Functionalized polymers are macromolecules to which chemically bound functional groups are attached which can be used as catalysts, reagents, protective groups, etc. Functionalized polymers have low cost, ease of processing and attractive features for functional organic molecules. Chemical reactions for the introduction of functional groups in polymers and the conversion of functional groups in polymers depend on different properties. Such properties are of great importance for functionalization reactions for possible applications of reactive polymers. This book deals with the synthesis and design of various functional polymers, the modification of preformed polymer backbones and their various applications.

Control over macromolecular architecture and resulting material properties has been a central goal of polymer chemistry. There has been much interest in developing new synthetic routes to prepare smart materials with novel compositions and topologies for various applications. The considerable progress in the metal mediated macromolecular engineering over the past decade has had a major impact on the development of well-defined macromolecular architectures and the synthesis of smart materials. Particularly, remarkable strong developments have been observed for the synthesis of smart materials via four metal mediated macromolecular engineering techniques; Anionic, ROMP, ATRP and Click Chemistry. These materials have found uses in advanced microelectronics, technical and biomedical applications as well as in chemical sensors applications.

This book is comprised of 27 chapters written by leading scientists from NATO and Partner Countries who have greatly contributed in the area of Anionic, ROMP, ATRP and Click Chemistry. It highlights the fundamental aspects and recent developments of these four powerful techniques and evaluate their potential in the syntheses of smart materials from complex structures (grafts, brushes, dendrimers, etc.) to nanostructures (self-assembly, nano-size, etc) for a wide range of applications.

The book reports on the synthesis of a wide range of well-defined complex polymeric systems such as thermoresponsive smart polymers, star copolymers, biocompatible polymers, amphipilic smart nano structured, conducting polymers, self assembled polymers, and hyperbranced polymers.

Thermodynamic data form the basis for separation processes used in different fields of science and industry, from specialty chemicals to foods and pharmaceuticals. One obstacle to developing new production processes, products, or optimization is the lack, or inaccessibility, of experimental data related to phase equilibrium. Access More Than 1200 Data Sets, Including 810 Binary Systems, 325 Ternary Systems, and 25 Quaternary (or Higher) Systems The CRC Handbook of Liquid-Liquid Equilibrium Data of Polymer Solutions provides a thorough and up-to-date compilation of experimental liquid-liquid equilibrium (LLE) data and their original sources. Arranged in a consistent format, the handbook provides convenient access to cloud-point and coexistence data as well as upper and lower critical solution temperatures and important demixing data for each system. An Excellent Companion to the Author's Previous Collections of Thermodynamic Data! While the author's previous data compilations center around specific types of polymer systems, Wohlfharth'slatest work distinguishes itself by focusing instead on representing LLE data for all types of polymer systems in a single source.

The Handbook of Thermodynamic Data of Copolymer Solutions is the world's first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the CRC Handbook of Chemistry and Physics, has gathered up-to-the-minute data from more than 300 literature sources. Fully committed to ensuring the reliability of the data, the author included results in the handbook only if numerical values were published or if authors provided their numerical results by personal communication. With volumetric, calormetric, and various phase equilibrium data on more than 165 copolymers and 165 solvents, this handbook furnishes: 250 vapor-pressure isotherms 75 tables of Henry's constants 50 LLE data sets 175 HPPE data sets 70 PVT data tables Carefully organized, clearly presented, and fully referenced, The Handbook of Thermodynamic Data of Copolymer Solutions will prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers. CRC Handbook of Thermodynamic Data of Polymer Solutions, Three Volume Set CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions CRC Handbook of Thermodynamic Data of Copolymer Solutions

Rubber-to-metal bonded systems are widely used in industry with long term service, such as in high-speed trains and marine ships. These complex systems are difficult to model and predict. Hence, a comprehensive book for simulation methods in this specialized field is desirable.This book is intended for engineers who work in industry on the simulation, design and applications of rubber anti-vibration systems. In addition, it can serve as a reference book for scientists.This book is the Second Edition of the book entitled 'Numerical Prediction & Case Validation for Rubber Anti-vibration System' (in both English and Chinese). The newly added content contains predictions on idealized Mullins effect without data fitting; creep/relaxation variations from temperature change, loading, hardness and different component and dynamic interaction between solid rubber and fluid.

