Organometallic chemistry is a well established research area at the interface of organic and inorganic chemistry. In recent years this field has undergone a ren aissance as our understanding of organometallic structure, properties and mechanism has opened the way for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as medicine, biology, materials and polymer sciences and organic synthesis. For example, in the de velopment of new catalytic processes, organometallic chemistry is helping meet the challenge to society that the economic and environmental necessities of the future pose. As this field becomes increasingly interdisciplinary, we recognize the need for critical overviews of new developments that are of broad significance. This is our goal in starting this new series Topics in Organometallic Chemistry. The scope of coverage includes a broad range of topics of pure and applied or ganometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. Topics in Organometallic Chemistry differs from existing review series in that each volume is thematic, giving an overview of an area that has reached a stage of maturity such that coverage in a single review article is no longer possible. Furthermore, the treatment addresses a broad audience of researchers, who are not specialists in the field, starting at the graduate student level. Discussion of possible future research directions in the areas covered by the individual volumes is welcome."

The word Polyethylene was probably first pronounced in a lecture which M. P. E. Berthelot delivered on April ,27, 1863 to the Chemical Society in Paris, reporting on the "polymerization" of various simple organic compounds (1). Much later this work appeared twice in the literature before the classical ICI breakthrough in the 1930's which is so colorfully described in Ballard's lecture. Once it came up at the end of the last century when H. von Pechmann obtained "a white flocculant material" from the decomposition of diazomethane which, one year later, was termed to be "polymethylene" - (CH ) - from E. Bamberger 2 and F. Tschiemer (1). At that time the investigators were disappointed about this product because it was not what they had expected to find in their experiments. As a result any further work was discontinued. The second time that the word polyethylene appeared in the literature to describe a "white solid powder" was in 1930 when C. S. Marvel and M. E. P. Friedericks (2) attempted to prepare alkylated As compounds in which all five valencies were covalently bonded to five monovalent-aTkyl groups. They reacted Tetra-ethyl-arsenium bromide with butyllithium and expected to get tetra ethyl butyl arsenium. Instead they obtained LiBr + AsEt3 + gaseous products. Delicate and somewhat time-consuming analysis gave a surprising result: ethane and C 's were there in the 4 expected quantities but ethylene was missing - or almost missing - in the gas mixture.

Epoxy resins are regarded as thermosetting resins and have found various c- mercial applications after crosslinking with adequate curing agents [1-3]. H- ever, some epoxy resins have been used as thermoplastic resins without curing agents. Figure 1 shows the applications of epoxy resins that are classi?ed to three categories: thermosets in combination with curing agents, thermoplastics wi- out curing agents, and raw materials for modi?cation. The use in thermoplastics is not popular compared with the two other applications. Typical thermoplastic applications are found in stabilizers for vinyl resins, toners for copying - chines, ?re retardants for engineering plastics, and sizing material for glass or carbon ?bers. The epoxy resin most frequently used is the oligomer of the diglycidyl ether of bisphenol-A (DGEBA) whose chemical structure is shown below [1-3]. The DGEBA is composed of linear molecules with different molecular weights according to the variation of the repeated number (n) in the structural formula.

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This review shows that the measurement of viscoelastic properties is a powerful tool in the study of thermoreversible gels. Although many conclusions may be drawn about network development and its structure, it is also shown that the use of additional techniques (e.g. small angle S-ray and neutron scattering techniques and optical rotation) and the combination with thermodynamics and network models, widens the insight in the crosslinking process and the gel structure temendously. A general Introduction is followed by eight Chapters concerning synthetic polymers (PVC, PVAL, PMMA, PS, PAN, PE, ABA blockcopolymers and LCP's) and four Chapters concerning biopolymers (gelatin, agarose, carrageenans and gellan gum).

