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Books > Science & Mathematics > Chemistry > Organic chemistry > Polymer chemistry
This volume provides a thorough insight into the chemistry and mechanism of ionic gelations of various ionic biopolysaccharides, like alginate, gellan gum, pectin, chitosan, carboxymethyl cellulose, etc., and the applications of various ionically gelled biopolysaccharides in drug delivery fields, with chapters emphasizing the recent advances in the field by the experts. This book will be of interest to graduate students and academic and industry researchers from pharmacy, biotechnology, bioengineering, biomedical and material sciences fields.
Polymeric Liquids & Networks: Dynamics and Rheology is the second part of a two-volume treatise serving as a status report on a broad area of polymer science research. It represents an effort to unify and consolidate the work of many polymer researchers from all over the world, over the past 60-70 years. Both books are based on the graduate courses taught by the author at Princeton and Northwestern. The increasing need to apply new understandings about liquid structure to rheological behavior squeezed equilibrium aspects out of the rheology course and into another graduate course, which eventually became the basis for Volume 1, Structure and Properties, published in 2004. Volume 2 follows the original plan by building upon Volume 1-covering continuum background along with experimental observations, then molecular theories and applications to such topics as solution properties, long-chain branching and structural heterodispersity. Dynamics and Rheology aims to leave readers with a solid grounding in the principles that underlie the dynamics and rheological behavior of flexible chain polymer liquids and networks. Readers will develop an informed intuitive understanding of the connections between polymeric structure and rheological response. Theory, experiment, and simulation are woven together so as to leave the reader with a balanced grasp of the various areas, including exposure to important unsolved puzzles. The book will be a great resource for a range of academic researchers in chemistry, physics, materials science, and chemical engineering.
This book comprehensively covers the different topics of wood polymer composite materials mainly synthesis methods for the composite materials, various characterization techniques to study the superior properties and insights on potential advanced applications. It also discusses the chemistry, fabrication process, properties, applications, recycling and life cycle assessment of wood polymer composites. This is a useful reference source for both engineers and researchers working in composite materials science as well as the students attending materials science, physics, chemistry and engineering courses.
This volume covers various aspects of cross-linked polyethylene (XLPE). The contents include manufacture, morphology, structure, properties, applications, early stage development, cross-linking techniques, recycling process, physical and chemical properties as well as the scope and future aspects of XLPE. It focuses on the life cycle analysis of XLPE and their industrial applications and commercial importance. This book will be of use to academic and industry researchers, as well as graduate students working in the fields of polymer science and engineering, materials science, and chemical engineering.
The production and application of polymeric materials based on poly(butylene terephthalate) (PBT) has increased dramatically. The main reason for this is that PBT and its composites have a number of profitable properties, such as increased mechanical characteristics, good resistance to chemicals and water, processability, etc. This volume gives an analysis of recent achievements in the field of synthesis, structural investigations, and properties of PBT. Furthermore, the mechanism of PBT synthesis by equilibrium polycondensation reaction is described together with the used reagents, catalysts and stabilizers.
The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.
This book presents a unified approach to fracture behavior of natural and synthetic fiber-reinforced polymer composites on the basis of fiber orientation, the addition of fillers, characterization, properties and applications. In addition, the book contains an extensive survey of recent improvements in the research and development of fracture analysis of FRP composites that are used to make higher fracture toughness composites in various applications.The FRP composites are an emerging area in polymer science with many structural applications. The rise in materials failure by fracture has forced scientists and researchers to develop new higher strength materials for obtaining higher fracture toughness. Therefore, further knowledge and insight into the different modes of fracture behavior of FRP composites are critical to expanding the range of their application.
This volume serves as a cutting edge reference on XLPE based blends, nanocomposites, and their applications. The book provides an introduction to XLPE nanocomposites and discusses the incorporation of natural and inorganic nanoparticles in the XLPE matrix. It also focuses on its characterization as well as the morphological, rheological, mechanical, viscoelastic, thermal, and electrical, properties. It provides an in-depth review of various potential applications, with special emphasis on use in cable insulation. The book focuses on cutting edge research developments, looking at published papers, patents, and production data. This book will be of use to academic and industry researchers, as well as graduate students working in the fields of polymer science and engineering, materials science, and chemical engineering.
This book introduces readers to interfacial reactions in confinement on stimuli-responsive homopolymer and diblock copolymer films. It also includes investigations concerning the immobilization of (bio)molecules and the fabrication of biomolecular patterns by reactive microcontact printing on these reactive polymer films. In turn, the book takes advantage of the microphase separation of diblock copolymer films to study the fabrication of nanopatterns, which could contribute to the future development of a model system that allows us to area-selectively deposit and address (bio)molecules. Given its scope, the book broadens readers' perspective on the microfabrication of stimuli-responsive polymers.
