Over the past decade high performance computing has demonstrated the ability to model and predict accurately a wide range of physical properties and phenomena. Many of these have had an important impact in contributing to wealth creation and improving the quality of life through the development of new products and processes with greater efficacy, efficiency or reduced harmful side effects, and in contributing to our ability to understand and describe the world around us. Following a survey ofthe U.K.'s urgent need for a supercomputingfacility for aca demic research (see next chapter), a 256-processor T3D system from Cray Research Inc. went into operation at the University of Edinburgh in the summer of 1994. The High Performance Computing Initiative, HPCI, was established in November 1994 to support and ensure the efficient and effective exploitation of the T3D (and future gen erations of HPC systems) by a number of consortia working in the "frontier" areas of computational research. The Cray T3D, now comprising 512 processors and total of 32 CB memory, represented a very significant increase in computing power, allowing simulations to move forward on a number offronts. The three-fold aims of the HPCI may be summarised as follows; (1) to seek and maintain a world class position incomputational scienceand engineering, (2) to support and promote exploitation of HPC in industry, commerce and business, and (3) to support education and training in HPC and its application.

These volumes, 9 and 10, of Fracture Mechanics of Ceramics constitute the proceedings of an international symposium on the fracture mechanics of ceramic materials held at the Japan Fine Ceramics Center, Nagoya, Japan on July 15, 16, 17, 1991. These proceedings constitute the fifth pair of volumes of a continuing series of conferences. Volumes 1 and 2 were from the 1973 symposium, volumes 3 and 4 from a 1977 symposium, and volumes 5 and 6 from a 1981 symposium all of which were held at The Pennsylvania State University. Volumes 7 and 8 are from the 1985 symposium which was held at the Virginia Polytechnic Institute and State University. The theme ofthis conference, as for the previous four, focused on the mechanical behavior ofceramic materials in terms of the characteristics of cracks, particularly the roles which they assume in the fracture processes and mechanisms. The 82 contributed papers by over 150 authors and co-authors represent the current state of that field. They address many of the theoretical and practical problems ofinterest to those scientists and engineers concerned with brittle fracture.

Polymer composites represent materials of great and of continuously growing importance. Their potential for application appears to be limitless. They have been the subject of numerous studies both at academic and industrial levels. Much progress has been made in the incisive formulation of composites; sophisticated methods of property evaluation have been developed in the past decade and many, largely empirical solutions have been proposed to resolve the problem of their long-term performance under typical conditions of use (i. e. the use of silane or titane coupling agents to enhance adhesion within composite materials). Assuredly one of the most essential factors in the performance of these systems is the condition of the interface and interphase among the constituents of a given system. It has become clear that it is the interface/interphase, and the interactions which take place in this part of a system, which determine to a significant degree the initial properties of the material. In order to achieve leadership in the formulation and application of polymer composites, it is evident that in depth understanding of interfacial and interphase phenomena becomes a prerequisite.

Approximately half of the world production of the petrochemical industry (more than 100 million tonnes) is in the form of polymers, yet it would probably surprise most people to learn how much their lifestyle depends on polymers ranging, as they do, from detergents, kitchenware and electrical appliances to furnishings and a myriad other domestic goods. Still less are they likely to be aware of the extensive part they play in engineering applications for mechanical machine components and advanced high performance aircraft. This versatility derives from the fact that polymeric materials are made up of a range of molecules of varying length, whose properties are related to molecular structure and the proportions of the chains in the mixture. For example, polypropylene is a commodity polymer which is produced in hun dreds of different grades to meet specific market requirements. This depends on the catalyst as well as the operating conditions and reactor design. A major area for growth is in substituting polymers for conventional materials such as ceramics and metals. Not only can they match these materials in terms of mechanical strength and robustness but they have very good resistance to chemical attack. Polyamides, for example, are widely used for car bumpers and new polymers are being developed for engine manifolds and covers. In 1993 there is, typically, 100 kg of various polymers used in cars and this is continually increasing, giving a net weight reduction and hence better fuel economy."