The purpose of this book will be to demonstrate 1) the newly developed method of using reactive functionalized materials in agriculture to solve the economic and public health problems associated with using conventional agrochemicals; and 2) new technology aimed at achieving the greening of chemistry to meet appropriate environmental standards in both agriculture and industrial foodstuffs production. More specifically, the book will accomplish this goal by addressing 3 key issues in the field: 1) the production of reactive functionalized materials with enhanced properties that offer a major opportunity to overcome the disadvantages of using traditional materials; 2) the applications of functionalized materials in agriculture for the purpose of solving the economic and the environmental pollution problems associated with the uses of conventional agrochemicals; and 3) the contribution of polymers in solving problems associated with conventional procedures of food growth and processing, including those used in the dairy industry, sugar and fruit juices, beer and wine production, nutritive and nonnutritive food additives, and in food protection.

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" -Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Thermodynamic data of polymer solutions are paramount for industrial and laboratory processes. These data also serve to understand the physical behavior of polymer solutions, study intermolecular interactions, and gain insights into the molecular nature of mixtures. Nearly a decade has passed since the release of a similar CRC Handbook and since then a large amount of new experimental data have been published, which is now compiled in this book. The CRC Handbook of Phase Equilibria and Thermodynamic Data of Polymer Solutions at Elevated Pressures features nearly 500 newly published references containing approximately 175 new vapor-liquid equilibrium data sets, 25 new liquid-liquid equilibrium data sets, 540 new high-pressure fluid phase equilibrium data sets, 60 new data sets describing PVT properties of polymers, and 20 new data sets with densities or excess volumes. The book is a valuable resource for researchers, specialists, and engineers working in the fields of polymer science, physical chemistry, chemical engineering, materials science, biological science and technology, and those developing computerized predictive packages.

Polymer Electrolytes for Energy Storage Devices, Volume I, offers a detailed explanation of recent progress and challenges in polymer electrolyte research for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail. Features: * Discusses a variety of energy storage systems and their workings and a detailed history of LIBs * Covers a wide range of polymer-based electrolytes including PVdF, PVdF-co-HFP, PAN, blend polymeric systems, composite polymeric systems, and polymer ionic liquid gel electrolytes * Provides a comprehensive review of biopolymer electrolytes for energy storage applications * Suitable for readers with experience in batteries as well as newcomers to the field This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials, chemical, electrical, and mechanical engineers, as well as those involved in related disciplines.

Water-based technology has undergone revolutionary changes during the past two decades. Interest in the properties and uses of water-based coatings, paints and inks has continued to grow since the establishment of the Clean Air Act of 1970. The present book is devoted to recent developments and trends in water-based coating and ink technology. This volume is divided in three broad catagories: (1) Additives and Water-based Coating/Ink Systems, (2) Surface Modifications and Wettability, and (3) Ink/Coating Formulations and Their characterization. The role of various additives to improve the performance and properties of water-based coatings with special reference to surface phenomena such as wettability, adhesion, surface energies, dispersion stability, particle size and size distribution are presented in these sections. This volume documents the proceedings of the International symposium on Surface Phenomena and Additives in Water-Based Coatings and Printing Technology sponsored by the 21st Annual Meeting of the Fine Particle Society (FPS). This meeting was held in San Diego, california, AUgust 21-25, 1990. The symposium upon which this volume is based was organized in four sessions emphasizing several basic and applied aspects of water-based coatings and printing technology. Major topics discussed include advances in water-based technology, water-based flexo and gravure inks, hydrophobically-modified cellulosic thickeners, organosilicones, uv curable silicone release coatings, surface characterization of Ti02 pigments, polymer substrates, flexographic plates and coating films, pigment wetting and dispersing agents, hydrotrope effect in emulsion polymers, film thickness control, particle size measurements, rheological properties, and statistically designed mixtures for ink formulations.

