Thermal Analysis (TA) has become an indispensable family of analytical techniques in the polymer research. The increased importance of these techniques can be seen as the result of three more or less parallel developments:
a tempestuous development of TA measuring techniques in combination with a high degree of automation,
the strongly increased understanding of the underlaying theory and,
the increasing knowledge of the relation between the polymers' chemical structure and their physical properties.

These areas are still in their developmental stages, especially the third area. The increasing knowledge of the dependence of physical properties on chemical structure just accentuated more and more the need for accurate thermoanalytical measurements, and this knowledge is very important for the first stages of the development of new polymeric systems. Besides, the contribution of TA remains necessary for the technical and commercial development of such a new polymer system. The use of the various TA techniques in these processes is described in this book in nine chapters, while chapter ten illustrates the information obtained about different polymers during special case studies.

This book illustrates in this way, applications of a wide variety of TA techniques whilst it is written from a materials characterisation rather than from a TA point of view with attention being paid to the chemical structure/physical properties correlations.
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A handbook on syntheses and properties, production processes, and applications of maleic anhydride and maleic anhydride derived products - all in one text. This handbook provides a comprehensive overview of maleic anhydride chemistry and applications from the professional perspective. With chapters written by leading R&D scientists from the chemical industry, and edited by the Vice President and ASI Technology Chief at Ashland Specialty Ingredients (ASI), Dr. Osama M. Musa, readers will find a unique perspective and summary of the latest advancements in the field of maleic anhydride science. Maleic anhydride is produced industrially on large scale (10E3 kt/annum). Its rich chemistry makes it an important raw material for numerous products and processes (e.g. for applications in polymers and coatings), many of which are covered in this handbook for the first time in a comprehensive manner. The broad scope spans topics ranging from production techniques (including topics such as processes, catalysis, trouble-shooting), synthesis and properties of small and polymeric maleic anhydride based compounds (focusing on industrially relevant compounds as well as emerging areas of importance) and in-depth and broad discussions of commercial maleic anhydride based applications.

This new volume presents leading-edge research in the rapidly changing and evolving field of polymer science as well as on chemical processing. The topics in the book reflect the diversity of research advances in the production and application of modern polymeric materials and related areas, focusing on the preparation, characterization, and applications of polymers. Also covered are various manufacturing techniques. The book helps to fill the gap between theory and practice in industry. The book introduces current state-of-the-art technology in modern materials with an emphasis on the rapidly growing technologies. It takes a unique approach by presenting specific materials and then progresses into a discussion of the ways in which these materials and processes are integrated into today's functioning manufacturing industry. Readers will also discover how material properties relate to the process variables in a given process as well as how to perform quantitative engineering analysis of manufacturing processes.

This book reviews the latest research, development, and future potential of polyimides and green polymer chemistry. It combines the major interdisciplinary research in this area. Polymers with imidic structure, known as polyimides, are widely investigated owing to their practical implications in numerous industrial sectors. The book explains why polyimides offer versatility unparalleled in comparison to most other classes of macromolecules. In addition, developments in green polymer chemistry in this area have been stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunities to design and produce "green" products and processes. Major advances include new uses of green processing methodologies, and green polymeric products. Imidic Polymers and Green Polymer Chemistry: New Technology and Developments in Process and Product is targeted to scientists, engineers, and students who are involved or interested in green polymer chemistry and imidic polymers. This book will serve as a valuable reference for those with an interest in synthesis of polyimides and the chemistry and physical chemistry of polyimide compounds.

