Fluoropolymers are unique materials. Since the middle of the twentieth century fluropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Fascinating Fluoropolymers and Their Applications covers recent developments of fluoropolymer applications in energy, optical fibers, blood substitutes, textile coatings, membranes and other areas, written by experts in these fields. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the technology and applications of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries.

Fluoropolymers are very unique materials. Since the middle of the twentieth century fluoropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling covers recent developments in fluoropolymers, including synthesis of new copolymers, strategies for radical polymerization of fluoromonomers (conventional or controlled; RDRP), and the modification of fluoropolymers to achieve desired material characteristics. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the synthetic strategies, properties, and recycling of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries.

The continually growing plastics market consists of more than 250 million tons of product annually, making the recurring problem of polymer melt fracture an acute issue in the extrusion of these materials. Presenting a pictorial library of the different forms of melt fracture and real industrial extrusion melt fracture phenomena, Polymer Melt Fracture provides pragmatic identification and industrial extrusion defect remediation strategies based on detailed experimental and theoretical findings from the last 50 years.

Distinct microscopic photos

Each chapter in this comprehensive volume covers a different aspect of the science and technology relating to polymer melt fracture. The book begins with a collection of optical and scanning electron microscopy pictures. These photos show distorted capillary die extrudates for a number of commercially available polymers. The authors present a brief introduction to the basic science and technology of polymers. They explain what polymers are, how they are made, and how they can be characterized. They also discuss polymer rheology, review the principles of continuum mechanics, and define linear viscoelastic material functions.

Techniques for observing and measuring fracture

Next, the book explains how polymer melt fracture is actually experienced in the polymer processing industry. It explains the various ways polymer melt fracture may appear during polymer melt processing in different extrusion processes. The authors provide comprehensive reviews of the polymer melt fracture literature, with chapters on experimental findings and the techniques used to observe and measure polymer melt fracture, and the influence of polymer architecture and polymer processing conditions on the onset and types of polymer melt fracture. Posing a hypothesis about the phenomenon, the book presents the current understanding of polymer melt fracture.

Mathematical equations

Recognizing the importance of models for simulations that may indicate potential solutions, the book discusses aspects of non-linear constitutive equations and microscopic theory and develops a macroscopic model, explaining the capabilities and limitations of this approach. The book presents an overview of pragmatic tools and methods that have been used to prevent the appearance of polymer melt fracture and explains how to use them to suppress defects.

Polymer latex particles continue to become increasingly important in numerous commercial applications. Advanced synthesis techniques are the key to developing new functionality for nanoparticles. These methods make it possible to tailor the size, chemical composition, or properties of these particles, as well as the molecular weight of the polymer chain as a whole, based on given requirements. Advanced Polymer Nanoparticles: Synthesis and Surface Modifications summarizes important developments in the advanced synthesis and surface modification techniques used to generate and mold polymer particles. This book explores the evolution and enhancement of processes such as emulsion, mini-emulsion, micro-emulsion, dispersion, suspension, inverse emulsion (in organic phase), and polymerization. Understanding these developments will enable the reader to optimize particle system design, giving rise to a greater application spectrum. This book: Focuses on synthesis and characterization of particles with core-shell morphologies Details generation of nonspherical polymer particles using different synthetic routes Explores generation of specific architectures, such as block, star, graft, and gradient copolymer particles The authors describe pH-responsive nanoparticles and smart, thermally responsive particles. They also cover surface tailoring of various organic and inorganic nanoparticles by polymers, as well as theoretical studies on the kinetics of controlled radical polymerization techniques. Condensing and evaluating current knowledge of the development of polymer nanoparticles, this reference will prove a valuable addition to the area of polymer latex technology.

