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Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry
Aqueous-based film coating has become routine in the pharmaceutical industry. This process eliminates the use of organic solvents and thus avoids economic, environmental, and toxicological issues related to residual solvents and solvent recovery. Aqueous-based coating, however, is complex and many variables may impact the final product and its performance. This fourth edition of Aqueous Polymeric Coatings for Pharmaceutical Dosage Forms aims to provide insight into the factors and parameters that should be considered and controlled for the successful development and commercialization of a coated product. The fourth edition has been revised and expanded to reflect the most recent scientific advancements from the literature. The contributing authors explain in detail, using illustrated examples, appropriate steps to solve and ideally avoid formulation, processing, and stability problems and to achieve an optimized dosage form. Trade names and chemical names of commercially marketed coatings are used throughout the text to help familiarize the reader with the various materials available for pharmaceutical applications. This book will be a valuable resource for anyone in the pharmaceutical industry working in the area of aqueous-based film coating.
Polymer Coatings: Technologies and Applications provides a comprehensive account of the recent developments in polymer coatings encompassing novel methods, techniques, and a broad spectrum of applications. The chapters explore the key aspects of polymer coatings while highlighting fundamental research, different types of polymer coatings, and technology advances. This book also integrates the various aspects of these materials from synthesis to application. Current status, trends, future directions, and opportunities are also discussed. FEATURES Examines the basics to the most recent advances in all areas of polymer coatings Serves as a one-stop reference Discusses polymer-coated nanocrystals and coatings based on nanocomposites Describes morphology, spectroscopic analysis, adhesion, and rheology of polymer coatings Explores conducting, stimuli-responsive, self-healing, hydrophobic and hydrophilic, antifouling, and antibacterial polymer coatings Covers modeling and simulation With contributions from the top international researchers from industry, academia, government, and private research institutions, both new and experienced readers will benefit from this applications-oriented book. Sanjay Mavinkere Rangappa is a research scientist at the Natural Composites Research Group Lab, Academic Enhancement Department, King Mongkut's University of Technology North Bangkok, Thailand. Jyotishkumar Parameswaranpillai is a research professor at the Center of Innovation in Design and Engineering for Manufacturing, King Mongkut's University of Technology North Bangkok, Thailand. Suchart Siengchin is a professor at and president of King Mongkut's University of Technology North Bangkok, Thailand.
Polyamic Acids and Polyimides surveys significant developments in basic research in the chemistry and physics of polyamic acids and polyimides over the last several years. Traditional and new topics are discussed, including catalytical imidization, chemical reactions at thermal treatment, quantum-chemical study of synthesis and structure, properties of isolated molecules, and supermolecular and crystalline structures. The book will be an excellent reference for researchers, practitioners, and graduate students working with polyimides and related heat-resistant polymers and materials.
Molecular Cages and Capsules with Functionalized Inner Surfaces, by Stefan Kubik. Drug Delivery by Water-Soluble Organ metallic Cages, by Bruno Therrien. Reversibly Expanded Encapsulation Complexes, by Dariush Ajami und Julius Rebek. Container Molecules Based on Imine Type Ligands, by A. Carina Schulze und Iris M. Oppel. Molecular Capsules Derived from Resorcin 4]arenes by Metal-Coordination, by Tobias Schroder, Satya Narayan Sahu und Jochen Mattay. Coronates, Spherical Containers, Bowl-Shaped Surfaces, Porous 1D-, 2D-, 3D-Metallo-Coordination Polymers, and Metallodendrimers, by Rolf W. Saalfrank und Andreas Scheurer."
This book provides a comprehensive account of developments in the area of lightweight polymer composites. It encompasses design and manufacturing methods for the lightweight polymer structures, various techniques, and a broad spectrum of applications. The book highlights fundamental research in lightweight polymer structures and integrates various aspects from synthesis to applications of these materials. Features Serves as a one stop reference with contributions from leading researchers from industry, academy, government, and private research institutions across the globe Explores all important aspects of lightweight polymer composite structures Offers an update of concepts, advancements, challenges, and application of lightweight structures Current status, trends, future directions, and opportunities are discussed, making it friendly for both new and experienced researchers.
