This book reports the basics of hybrid phosphor materials, their synthesis routes and their special properties and characterization techniques. It gives the reader information about the natural origins and development of hybrid materials, which are developed by combining inorganic and organic species in one material interface-determined materials. The book provides a general classification of hybrid materials, wherein inorganic materials modified by organic moieties are distinguished from organic materials or matrices modified by inorganic constituents. It gives a focus to the functionalization of organic materials by inorganic additives. The application areas covered include optoelectronic field, sensor applications, biological and environmental applications.

Thermal analysis is an old technique. It has been neglected to some degree because developments of convenient methods of measurement have been slow and teaching of the understanding of the basics of thermal analysis is often wanting. Flexible, linear macromolecules, also not as accurately simply called polymers, make up the final, third, class of molecules which only was identified in 1920. Polymers have neverbeenfullyintegratedintothedisciplinesofscienceandengineering. Thisbook is designed to teach thermal analysis and the understanding of all materials, flexible macromolecules, as well as those of the small molecules and rigid macromolecules. The macroscopic tool of inquiry is thermal analysis, and the results are linked to microscopic molecular structure and motion. Measurements of heat and mass are the two roots of quantitative science. The macroscopic heat is connected to the microscopic atomic motion, while the macroscopic mass is linked to the microscopic atomic structure. The macroscopic unitsofmeasurementofheatandmassarethejouleandthegram, chosentobeeasily discernable by the human senses. The microscopic units of motion and structure are 12 10 the picosecond (10 seconds) and the angstrom (10 meters), chosen to fit the atomic scales. One notes a factor of 10,000 between the two atomic units when expressed in human units, second and gram with one gram being equal to one cubic centimeter when considering water. Perhaps this is the reason for the much better understanding and greater interest in the structure of materials, being closer to human experience when compared to molecular motion."

Awarded the 2009 Olle Prize! The field of coordination polymer research has undergone rapid expansion in recent years. No longer are these materials the vaguely defined 'insoluble material' at the bottom of your vessel that spell death for your reaction. They have gone from 'polymeric rubbish' to 'materials of the future'. Great leaps in the deliberate design of coordination polymers were made in the 1990s. These were allied with similar advances in related areas such as organic crystal engineering, metallosupramolecular chemistry and X-ray diffraction. No longer did we assemble things atom by atom. Whole molecules were used as building blocks and new materials were made. This is the first book to provide a broad overview of all the major facets of coordination polymer research in one place. It combines chapters on nets and interpenetration with wide-ranging surveys of transition metal and lanthanoid coordination polymers and their properties. The aim is to provide a flavour of each aspect whilst introducing the important concepts and developments using carefully selected examples. After an introduction, the text is split into three sections: -Design (nets, interpenetration, malleability) -Analysis (transition metal coordination polymers, lanthanoid coordination polymers, organometallic networks, organic-inorganic hybrids) -Application (magnetic properties, porosity, acentric and chiral networks, reactive coordination polymers, other properties). Written in the style of a tutorial review, the book is suitable for both senior specialists and new postgraduate students taking their first steps in the field. It also provides an authoritative and detailed reference source.

Carbohydrate chemistry has seen a resurgence of interest stimulated by increasing awareness of the roles of these substances in biological recognition regulation. In addition, the increasing power of theoretical, physical and synthetic methods have enabled deeper insights into the properties of carbohydrates and their potential for exploitation. Carbohydrates presents a contemporary picture of our knowledge of the structures and syntheses of monosaccharide, oligosaccharide and glycopeptide units, and the properties of some important examples and derivatives including sulphates and polysaccharides. Written by established experts in the field, the book provides informed perspective of nine key areas at a level between basic texts and special research treatments.

Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.

The present volume includes most of the material of the invited lectures delivered at the NATO Advanced Study Institute "Morphogenesis through the interplay of nonlinear chemical instabilities and elastic active media" held from 2th to 14th July 2007 at the Institut d'Etudes Scientifiques de Cargese (http: //www.iesc.univ-corse.fr/), in Corsica (France). This traditional place to organize Summer Schools and Workshops in a well equipped secluded location at the border of the Mediterranean sea has, over many years now, earned an increasing deserved reputation. Non-linear dynamics of non equilibrium systems has worked its way into a great number of fields and plays a key role in the understanding of se- organization and emergence phenomena in domains as diverse as chemical reactors, laser physics, fluid dynamics, electronic devices and biological morphogenesis. In the latter case, the viscoelastic properties of tissues are also known to play a key role. The control and formulation of soft responsive or "smart" materials has been a fast growing field of material science, specially in the area of po- mer networks, due to their growing applications in bio-science, chemical sensors, intelligent microfluidic devices, ... . Nature is an important p- vider of active materials whether at the level of tissues or at that of s- cellular structures. As a consequence, the fundamental understanding of the physical mechanisms at play in responsive materials also shines light in the understanding of biological artefacts."