BACKGROUND Polysiloxanes have chains constructed of alternately arranged silicon and oxygen atoms with organic groups attached to the silicon atoms. This structure gives them a unique combination of properties that hold great interest for a host of practical applications. Although they have been known and manufactured for many years, their applications continue to expand rapidly and this boosts progress in the generation of new and modified polysiloxanes. Polysiloxanes constitute the oldf'"' known class of silicon-based polymers and the broadest one when viewed in terms of the variety of structures differing in topology and the constitution of organic substituents. There are also many and various types of siloxane copolymers, some of purely siloxane structure and others of siloxane-organic composition. There is no doubt that polysiloxanes are the most technologically important silicon-based polymers. The broad class of model materials known as silicones is based on polysiloxanes. They are also the best known, as most research in the area of silicon polymers has for many years been directed towards the synthesis of new polysiloxanes, to understanding their properties and to extending their applications.

This volume provides a thorough insight into the chemistry and mechanism of ionic gelations of various ionic biopolysaccharides, like alginate, gellan gum, pectin, chitosan, carboxymethyl cellulose, etc., and the applications of various ionically gelled biopolysaccharides in drug delivery fields, with chapters emphasizing the recent advances in the field by the experts. This book will be of interest to graduate students and academic and industry researchers from pharmacy, biotechnology, bioengineering, biomedical and material sciences fields.

This book introduces the physics and chemistry of plastic scintillators (fluorescent polymers) that are able to emit light when exposed to ionizing radiation, discussing their chemical modification in the early 1950s and 1960s, as well as the renewed upsurge in interest in the 21st century. The book presents contributions from various researchers on broad aspects of plastic scintillators, from physics, chemistry, materials science and applications, covering topics such as the chemical nature of the polymer and/or the fluorophores, modification of the photophysical properties (decay time, emission wavelength) and loading of additives to make the material more sensitive to, e.g., fast neutrons, thermal neutrons or gamma rays. It also describes the benefits of recent technological advances for plastic scintillators, such as nanomaterials and quantum dots, which allow features that were previously not achievable with regular organic molecules or organometallics.

A valuable primer to help students and workers understand concepts and relationships which are developed more fully in other specialist texts on polymer molecular physics, Introduction to Molecular Motion in Polymers explains how molecular movement is determined by chemical structure, then how the motion controls the physical and technological properties of polymer materials. It is based upon the fact that the physical properties of polymeric materials are very dependent on various modes of motion of the molecules, and these in turn depend on the chemical structure. The reader is thus introduced to the concepts of molecular movement in polymers and the connections with causative chemical structure on the one hand and resulting bulk physical and technological behaviour on the other. The approach is non-mathematical, but is molecularly based and will enable the reader to understand the detailed chemical and rigorous mathematical discussions of more advanced texts. The book integrates polymer chemistry with polymer physics and polymer engineering, a fusion that is so often lacking in polymer education.This interdisciplinary treatment is given first to the mechanical properties of plastics and rubbers, since these are the most important in use. Closely connected to molecular motion, and also affecting physical behaviour, is the morphology of a bulk material. This, too, is accommodated along with the treatment of glasses and rubbers. Next in importance comes electrical behaviour, and in particular dielectric or insulation uses. The book also covers acoustic behaviour, light initiated or photo-properties and diffusion phenomena. Throughout, emphasis is placed on the way that time, temperature and frequency relationships apply in a similar way to all these phenomena.