This new book explores the consideration of relationships that connect the structural and basic mechanical properties of polymeric mediums within the frameworks of fractal analysis with cluster model representations attraction. Incidentally, the choice of any structural model of medium or their combinations is defined by expediency and further usage convenience only. This book presents leading-edge research in this rapidly changing and evolving field. The book presents descriptions of the main reactions of high-molecular substances within the frameworks of fractal analysis and irreversible aggregation models. Synergetics and percolation theory were also used. In spite of the enormous number of papers dealing with the influence of the medium on the rate of chemical reactions (including synthesis of polymers), no strict quantitative theory capable of "universal" application has been put forward up until now. It is now possible to describe the relationship between the reaction rate constants and the equilibrium constants with the nature of the medium in which the reactions take place by means of a single equation. This important book for the first time gives structural and physical grounds of polymers synthesis and curing, and the fractal analysis is used for this purpose. This new book: * Highlights some important areas of current interest in polymer products and chemical processes * Focuses on topics with more advanced methods * Emphasizes precise mathematical development and actual experimental details * Analyzes theories to formulate and prove the physicochemical principles * Provides an up-to-date and thorough exposition of the present state of the art of complex polymeric materials

This book provides a vast amount of information on new approaches, limitations, and control on current polymers and chemicals complexity of various origins, on scales ranging from single molecules and nano-phenomena to macroscopic chemicals. Starting with a detailed introduction, the book is comprised of chapters that survey the current progress in particular research fields. The chapters, prepared by leading international experts, yield together a fascinating picture of a rapidly developing research discipline that brings chemical technology and polymers to new frontiers.

This book covers a broad range of polymeric materials and provides industry professionals and researchers in polymer science and technology with a single, comprehensive book summarizing all aspects involved in the functional materials production chain. This volume presents the latest developments and trends in advanced polymer materials and structures. It discusses the developments of advanced polymers and respective tools to characterize and predict the material properties and behavior. This book has an important role in advancing polymer materials in macro and nanoscale. Its aim is to provide original, theoretical, and important experimental results that use non-routine methodologies. It also includes chapters on novel applications of more familiar experimental techniques and analyses of composite problems that indicate the need for new experimental approaches. This new book: * Provides a collection of articles that highlight some important areas of current interest in key polymeric materials and technology * Gives an up-to-date and thorough exposition of the present state of the art of key polymeric materials and technology * Describes the types of techniques now available to the engineers and technicians and discusses their capabilities, limitations, and applications * Provides a balance between materials science and chemical aspects, basic and applied research * Focuses on topics with more advanced methods * Emphasizes precise mathematical development and actual experimental details * Explains modification methods for changing of different materials properties

This book is intended to fiber technologists, textile dealers, and textile salesmen a practical guideline to become acquainted with and to deepen their knowledge of the processes for the manufacture of film tapes, split-film yarns, and fibrillated film fibers.

Semiconducting polymers are of great interest for applications in electroluminescent devices, solar cells, batteries, and diodes. This volume provides a thorough introduction to the basic concepts of the photophysics of semiconducting polymers as well as a description of the principal polymerization methods for luminescent polymers. Divided into two main sections, the book first introduces the advances made in polymer synthesis and then goes on to focus on the photophysics aspects, also exploring how new advances in the area of controlled syntheses of semiconducting polymers are applied. An understanding of the photophysics process in this kind of material requires some knowledge of many different terms in this field, so a chapter on the basic concepts is included. The process that occurs in semiconducting polymers spans time scales that are unimaginably fast, sometimes less than a picosecond. To appreciate this extraordinary scale, it is necessary to learn a range of vocabularies and concepts that stretch from the basic concepts of photophysics to modern applications, such as electroluminescent devices, solar cells, batteries, and diodes. This book provides a starting point for a broadly based understanding of photophysics concepts applied in understanding semiconducting polymers, incorporating critical ideas from across the scientific spectrum.

Thermodynamic data of polymer solutions are paramount for industrial and laboratory processes. These data also serve to understand the physical behavior of polymer solutions, study intermolecular interactions, and gain insights into the molecular nature of mixtures. Nearly a decade has passed since the release of a similar CRC Handbook and since then a large amount of new experimental data have been published, which is now compiled in this book. The CRC Handbook of Phase Equilibria and Thermodynamic Data of Polymer Solutions at Elevated Pressures features nearly 500 newly published references containing approximately 175 new vapor-liquid equilibrium data sets, 25 new liquid-liquid equilibrium data sets, 540 new high-pressure fluid phase equilibrium data sets, 60 new data sets describing PVT properties of polymers, and 20 new data sets with densities or excess volumes. The book is a valuable resource for researchers, specialists, and engineers working in the fields of polymer science, physical chemistry, chemical engineering, materials science, biological science and technology, and those developing computerized predictive packages.

