crystal materials and the application of cholesteric liquid-crystal compounds in technical friction units and in human and animal joints. Further, it shows the connection between the tribological and other physical properties of liquid-crystal cholesterol compounds and develops a lubricity conceptual model of cholesteric-nematic, liquid-crystalline nanostructures on the basis of physical and energetic interpretations. This general model is valid for all surfaces and friction pairs, including biopolymers, and could lead to applications of cholesteric liquid-crystalline nanomaterials in different friction units and tribosystems as well as in the treatment of joint diseases.

This book focuses on different aspects of microplastic pollution, offering authors and readers the opportunity to share their knowledge, identify issues and propose solutions and actions to face this environmental threat. Although plastic pollution is a well-known global problem, the recent discovery of microplastics and nanoplastics in seas and oceans represents a very alarming new environmental challenge. The book offers comprehensive insights into the origins of the problem, its impact on marine environments, particularly the Mediterranean Sea and coasts, and the current research trends aimed at finding technical solutions to mitigate the phenomenon. It is primarily intended for scientists and decision makers from industry, international, national and local institutions and NGOs

This successor to the popular textbook, "Polymer Physics" (Springer, 1999), is the result of a quarter-century of teaching experience as well as critical comments from specialists in the various sub-fields, resulting in better explanations and more complete coverage of key topics. With a new chapter on polymer synthesis, the perspective has been broadened significantly to encompass polymer science rather than "just" polymer physics. Polysaccharides and proteins are included in essentially all chapters, while polyelectrolytes are new to the second edition. Cheap computing power has greatly expanded the role of simulation and modeling in the past two decades, which is reflected in many of the chapters. Additional problems and carefully prepared graphics aid in understanding. Two principles are key to the textbook's appeal: 1) Students learn that, independent of the origin of the polymer, synthetic or native, the same general laws apply, and 2) students should benefit from the book without an extensive knowledge of mathematics. Taking the reader from the basics to an advanced level of understanding, the text meets the needs of a wide range of students in chemistry, physics, materials science, biotechnology, and civil engineering, and is suitable for both masters- and doctoral-level students. Praise for the previous edition: ...an excellent book, well written, authoritative, clear and concise, and copiously illustrated with appropriate line drawings, graphs and tables. - Polymer International ...an extremely useful book. It is a pleasure to recommend it to physical chemists and materials scientists, as well as physicists interested in the properties of polymeric materials. - Polymer News This valuable book is ideal for those who wish to get a brief background in polymer science as well as for those who seek a further grounding in the subject. - Colloid Polymer Science The solutions to the exercises are given in the final chapter, making it a well thought-out teaching text. - Polymer Science

This book is the first of two volumes providing comprehensive coverage of the fundamental knowledge and technology of composite materials. It covers a variety of design, fabrication and characterization methods as applied to composite materials, particularly focusing on the fiber-reinforcement mechanism and related examples. It is ideal for graduate students, researchers, and professionals in the fields of Materials Science and Engineering, and Mechanical Engineering.

On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry. In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials. Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices. Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this book are available open access under a CC BY 4.0 license at link.springer.com

This book presents the reader with a story-based narrative of discovery and development of radiation-induced graft polymerization. The report presented here accomplishes this by relating the inspiring account of research and development based on long-term collaboration among a professor, an engineer, and an entrepreneur. Their goal, ultimately successful, was to come up with a method for grafting functional polymer chains onto existing trunk polymers. The desired outcome was to produce feasible forms for practical use as adsorbents such as porous hollow-fiber membranes, porous sheets, nonwoven fabrics, and fibers. Adsorbents that specifically and efficiently bind to target ions and molecules are essential for capturing uranium species in seawater and antibody drugs in biological fluids and for removing metal ions from ultrapure water and radioactive cesium ions from contaminated water. This unique volume, with its clearly written text and many illustrative figures and diagrams, demonstrates the advantages of the high-adsorption capacity and rate and the easy handling of new polymeric adsorbents over conventional adsorbents. The dynamic behavior of graft chains as described here is certain to appeal especially to chemists, physicists, and material scientists as well as to other readers with an interest in this valuable subject.

This book presents the most important advances in the class of topological materials and discusses the topological characterization, modeling and metrology of materials. Further, it addresses currently emerging characterization techniques such as optical and acoustic, vibrational spectroscopy (Brillouin, infrared, Raman), electronic, magnetic, fluorescence correlation imaging, laser lithography, small angle X-ray and neutron scattering and other techniques, including site-selective nanoprobes. The book analyzes the topological aspects to identify and quantify these effects in terms of topology metrics. The topological materials are ubiquitous and range from (i) de novo nanoscale allotropes of carbons in various forms such as nanotubes, nanorings, nanohorns, nanowalls, peapods, graphene, etc. to (ii) metallo-organic frameworks, (iii) helical gold nanotubes, (iv) Moebius conjugated polymers, (v) block co-polymers, (vi) supramolecular assemblies, to (vii) a variety of biological and soft-matter systems, e.g. foams and cellular materials, vesicles of different shapes and genera, biomimetic membranes, and filaments, (viii) topological insulators and topological superconductors, (ix) a variety of Dirac materials including Dirac and Weyl semimetals, as well as (x) knots and network structures. Topological databases and algorithms to model such materials have been also established in this book. In order to understand and properly characterize these important emergent materials, it is necessary to go far beyond the traditional paradigm of microscopic structure-property-function relationships to a paradigm that explicitly incorporates topological aspects from the outset to characterize and/or predict the physical properties and currently untapped functionalities of these advanced materials. Simulation and modeling tools including quantum chemistry, molecular dynamics, 3D visualization and tomography are also indispensable. These concepts have found applications in condensed matter physics, materials science and engineering, physical chemistry and biophysics, and the various topics covered in the book have potential applications in connection with novel synthesis techniques, sensing and catalysis. As such, the book offers a unique resource for graduate students and researchers alike.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