The second edition of this textbook is identical with its fourth German edi tion and it thus has the same goals: precise definition of basic phenomena, a broad survey of the whole field, integrated representation of chemistry, physics, and technology, and a balanced treatment of facts and comprehen sion. The book thus intends to bridge the gap between the often oversimpli fied introductory textbooks and the highly specialized texts and monographs that cover only parts of macromolecular science. The text intends to survey the whole field of macromolecular science. Its organization results from the following considerations. The chemical structure of macromolecular compounds should be inde pendent of the method of synthesis, at least in the ideal case. Part I is thus concerned with the chemical and physical structure of polymers. Properties depend on structure. Solution properties are thus discussed in Part II, solid state properties in Part III. There are other reasons for dis cussing properties before synthesis: For example, it is difficult to understand equilibrium polymerization without knowledge of solution thermodynamics, the gel effect without knowledge of the glass transition temperature, etc. Part IV treats the principles of macromolecular syntheses and reactions.

Conformations and Solution Properties of Star-Branched Polyelectrolytes, by Oleg V. Borisov, Ekaterina B. Zhulina, Frans A. M. Leermakers, Matthias Ballauff and Axel H. E. Muller; Self-Assembled Structures of Amphiphilic Ionic Block Copolymers: Theory, Self-Consistent Field Modeling and Experiment, by Oleg V. Borisov, Ekaternia B. Zhulina, Frans A. M. Leermakers and Axel H. E. Muller; Interpolyelectrolyte Complexes Based on Polyionic Species of Branched Topology, by Dmitry V. Pergushov, Oleg V. Borisov, Alexander B. Zezin and Axel H. E. Muller; Co-assembly of Charged Copolymers as a Novel Pathway Towards Reversible Janus Micelles, by Ilja K. Voets, Frans A. Leermakers, Arie de Keizer, Marat Charlaganov and Martien A. Cohen Stuart; Fluorescence Spectroscopy as a Tool for Investigating the Self-Organized Polyelectrolyte Systems, by Karel Prochazka, Zuzana Limpouchova, Filip Uhlik, Peter Kosovan, Pavel Matejicek, Miroslav Stepanek, Mariusz Uchman, Jitka Kuldova, Radek Sachl, Jana Humpolickova, and M. Hof

Das Buch enthalt Kapitel uber: N. Kinjo, M. Ogata, Ibaraki-ken; K. Nishi, Tokyo; A. Kaneda, Yokohama, Japan: Epoxyd-Formmassen als Einschlussmaterialien fur mikroelektronische Gerate Yu.S. Lipatov, T.E. Lipatova, L.F. Kosyanchuk, Kiev, UdSSR: Synthese und Struktur struktureller Makromolekule K. Horie, I. Mita, Tokyo, Japan: Reaktionen und Photodynamik in polymeren Festkorpern Yu.K. Godovsky, V.S. Papkov, Moskau, UdSSR: Thermotrope Mesophasen elementorganischer Polymere

This monograph gives a detailed introductory exposition of research results for various models, mostly two-dimensional, of directed walks, interfaces, wetting, surface adsorption (of polymers), stacks, compact clusters (lattice animals), etc. The unifying feature of these models is that in most cases they can be solved analytically. The methods used include transfer matrices, generating functions, recurrence relations, and difference equations, and in some cases involve utilization of less familiar mathematical techniques such as continued fractions and q-series. The authors emphasize an overall view of what can be learned generally of the statistical mechanics of anisotropic systems, including phenomena near surfaces, by studying the solvable models. Thus, the concept of scaling and, where known, finite-size scaling properties are elucidated. Scaling and statistical mechanics of anisoptropic systems in general are active research topics. The volume provides a comprehensive survey of exact model results in this field.

The 9th Symposium on Analytical Ultracentrifugation (AUC) which was held at the Max Delbruck Center for Molecular Medicine in Berlin-Buch, March, 1995, is the basis of this volume. It presents an actual survey of recent developments and results of ultracentrifugation methods in the frame of the following topics: Reversible Association Reactions.- Analysis of Supramolecular Structures Including Modeling.- Size Distribution Analysis and Gel Formation.- Hardware and Software Developments."