This book presents a comprehensive survey about the most recent developments in industrial applications, processing techniques and modifications of polymers from marine sources. It systematically introduces the reader to the biomaterials Chitin, Collagen, Alginates, Cellulose and Polyesters and links their interwoven industrial significance and environmental implications. The book elucidates the impact of industrial sourcing of the aquatic system for organic and inorganic matter on the environment and deepens the understanding of the industrial and economic significance of aquatic biopolymers. Further it addresses the question of how to balance the conservation of aquatic life and the industrial and economic interest in developing biodegradable alternatives for plastic. Thus the book will appeal to scientists in the field of chemistry, materials and polymer science as well as engineering.

This book is a snapshot of the current state of the art of research and development on the properties and characteristics of silk and their use in medicine and industry. The field encompasses backyard silk production from ancient time to industrial methods in the modern era and includes an example of efforts to maintain silk production on Madagascar. Once revered as worth its weight in gold, silk has captured the imagination from its mythical origins onwards. The latest methods in molecular biology have opened new descriptions of the underlying properties of silk. Advances in technological innovation have created silk production by microbes as the latest breakthrough in the saga of silk research and development. The application of silk to biomaterials is now very active on the basis of excellent properties of silks including recombinant silks for biomaterials and the accumulated structural information.

Ceramic and Specialty Electrolytes for Energy Storage Devices, Volume II, investigates recent progress and challenges in a wide range of ceramic solid and quasi-solid electrolytes and specialty electrolytes for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail. Features: * Offers a detailed outlook on the performance requirements and ion transportation mechanism in solid polymer electrolytes * Covers solid-state electrolytes based on oxides (perovskite, anti-perovskite) and sulfide-type ion conductor electrolytes for lithium-ion batteries followed by solid-state electrolytes based on NASICON and garnet-type ionic conductors * Discusses electrolytes employed for high-temperature lithium-ion batteries, low-temperature lithium-ion batteries, and magnesium-ion batteries * Describes sodium-ion batteries, transparent electrolytes for energy storage devices, non-platinum-based cathode electrocatalyst for direct methanol fuel cells, non-platinum-based anode electrocatalyst for direct methanol fuel cells, and ionic liquid-based electrolytes for supercapacitor applications * Suitable for readers with experience in batteries as well as newcomers to the field This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials and chemical engineers, as well as those involved in related disciplines.

This book presents the chemical properties of lignocellulosic fibers, knowledge of which is essential for innovation and sustainable development of their transformation. Thermochemical transformation of wood and other lignocellulosics is presented to highlight its volatile, liquid and solid products and their novel applications. Forest biorefinery is described to emphasize the new products from lignocellulosic constituents, both structural (cellulose, hemicelluloses and lignins) and those extraneous to cell walls-extractives. New developments in cellulose technology related to nanocellulose are discussed in relation to new applications. Industrial lignins are presented in detail, both in terms of extraction procedures from spent liquors and structural characterization of the isolated lignins. Application of lignocellulosic biopolymers in new composite materials, or in biomaterials for medicinal purposes, and in solid wood preservation, are described. The example of an industrial biorefinery installed in southwestern France more than 40 years ago is presented.

This book addresses a broad range of issues concerning microplastic pollution, including microplastic pollution in various environments (freshwater, marine, air and soil); the sources, fate and effects of microplastics; detection systems for microplastic pollution monitoring; green approaches for the synthesis of environmentally friendly polymers; recovery and recycling of marine plastics; wastewater treatment plants as a microplastic entrance route; nanoplastics as emerging pollutants; degradation of plastics in the marine environment; impacts of microplastics on marine life; microplastics: from marine pollution to the human food chain; mitigation of microplastic impacts and innovative solutions; sampling, extraction, purification and identification approaches for microplastics; adsorption and transport of pollutants on and in microplastics; and lastly, the socio-economic and environmental impacts: assessment and risk analysis. In addition to presenting cutting-edge information and highlighting current trends and issues, the book proposes concrete solutions to help face this significant environmental threat. It is chiefly intended for researchers and industry decision-makers; international, national and local institutions; and NGOs, providing them with comprehensive information on the origin of the problem; its effects on marine environments, with a particular focus on the Mediterranean Sea and coasts; and recent and ongoing research activities and projects aimed at finding technical solutions to mitigate the phenomenon.

