This book reviews the latest research, development, and future potential of polyimides and green polymer chemistry. It combines the major interdisciplinary research in this area. Polymers with imidic structure, known as polyimides, are widely investigated owing to their practical implications in numerous industrial sectors. The book explains why polyimides offer versatility unparalleled in comparison to most other classes of macromolecules. In addition, developments in green polymer chemistry in this area have been stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunities to design and produce "green" products and processes. Major advances include new uses of green processing methodologies, and green polymeric products. Imidic Polymers and Green Polymer Chemistry: New Technology and Developments in Process and Product is targeted to scientists, engineers, and students who are involved or interested in green polymer chemistry and imidic polymers. This book will serve as a valuable reference for those with an interest in synthesis of polyimides and the chemistry and physical chemistry of polyimide compounds.

This book provides comprehensive coverage on the latest developments of research in the ever-expanding area of polymers and advanced materials and their applications to broad scientific fields including physics, chemistry, biology, and materials. It presents physical principles in explaining and rationalizing polymeric phenomena. Featuring classical topics that are conventionally considered as part of chemical technology, the book covers the chemical principles from a modern point of view. It analyzes theories to formulate and prove the polymer principles and offers future outlooks on applications of bioscience in chemical concepts.

"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" -Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Polymeric foams are sturdy yet lightweight materials with applications across a variety of industries, from packaging to aerospace. As demand for these materials increase, so does innovation in the development of new processes and products. This book captures the most dynamic advances in processes, technologies, and products related to the polymeric foam market. It describes the latest business trends including new microcellular commercialization, sustainable foam products, and nanofoams. It also discusses novel processes, new and environmentally friendly blowing agents, and the development and usage of various types of foams, including bead and polycarbonate, polypropylene, polyetherimide microcellular, and nanocellular. The book also covers flame-retardant foams, rigid foam composites, and foam sandwich composites and details applications in structural engineering, electronics, and insulation. Authored by leading experts in the field, this book minimizes the gap between research and application in this important and growing area.

This book is intended to fiber technologists, textile dealers, and textile salesmen a practical guideline to become acquainted with and to deepen their knowledge of the processes for the manufacture of film tapes, split-film yarns, and fibrillated film fibers.

There has been much scientific interest in the behaviour of colloidal particles at liquid interfaces. From a research aspect they provide model systems for fundamental studies of condensed matter physics. From a commercial aspect they provide applications for making new materials in the cosmetics, food and paint industries. In many cases of colloidal particles at interfaces, the mechanism of particle interactions is still unknown. Particle-Stabilized Emulsions and Colloids looks at recent studies on the behaviour of particles at liquid interfaces. The book first introduces the basic concepts and principles of colloidal particles at liquid-liquid interfaces including the interactions and conformations. The book then discusses the latest advances in emulsions and bicontinuous emulsions stabilized by both solid and soft particles and finally the book covers applications in food science and oil extraction. With contributions from leading experts in these fields, this book will provide a background to academic researchers, engineers, and graduate students in chemistry, physics and materials science. The commercial aspects will also be of interest to those working in the cosmetics, food and oil industry.

Pressure is one of the essential thermodynamic variables that, due to some former experimental difficulties, was long known as the forgotten variable. But this has changed over the last decade. This book includes the most essential first experiments from the 1960s and reviews the progress made in understanding glass formation with the application of pressure in the last ten years. The systems include amorphous polymers and glass-forming liquids, polypeptides and polymers blends. The thermodynamics of these systems, the relation of the structural relaxation to the chemical specificity, and their present and future potential applications are discussed in detail. The book provides (a) an overview of systems exhibiting glassy behavior in relation to their molecular structure and provides readers with the current state of knowledge on the liquid-to-glass transformation, (b) emphasizes the relation between thermodynamic state and dynamic response and (c) shows that the information on the pressure effects on dynamics can be employed in the design of materials for particular applications. It is meant to serve as an advanced introductory book for scientists and graduate students working or planning to work with dynamics. Several scientific papers dealing with the effects of pressure on dynamics have appeared in leading journals in the fields of physics in the last ten years. The book provides researchers and students new to the field with an overview of the knowledge that has been gained in a coherent and comprehensive way.