"Organic and Physical Chemistry of Polymers" provides a thorough introduction to the fundamentals of polymers, including their structure and synthesis as well as their chemical and physical properties. This accessible guide illuminates the increasingly important role of polymers in modern chemistry, beginning with the essentials, then covering thermodynamics, conformation, morphology, and measurements of molar masses; polymerization mechanisms, reaction of polymers, synthesis of block and graft polymers, and complex topologies; and the mechanical properties, rheology, polymer processing, and fabrication of fibers and films.
This practical book sets the standard as a valuable, time-saving resource offering systematic fundamental information about industrial radiation technologies. This new edition explores updates to emerging applications of ultraviolet (UV) and electron beam (EB) radiation to polymer processing and offers updates throughout to detail changes changes, new trends, and general issues in radiation technology. It presents vital, cutting-edge information to aid further reduction of volatile organic compounds and toxic substances in the environment, develop alternative sources of energy, and harness energy in both medical and industrial applications. New features of this edition include: Stresses the practical aspects of UV/EB technology and its industrial application Includes updates on UV radiation processes and applications of UV radiation Explores new engineering data of selected commercial products Written by an expert with over forty years of experience, this book would make an excellent resource for scientists and engineers in the fields of materials science and polymer chemistry.
This book focuses on flame retardants (FR) for textile materials. It discusses basics of flame retardancy and flammability and covers various types of flame retardants and materials, including natural FRs, halogen, phosphorous, and nanomaterial-based FRs. This book also discusses methods of applications of FRs and discusses FRs and the environment. Covers a variety of interdisciplinary applications in the textile industry Emphasizes environmental aspects Reports on a large number of FR compounds studied globally Discusses in detail recent developments in halogen-free eco-friendly flame retardants Extensively describes basic aspects of flame retardancy and their measurements Aimed at the practitioner and textile engineering professional this work aims to ensure development of safe textile materials for various uses, including apparel, protective wear, floor coverings, upholstery, drapery, and others.
From Reports in Volume 5: "Recently polymer blends have emerged as one of the most important areas of research activity in the field of polymer science and technology. Because of their satisfactory performance in meeting specific needs of the polymer industry, they have drawn considerable attention in replacing not only many conventional materials, but also some of the polymers that are in vogue. By suitably varying the blend compositions and manipulating the processing conditions, tailor-made products with a unique set of end use properties can be achieved at a much lower cost and within a shorter time than would have been necessary for the development of a new polymer. The usefulness of such blends increases with the increasing range of applications of this type of materials." (Chapter 4) "New and growing demands on polymeric materials cannot be satisfied in future by an assortment extension of basic polymers. Although the introduction of new major-use basic polymer is possible, it seems unlikely in view of current projected economic and technical considerations. On the other hand, new products based on the modification of existing polymers have and will continue to be fruitful areas for both scientific and commercial developments. The driving forces for these developments are: 1. Improved performance, 2. Reduced cost, 3. Present, pending and future legislation dealing with health and environmental issues." (Chapter 11)
New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of polymer chains affects polymer properties and presents the latest strategies for developing tactic polymers using single-site catalysis. This unified volume explains the mechanistic basics of tactic polymerizations, beginning with an extensive survey of the most important classes of metallocene and post-metallocene catalysts used to make polypropylenes. It also focuses on tactic stereoblock and ethylene/propylene copolymers and catalyst active site models, followed by chapters discussing the structure of more stereochemically complex polymers and polymerizations that proceed via non-vinyl-addition mechanisms. Individual chapters thoroughly describe tactic polymerizations of -olefins, styrene, dienes, acetylenes, lactides, epoxides, acrylates, and cyclic monomers, as well as cyclopolymerizations and ditactic structures, olefin/CO polymers, and metathesis polyalkenamers. An ideal reference and supplementary text, Stereoselective Polymerization with Single-Site Catalysts enables both new and experienced chemists to better understand tactic polymers and select appropriate catalyst systems for their preparation.
Electrical Properties of Polymers describes the electric phenomena responsible for determining the chemical and supramolecular structure of polymers and polymeric materials. The authors explore the properties of quasi-static dipoles, reviewing Brownian motion, Debye theory, Langevin and Smoluchowski equations, and the Onsager model. This reference displays Maxwell and entropy equations, along with several others, that depict the thermodynamics of dielectric relaxation. Featuring end-of-chapter problems and useful appendices, the book reviews molecular dynamics simulations of dynamic dielectric properties and inspects mean-square dipole moments of gases, liquids, polymers, and fixed conformations.