Constitutional Dynamic Chemistry: Bridge from Supramolecular Chemistry to Adaptive Chemistry, by Jean-Marie Lehn Multistate and Phase Change Selection in Constitutional Multivalent Systems, by Mihail Barboiu Dynamic Systemic Resolution, by Morakot Sakulsombat, Yan Zhang and Olof Ramstroem Dynamic Combinatorial Self-Replicating Systems, by Emilie Moulin and Nicolas Giuseppone DCC in the Development of Nucleic Acid Targeted and Nucleic Acid Inspired Structures, by Benjamin L. Miller Dynamic Nanoplatforms in Biosensor and Membrane Constitutional Systems, by Eugene Mahon, Teodor Aastrup und Mihail Barboiu Dynamic Assembly of Block-Copolymers, by D. Quemener, A. Deratani und S. Lecommandoux Dynamic Chemistry of Anion Recognition, by Radu Custelcean Supramolecular Naphthalenediimide Nanotubes, by Nandhini Ponnuswamy, Artur R. Stefankiewicz, Jeremy K. M. Sanders und G. Dan Pantos Synthetic Molecular Machines and Polymer/Monomer Size Switches that Operate Through Dynamic and Non-Dynamic Covalent Changes, by Adrian-Mihail Stadler und Juan Ramirez Reversible Covalent Chemistries Compatible with the Principles of Constitutional Dynamic Chemistry: New Reactions to Create More Diversity, by Kamel Meguellati und Sylvain Ladame.

This text covers the field of steady-state kinetics from basic principles to the control of the multi-enzyme systems which constitute metabolic pathways. Emphasis is placed on the interpretation of the kinetic behaviour of enzyme-catalyzed reactions in terms of mechanisms. Algorithms are developed which can be implemented in computer programs for the derivation of equations. The treatment of steady-state enzyme kinetics is extended to allosteric enzymes and subunit interactions in polymeric enzymes. Principles are presented which provide for mathematical analysis of the control of multi-enzyme systems. Problems are included at the end of each chapter and their solutions are found at the end of the book. This book will be a useful text for advanced undergraduates and graduate students taking courses in enzyme chemistry and enzyme kinetics.

Polymeric foams are sturdy yet lightweight materials with applications across a variety of industries, from packaging to aerospace. As demand for these materials increase, so does innovation in the development of new processes and products. This book captures the most dynamic advances in processes, technologies, and products related to the polymeric foam market. It describes the latest business trends including new microcellular commercialization, sustainable foam products, and nanofoams. It also discusses novel processes, new and environmentally friendly blowing agents, and the development and usage of various types of foams, including bead and polycarbonate, polypropylene, polyetherimide microcellular, and nanocellular. The book also covers flame-retardant foams, rigid foam composites, and foam sandwich composites and details applications in structural engineering, electronics, and insulation. Authored by leading experts in the field, this book minimizes the gap between research and application in this important and growing area.

This book reviews the rapidly emerging field of switchable interfaces and its implications for bioelectronics. The authors piece together early breakthroughs and key developments and highlight the future of switchable bioelectronics by focusing on bioelectrochemical processes based on mimicking and controlling biological environments with external stimuli as well as responsive systems for drug delivery. All chapters in the book strive to answer the fundamental question: How do living systems probe and respond to their surroundings? Following on from that, how can one transform these concepts to serve the practical world of bioelectronics? The central obstacle to this vision is the absence of versatile interfaces that are able to control and regulate the means of communication between biological and electronic systems. This book summarizes the overall progress made to date in building such interfaces at the level of individual biomolecules and focuses on the latest efforts to generate device platforms that integrate biointerfaces with electronics. Chapter 1 introduces the general concept of dynamic interfaces for bioelectronics and gives an overview of the importance of materials and systems for switchable bioelectronics, introducing the reader to different biointerfaces. Chapter 2 pieces together different types of stimuli-responsive polymers and applications. Chapter 3 lays special emphasis on stimuli-responsive polymers with tunable release kinetics and describes the importance of polymer design for delivery applications. Chapter 4 reviews the field of conformational switching in nanofibers for gas-sensing applications. Finally, Chapter 5 focuses on molecular imprinting polymers as recognition elements for sensing applications. As informative as it is lucid, this handbook makes an essential resource for advanced undergraduate- and graduate-level students in chemistry, as well as researchers in polymer science and electrochemistry, especially those with an interest in responsive polymers and biosensors.

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.