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Polyamic Acids and Polyimides surveys significant developments in basic research in the chemistry and physics of polyamic acids and polyimides over the last several years. Traditional and new topics are discussed, including catalytical imidization, chemical reactions at thermal treatment, quantum-chemical study of synthesis and structure, properties of isolated molecules, and supermolecular and crystalline structures. The book will be an excellent reference for researchers, practitioners, and graduate students working with polyimides and related heat-resistant polymers and materials.

Aqueous-based film coating has become routine in the pharmaceutical industry. This process eliminates the use of organic solvents and thus avoids economic, environmental, and toxicological issues related to residual solvents and solvent recovery. Aqueous-based coating, however, is complex and many variables may impact the final product and its performance. This fourth edition of Aqueous Polymeric Coatings for Pharmaceutical Dosage Forms aims to provide insight into the factors and parameters that should be considered and controlled for the successful development and commercialization of a coated product. The fourth edition has been revised and expanded to reflect the most recent scientific advancements from the literature. The contributing authors explain in detail, using illustrated examples, appropriate steps to solve and ideally avoid formulation, processing, and stability problems and to achieve an optimized dosage form. Trade names and chemical names of commercially marketed coatings are used throughout the text to help familiarize the reader with the various materials available for pharmaceutical applications. This book will be a valuable resource for anyone in the pharmaceutical industry working in the area of aqueous-based film coating.

This book covers the advances in the studies of hydrogen-bonding-driven supramolecular systems made over the past decade. It is divided into four parts, with the first introducing the basics of hydrogen bonding and important hydrogen bonding patterns in solution as well as in the solid state. The second part covers molecular recognition and supramolecular structures driven by hydrogen bonding. The third part introduces the formation of hollow and giant macrocycles directed by hydrogen bonding, while the last part summarizes hydrogen bonded supramolecular polymers. This book is designed to bring together in a single volume the many important aspects of hydrogen bonding supramolecular chemistry and will be a valuable resource for graduates and researchers working in supramolecular and related sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China. Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China.

Polymer Coatings: Technologies and Applications provides a comprehensive account of the recent developments in polymer coatings encompassing novel methods, techniques, and a broad spectrum of applications. The chapters explore the key aspects of polymer coatings while highlighting fundamental research, different types of polymer coatings, and technology advances. This book also integrates the various aspects of these materials from synthesis to application. Current status, trends, future directions, and opportunities are also discussed. FEATURES Examines the basics to the most recent advances in all areas of polymer coatings Serves as a one-stop reference Discusses polymer-coated nanocrystals and coatings based on nanocomposites Describes morphology, spectroscopic analysis, adhesion, and rheology of polymer coatings Explores conducting, stimuli-responsive, self-healing, hydrophobic and hydrophilic, antifouling, and antibacterial polymer coatings Covers modeling and simulation With contributions from the top international researchers from industry, academia, government, and private research institutions, both new and experienced readers will benefit from this applications-oriented book. Sanjay Mavinkere Rangappa is a research scientist at the Natural Composites Research Group Lab, Academic Enhancement Department, King Mongkut's University of Technology North Bangkok, Thailand. Jyotishkumar Parameswaranpillai is a research professor at the Center of Innovation in Design and Engineering for Manufacturing, King Mongkut's University of Technology North Bangkok, Thailand. Suchart Siengchin is a professor at and president of King Mongkut's University of Technology North Bangkok, Thailand.

The first volume of the "Handbook of Polyhydroxyalkanoates (PHA): Microbial Biosynthesis and Feedstocks" focusses on feedstock aspects, enzymology, metabolism and genetic engineering of PHA biosynthesis. It addresses better understanding the mechanisms of PHA biosynthesis in scientific terms and profiting from this understanding in order to enhance PHA biosynthesis in bio-technological terms and in terms of PHA microstructure. It further discusses making PHA competitive for outperforming established petrol-based plastics on industrial scale and obstacles for market penetration of PHA. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this book Covers the intracellular on-goings in PHA-accumulating bacteria Assesses diverse feedstocks to be used as carbon source for PHA production including current knowledge on PHA biosynthesis starting from inexpensive waste feedstocks Summarizes recent relevant results dealing with PHA production from various organic by-products Presents the key elements to understand and fine-tune the microstructure and sequence-controlled molecular architecture of PHA co-polyesters Discusses the use of CO-rich syngas, sourced from various organic waste materials, for PHA biosynthesis