The book focuses on the thermal transformations of various types of metal chelates, e.g. low molecular weight and polymeric metal chelates, coordination polymers and metal-organic frameworks. It analyzes the major advances and the problems in the preparation of metal oxide materials, mixed-oxide nanocomposites, carbon materials and polymer derived non-oxide nanocomposites by the thermolysis of different metal chelates. It also highlights the influence of the spatial and electronic structure of metal chelates on the mechanism and kinetics of their thermal transformations, and discusses important issues like conjugate thermolysis and computer modelling of the thermolysis process. This book is useful for researchers experienced in thermolysis as well as for young scientists interested in this area of science.

This book reports on the design, synthesis and characterization of new small molecule electron acceptors for polymer solar cells. Starting with a detailed introduction to the science behind polymer solar cells, the author then goes on to review the challenges and advances made in developing non-fullerene acceptors so far. In the main body of the book, the author describes the design principles and synthetic strategy for a new family of acceptors, including detailed synthetic procedures and molecular modeling data used to predict physical properties. An indepth characterization of the photovoltaic performance, with transient absorption spectroscopy (TAS), photo-induced charge extraction, and grazing incidence X-ray diffraction (GIXRD) is also included, and the author uses this data to relate material properties and device performance. This book provides a useful overview for researchers beginning a project in this or related areas.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapter "Polymeric Nanoparticle-Mediated Gene Delivery for Lung Cancer Treatment" is available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.

This thesis provides essential information on the systematic design of assembled lanthanide complexes for functional luminescent materials. It discusses the relationships between assembled structures and photo, thermal, and mechanical properties on the basis of crystallography, spectroscopy, and thermodynamics. The described guidelines for assembled structures will be extremely valuable, both for industrial applications and for readers' fundamental understanding of solid-state photophysics and materials chemistry. Luminescent lanthanide complexes are promising candidates for lighting devices, lasers, and bio-probes owing to their line-like and long-lived emission arising from characteristic 4f-4f transitions. Low-vibrational and asymmetrical coordination structures around lanthanide ions have been introduced to achieve strong luminescence, using specific organic ligands. Recently, assembled lanthanide complexes including coordination polymers and metal organic frameworks have increasingly attracted attention as a new class of luminescent materials offering thermal stability and color tunability. However, improving the luminescence efficiencies of these compounds remains a challenge, and specific molecular designs to control assembled structures and yield additional physical properties have not been established. The author provides a group of bent-angled bridging ligands to boost photoluminescence efficiency, and successfully introduces for the first time glass formability and strong triboluminescence properties.

This brief explores recent progress in the area of polysaccharides and their composites and nanocomposites. It is a complete resource for the evolving field of polysaccharide based biomaterials and their applications in different fields. The volume focuses on their composition, properties, characterization, chemistry and applications and also highlights recent developments in polysaccharide based composites and nanocomposites spurred by advances in polymer technology and biotechnology. Divided into different sections featuring alginates, carrageenans, cellulose, starch, chitin, chitosan, gums, etc, each chapter presents chemical, physical, and biological attributes, and reviews the recent research performed such as drug carriers, selective water absorption materials from oil-water emulsions, purification of water, biomedical applications, etc. The authors hope that this brief will help to inspire scientists towards novel sources for chemicals, materials, and energy in the years to come.

Extensively revised and updated to keep abreast of recent advances, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide a broad-based, high-information text at an introductory, reader-friendly level that illustrates the multidisciplinary nature of polymer science. Adding or amending roughly 50% of the material, this new edition strengthens its aim to contribute a comprehensive treatment by offering a wide and balanced selection of topics across all aspects of the chemistry and physics of polymer science, from synthesis and physical properties to applications. Although the basics of polymer science remain unchanged, significant discoveries in the area of control over molecular weight, macromolecular structure and architecture, and the consequent ability to prepare materials with specific properties receive extensive mention in the third edition. Expanded chapters include controlled radical polymerizations, metallocene chemistry, and the preparation of block and graft copolymers, as well as multiarmed and dendritic structures. Reflecting the growth of polymer applications in industry, the book presents detailed examples to illustrate polymer use in electronic, biological, and medical settings. The authors introduce new understandings of rheological behavior and replace old and outmoded methods of polymer characterization with new and up-to-date techniques. Also new to this edition are a series of problems at the end of each chapter that will test whether the reader has understood the various points and in some cases expand on that knowledge. An accompanying solutions manual is also available for qualifying course adoptions. Offering the highest quality, comprehensive coverage of polymer science in an affordable, accessible format, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide undergraduate and graduate students and professors with the most complete and current coverage of modern polymer science.