This book focuses on polymer/silver nanocomposites as the main component in bioengineering systems. It describes in detail the synthesis and characterization (morphological, thermal, mechanical & dynamic mechanical properties), as well as the different applications of these composites. A special chapter is dedicated to the toxicity aspects of silver nanoparticles
Simulation Methods for Polymers is the only comprehensive source to
delineate the technical steps and efficacy of contemporary polymer
simulation methods using a highly instructive, easy-to-grasp
format, and it offers a logical sequence of polymer physics
background, methods, calculations, and application guidelines.
Including coverage of recently developed techniques and algorithms
for modeling and simulation, this reference/text also provides an
introduction to the statistical mechanics of the various simulation
techniques presented and explores coarse-graining, CONNFFESSIT
simulation, dissipative particle dynamics, and dynamic density
functional theory approaches.
This book presents synthesis methods, characterization techniques, properties and applications of hybrid conducting polymers. Special emphasis is given to the applications of hybrid conductive polymers, with chapters ranging from electronic devices, environmental remediation, and sensors, to medical applications.
The book comprehensively covers the different topics of graphene based biopolymer and nanocomposites, mainly synthesis methods for the composite materials, various characterization techniques to study the superior properties and insights on potential advanced applications.The book will address and rectify the complications of using plastics that are non-degradable and has abhorrent impact on environment. The limitations of properties of biopolymer can be vanquished by employing graphene as a nanomaterial. Outstanding properties of graphene in accordance with biopolymer can be utilized to develop applications like water treatment, tissue engineering, photo-catalysts, super-absorbents. This is a useful reference source for both engineers and researchers working in composite materials science as well as the students attending materials science, physics, chemistry, and engineering courses.
This edited volume brings together the state of the art in polymer nanocomposite theory and modeling, creating a roadmap for scientists and engineers seeking to design new advanced materials. The book opens with a review of molecular and mesoscale models predicting equilibrium and non-equilibrium nanoscale structure of hybrid materials as a function of composition and, especially, filler types. Subsequent chapters cover the methods and analyses used for describing the dynamics of nanocomposites and their mechanical and physical properties. Dedicated chapters present best practices for predicting materials properties of practical interest, including thermal and electrical conductivity, optical properties, barrier properties, and flammability. Each chapter is written by leading academic and industrial scientists working in each respective sub-field. The overview of modeling methodology combined with detailed examples of property predictions for specific systems will make this book useful for academic and industrial practitioners alike.
This book gives the reader an introduction to the field of surfactants in solution as well as polymers in solution. Starting with an introduction to surfactants the book then discusses their environmental and health aspects. Chapter 3 looks at fundamental forces in surface and colloid chemistry. Chapter 4 covers self-assembly and 5 phase diagrams. Chapter 6 reviews advanced self-assembly while chapter 7 looks at complex behaviour. Chapters 8 to 10 cover polymer adsorption at solid surfaces, polymers in solution and surface active polymers, respectively. Chapters 11 and 12 discuss adsorption and surface and interfacial tension, while Chapters 13- 16 deal with mixed surfactant systems. Chapter 17, 18 and 19 address microemulsions, colloidal stability and the rheology of polymer and surfactant solutions. Wetting and wetting agents, hydrophobization and hydrophobizing agents, solid dispersions, surfactant assemblies, foaming, emulsions and emulsifiers and microemulsions for soil and oil removal complete the coverage in chapters 20-25.
This volume, Bioresponsive Polymers: Design and Application in Drug Delivery, focuses on recent advancements in bioresponsive polymers and their design, characterization, and applications in varied fields, such as drug delivery and gene delivery. It looks at several carriers for drug delivery and biological molecules using different bioresponsive polymers. To address the many difficulties in existing dosage forms, this book provides information on recent developments to overcome drawbacks of conventional forms of the drug delivery. The chapters cover most areas of bioresponsive polymers, starting with a basic introduction to bioresponsive polymers, followed by chapters on design, characterization, and mechanism of bioresponsive polymers; and applications of drug and gene delivery using bioresponsive polymers via oral, topical, nasal, ocular, and parenteral methods. The book also reviews recent advancements in bioresponsive polymers and advanced applications, such as engineering particulate moieties, biomedical applications, hydrogels as emerging therapy, and electrochemical responses, bioresponsive nanoparticles, and bioresponsive hydrogels.
This book introduces the reader to important aspects of the nano-hydrogels. It covers the development of hydrogels and their biology, chemistry and properties. Focus is also given to innovative characterization techniques and advances in structural design, with special emphasis on molecular structure, dynamic behavior and structural modifications of hydrogels. This book serves as a consolidated reference work for the diverse aspects of hydrogels, creating a valuable resource for students and researchers in academia and industry.
The science of mathematical modelling and numerical simulation is generally accepted as the third mode of scienti?c discovery (with the other two modes being experiment and analysis), making this ?eld an integral component of c- ting edge scienti?c and industrial research in most domains. This is especially so in advanced biomaterials such as polymeric hydrogels responsive to biostimuli for a wide range of potential BioMEMS applications, where multiphysics and mul- phase are common requirements. These environmental stimuli-responsive hydrogels are often known as smart hydrogels. In the published studies on the smart or stimu- responsive hydrogels, the literature search clearly indicates that the vast majority are experimental based. In particular, although there are a few published books on the smart hydrogels, none is involved in the modelling of smart hydrogels. For the few published journal papers that conducted mathematical modelling and numerical simulation, results were far from satisfactory, and showed signi?cant d- crepancies when compared with existing experimental data. This has resulted in ad hoc studies of these hydrogel materials mainly conducted by trial and error. This is a very time-consuming and inef?cient process, and certain aspects of fun- mental knowledge are often missed or overlooked, resulting in off-tangent research directions.