The third volume of the Handbook of Polyhydroxyalkanoates (PHA) focusses on the production of functionalized PHA bio-polyesters, the post-synthetic modification of PHA, processing and additive manufacturing of PHA, development and properties of PHA-based (bio)composites and blends, the market potential of PHA and follow-up materials, different bulk- and niche applications of PHA, and the fate and use of spent PHA items. Divided into fourteen chapters, it describes functionalized PHA and PHA modification, processing and their application including degradation of spent PHA-based products and fate of these bio-polyesters during compositing and other disposal strategies. Aimed at graduate students and professionals in Polymer science, chemical engineering and bioprocessing, it: Covers current state of the art in the development of chemically modifiable PHA including mult-istep modifications of isolated biopolyesters, short syntheses of monomer feedstocks and so forth. Describes design of functionalized PHA-based polymeric materials by chemical modification . Illustrates preparation of bioactive oligomers derived from microbial PHA and synthetic analogues of natural PHA oligomers. Discusses processing and thermomechanical properties of PHA. Reviews advantages of PHA against other bio-based and conventional polymers with current applications and potential uses of PHA-based polymers highlighting innovative products.

From Reports in Volume 5: "Recently polymer blends have emerged as one of the most important areas of research activity in the field of polymer science and technology. Because of their satisfactory performance in meeting specific needs of the polymer industry, they have drawn considerable attention in replacing not only many conventional materials, but also some of the polymers that are in vogue. By suitably varying the blend compositions and manipulating the processing conditions, tailor-made products with a unique set of end use properties can be achieved at a much lower cost and within a shorter time than would have been necessary for the development of a new polymer. The usefulness of such blends increases with the increasing range of applications of this type of materials." (Chapter 4) "New and growing demands on polymeric materials cannot be satisfied in future by an assortment extension of basic polymers. Although the introduction of new major-use basic polymer is possible, it seems unlikely in view of current projected economic and technical considerations. On the other hand, new products based on the modification of existing polymers have and will continue to be fruitful areas for both scientific and commercial developments. The driving forces for these developments are: 1. Improved performance, 2. Reduced cost, 3. Present, pending and future legislation dealing with health and environmental issues." (Chapter 11)

This book discusses the synthesis of chitosan-based solid foams using foam templating. Solid foams with pore sizes between a few micrometres and a few millimetres are widely used in a range of established and emerging applications, including filtration, catalysis, sound and thermal insulation, human protection, and tissue engineering. They are lightweight with large surface-to-volume ratios, and have excellent mechanical, acoustic, and thermal properties. However, most foaming processes are extremely complex, and there remains a lack of sound scientific understanding of-and therefore control over-the parameters that determine the properties of the material. One route towards tailor-made solid foams is liquid foam templating, where the liquid foam is generated first (with the desired structure) before being solidified into a solid foam with the desired structure. This book describes how liquid foam templating can be used to synthesise monodisperse solid foams as well as solid foams with a tuneable polydispersity.

This book provides a comprehensive account of developments in the area of lightweight polymer composites. It encompasses design and manufacturing methods for the lightweight polymer structures, various techniques, and a broad spectrum of applications. The book highlights fundamental research in lightweight polymer structures and integrates various aspects from synthesis to applications of these materials. Features Serves as a one stop reference with contributions from leading researchers from industry, academy, government, and private research institutions across the globe Explores all important aspects of lightweight polymer composite structures Offers an update of concepts, advancements, challenges, and application of lightweight structures Current status, trends, future directions, and opportunities are discussed, making it friendly for both new and experienced researchers.

This practical book sets the standard as a valuable, time-saving resource offering systematic fundamental information about industrial radiation technologies. This new edition explores updates to emerging applications of ultraviolet (UV) and electron beam (EB) radiation to polymer processing and offers updates throughout to detail changes changes, new trends, and general issues in radiation technology. It presents vital, cutting-edge information to aid further reduction of volatile organic compounds and toxic substances in the environment, develop alternative sources of energy, and harness energy in both medical and industrial applications. New features of this edition include: Stresses the practical aspects of UV/EB technology and its industrial application Includes updates on UV radiation processes and applications of UV radiation Explores new engineering data of selected commercial products Written by an expert with over forty years of experience, this book would make an excellent resource for scientists and engineers in the fields of materials science and polymer chemistry.