Taking a critical approach toward novel colloid systems and phenomena, this series provides both the historical development and a digest of recent advances. The current volume focuses on solutions containing surfactants and polymers, with special emphasis on micelle formation and microemulsions.

Polymers continue to play an ever increasing role in the modern world. In fact it is quite inconceivable to most people that we could ever have existed of the increased volume and variety of materials without them. As a result currently available, and the diversity of their application, characterisation has become an essential requirement of industrial and academic laboratories in volved with polymeric materials. On the one hand requirements may come from polymer specialists involved in the design and synthesis of new materials who require a detailed understanding of the relationship between the precise molecular architecture and the properties of the polymer in order to improve its capabilities and range of applications. On the other hand, many analysts who are not polymer specialists are faced with the problems of analysing and testing a wide range of polymeric materials for quality control or material specification purposes. We hope this book will be a useful reference for all scientists and techno or industrial laboratories, logists involved with polymers, whether in academic and irrespective of their scientific discipline. We have attempted to include in one volume all of the most important techniques. Obviously it is not possible to do this in any great depth but we have encouraged the use of specific examples to illustrate the range of possibilities. In addition numerous references are given to more detailed texts on specific subjects, to direct the reader where appropriate. The book is divided into II chapters."

A comprehensive and up to date survey of the science and technology of polymeric dispersions. The book discusses the kinetics and mechanisms of polymerization in dispersed media, examines the processes controlling particle morphology, presents both off-line and on-line methods for the characterization of polymer colloids, considers reactor engineering and control, and covers a wide variety of applications, such as latex paint formulations, encapsulation of inorganic particles, reactive latexes, adhesives, paper coating, and biomedical and pharmaceutical applications. Audience: A valuable resource for scientists and engineers, academic and industrial, who are involved in the manufacture or application of polymeric dispersions.

Assessing the quality of textiles using textile microscopy remains one of the important instruments for permanent process improvement in the fiber, textile and apparel industries. The degree of international interlinking in the textile producing and finishing industries and their markets demands dearly defined and reproducible methods of detecting damage or defects at all process stages. This book -Quality Assessment of Textiles -Damage Detection by Microsco- py - has in the meantime established itself so well as "the Mahall" in research institute laboratories investigating defects, in universities and colleges, in the training of textile chemists and technologists, and in the industry and the retail trade, that it has become necessary to bring out a new edition. This edition has been revised and supplemented by Mr. Mahall and his succes- sor Ms. Irmhild Goebel and her staff. Cognis, as the successor organization continuing the textile business of the for- mer Textile Technology department of Henkel, is pleased to make this new edi- tion available to specialists, to students and to any other interested readers. June 2002 Dr. U. Kloubert (Cognis Deutschland GmbH & Co. KG) Prof E. Finnimore (Fachhochschule Hof, Germany) Foreword to the First Edition Quality is the decisive criterion by which textile industry is measured in the international competition. Today this is particularly true.

Supramolecular stereochemistry is a topic with enormous breadth, and this book brings together experts in polymer chemistry, bioorganic chemistry, crystallography, materials science, dendrimer science, nanochemistry, conformational analysis, molecular recognition chemistry, and topological stereochemistry. Contains 19 plenary and 12 poster contributions.

This volume chronicles the proceedings of the Third Symposium on Metallized Plastics: Fundamental and Applied Aspects held under the auspices of the Dielectric Science and Technology Division of the Electrochemical Society in Phoenix, Arizona, October 13-18, 1991. This series of symposia to address the subject of metallized plastics was initiated in 1988 and the premier symposium was held in Chicago, October 10-12, 1988, followed by the second event in Montreal, Canada, May 7-10, 1990. The rroceedings of these two symposia have been properly documented ,2. The third symposium was a huge success like the previous two events, and all this is testimonial to the brisk interest and high tempo of R&D activity in the fie14 of metallized plastics. This further bolsters our earlier thinking that there was a conspicuous need to hold symposia on this topic on a regular basis and the fourth is planned for May 16-21, 1993 in Honolulu, Hawaii. The study of metallized plastics constitutes an important human endeavor l and as pointed out earlier there are myriad applications of metallized plastics ranging from very commonplace to exotic. Also a survey of the recent literature will reveal that both the fundamental and applied aspects of metallized plastics are being pursued with great vigor.