The Handbook of Thermodynamic Data of Copolymer Solutions is the world's first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the CRC Handbook of Chemistry and Physics, has gathered up-to-the-minute data from more than 300 literature sources. Fully committed to ensuring the reliability of the data, the author included results in the handbook only if numerical values were published or if authors provided their numerical results by personal communication. With volumetric, calormetric, and various phase equilibrium data on more than 165 copolymers and 165 solvents, this handbook furnishes: 250 vapor-pressure isotherms 75 tables of Henry's constants 50 LLE data sets 175 HPPE data sets 70 PVT data tables Carefully organized, clearly presented, and fully referenced, The Handbook of Thermodynamic Data of Copolymer Solutions will prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers. CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions CRC Handbook of Thermodynamic Data of Copolymer Solutions

There is increasing interest in the area of protective vests, either for protection against bullets or protection from the most realistic threats within domestic frontline operations: edged weapon, knives, and medical needles. This volume addresses that need. This new book provides an in-depth survey of the state-of-the-art research and practical techniques in the area of protected fabrics, especially stab-resistant and bulletproof fabrics. The book covers: * The history of protective armor: the long history of the art of protective armor manufacturing. * Materials used for body armor: the design and materials used for soft armor to increase its perforation-resistance utilizing high-performance fibers. * Anti-stab and anti-bullet armor design: the different design parameters required for the design of flexible armor in order to stop high-velocity projectiles. * The comfort of the body armor design: the flexibility, thermal resistivity, and evaporative moisture resistivity through the fabric. * Methods of testing the flexible body armors: testing the components of flexible body armor, according to the level of the protection required, such as NIJ Standards, HOSDB Body Armour Standards for UK Police, and the German SK1 Standard, among others. Written by an expert in textile composite material engineering, this volume fills an important gap in the area of protective fabric against stabbing or bullets and provides invaluable practical knowledge for body armor design.

Thermodynamic data form the basis for separation processes used in different fields of science and industry, from specialty chemicals to foods and pharmaceuticals. One obstacle to developing new production processes, products, or optimization is the lack, or inaccessibility, of experimental data related to phase equilibrium. Access More Than 1200 Data Sets, Including 810 Binary Systems, 325 Ternary Systems, and 25 Quaternary (or Higher) Systems The CRC Handbook of Liquid-Liquid Equilibrium Data of Polymer Solutions provides a thorough and up-to-date compilation of experimental liquid-liquid equilibrium (LLE) data and their original sources. Arranged in a consistent format, the handbook provides convenient access to cloud-point and coexistence data as well as upper and lower critical solution temperatures and important demixing data for each system. An Excellent Companion to the Author's Previous Collections of Thermodynamic Data! While the author's previous data compilations center around specific types of polymer systems, Wohlfharth'slatest work distinguishes itself by focusing instead on representing LLE data for all types of polymer systems in a single source.

Nanomaterials are becoming ubiquitous; microbes similarly are everywhere. This book focuses on various ways the diverse nanomaterials interact with microbial communities and implications of such interactions. Both toxicity and beneficial effects of nanomaterial-microbe interactions have been covered. This includes areas such as fate and bioavailability of nanomaterials in environments, microbial synthesis of nanomaterials and antimicrobial action of nanomaterials. Fairly comprehensive but with narrow focus, the book provides useful insights into these interactions which need to be factored in while designing nanoscience based new technologies.