This book focuses on flame retardants (FR) for textile materials. It discusses basics of flame retardancy and flammability and covers various types of flame retardants and materials, including natural FRs, halogen, phosphorous, and nanomaterial-based FRs. This book also discusses methods of applications of FRs and discusses FRs and the environment. Covers a variety of interdisciplinary applications in the textile industry Emphasizes environmental aspects Reports on a large number of FR compounds studied globally Discusses in detail recent developments in halogen-free eco-friendly flame retardants Extensively describes basic aspects of flame retardancy and their measurements Aimed at the practitioner and textile engineering professional this work aims to ensure development of safe textile materials for various uses, including apparel, protective wear, floor coverings, upholstery, drapery, and others.

Constitutional Dynamic Chemistry: Bridge from Supramolecular Chemistry to Adaptive Chemistry, by Jean-Marie Lehn Multistate and Phase Change Selection in Constitutional Multivalent Systems, by Mihail Barboiu Dynamic Systemic Resolution, by Morakot Sakulsombat, Yan Zhang and Olof Ramstroem Dynamic Combinatorial Self-Replicating Systems, by Emilie Moulin and Nicolas Giuseppone DCC in the Development of Nucleic Acid Targeted and Nucleic Acid Inspired Structures, by Benjamin L. Miller Dynamic Nanoplatforms in Biosensor and Membrane Constitutional Systems, by Eugene Mahon, Teodor Aastrup und Mihail Barboiu Dynamic Assembly of Block-Copolymers, by D. Quemener, A. Deratani und S. Lecommandoux Dynamic Chemistry of Anion Recognition, by Radu Custelcean Supramolecular Naphthalenediimide Nanotubes, by Nandhini Ponnuswamy, Artur R. Stefankiewicz, Jeremy K. M. Sanders und G. Dan Pantos Synthetic Molecular Machines and Polymer/Monomer Size Switches that Operate Through Dynamic and Non-Dynamic Covalent Changes, by Adrian-Mihail Stadler und Juan Ramirez Reversible Covalent Chemistries Compatible with the Principles of Constitutional Dynamic Chemistry: New Reactions to Create More Diversity, by Kamel Meguellati und Sylvain Ladame.

The extraordinary growth in the production and use of man-made fibers over the past fewdecades has focused attention on the surface properties of fibers and textiles. This volumecombines surface science and technology in its presentation of the substantial progressthat has been made in the technology related to the surface characteristics of natural,synthetic, and glass fibers and textiles.Adopting an interdisciplinary approach , the coverage places emphasis upon the wetting,soiling, staining, frictional, and adhesive properties of fibers and fabrics, as well asphenomena related to these properties. The book offers critical reviews which describeexperimental facts, theories, and processes. Symbols are clearly defined in each chapter.Among the subjects covered are the surface properties of glass fibers, soil release, stainand water repellance, friction of fabrics, bonding of nonwovens, and the wetting of fibers.Surface Characteristics of Fibers and Textiles, Part II is an outstanding textbook forcourses dealing with surface chemistry, the mechanical properties of textiles, textiletechnology, and polymer chemistry . It is also a valuable reference book designed to makecurrent knowledge on these subjects accessible to industrial and academic researchers.

New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of polymer chains affects polymer properties and presents the latest strategies for developing tactic polymers using single-site catalysis. This unified volume explains the mechanistic basics of tactic polymerizations, beginning with an extensive survey of the most important classes of metallocene and post-metallocene catalysts used to make polypropylenes. It also focuses on tactic stereoblock and ethylene/propylene copolymers and catalyst active site models, followed by chapters discussing the structure of more stereochemically complex polymers and polymerizations that proceed via non-vinyl-addition mechanisms. Individual chapters thoroughly describe tactic polymerizations of -olefins, styrene, dienes, acetylenes, lactides, epoxides, acrylates, and cyclic monomers, as well as cyclopolymerizations and ditactic structures, olefin/CO polymers, and metathesis polyalkenamers. An ideal reference and supplementary text, Stereoselective Polymerization with Single-Site Catalysts enables both new and experienced chemists to better understand tactic polymers and select appropriate catalyst systems for their preparation.