Written by a chemical physicist specializing in macromolecular physics, this book brings to life the definitive work of celebrated scientists who combined multidisciplinary perspectives to pioneer the field of polymer science. The author relates firsthand the unique environment that fostered the experimental breakthroughs underlying some of today's most widely accepted theories, mathematical principles, and models for characterizing macromolecules.

Physical Chemistry of Macromolecules employs the unifying principles of physical chemistry to define the behavior, structure, and intermolecular properties of macromolecules in both solution and bulk states. The text explains the experimental techniques, such as light scattering, and results used to support current theories. Examining both equilibrium and transport properties, the book describes the properties of dilute, semi-dilute, and concentrated polymer solutions, including compressible fluids. It then covers amorphous liquids and glasses, and polymer networks. The final chapters discuss the properties of solutions containing stiff-chain molecules and polyelectrolytes. Topics also include the macromolecular nature of rubber elasticity, viscoelasticity, and the distribution of relaxation times associated with the glass transition.

By explaining the experimental and mathematical basis for the theories and models used to define macromolecular behavior, Physical Chemistry of Macromolecules demonstrates how these techniques and models can be applied to analyze and predict the properties of new polymeric materials.

This book presents a comprehensive overview of the freezing of colloidal suspensions and explores cutting-edge research in the field. It is the first book to deal with this phenomenon from a multidisciplinary perspective, and examines the various occurrences, their technological uses, the fundamental phenomena, and the different modeling approaches. Its chapters integrate input from fields as diverse as materials science, physics, biology, mathematics, geophysics, and food science, and therefore provide an excellent point of departure for anyone interested in the topic. The main content is supplemented by a wealth of figures and illustrations to elucidate the concepts presented, and includes a final chapter providing advice for those starting out in the field. As such, the book provides an invaluable resource for materials scientists, physicists, biologists, and mathematicians, and will also benefit food engineers, civil engineers, and materials processing professionals.

This book delivers a comprehensive overview of the characteristics of several types of materials that are widely used in the current era of supercapacitors; namely, architectured carbon materials, transition metal oxides and conducting polymers. It provides readers with a complete introduction to the fundamentals of supercapacitors, including the development of new electrolytes and electrodes, while highlighting the advantages, challenges, applications and future of these materials. This book is part of the Handbook of Nanocomposite Supercapacitor Materials. Supercapacitors have emerged as promising devices for electrochemical energy storage, playing an important role in energy harvesting for meeting the current demands of increasing global energy consumption. The handbook covers the materials science and engineering of nanocomposite supercapacitors, ranging from their general characteristics and performance to materials selection, design and construction. Covering both fundamentals and recent developments, this handbook serves a readership encompassing students, professionals and researchers throughout academia and industry, particularly in the fields of materials chemistry, electrochemistry, and energy storage and conversion. It is ideal as a reference work and primary resource for any introductory senior-level undergraduate or beginning graduate course covering supercapacitors.

Interior Provocations: History, Theory, and Practice of Autonomous Interiors addresses the broad cultural, historical, and theoretical implications of interiors beyond their conventionally defined architectural boundaries. With provocative contributions from leading and emerging historians, theorists, and design practitioners, the book is rooted in new scholarship that expands traditional relationships between architecture and interiors and that reflects the latest theoretical developments in the fields of interior design history and practice. This collection contains diverse case studies from the late eighteenth century to the twenty-first century including Alexander Pope's Memorial Garden, Design Indaba, and Robin Evans. It is an essential read for researchers, practitioners, and students of interior design at all levels.