The extraordinary growth in the production and use of man-made fibers over the past fewdecades has focused attention on the surface properties of fibers and textiles. This volumecombines surface science and technology in its presentation of the substantial progressthat has been made in the technology related to the surface characteristics of natural,synthetic, and glass fibers and textiles.Adopting an interdisciplinary approach , the coverage places emphasis upon the wetting,soiling, staining, frictional, and adhesive properties of fibers and fabrics, as well asphenomena related to these properties. The book offers critical reviews which describeexperimental facts, theories, and processes. Symbols are clearly defined in each chapter.Among the subjects covered are the surface properties of glass fibers, soil release, stainand water repellance, friction of fabrics, bonding of nonwovens, and the wetting of fibers.Surface Characteristics of Fibers and Textiles, Part II is an outstanding textbook forcourses dealing with surface chemistry, the mechanical properties of textiles, textiletechnology, and polymer chemistry . It is also a valuable reference book designed to makecurrent knowledge on these subjects accessible to industrial and academic researchers.
Agricultural biomass is abundant worldwide and it can be considered as alternative source of renewable and sustainable materials which can be used as potential materials for different applications. Despite this enormous production of agricultural biomass, only a small fraction of the total biomass is utilized for different applications. Industry must be prepared to take advantage of the situation and utilize the available biomass in the best possible manner. Agricultural biomass such as natural fibres has been successfully investigated as a great potential to be used as a renewable and sustainable materials for the production of composite materials. Natural fibres offer excellent specific properties and have potential as outstanding reinforcing fillers in the matrix and can be used as an alternative material for biocomposites, hybrid composites, pulp, and paper industries. Natural fibre based polymer composites made of jute, oil palm, flex, hemp, kenaf have a low market cost, attractive with respect to global sustainability and find increasing commercial use in different applications. Agricultural biomass based composites find applications in a number of fields viz., automotive industry and construction industry. Future research on agricultural biomass-natural fibre based composites should not only be limited to its automotive applications but can be explored for its application in aircraft components, construction industry, rural housing and biomedical applications. In this book we will cover the chemical, physical, thermal, electrical, and biodegradability properties of agricultural biomass based composite materials and its different potential applications. The main goal of this volume is to familiarize researchers, scientists and engineers with the unique research opportunities and potentials of agricultural biomass based materials. Up-to-date information on alternative biomass utilization Academic and industry leaders discuss unique properties of biomass based composite materials Direct application of agricultural biomass materials as sustainable and renewable alternatives
This series presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and materials science. It is addressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered. Impact Factor Ranking: Always number one in Polymer Science.
Functional Polymer Conjugates for Medicinal Nucleic Acid Delivery, by Ernst Wagner Biodegradable Nanoparticles as Vaccine Adjuvants and Delivery Systems: Regulation of Immune Responses by Nanoparticle-Based Vaccine, by Takami Akagi, Masanori Baba and Mitsuru Akashi Biodegradable Polymeric Assemblies for Biomedical Materials, by
Yuichi Ohya, Akihiro Takahashi and Koji Nagahama Cytocompatible Hydrogel Composed of Phospholipid Polymers for Regulation of Cell Functions, by Kazuhiko Ishihara, Yan Xu and Tomohiro Konno
Advances in Tissue Engineering Approaches to Treatment of Intervertebral Disc Degeneration: Cells and Polymeric Scaffolds for Nucleus Pulposus Regeneration, by Jeremy J. Mercuri and Dan T. Simionescu Functionalized Biocompatible Nanoparticles for Site-Specific Imaging and Therapeutics, by Ranu K. Dutta, Prashant K. Sharma, Hisatoshi Kobayashi and Avinash C. Pandey "
This volume is based on lectures given at the NATO-Advanced Study Institute on Structure and Dynamics of Polymer and Colloid Systems held in Les Houches, France from September 14-24, 1999. The meeting arose from a perceived need to bring together scientists studying the polymer and colloid fields. Although these fields are intertwined and share many techniques (e. g. , light, neutron and x-ray scattering), it is remarkable how little the approaches and concepts used by the one field penetrate the other. For instance, the theory of spherical colloids is very highly developed and many of the concepts developed for these systems can be extended to those with non-spherical morphology, such as solutions of rigid rod polymers. In addition, mixtures of polymers and colloids, both in the bulk and at interfaces, are the basis for many industrial products. Methods are now rapidly being developed for understanding the structure and dynamics in polymer/colloid mixtures at the molecular level, but the point of view of the colloid scientist is often rather different from that of the polymer scientist. The NATO-ASI brought together polymer and colloid scientists, including many young researchers, who presented and discussed recent developments in these fields and the possibilities for cross-fertilization This volume contains articles on a wide variety of topics at the research forefront of the polymer and colloid fields by some of the world's foremost experts at a level accessible to graduate students, post-docs and researchers.