At the heart of organic chemistry is the effective synthesis of natural products or compounds, which are important for pharmaceuticals and agrochemicals, for example. These syntheses often include new reactions and novel concepts in organic chemistry, such that there is always a need for innovative strategies and improved methods.
This textbook presents not only synthetic ways to design organic compounds, it also contains a compilation of total synthesis with a comparative view of multiple designs for the same targets. It explains different tactics and strategies, making it easy to apply to many problems, whatever the synthetic question in hand. Following a historical view of the evolution of synthesis, the book goes on to look at principles and issues impacting synthesis and design as well as principles and issues of methods. The sections on comparative design cover classics in terpenes and alkaloid synthesis, while a further section covers such miscellaneous syntheses as Maytansine, Palytoxin, Brevetoxin B and Indinavir. The whole is rounded off with a look at future perspectives.
With its attractive layout highlighting key parts and tactics using a second color this is a useful tool for organic chemists, lecturers and students in chemistry, as well as those working in the chemical industry.
A native of North Carolina, Josephine Reed was educated at the University of North Carolina at Greensboro (B.A., English), Appalachian State University (B.A., biology and chemistry), and Virginia Tech (Ph.D., chemistry). Besides her many, many years as a student, she has spent time as a department store clerk, a waitress, a banker, a bartender, and a chemistry instructor. Shecontinues her eclectic career at Brock University in St. Catharines, Ontario, where she shares her life and her work with the co-author and their son. Still an English major at heart, Josie has always had a secret desire to be a writer, preferably a poet, and is delighted to be a part of the making of this book.
Tomas Hudlicky was born and raised in Prague, Czechoslovakia and emigrated to the US in 1968. He received his PhD in 1977 under the direction of Professor Ernest Wenkert in the field of indole alkaloid total synthesis. He then spent a year at the University of Geneva working under the late Professor Wolfgang Oppolzer on the synthesis of isocomene. He began his academic career in 1978 at the Illinois Institute of Technology and moved to Virginia tech (1982) and to the University of Florida(1995). In 2003, he accepted an offer from Brock University where he currently holds the position of Canada Research Chair professor of Organic synthesis and Biocatalysis. His current research interests include the development of enantioselective synthetic methods, bacterial dioxygenase-mediated degradation of aromatics and isolation of chiral metabolites for use in asymmetric synthesis, design and synthesis of fluorinated inhalation anesthetic agents, synthesis of morphine and Amaryllidaceae alkaloids, organic electrochemistry, and design of unnatural oligo-saccharide conjugates and polymers with new molecular properties. His hobbies include martial arts, music, hockey, and skiing and he enjoys all of these with his 17 year old son Jason.

Polymeric Liquids & Networks: Dynamics and Rheology is the second part of a two-volume treatise serving as a status report on a broad area of polymer science research. It represents an effort to unify and consolidate the work of many polymer researchers from all over the world, over the past 60-70 years. Both books are based on the graduate courses taught by the author at Princeton and Northwestern. The increasing need to apply new understandings about liquid structure to rheological behavior squeezed equilibrium aspects out of the rheology course and into another graduate course, which eventually became the basis for Volume 1, Structure and Properties, published in 2004. Volume 2 follows the original plan by building upon Volume 1-covering continuum background along with experimental observations, then molecular theories and applications to such topics as solution properties, long-chain branching and structural heterodispersity. Dynamics and Rheology aims to leave readers with a solid grounding in the principles that underlie the dynamics and rheological behavior of flexible chain polymer liquids and networks. Readers will develop an informed intuitive understanding of the connections between polymeric structure and rheological response. Theory, experiment, and simulation are woven together so as to leave the reader with a balanced grasp of the various areas, including exposure to important unsolved puzzles. The book will be a great resource for a range of academic researchers in chemistry, physics, materials science, and chemical engineering.

The production and application of polymeric materials based on poly(butylene terephthalate) (PBT) has increased dramatically. The main reason for this is that PBT and its composites have a number of profitable properties, such as increased mechanical characteristics, good resistance to chemicals and water, processability, etc. This volume gives an analysis of recent achievements in the field of synthesis, structural investigations, and properties of PBT. Furthermore, the mechanism of PBT synthesis by equilibrium polycondensation reaction is described together with the used reagents, catalysts and stabilizers.

The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.

Handbook of Curatives and Crosslinkers presents the mechanisms of action of these additives, methods of their use, their effects on properties of transformed products, and their applications. Chapters cover the common use of curatives in many industrial products manufactured in large scale, such as adhesives, sealants, coatings, inks, explosives, propellants and foams, and in emerging products, such as optoelectronics, shape-memory applications, light-emitting diodes, and more. In addition, crosslinkers used in typical industrial processing methods, such as solar cells, vulcanization, adhesives, foams and roofing are covered. Each section presents the effect of the additive, including an evaluation of its chemical and physical properties.