Polymer Processing Instabilities: Control and Understanding offers a practical understanding of the various flows that occur during the processing of polymer melts. The book pays particular attention to flow instabilities that affect the rate of production and the methods used to prevent and eliminate flow instabilities in order to increase production rates and enhance manufacturing efficiency. Polymer Processing Instabilities: Control and Understanding summarizes experimental observations of flow instabilities that occur in numerous processing operations such as extrusion, injection molding, fiber spinning, film casting, and film blowing for a wide range of materials, including most commodity polymers that are processed as melts at temperatures above their melting point or as concentrated solutions at lower temperatures. The book first presents the fundamental principles in rheology and flow instabilities. It relates the operating conditions with flow curves, the critical wall shear stress for the onset of the instabilities, and new visualization techniques with numerical modeling and molecular structure. It reviews one-dimensional phenomenological relaxation/oscillation models describing the experimental pressure and flow rate oscillations, analyzes the gross melt fracture (GMF) instability, and examines how traditional and non-traditional processing aids eliminate melt fracture and improve polymer processability. It supplies a numerical approach for the investigation of the linear viscoelastic stability behavior of simplified injection molding flows and examines a newly discovered family of instabilities that occur in co-extrusion. Polymer Processing Instabilities: Control and Understanding is unique in that it fills a gap in the polymer processing literature where polymer flow instabilities are not treated in-depth in any book. It summarizes state-of-the-art developments in the field, particularly those of the last ten years, and contains significant data based on this research.

Providing an up-to-date overview of the field, this reference presents extensive discussions on a wide range of approaches for molecular imprinting written by pioneering experts on the subject. Molecularly Imprinted Materials: Science and Technology offers experimental protocols that exemplify specific techniques, as well as detailed surveys on molecular imprinting research and applications. Provides a comprehensive tutorial for those who wish to learn basic techniques and make new contributions to the field, as well as in-depth discussions, guidelines, and experimental protocols to help beginners gain a jump-start in the field of molecular imprinting The book examines the recent evolution of the technology, offering step-by-step instruction on methods to design and optimize molecularly imprinted polymers and suggestions, recommendations, and troubleshooting strategies for alternative approaches and improvements discussed in the text. about the editors... MINGDI YAN is Associate Professor, Department of Chemistry, Portland State University, Oregon. After serving as a senior research scientist at Ikonos Corporation, Portland, Oregon, she joined the Portland State University faculty and now leads a research group in organic and polymeric materials science. She received the B.S. degree in polymer physics from the University of Science and Technology, China, and the Ph.D. degree in organic chemistry from the University of Oregon. OLOF RAMSTROEM is Associate Professor, Royal Institute of Technology, Stockholm, Sweden. After serving with Professor Jean-Marie Lehn at Universite Louis Pasteur, Strasbourg, France, he joined the Royal Institute of Technology and is now leading a group specializing in supramolecular chemistry and molecular recognition. He received the M.Sc. degree in chemical engineering and the Ph.D. degree in bioorganic chemistry/applied biochemistry from Lund Institute of Technology/Lund University, Sweden.

An in-depth review of important preparative methods for the synthesis and chemical modification of polymers, this authoritative second edition examines the advantages and limitations of various polymerization applications and procedures. It features new approaches and innovative strategies from the most prominent industry and academic laboratories, reflecting the burgeoning role of polymers in modern science and technology. The book analyzes biodegradable polymers for biomedical applications; investigates the use of polyolefins, polymeric dienes, aromatic polyethers, polymides, and metal-containing macromolecules; and covers polymers of acrylic acid, methacrylic acid, and maleic acid.

Electrical Properties of Polymers describes the electric phenomena responsible for determining the chemical and supramolecular structure of polymers and polymeric materials. The authors explore the properties of quasi-static dipoles, reviewing Brownian motion, Debye theory, Langevin and Smoluchowski equations, and the Onsager model. This reference displays Maxwell and entropy equations, along with several others, that depict the thermodynamics of dielectric relaxation. Featuring end-of-chapter problems and useful appendices, the book reviews molecular dynamics simulations of dynamic dielectric properties and inspects mean-square dipole moments of gases, liquids, polymers, and fixed conformations.