Oxireductases in the Enzymatic Synthesis of Water-Soluble Conducting Polymers, by E. Ochoteco and D. Mecerreyes
*

Transferases in Polymer Chemistry, by J. van der Vlist and K. Loos
*

Hydrolases Part I: Enzyme Mechanism, Selectivity and Control in the Synthesis of Well-Defined Polymers, by M.A.J. Veld and A.R.A. Palmans
*

Hydrolases in Polymer Chemistry: Chemoenzymatic Approaches to Polymeric Materials, by A. Heise and A.R.A. Palmans
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Hydrolases in Polymer Chemistry: Part III: Synthesis and Limited Surface Hydrolysis of Polyesters and Other Polymers, by G.M. Guebitz
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Exploiting Biocatalysis in the Synthesis of Supramolecular Polymers, by S. Roy and R. V. Ulijn

-Shear-Induced Transitions and Instabilities in Surfactant Wormlike Micelles By S. Lerouge, J.-F. Berret -Laser-Interferometric Creep Rate Spectroscopy of Polymers By V. A. Bershtein, P. N. Yakushev -Polymer Nanocomposites for Electro-Optics: Perspectives on Processing Technologies, Material Characterization, and Future Application K. Matras-Postolek, D. Bogdal

This volume includes 11 contributions to the 23rd Conference of the European Colloid and Interface Society which took in Antalya, Turkey between September 6th and 11th, 2009. The contributions from leading scientists cover a broad spectrum of topics concerning* Self Assembly* Interfacial Phenomena* Colloidal Dispersions and Colloidal Stability* Polymer Solution, Gels and Phase Behaviour* Nanostructured Materials* Biomaterials and Medical AspectsDue to the increasing significance of Colloid and Interface Science for both scientific and technical applications where scientific principles also contribute to new technologies in fast improving Nanotechnology and Medical Science, this book will be an essential source of information with respect to recent developments and results related to this field.

Proceedings of the European Membrane Society XVI Annual Summer School on Integration of Membrane Processes into Bioconversions, held August 22-27, 1999, in Veszprem, Hungary. The purpose of this book is to give an overview of the current situation of membrane separation processes in the field of bioengineering and also to describe how their joint application possibilities can be used in both laboratory and industrial scale applications. In commercial applications, focus is centered on the fields of food industry, chemical/fine chemical industry, and environmental protection. Most of the European experts in the interdisciplinary fields of membrane processes and bioconversions have contributed to the chapters in this work, making it the most up-to-date volume currently available.

In recent years biocompatible polymers for injuries and wounds have seen advances and innovations that have outpaced the growing field's literature. In this book Dr. Jan W. Gooch, a National Research Council Research Associateship Award recipient, reveals how innovative polymer technology can be applied to the common combat and trauma wounds associated with damaged soft tissue and bleeding. The scope of his investigation spans four distinct devices for wounds, liquid and particulate barrier dressings for soft tissue wounds, sutureless tissue adhesives, antibacterial nanoemulsions, one-hand operated and automatic tourniquets for the battlefield.