Every electrochemical source of electric current is composed of two electrodes with an electrolyte in between. Since storage capacity depends predominantly on the composition and design of the electrodes, most research and development efforts have been focused on them. Considerably less attention has been paid to the electrolyte, a battery's basic component. This book fills this gap and shines more light on the role of electrolytes in modern batteries. Today, limitations in lithium-ion batteries result from non-optimal properties of commercial electrolytes as well as scientific and engineering challenges related to novel electrolytes for improved lithium-ion as well as future post-lithium batteries.

Heterophase polymerization is a century-old technology with a wide range of relevant industrial applications, including coatings, adhesives, rubbers, and many other specialized biomedical and high-performance materials. However, due to its multiscale complexity, it still remains a challenging research topic. It is a broad field covering all heterogeneous polymerization processes that result in polymer dispersions. Its technical realizations comprise emulsion polymerization, dispersion polymerization, suspension polymerization, miniemulsion polymerization, microemulsion polymerization, and others. This book is devoted to the science and technology of heterophase polymerization, considering it a generic term as well as an umbrella expression for all of its technical realizations. It presents, from a modern perspective, the basic concepts and principles required to understand the kinetics and thermodynamics of heterophase polymerization at the atomistic, molecular, macromolecular, supramolecular, colloidal, microscopic, mesoscopic, and macroscopic scales. It critically discusses the important physicochemical mechanisms involved in heterophase polymerization, such as nucleation, particle aggregation, mass transfer, swelling, spontaneous emulsification, and polymerization kinetics, along with the experimental evidences at hand.

Renowned experts give all essential aspects of the techniques and applications of graft copolymers based on polysaccharides. Polysaccharides are the most abundant natural organic materials and polysaccharide based graft copolymers are of great importance and widely used in various fields. Natural polysaccharides have recently received more attention due to their advantages over synthetic polymers by being non-toxic, biodegradable and available at low cost. Modification of polysaccharides through graft copolymerization improves the properties of polysaccharides. Grafting is known to improve the characteristic properties of the backbones. Such properties include water repellency, thermal stability, flame resistance, dye-ability and resistance towards acid-base attack and abrasion. Polysaccharides and their graft copolymers find extensive applications in diversified fields. Applications of modified polysaccharides include drug delivery devices, controlled release of fungicides, selective water absorption from oil-water emulsions, purification of water etc.

This timely volume provides an overview of polymer characterization test methods and presents experimental research in polymers using modern methods. Each chapter describes the principle of the respective method, as well as the detailed procedures of experiments with examples of actual applications and demonstrates the advantages and disadvantages of each physical technique. Thus, readers will be able to apply the concepts as described in the book to their own experiments. The successful characterization of polymer systems is one of the most important objectives of today's experimental research of polymers. Considering the tremendous scientific, technological, and economic importance of polymeric materials, especially in industry, it is impossible to overestimate the usefulness of experimental techniques in this field. Since the chemical, pharmaceutical, medical, and agricultural industries, as well as many others, depend on this progress to an enormous degree, it is critical to be as efficient, precise, and cost-effective in our empirical understanding of the performance of polymer systems as possible. This presupposes our proficiency with, and understanding of, the most widely used experimental methods and techniques. The methods and instrumentation described in this volume represent modern analytical techniques useful to researchers, product development specialists, and quality control experts in polymer synthesis and manufacturing. Engineers, polymer scientists, and technicians will find this volume useful in selecting approaches and techniques applicable to characterizing molecular, compositional, rheological, and thermodynamic properties of elastomers and plastics.

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" -Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

This book provides a broad overview of current studies in the engineering of polymers and chemicals of various origins. The innovative chapters cover the growth of educational, scientific, and industrial research activities among chemists, biologists, and polymer and chemical engineers. This book publishes significant research and reviews reporting new methodologies and important applications in the fields of industrial chemistry, industrial polymers, and biotechnology, as well the latest coverage of chemical databases and the development of new computational methods and efficient algorithms for chemical software and polymer engineering.