This volume serves as a cutting edge reference on XLPE based blends, nanocomposites, and their applications. The book provides an introduction to XLPE nanocomposites and discusses the incorporation of natural and inorganic nanoparticles in the XLPE matrix. It also focuses on its characterization as well as the morphological, rheological, mechanical, viscoelastic, thermal, and electrical, properties. It provides an in-depth review of various potential applications, with special emphasis on use in cable insulation. The book focuses on cutting edge research developments, looking at published papers, patents, and production data. This book will be of use to academic and industry researchers, as well as graduate students working in the fields of polymer science and engineering, materials science, and chemical engineering.

This book presents a unified approach to fracture behavior of natural and synthetic fiber-reinforced polymer composites on the basis of fiber orientation, the addition of fillers, characterization, properties and applications. In addition, the book contains an extensive survey of recent improvements in the research and development of fracture analysis of FRP composites that are used to make higher fracture toughness composites in various applications.The FRP composites are an emerging area in polymer science with many structural applications. The rise in materials failure by fracture has forced scientists and researchers to develop new higher strength materials for obtaining higher fracture toughness. Therefore, further knowledge and insight into the different modes of fracture behavior of FRP composites are critical to expanding the range of their application.

This book introduces readers to interfacial reactions in confinement on stimuli-responsive homopolymer and diblock copolymer films. It also includes investigations concerning the immobilization of (bio)molecules and the fabrication of biomolecular patterns by reactive microcontact printing on these reactive polymer films. In turn, the book takes advantage of the microphase separation of diblock copolymer films to study the fabrication of nanopatterns, which could contribute to the future development of a model system that allows us to area-selectively deposit and address (bio)molecules. Given its scope, the book broadens readers' perspective on the microfabrication of stimuli-responsive polymers.

This book focuses on polymer/silver nanocomposites as the main component in bioengineering systems. It describes in detail the synthesis and characterization (morphological, thermal, mechanical & dynamic mechanical properties), as well as the different applications of these composites. A special chapter is dedicated to the toxicity aspects of silver nanoparticles

Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science. New to the Third Edition Part I This first part covers newer developments in polymer synthesis, including 'living' radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements. Part II In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory-Huggins theory for polymer solutions and their phase separation is treated more rigorously. Part III A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology. Part IV The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded. While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.

This book presents synthesis methods, characterization techniques, properties and applications of hybrid conducting polymers. Special emphasis is given to the applications of hybrid conductive polymers, with chapters ranging from electronic devices, environmental remediation, and sensors, to medical applications.

Simulation Methods for Polymers is the only comprehensive source to delineate the technical steps and efficacy of contemporary polymer simulation methods using a highly instructive, easy-to-grasp format, and it offers a logical sequence of polymer physics background, methods, calculations, and application guidelines. Including coverage of recently developed techniques and algorithms for modeling and simulation, this reference/text also provides an introduction to the statistical mechanics of the various simulation techniques presented and explores coarse-graining, CONNFFESSIT simulation, dissipative particle dynamics, and dynamic density functional theory approaches.