The first NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts was held on September 10-22, 1989 in Akcay, Turkey. Based on the fundamental research of RRSchrock, RGrubbs and K.B.Wagener in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within the last years. Therefore the second NATO-ASI held on metathesis reactions was on Ring Opening Metathesis Po lymerization of Olefins and Polymerization of Alkynes on September 3-16, 1995 in Akcay, Turkey. The course joined inorganic, organic and polymer chemists to exchange their knowledge in this field. This volume contains the main and short lectures held in Akcay. To include ADMET reactions better into the title of this volume we changed it into: Metathesis Polymerization of Olefins and Alkyne Polymerization. This volume is addressed to research scientists, but also to those who start to work in the area of olefin metathesis and alkyne polymerization. The topics of the course were: mechanism of ROMP reactions/ new catalysts for ROMP/ new products by ROMP/ new catalysts for ADMET/ new products by ADMETI degradation of polymer by metathesis reactions/ alkyne polymerization and metathesis/ industrial application of metathesis reactions. The Advanced Study Institute was generously sponsored by the Scientific Affairs Division of NATO and the editor gratefully acknowledges this sponsorship. We also thank the Members of the Local Organizing Committee for their engagement on a successful NATO-AS ."

Advanced composite materials have been a major research focus for the past forty years. As a reinforcement for conventional materials including glass, ceramics and polymers, carbon has proved to be the most successful. Carbon gives these materials flexibility so that they may be produced in bulk form with a wide variety of properties. Whereas carbon/carbon composites are the most effective materials in extreme temperature conditions. Application ranges from brakes to missile nose cones. Carbon Reinforcements and Carbon/Carbon Composites gives the present state on this subject in comprehensive form, as well as projections for other "High Tech" materials and their application.

-Lignin Structure, Properties, and Applications By H. Hatakeyama, T. Hatakeyama -Tensile Mechanics of -Helical Coil Springs By A. Ikai -Bioactive Polymer/Hydroxyapatite (Nano)composites for Bone Tissue Regeneration By K. Pielichowska, S. Blazewicz"

-On the Mechanisms Leading to Exfoliated Nanocomposites Prepared by Mixing By C. D. Han -Phase Behavior and Phase Transitions in AB- and ABA-type Microphase-Separated Block Copolymers By J. K. Kim, C. D. Han -New Class Materials of Organic-Inorganic Hybridized Nanocrystals/Nanoparticles, and Their Assembled Microand Nano-Structure Toward Photonics By H. Oikawa, T. Onodera, A. Masuhara, H. Kasai, H. Nakanishi -Poly(substituted Methylene) Synthesis: Construction of C-C Main Chain from One Carbon Unit By E. Ihara

Polymer blends, grafts, and blocks, broadly defined, encompass all of the ways in which two or more kinds of poly mer molecules can be mixed and/or joined. Because these mate rials exhibit non-linear and often synergistic properties, they have found increasing application in our technology. Their multifarious uses have, in turn, spurred new research efforts, to find yet different ways of joining two kinds of polymer molecules, with novel physical and/or mechanical behavior patterns. In August, 1973, the Polymer Division of the American Chemical Society sponsored a symposium at its meeting in Chi cago on Polymer Blends, Grafts, and Blocks. This book collects the papers presented at that symposium. Yet, it is more than just a collection of papers, for we here display the thinking and efforts of a number of top-ranking American and foreign scientists in one of the world's more active research areas. The symposium emphasized the interrelationships among synthetic detail, morphology, and physical and mechanical properties. Several novel syntheses were presented. These include oxidation resistant thermoplastic elastomers (Holden), a graft copolymer based thermoplastic elastomer (Kennedy and Smith), a cationic graft copolymer (Kennedy, Charles, and Davidson), an AB crosslinked copolymer (Bamford and Eastmond), an interpenetrating polymer network (Donatelli, Thomas, and Sperling), and simultaneous interpenetrating networks (Frisch, Klempner, Frisch, and Ghiradella). Most polymer blends, grafts, and blocks exhibit two phases. The theory of microdomain structure was discussed (Helfand). The different ways that the two molecules can be joined together was examined (Kenney), and their topology was explored (Sperling)."