Interior Provocations: History, Theory, and Practice of Autonomous Interiors addresses the broad cultural, historical, and theoretical implications of interiors beyond their conventionally defined architectural boundaries. With provocative contributions from leading and emerging historians, theorists, and design practitioners, the book is rooted in new scholarship that expands traditional relationships between architecture and interiors and that reflects the latest theoretical developments in the fields of interior design history and practice. This collection contains diverse case studies from the late eighteenth century to the twenty-first century including Alexander Pope’s Memorial Garden, Design Indaba, and Robin Evans. It is an essential read for researchers, practitioners, and students of interior design at all levels.

The CRC Handbook of Enthalpy Data of Polymer-Solvent Systems presents data that is as essential to the production, process design, and use of polymers as it is to understanding the physical behavior and intermolecular interactions in polymer solutions and in developing thermodynamic polymer models. Providing an all-encompassing collection of current enthalpy data for all types of polymer solutions, this handbook is a ready companion with Christian Wohlfarth's previously published handbooks of thermodynamic data for copolymer solutions, aqueous polymer solutions, and polymer solutions at elevated pressures, which contain only a small amount of enthalpic data in comparison to the data presented here. This volume contains 1770 data sets that include enthalpies of mixing and dilution for the entire concentration range as well as partial enthalpies of mixing and solution at infinite dilution. Special appendices allow scientists to access specific systems and data easily. The CRC Handbook of Enthalpy Data of Polymer-Solvent Systems is a practical, one-stop resource that allows polymer chemists, biochemists, chemical engineers, materials scientists, and physical chemists involved in both industrial and laboratory processes to quickly retrieve relevant information as needed.

New fields of science and technology call for new materials with valuable performance characteristics. Long-term resistance to such temperatures can be found only in polymers with chains made up of thermostable fragments. Particularly interesting in this respect are elementorganic polymers with inorganic and organo-inorganic molecular chains. Elementorganic polymers are not only highly thermostable, but also perform well under low temperatures, sunlight, humidity, weather, etc. Thus, these polymers (especially silicones) are widely and effectively used in the electrical, radio, coal, mechanical rubber, aircraft, metallurgical, textile and other industries. They are of great utility not only in industry, but also in households and in medicine, where their merits can hardly be overestimated. The need to publish this book arose with the scientific and technical developments of the last decade, the reconstruction and technical renovation of existing factories, as well as fundamental changes in some syntheses of elementorganic monomers and polymers. Moreover, nowadays it is essential to train highly-skilled chemical engineers with a comprehensive knowledge of current chemistry, of the production technology of elementorganic monomers and polymers, and of their characteristics and applications.

Vincent Bulone et al.: Cellulose sources and new understanding of synthesis in plants Thomas Heinze et al.:Cellulose structure and properties Thomas Rosenau, Antje Potthast, Ute Henniges et al.: Recent developments in cellulose aging (degradation / yellowing / chromophore formation) Sunkyu Park et al.:Cellulose crystallinity Lina Zhang et al.:Gelation and dissolution behavior of cellulose Yoshiyuki Nishio et al.:Cellulose and derivatives in liquid crystals Alessandro Gandini, Naceur Belgacem et al.:The surface and in-depth modification of cellulose fibers Emily D. Cranston et al.:Interfacial properties of cellulose Herbert Sixta, Michael Hummel et al.Cellulose Fibers Regenerated from Cellulose Solutions in Ionic Liquids Qi Zhou et al.:Cellulose-based biocomposites Orlando Rojas et al.:Films of cellulose nanocrystals and nanofibrils Pedro Fardim et al.:Functional cellulose particles Wadood Hamad et al.:Cellulose Composites

This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine containing monomers of diallyl and acrylic nature and their structure and investigation of their radical (co)polymerization and properties of new (co)polymers. The first parts of the book describe radical polymerization of these monomers and their co-polymerization with diallyldialkylammonium derivatives, features of their kinetic behavior in these processes (for example, polymerization rates, reactivity ratios) The sections on phycal chemical methods (IR, NMR, DSC ect.) are especially important for studying of structure and properties of synthesized monomer and polymer compounds. The book is finely illustrated with about hundred original figures, schemes and tables including kinetics, NMR, IR spectroscopy, biocide and other data.