The basic problem of polymer physics is obtaining 'structure-properties' correlations for their future application for practical purposes. However, these cannot be obtained without the development of a quantitative model of the polymer structure.
This problem has been actively investigated during the last 45 years, which resulted in obtaining a great amount of experimental (mostly indirect) proofs of existence of the local order in the polymer amorphous state. Now, the time has come for creating a structural model of polymer basing based on the local order ideas. The cluster model, as presented in this monograph, of the polymer amorphous state structure represents the realization of such attempts.
The development of this cluster model is based on well-known experimental observation: the behavior of glassy polymers in the area of stimulated high-elasticity plateau is described in the framework of rubber elasticity concepts. This gives an opportunity to present the local order (cluster) zone as a multifunctional entanglement of the physical network consisting of several collinear closely packed segments of different macromolecules (the amorphous analogue of crystallite with extended chains) and surrounded by a packless matrix. An independent method for assessing local order zone fraction in the structure has been elaborated. Segment length in the cluster equals the length of the chain statistical segment that gives a correlation between molecular and structural parameters of the polymer.
Application of the cluster model allowed description and obtaining of analytical 'structure-properties' correlations for many processes proceeding in polymers: elasticity, yielding, degradation, transport, some thermodynamic processes, structural relaxation, plasticization, structural stabilization at thermo-oxidative degradation, etc.
The relation between the cluster model and some modern physical concepts, for instance fractal analysis, fluctuation free volume kinetic theory, percolation theory, irreversible colloidal aggregation models, are outlined.
A separate chapter is devoted to the features of formation and control of the relative part of local order zones in non-crystalline domains of semi-crystalline polymers and their connection to the structure of crystallites.

The book comprehensively covers the different topics of graphene based biopolymer and nanocomposites, mainly synthesis methods for the composite materials, various characterization techniques to study the superior properties and insights on potential advanced applications.The book will address and rectify the complications of using plastics that are non-degradable and has abhorrent impact on environment. The limitations of properties of biopolymer can be vanquished by employing graphene as a nanomaterial. Outstanding properties of graphene in accordance with biopolymer can be utilized to develop applications like water treatment, tissue engineering, photo-catalysts, super-absorbents. This is a useful reference source for both engineers and researchers working in composite materials science as well as the students attending materials science, physics, chemistry, and engineering courses.

This book presents a detailed discussion of the fundamentals and practical applications of membrane technology enhancement in a range of industrial processes, energy recovery, and resource recycling. To date, most books on the applications of membrane technology have mainly focused on gas pollution removal or industrial wastewater treatment. In contrast, the enhancement of various membrane processes in the areas of energy and the environment has remained largely overlooked. This book highlights recent works and industrial products using membrane technology, while also discussing experiments and modeling studies on the membrane enhancement process.

The science of mathematical modelling and numerical simulation is generally accepted as the third mode of scienti?c discovery (with the other two modes being experiment and analysis), making this ?eld an integral component of c- ting edge scienti?c and industrial research in most domains. This is especially so in advanced biomaterials such as polymeric hydrogels responsive to biostimuli for a wide range of potential BioMEMS applications, where multiphysics and mul- phase are common requirements. These environmental stimuli-responsive hydrogels are often known as smart hydrogels. In the published studies on the smart or stimu- responsive hydrogels, the literature search clearly indicates that the vast majority are experimental based. In particular, although there are a few published books on the smart hydrogels, none is involved in the modelling of smart hydrogels. For the few published journal papers that conducted mathematical modelling and numerical simulation, results were far from satisfactory, and showed signi?cant d- crepancies when compared with existing experimental data. This has resulted in ad hoc studies of these hydrogel materials mainly conducted by trial and error. This is a very time-consuming and inef?cient process, and certain aspects of fun- mental knowledge are often missed or overlooked, resulting in off-tangent research directions.

This volume, Bioresponsive Polymers: Design and Application in Drug Delivery, focuses on recent advancements in bioresponsive polymers and their design, characterization, and applications in varied fields, such as drug delivery and gene delivery. It looks at several carriers for drug delivery and biological molecules using different bioresponsive polymers. To address the many difficulties in existing dosage forms, this book provides information on recent developments to overcome drawbacks of conventional forms of the drug delivery. The chapters cover most areas of bioresponsive polymers, starting with a basic introduction to bioresponsive polymers, followed by chapters on design, characterization, and mechanism of bioresponsive polymers; and applications of drug and gene delivery using bioresponsive polymers via oral, topical, nasal, ocular, and parenteral methods. The book also reviews recent advancements in bioresponsive polymers and advanced applications, such as engineering particulate moieties, biomedical applications, hydrogels as emerging therapy, and electrochemical responses, bioresponsive nanoparticles, and bioresponsive hydrogels.