Polymer Processing Instabilities: Control and Understanding offers a practical understanding of the various flows that occur during the processing of polymer melts. The book pays particular attention to flow instabilities that affect the rate of production and the methods used to prevent and eliminate flow instabilities in order to increase production rates and enhance manufacturing efficiency. Polymer Processing Instabilities: Control and Understanding summarizes experimental observations of flow instabilities that occur in numerous processing operations such as extrusion, injection molding, fiber spinning, film casting, and film blowing for a wide range of materials, including most commodity polymers that are processed as melts at temperatures above their melting point or as concentrated solutions at lower temperatures. The book first presents the fundamental principles in rheology and flow instabilities. It relates the operating conditions with flow curves, the critical wall shear stress for the onset of the instabilities, and new visualization techniques with numerical modeling and molecular structure. It reviews one-dimensional phenomenological relaxation/oscillation models describing the experimental pressure and flow rate oscillations, analyzes the gross melt fracture (GMF) instability, and examines how traditional and non-traditional processing aids eliminate melt fracture and improve polymer processability. It supplies a numerical approach for the investigation of the linear viscoelastic stability behavior of simplified injection molding flows and examines a newly discovered family of instabilities that occur in co-extrusion. Polymer Processing Instabilities: Control and Understanding is unique in that it fills a gap in the polymer processing literature where polymer flow instabilities are not treated in-depth in any book. It summarizes state-of-the-art developments in the field, particularly those of the last ten years, and contains significant data based on this research.
Providing an up-to-date overview of the field, this reference presents extensive discussions on a wide range of approaches for molecular imprinting written by pioneering experts on the subject. Molecularly Imprinted Materials: Science and Technology offers experimental protocols that exemplify specific techniques, as well as detailed surveys on molecular imprinting research and applications. Provides a comprehensive tutorial for those who wish to learn basic techniques and make new contributions to the field, as well as in-depth discussions, guidelines, and experimental protocols to help beginners gain a jump-start in the field of molecular imprinting The book examines the recent evolution of the technology, offering step-by-step instruction on methods to design and optimize molecularly imprinted polymers and suggestions, recommendations, and troubleshooting strategies for alternative approaches and improvements discussed in the text. about the editors... MINGDI YAN is Associate Professor, Department of Chemistry, Portland State University, Oregon. After serving as a senior research scientist at Ikonos Corporation, Portland, Oregon, she joined the Portland State University faculty and now leads a research group in organic and polymeric materials science. She received the B.S. degree in polymer physics from the University of Science and Technology, China, and the Ph.D. degree in organic chemistry from the University of Oregon. OLOF RAMSTROEM is Associate Professor, Royal Institute of Technology, Stockholm, Sweden. After serving with Professor Jean-Marie Lehn at Universite Louis Pasteur, Strasbourg, France, he joined the Royal Institute of Technology and is now leading a group specializing in supramolecular chemistry and molecular recognition. He received the M.Sc. degree in chemical engineering and the Ph.D. degree in bioorganic chemistry/applied biochemistry from Lund Institute of Technology/Lund University, Sweden.