This second volume of the "Handbook of Polyhydroxyalkanoates (PHA): Kinetics, Bioengineering and Industrial Aspects" focusses on thermodynamic and mathematical considerations of PHA biosynthesis, bioengineering aspects regarding bioreactor design and downstream processing for PHA recovery from microbial biomass. It covers microbial mixed culture processes and includes a strong industry-focused section with chapters on the economics of PHA production, industrial-scale PHA production from sucrose, next generation industrial biotechnology approaches for PHA production based on novel robust production strains, and holistic techno-economic and sustainability considerations on PHA manufacturing. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this book Provides an insight into microbial thermodynamics to reveal the central domain governing in PHA formation, both aerobically and anaerobically. Includes systematic overview of mathematical modelling approaches, starting from low-structured and formal kinetic models until modern tools like metabolic models, cybernetic models and so forth Discusses challenges during scale up of PHA production processes and on development of non-sterile processes and contamination-resistant strains Presents a holistic picture of the current state of PHA research by mixed cultures Reviews the industry-related point of view about current and future trends in PHA production and processing

The Handbook of Polyhydroxyalkanoates (PHA) focusses on and addresses varying facets of PHA biosynthesis and processing, spread across three volumes. The first volume discusses feedstock aspects, enzymology, metabolism and genetic engineering of PHA biosynthesis. It addresses better understanding the mechanisms of PHA biosynthesis in scientific terms and profiting from this understanding in order to enhance PHA biosynthesis in bio-technological terms and in terms of PHA microstructure. It further discusses making PHA competitive for outperforming established petrol-based plastics on industrial scale and obstacles for market penetration of PHA. This second volume focusses on thermodynamic and mathematical considerations of PHA biosynthesis, bioengineering aspects regarding bioreactor design and downstream processing for PHA recovery from microbial biomass. It covers microbial mixed culture processes and includes a strong industry-focused section with chapters on the economics of PHA production, industrial-scale PHA production from sucrose, next generation industrial biotechnology approaches for PHA production based on novel robust production strains, and holistic techno-economic and sustainability considerations on PHA manufacturing. Third volume is on the production of functionalized PHA bio-polyesters, the post-synthetic modification of PHA, processing and additive manufacturing of PHA, development and properties of PHA-based (bio)composites and blends, the market potential of PHA and follow-up materials, different bulk- and niche applications of PHA, and the fate and use of spent PHA items. Divided into fourteen chapters, it describes functionalized PHA and PHA modification, processing and their application including degradation of spent PHA-based products and fate of these bio-polyesters during compositing and other disposal strategies. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this set: Presents comprehensive and holistic consideration of these microbial bioplastics in the volumes. Enables reader to learn about microbiological, enzymatic, genetic, synthetic biology, and metabolic aspects of PHA biosynthesis based on the latest scientific discoveries. Discusses design and operate a PHA production plant. Strong focus on post-synthetic modification, preparation of functional PHA and follow-up products, and PHA processing. Covers all related engineering considerations

This series presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and materials science. It is addressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered.

Impact Factor Ranking: Always number one in Polymer Science. More information as well as the electronic version of the whole content available at: www.springerlink.com

First Published in 2006. This volume introduces and provides a semantic analysis of Discourse Adjectives, a natural class of adjectives that the author argues includes apparent, clear, evident, and obvious among its prototypical members. With a main claim that Discourse Adjectives do not provide information about the facts of the world. Rather, they are used by interlocutors to negotiate the status of propositions in a discourse.

Supramolecular Polymers, Second Edition details assembly processes and structure-function correlation in natural and synthetic self-assembling materials, focusing on developments occurred over the past five years.

The book highlights developments in the synthesis of complex structures, chemical design principles, and theoretical models of growth processes resulting in an increasingly accurate prediction of stability, degree of polymerization, and shape of various assemblies. It focuses on the rich variety of properties, functions, and applications of self-assembling supramolecular polymers. Supramolecular Polymers, Second Edition ties together potential applications such as those of nanostructures with dynamic-combinatorial-adaptive self-healing features, opto-electronic devices, supramolecular amphiphiles, hydrogels, organic/inorganic nanocomposites, molecular biosensors, molecular imprinting, molecular engines, templates for superlattices with prescribed symmetry. Several chapters of the first edition have been updated or rewritten, and an equal number of new chapters have been added. More than 500 drawings, photographs, micrographs, equations, and tables enhance and reinforce essential concepts presented in the book.

Authored by an expert in polymer mechanics, biopolymers, liquid crystals, and supramolecular assemblies, Supramolecular Polymers, Second Edition emphasizes fundamental principles at the basis of bottom-up nanotechnology, chemical design strategies, and exciting applications for various self-assembling materials for a unified and cutting-edge account of the field.