The liquid crystalline state may be identified as a distinct and unique state of matter which is characterised by properties which resemble those of both solids and liquids. It was first recognised in the middle of the last century through the study of nerve myelin and derivatives of cholesterol. The research in the area really gathered momentum, however, when as a result of the pioneering work of Gray in the early 1970's organic compounds exhibiting liquid crystalline properties were shown to be suitable to form the basis of display devices in the electronic products. The study of liquid crystals is truly multidisciplinary and has attached the attention of physicists, biologists, chemists, mathematicians and electronics engineers. It is therefore impossible to cover all these aspects fully in two small volumes and therefore it was decided in view of the overall title of the series to concentrate on the structural and bonding aspects of the subject. The Chapters presented in these two volumes have been organised to cover the following fundamental aspects of the subiect. The calculation of the structures of liquid crystals, an account of their dynamical properties and a discussion of computer simulations of liquid crystalline phases formed by Gay Berne mesogens. The relationships between molecular conformation and packing are analysed in some detail. The crystal structures of liquid crystal mesogens and the importance of their X ray scattering properties for characterisational purposes are discussed.

Improvement of the catalytic properties of biological catalysts is equally important in the optimization of industrial processes as in the fundamental understanding of the catalytic machinery at the molecular level. The approaches taken are diverse and span from purely result-oriented, but nevertheless methodologically subtle, making and screening of combinatorial libraries to highly sophisticated tailoring of the environment of active sites. This volume illustrates four different concepts for modifying a given biocatalyst framework or create novel functions using Nature's basic building blocks. Summing up the state-of-the-art biocatalyst engineering it, serves as an orientational landmark and a platform for the specialist and non-expert alike to keep abreast of developments in this rapidly evolving field.

Adsorption at solid/liquid interfaces Ulbig P, Seippel J: Development of a group contribution method for liquid-phase adsorption onto activated carbons ..................... Laszlb K: Adsorption from aqueous phenol and 2,3,4-trichlorophenol solutions on nanoporous carbon prepared from poly(ethy1ene terephthalate) . . Mizukami M, Kurihara K: Alcohol cluster formation on silica surfaces in cyclohexane . . Tombacz E, Szekeres M: Effects of impurity and solid-phase dissolution on surface charge titration of aluminium oxide ............................... Horanyi G, Job P: Radiotracer study of the specific adsorption of anions on oxides Kovaeevit D, cop A, Bradetic A, Interfacial equilibria at a goethite aqueous interface in the presence Kallay N, Pohlmeier A, of amino acids ......................................... Narres H-D, Lewandowski H: Ruffmann B, Zimehl R: Liquid sorption and stability of polystyrene latices ........... Zimehl R, Hannig M: Adsorption onto tooth enamel the - biological interface and its modification ........................................... Lengyel Z, Foldinyi R: Adsorption of chloroacetanilide herbicides on Hungarian soils ..... Paszli I, Laszlo K: Stagnation phenomenon of solid/fluid interfaces ................ Mielke M, Zimehl R: Measures to determine the hydrophobicity of colloidal polymers . Farkas A, Dekany I: Interlamellar adsorption of organic pollutants on hydrophobic . . vermiculite ............................................ Dabrowski A, Biilow M, Adsorption against pollution: current state and perspectives ....... Podkocielny P: Textor T, Bahners T, Schollmeyer E: Organically modified ceramics for coating textile materials ........ Nanostructured materials Esumi K, Torigoe K: Preparation and characterization of noble metal nanoparticles using ........................... dendrimers as protective colloids Mogyorbsi K, Nemeth J, Dekany I, Preparation, characterization, and photocatalytic properties Fendler JH: of layered-silicate-supported TiOz and ZnO nanoparticles ........

This series presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and materials science. It is addressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered.

Impact Factor Ranking: Always number one in Polymer Science. More information as well as the electronic version of the whole content available at: www.springerlink.com