may never overcome the effects of hysteresis and stress (see Chapters 6 and 12). The first sentence of the reference work, Handbook of Liquid Crystals, reads: The terms liquid crystals, crystalline liquid, mesophase, and mesomorphous state are used synonymously to describe a state of aggregation that exhibits a molecular order in a size range similar to that of a crystal but acts more or less as a viscous liquid: [2] In other words, molecules within a liquid crystalline phase possess some orientational order and lack positional order; furthermore, the shape of a liquid crystalline sample is determined by the vessel in which it is contained rather than by the orientational order of its aggregated molecules. The authors recognized the limitations and imprecision of this definition but, like others preceding them, could not devise a simple and generally applicable one that is better. Regardless, the terms 'liquid crystal' and 'mesophase' should not be used interchangeably. As mentioned above, all liquid crystals are mesophases, but all mesophases are not liquid crystals. Recent studies, employing elaborate and sophisticated analytical techniques, have permitted finer distinctions between classical crystals and mesophases. At the same time, they have made definitions like that from the Handbook of Liquid Crystals somewhat obsolete for reasons other than terminology. One part of the problem arises from the use of a combination of bulk properties (like flow) and microscopic properties (like molecular ordering) within the same definition.

Diffusion Barrier Stack - 5 nm -3 nm -2 nm :. . . -. . . . : . . O. 21-lm Figure 2: Schematic representing a cross-sectional view of the topography that is encountered in the processing of integrated circuits. (Not to scale) these sub-micron sized features is depicted in Fig. 2. The role of the diffusion barrier is to prevent the diffusion of metallic ions into the interlayer dielectric (lLD). Depending on the technology, in particular the choice of the ILD and the metal interconnect, the diffusion barrier may be Ti, Ta, TiN, TaN, or a multi-layered structure of these materials. The adhesion of the barrier to the dielectric, the conformality of the barrier to the feature, the physical structure of the film, and the chemical composition of the film are key issues that are determined in part by the nature of the deposition process. Likewise, after the growth of the barrier, a conducting layer (the seed layer) is needed for subsequent filling of the trench by electrochemical deposition. Again, the growth process must be able to deposit a film that is continuous along the topography of the sub-micron sized features. Other factors of concern are the purity and the texture of the seed layer, as both of these factors influence the final resistivity of the metallic interconnect. Sputter-deposited coatings are also commonly employed for their electro-optical properties. For example, an electrochromic glazing is used to control the flux of light that is transmitted through a glazed material.

This publication presents the proceedings of ICPMSE-3, the third international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 25-26, 1996. The conference was hosted and organized by Integrity Testing Laboratory Inc, (ITL), and held at the University of Toronto's Institute for Aerospace Studies (UTIAS), where ITL is located. Twenty industrial companies, seven wliversities and eight government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 55 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-five speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space, Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories of major aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment, These proceedings are organized into four sections: a) AONOV and Radiation Effects on Materials and Structures in the Leo Space Environment; b) Interaction of Matter with the LEO Environment; c) Large Scale Coating Process Developments for Protection in LEO; d) Synthesis and Modification of Materials and Surfaces for Protection in LEO, This is the third in our on-going series of bi-annual international space materials conferences wllich began in 1992 in Toronto. Jacob Kleiman, Integrity Testing Laboratory Inc.

This publication presents the proceedings of ICPMSE-4, the fourth international conference on Protection of Materials and Structures from the Low Earth Orbit Space Environment, held in Toronto April 23-24, 1998. The conference was hosted and organized by Integrity Testing Laboratory Inc. (ITL), and held at the University ofToronto's Institute for Aerospace Studies (UTIAS). Twenty two industrial companies, six universities and fourteen government agencies from Canada, USA, United Kingdom, France, Israel, Russia, Ukraine and the Netherlands were represented by over 75 participants indicating increasing international co-operation in this critical arena of protection of materials in space. Twenty-seven speakers, world experts in their fields, delivered talks on a wide variety of topics on various aspects of material protection in space. Representatives from the Canadian, American, European and Israeli space agencies as well as from leading space research laboratories ofmajor aerospace industries gathered at UTIAS to discuss the latest developments in the field of material and structure protection from the harsh space environment.

A comprehensive encyclopaedic dictionary on polymer technology with expanded entries - trade name and trade marks, list of abbreviations and property tables.