Ceramic and Specialty Electrolytes for Energy Storage Devices, Volume II, investigates recent progress and challenges in a wide range of ceramic solid and quasi-solid electrolytes and specialty electrolytes for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail. Features: * Offers a detailed outlook on the performance requirements and ion transportation mechanism in solid polymer electrolytes * Covers solid-state electrolytes based on oxides (perovskite, anti-perovskite) and sulfide-type ion conductor electrolytes for lithium-ion batteries followed by solid-state electrolytes based on NASICON and garnet-type ionic conductors * Discusses electrolytes employed for high-temperature lithium-ion batteries, low-temperature lithium-ion batteries, and magnesium-ion batteries * Describes sodium-ion batteries, transparent electrolytes for energy storage devices, non-platinum-based cathode electrocatalyst for direct methanol fuel cells, non-platinum-based anode electrocatalyst for direct methanol fuel cells, and ionic liquid-based electrolytes for supercapacitor applications * Suitable for readers with experience in batteries as well as newcomers to the field This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials and chemical engineers, as well as those involved in related disciplines.

This book discusses the synthesis of chitosan-based solid foams using foam templating. Solid foams with pore sizes between a few micrometres and a few millimetres are widely used in a range of established and emerging applications, including filtration, catalysis, sound and thermal insulation, human protection, and tissue engineering. They are lightweight with large surface-to-volume ratios, and have excellent mechanical, acoustic, and thermal properties. However, most foaming processes are extremely complex, and there remains a lack of sound scientific understanding of-and therefore control over-the parameters that determine the properties of the material. One route towards tailor-made solid foams is liquid foam templating, where the liquid foam is generated first (with the desired structure) before being solidified into a solid foam with the desired structure. This book describes how liquid foam templating can be used to synthesise monodisperse solid foams as well as solid foams with a tuneable polydispersity.

Green chemistry is the design of chemical products and processes that reduce or eliminate the use or generation of hazardous substances. Green polymer chemistry is an extension of green chemistry to polymer science and engineering. Developments in this area have been stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunities to design and produce "green" products and processes. Major advances include new uses of biobased feedstock, green reactions, green processing methodologies, and green polymeric products. A current feature of green polymer chemistry is that it is both global and multidisciplinary. Thus, publications in this field are spread out over different journals in different countries. Moreover, a successful research effort may involve collaborations of people in various disciplines, such as organic chemistry, polymer chemistry, material science, chemical engineering, biochemistry, molecular biology, microbiology, enzymology, toxicology, environmental science, and analytical chemistry. This book combines the major interdisciplinary research in this field and is targeted for scientists, engineers, and students, who are involved or interested in green polymer chemistry. These may include chemists, biochemists, material scientists, chemical engineers, microbiologists, molecular biologists, enzymologists, toxicologists, environmental scientists, and analytical chemists. It can be a textbook for a course on green chemistry and also a reference book for people who need information on specific topics involving biocatalysis and biobased materials.

This book is intended to fiber technologists, textile dealers, and textile salesmen a practical guideline to become acquainted with and to deepen their knowledge of the processes for the manufacture of film tapes, split-film yarns, and fibrillated film fibers.

The first volume of the "Handbook of Polyhydroxyalkanoates (PHA): Microbial Biosynthesis and Feedstocks" focusses on feedstock aspects, enzymology, metabolism and genetic engineering of PHA biosynthesis. It addresses better understanding the mechanisms of PHA biosynthesis in scientific terms and profiting from this understanding in order to enhance PHA biosynthesis in bio-technological terms and in terms of PHA microstructure. It further discusses making PHA competitive for outperforming established petrol-based plastics on industrial scale and obstacles for market penetration of PHA. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this book Covers the intracellular on-goings in PHA-accumulating bacteria Assesses diverse feedstocks to be used as carbon source for PHA production including current knowledge on PHA biosynthesis starting from inexpensive waste feedstocks Summarizes recent relevant results dealing with PHA production from various organic by-products Presents the key elements to understand and fine-tune the microstructure and sequence-controlled molecular architecture of PHA co-polyesters Discusses the use of CO-rich syngas, sourced from various organic waste materials, for PHA biosynthesis