This book addresses a range of synthesis and characterization techniques that are critical for tailoring and broadening the various aspects of polymer gels, as well as the numerous advantages that polymer gel-based materials offer. It presents a comprehensive collection of chapters on the recent advances and developments in the science and fundamentals of both synthetic and natural polymer-based gels. Topics covered include: synthesis and structure of physically/chemically cross-linked polymer-gels/polymeric nanogels; gel formation through non-covalent cross-linking; molecular design and characterization; polysaccharide-based polymer gels: synthesis, characterization, and properties; modified polysaccharide gels: silica-based polymeric gels as platforms for the delivery of pharmaceuticals; gel-based approaches in genomic and proteomic sciences; emulgels in drug delivery; and organogels. The book provides a cutting-edge resource for researchers and scientists working in various fields involving polymers, biomaterials, bio-nanotechnology and functional materials.

This volume collects the proceedings from the International Congress of Polymers in Concrete 2018 (ICPIC), held under the theme "Polymers for Resilient and Sustainable Concrete Infrastructure." ICPIC 2018 provides an opportunity for researchers and specialists working in the fields of polymers to exchange ideas and follow the latest progress in the use of polymers in concrete infrastructure. It also showcases the use of polymers and polymer concrete in sustainable and resilient development, and provides a platform for local and overseas suppliers, developers, manufacturers and contractors using polymers, polymer concrete and polymer composites in concrete structures to develop new business opportunities and follow the latest developments in the field. The International Congress of Polymers in Concrete is an international forum that has taken place every three years for the last 40 years with the objective of following progress in the field of polymers and their use in concrete and construction. Following 15 successful congresses held in London (1975), Austin (1978), Koriyama (1981), Darmstadt (1984), Brighton (1987), Shanghai (1990), Moscow (1992), Oostende (1995), Bologna (1998), Honolulu (2001), Berlin (2004), Chuncheon (2007), Funchal (2010), Shanghai (2013) and Singapore (2015), the 16th ICPIC will take place in Washington, DC, from April 29 to May 1st, 2018.

This book describes the advanced developments in methodology and applications of NMR spectroscopy to life science and materials science. Experts who are leaders in the development of new methods and applications of life and material sciences have contributed an exciting range of topics that cover recent advances in structural determination of biological and material molecules, dynamic aspects of biological and material molecules, and development of novel NMR techniques, including resolution and sensitivity enhancement. First, this book particularly emphasizes the experimental details for new researchers to use NMR spectroscopy and pick up the potentials of NMR spectroscopy. Second, the book is designed for those who are involved in either developing the technique or expanding the NMR application fields by applying them to specific samples. Third, the Nuclear Magnetic Resonance Society of Japan has organized this book not only for NMR members of Japan but also for readers worldwide who are interested in using NMR spectroscopy extensively.

The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from Hz up to the Infrared, thus covering typically 20 decades or more. This extraordinary span enables to trace the scaling and the mutual interactions of relaxation processes in detail, e.g. the dynamic glass transition and secondary relaxations, but as well far infrared vibrations, like the Boson peak. Additionally the evolution of intra-molecular interactions in the course of the dynamic glass transition is also well explored by (Fourier Transform) Infrared Spectroscopy. This volume within 'Advances in Dielectrics' summarizes this knowledge and discusses it with respect to the existing and often competing theoretical concepts.

This book describes the development of three dimensional electroactive fibres using a novel coaxial wet-spinning approach from organic conductors in combination with non-conducting hydrogel polymers. This book also presents the characterization and evaluation of multiaxial biofibres in terms of mechanical, physical, electrochemical and biological properties, and explores their use in a diverse range of applications including implantable electrodes, drug delivery systems and energy-storage systems. In the first chapter, the author highlights the significance of engineering three dimensional fibres, introduces the involved hydrogels and organic conductors with emphasis on their biomedical application, and collects some of the previously established methods for fabrication of biofibres. In the second chapter, particular attention is given to the overall experimental fabrication methods and characterization analyses conducted in the work. Chapters three to five present the main findings of this work, in which readers will discover how novel hybrid hydrogel fibres with an inner core of chitosan and alginate were prepared and characterized, how graphene was incorporated into coaxial wet-spun biofibres, and how one-dimensional triaxial fibres were developed using a novel coaxial wet-spinning fibre production method and applied as potential battery devices. In the final chapter of this work, the author summarizes the main achievements of the work and outlines some recommendations for future research.

The second edition of this popular textbook thoroughly covers the practical basics and applications of conducting polymers. It also addresses materials that have gained prominence since the first edition of this book was published, namely carbon nanotubes and graphene. The features of this new edition include: New and updated chapters on novel concepts in conducting polymers Details on interdisciplinary applications of conducting polymers An in depth description of classes of conducting polymers