This new book provides a solid understanding of the recent developments in the field of composites and nanocomposites. It explains the significance of the new fillers, such as graphene and arbon nanotubes in different matrix systems. The application of these materials in biological and others fields also makes this book unique. This detailed study of nanocomposites, their structure, processing and characterization will be of value in all walks of engineering life. The book covers the following topics: * polymer matrix composites * ceramic matrix composites * carbon matrix composites * wood-based composites * biocomposites * ecocomposites * nanocomposites * processing * properties * fracture and damage mechanics * durability * and more Composite materials are solids that contain two or more distinct constituent materials or phases, on a scale larger than the atomic. The term "composite" is usually reserved for those materials in which the distinct phases are separated on a scale larger than the atomic, and in which properties such as the elastic modulus are significantly altered in comparison with those of a homogeneous material. Composites have properties that cannot be achieved by either of the constituent materials alone. Composites are becoming more and more important as they can help improve our quality of life. Composites are put into service in flight vehicles, automobiles, boats, pipelines, buildings, roads, bridges, and dozens of other products. Researchers are finding ways to improve other qualities of composites so they may be strong, lightweight, long-lived, and inexpensive to produce. The science and engineering of composites and nanocomposites draws on traditional characterization and processing technologies. Research describing structures containing nanoparticles seems to rely on methods that are being pushed to the limit of resolution. Preparation of nanocomposites also poses very real processing challenges. The list of questions about the fabrication, characterization, and use of nanocomposites is long despite massive financial and intellectual investment. The magnitude of the effects these small particles impart to the bulk properties of a composite are great enough that the science is likely to continue to grow in importance.

Using fractal analysis, irreversible aggregation models, synergetics, and percolation theory, this book describes the main reactions of high-molecular substances. It is the first to give the structural and physical grounds of polymers synthesis and curing based on fractal analysis. It provides a single equation for describing the relationship between the reaction rate constants and the equilibrium constants with the nature of the medium.

This new book presents the authors' biomedical studies of natural degradable biopolymers (polyhydroxyalkanoates [PHAs]) and discusses the demand for medical-grade materials and modern trends, focusing on the present status and future potential of PHAs. The authors present and summarize their most important results and findings obtained during the last few years in experimental studies and clinical trials of PHAs at the Institute of Biophysics Siberian Branch of Russian Academy of Science.

Green Polymers and Environment Pollution Control examines the latest developments in the important and growing field of producing conventional polymers from sustainable sources. Presenting cutting-edge research from a group of leading international researchers from academia, government, and industrial institutions, the book explains what green polymers are, why green polymers are needed, which green polymers to use, and how manufacturing companies can integrate them into their manufacturing operations. It goes on to provide guidelines for implementing sustainable practices for traditional petroleum-based plastics, biobased plastics, and recycled plastics. With recent advancements in synthesis technologies and the discovery of new functional monomers, research shows that green polymers with better properties can be produced from renewable resources. The book describes these advances in synthesis, processing, and technology. It provides not only state-of-the-art information but also acts to stimulate research in this direction. Green Polymers and Environment Pollution Control offers an excellent resource for researchers, upper-level graduate students, brand owners, environment and sustainability managers, business development and innovation professionals, chemical engineers, plastics manufacturers, agriculture specialists, biochemists, and suppliers to the industry to debate sustainable, economic solutions for polymer synthesis.

With growing concern for the environment and the rising price of crude oil, there is increasing demand for non-petroleum-based polymers from renewable resources. Recognizing emerging developments in biopolymer systems research, this book brings together a number of key biopolymer and bioplastic topics in one place. The book highlights the importance and impact of eco-friendly green biopolymers and bioplastics, both environmentally and economically. It provides important insight into the diversity of polymers obtained directly from, or derived from, renewable resources. This volume, Applied Biopolymer Technology and Bioplastics: Sustainable Development by Green Engineering Materials, will be valuable for a broad audience of engineers and scientists, especially those designing with biopolymers and biodegradable plastics, or evaluating the options for switching from traditional plastics to biopolymers. The content of this book will prove useful for students, researchers, and professionals working in the field of green technology.