The third volume of the Handbook of Polyhydroxyalkanoates (PHA) focusses on the production of functionalized PHA bio-polyesters, the post-synthetic modification of PHA, processing and additive manufacturing of PHA, development and properties of PHA-based (bio)composites and blends, the market potential of PHA and follow-up materials, different bulk- and niche applications of PHA, and the fate and use of spent PHA items. Divided into fourteen chapters, it describes functionalized PHA and PHA modification, processing and their application including degradation of spent PHA-based products and fate of these bio-polyesters during compositing and other disposal strategies. Aimed at graduate students and professionals in Polymer science, chemical engineering and bioprocessing, it: Covers current state of the art in the development of chemically modifiable PHA including mult-istep modifications of isolated biopolyesters, short syntheses of monomer feedstocks and so forth. Describes design of functionalized PHA-based polymeric materials by chemical modification . Illustrates preparation of bioactive oligomers derived from microbial PHA and synthetic analogues of natural PHA oligomers. Discusses processing and thermomechanical properties of PHA. Reviews advantages of PHA against other bio-based and conventional polymers with current applications and potential uses of PHA-based polymers highlighting innovative products.

The updated and expanded second edition of this book explores the physical and mechanical properties of carbon fibers and their composites, their manufacture and processing, and their current and emerging applications. Over 10 chapters, the book describes manufacturing methods, surface treatment, composite interfaces, and microstructure-property relationships with underlying fundamental physical and mechanical principles. It discusses the application of carbon materials in delivering improved performance across a diverse range of fields including sports, wind energy, oil and gas, infrastructure, defence, and the aerospace, automotive and semiconductor industries. This new edition introduces chapters related to the manufacturing of carbon/carbon composites (C/C composites), antioxidation characteristics of C/C composites, and their applications. Furthermore, it addresses the effect of graphene and carbon nanotubes on the physical and chemical properties of carbon fibers. A final chapter looks at the emerging and future prospects for carbon fiber technology.

Aqueous-based film coating has become routine in the pharmaceutical industry. This process eliminates the use of organic solvents and thus avoids economic, environmental, and toxicological issues related to residual solvents and solvent recovery. Aqueous-based coating, however, is complex and many variables may impact the final product and its performance. This fourth edition of Aqueous Polymeric Coatings for Pharmaceutical Dosage Forms aims to provide insight into the factors and parameters that should be considered and controlled for the successful development and commercialization of a coated product. The fourth edition has been revised and expanded to reflect the most recent scientific advancements from the literature. The contributing authors explain in detail, using illustrated examples, appropriate steps to solve and ideally avoid formulation, processing, and stability problems and to achieve an optimized dosage form. Trade names and chemical names of commercially marketed coatings are used throughout the text to help familiarize the reader with the various materials available for pharmaceutical applications. This book will be a valuable resource for anyone in the pharmaceutical industry working in the area of aqueous-based film coating.

Polymer Coatings: Technologies and Applications provides a comprehensive account of the recent developments in polymer coatings encompassing novel methods, techniques, and a broad spectrum of applications. The chapters explore the key aspects of polymer coatings while highlighting fundamental research, different types of polymer coatings, and technology advances. This book also integrates the various aspects of these materials from synthesis to application. Current status, trends, future directions, and opportunities are also discussed. FEATURES Examines the basics to the most recent advances in all areas of polymer coatings Serves as a one-stop reference Discusses polymer-coated nanocrystals and coatings based on nanocomposites Describes morphology, spectroscopic analysis, adhesion, and rheology of polymer coatings Explores conducting, stimuli-responsive, self-healing, hydrophobic and hydrophilic, antifouling, and antibacterial polymer coatings Covers modeling and simulation With contributions from the top international researchers from industry, academia, government, and private research institutions, both new and experienced readers will benefit from this applications-oriented book. Sanjay Mavinkere Rangappa is a research scientist at the Natural Composites Research Group Lab, Academic Enhancement Department, King Mongkut's University of Technology North Bangkok, Thailand. Jyotishkumar Parameswaranpillai is a research professor at the Center of Innovation in Design and Engineering for Manufacturing, King Mongkut's University of Technology North Bangkok, Thailand. Suchart Siengchin is a professor at and president of King Mongkut's University of Technology North Bangkok, Thailand.