This book presents a detailed discussion of the fundamentals and practical applications of membrane technology enhancement in a range of industrial processes, energy recovery, and resource recycling. To date, most books on the applications of membrane technology have mainly focused on gas pollution removal or industrial wastewater treatment. In contrast, the enhancement of various membrane processes in the areas of energy and the environment has remained largely overlooked. This book highlights recent works and industrial products using membrane technology, while also discussing experiments and modeling studies on the membrane enhancement process.
This book presents new approaches that offer a better characterization of the interrelationship between crystalline and amorphous phases. In recent years, the use of dielectric spectroscopy has significantly improved our understanding of crystallization. The combination of modern scattering methods, using either synchrotron light or neutrons and infrared spectroscopy with dielectrics, is now helping to reveal modifications of both crystalline and amorphous phases. In turn, this yields insights into the underlying physics of the crystallization process in various materials, e.g. polymers, liquid crystals and diverse liquids. The book offers an excellent introduction to a valuable application of dielectric spectroscopy, and a helpful guide for every scientist who wants to study crystallization processes by means of dielectric spectroscopy.
This book commemorates the "Nobel Laureate Professor Suzuki Special Symposium" at the International Union of Material Research Society-International Conference on Advanced Materials (IUMRS-ICAM2017), which was held at Kyoto University, Japan, in 2017. The book begins with a foreword by Professor Akira Suzuki. Subsequently, many authors who attended the special symposium describe the latest scientific advances in the field of carbon materials and carbon nanomaterials including polymers, carbon nanocomposites, and graphene. Carbon-based materials have recently been the focus of considerable attention, given their wide range of potential applications. Fittingly, the chapters in this book cover both experimental and theoretical approaches in several categories of carbon-related materials.
The long-awaited Third Edition of the classic in polymer synthesis Thirty years ago, the Second Edition of Preparative Methods of Polymer Chemistry further established its reputation as the laboratory bible for polymer synthesis. The last three decades have witnessed a deeper understanding of the principles involved in preparing and processing polymers, leading to tremendous advances in polymer synthesis. Guiding practicing scientists through the methods of synthesizing polymers, the Third Edition retains theory and vital protocols, while revising and updating the sections on synthesis, fabrication techniques, and characterization methods. Delving into the physical and chemical aspects of polymer processing, each chapter includes a discussion of the relevant background and principles, enabling the scientist to apply synthetic techniques intelligently. The Third Edition also contains sections on current topics such as:
Preparative Methods of Polymer Chemistry, Third Edition provides essential information for both students and practicing polymer scientists.
The book provides practical recommendations for creation of fire retardant materials with an increased service life. The enhanced fire resistance seen in these materials is based on the regularities of the chemical and physicochemical interaction of the components of intumescent composition in the process of thermolytic synthesis of heat-insulating char-foamed layers. The aim of fire protection of various objects with intumescent materials is to create a heat-insulating charred layer on the surface of structural elements; this layer can withstand high temperatures and mechanical damage which are typical during fires. The authors describe the contribution of basic components (melamine, pentaerythritol, ammonium polyphosphate), additional components (chlorinated paraffin, urea, cellulose, carbon nano additives, etc.) and polymer binders of intumescent compositions on the process of charring. The technological aspects of manufacturing, application and operation of fire retardant intumescent compositions, which can be useful for organizations that produce and use fire retardant materials, are also described.
"Presents the latest knowledge on a wide range of topics in polymer science, including the dynamics, preparation, application, and physiochemical properties of polymer solutions and colloids; the adsorption characteristics at polymer surfaces; and the adhesion properties (including acid-base) of polymer surfaces."
This volume covers experimental and theoretical advances on the relationship between composition, structure and macroscopic mechanical properties of novel hydrogels containing dynamic bonds. The chapters of this volume focus on the control of the mechanical properties of several recently discovered gels with the design of monomer composition, chain architecture, type of crosslinking or internal structure. The gels discussed in the different chapters have in common the capability to dissipate energy upon deformation, a desired property for mechanical toughness, while retaining the ability to recover the properties of the virgin material over time or to self-heal when put back in contact after fracture. Some chapters focus on the synthesis and structural aspects while others focus on properties or modelling at the continuum or mesoscopic scale. The volume will be of interest to chemists and material scientists by providing guidelines and general structure-property considerations to synthesize and develop innovative gels tuned for applications. In addition it will provide physicists with a better understanding of the role of weak interactions between molecules and physical crosslinking on macroscopic dissipative properties and self-healing or self-recovering properties. |
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