An in-depth review of important preparative methods for the synthesis and chemical modification of polymers, this authoritative second edition examines the advantages and limitations of various polymerization applications and procedures. It features new approaches and innovative strategies from the most prominent industry and academic laboratories, reflecting the burgeoning role of polymers in modern science and technology. The book analyzes biodegradable polymers for biomedical applications; investigates the use of polyolefins, polymeric dienes, aromatic polyethers, polymides, and metal-containing macromolecules; and covers polymers of acrylic acid, methacrylic acid, and maleic acid.
Volume A of Handbook of Polymer Nanocomposites deals with Layered Silicates. In some 20 chapters the preparation, architecture, characterisation, properties and application of polymer nanocomposites are discussed by experts in their respective fields
The first four volumes of the series on 'Charged and Reactive Polymers' have been devoted to polymers in solution (Voh. I and II) or in gel and membrane forms (Vols. III and IV). In correlation with charges, other physical or chemical properties of macro molecules have been considered. Understanding of charge and hydrophobic effects is equally important for synthetic and biopolymers or their systems. Optically Active Polymers are related to problems of the same class, since optical activity is an inherent property of both natural macromolecules as well as a great variety of polymers synthesized in the Jast twenty years. Optical activity is a physical spectral property of chiral matter caused by asymmetrical configurations, conformations and structures which have no plane and no center of symmetry and consequently have two mirror image enantiomeric forms of inverse optical rotation. The racemic mixture of chiral enantiomers is optically inactive. The most common form of optical activity was first measured at a constant wavelength by the angle of rotation of linearly polarized light. More recently the measurements have been extended to the entire range of visible and attainable ultraviolet regions where electronic transitions are observed, giving rise to the ORD technique (Optical Rotatory Dispersion). The Cotton effects appear in the region of optically active absorption bands; outside of these bands the plain curve spectrum is also dependent on all the electronic transitions of the chromophores."
In the past few decades, marine organisms, including macroalgae and microalgae, have been extensively explored as potential sources of bioactive compounds with applications in various fields such as pharmaceuticals, biomedicine, cosmetics and foodstuffs. Marine polysaccharides, such as chitin/chitosan, ulvans, fucans, alginates and carrageenans, are biochemical compounds with several important properties such as anticoagulant and/or antithrombotic, immunomodulatory, antitumor, antilipidemic, hypoglycemic, antibiotic, anti-inflammatory and antioxidant properties. Due to their biocompatible, nontoxic and biodegradable nature, marine polysaccharides offer a better alternative to be used in advancement of the biomedical field. This book focuses on marine polysaccharides; their derivatives, blends, composites and hydrogels; and their multifaceted applications in various fields. The book also discusses the various aspects of marine polysaccharides from the point of view of chemistry and related applications. It is an important reference for marine biotechnologists, natural product scientists, students, researchers and academicians working in the area of materials science, marine science and polymer chemistry.
This book discusses the fundamental of bending actuation with a focus on ionic metal composites. It describes the applications of ionic polymer metal composite (IPMC) actuators, from conventional robotic systems to compliant micro robotic systems used to handle the miniature and fragile components during robotic micro assembly. It also presents mathematical modelings of actuators for engineering, biomedical, medical and environmental systems. The fundamental relation of IPMC actuators to the biomimetic systems are also included.
The concept to utilize an ion-conducting polymer membrane as a solid po- mer electrolyte offers several advantages regarding the design and operation of an electrochemical cell, as outlined in Volume 215, Chapter 1 (L. Gubler, G.G. Scherer). Essentially, the solvent and/or transport medium, e.g., H O, 2 + for the mobile ionic species, e.g., H for a cation exchange membrane, is taken up by and con?ned into the nano-dimensional morphology of the i- containingdomainsofthepolymer.Asaconsequence, aphaseseparationinto a hydrophilic ion-containing solvent phase and a hydrophobic polymer ba- bone phase establishes. Because of the narrow solid electrolyte gap in these cells, low ohmic losses reducing the overall cell voltage can be achieved, even at highcurrent densities. This concept was applied to fuel cell technology at a very early stage; h- ever, performance and reliability of the cells were low due to the dissatisfying membrane properties at that time. The development of per?uoro sulfonate and carboxylate-type membranes, in particular for the chlor-alkali process, directly fostered the further development of proton-conducting membranes and, as a consequence, also the progress in this type of fuel cell technology (polymer electrolyte fuel cell, PEFC) |
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