This book critically assesses the current state of knowledge on new and important detection technologies, e.g. mass spectrometry, tandem mass spectrometry, biosensor detection and tissue imaging, in connection with toxic chemical and biological agents. In general, the main topics discussed concern the risks and consequences of chemical and biological agents for human health in general, with special emphasis on all biochemical and metabolic pathways including the reproductive system. The exposome, genetic risks and the environment, various health hazard agents, risk assessment, environmental assessment and preparedness, and analysis of sub-lethal effects at the molecular level are also discussed. In closing, the book provides comprehensive information on the diagnosis of exposure, and on health concerns related to toxic chemical and biological agents.

This book provides a comprehensive overview of the fascinating recent developments in atomic- and nanoscale magnetism, including the physics of individual magnetic adatoms and single spins, the synthesis of molecular magnets for spintronic applications, and the magnetic properties of small clusters as well as non-collinear spin textures, such as spin spirals and magnetic skyrmions in ultrathin films and nanostructures. Starting from the level of atomic-scale magnetic interactions, the book addresses the emergence of many-body states in quantum magnetism and complex spin states resulting from the competition of such interactions, both experimentally and theoretically. It also introduces novel microscopic and spectroscopic techniques to reveal the exciting physics of magnetic adatom arrays and nanostructures at ultimate spatial and temporal resolution and demonstrates their applications using various insightful examples. The book is intended for researchers and graduate students interested in recent developments of one of the most fascinating fields of condensed matter physics.

A comprehensive device model considering both spatial distributions of the terahertz field and the field-effect self-mixing factor has been constructed for the first time in the thesis. The author has found that it is the strongly localized terahertz field induced in a small fraction of the gated electron channel that plays an important role in the high responsivity. An AlGaN/GaN-based high-electron-mobility transistor with a 2-micron-sized gate and integrated dipole antennas has been developed and can offer a noise-equivalent power as low as 40 pW/Hz1/2 at 900 GHz. By further reducing the gate length down to 0.2 micron, a noise-equivalent power of 6 pW/Hz1/2 has been achieved. This thesis provides detailed experimental techniques and device simulation for revealing the self-mixing mechanism including a scanning probe technique for evaluating the effectiveness of terahertz antennas. As such, the thesis could be served as a valuable introduction towards further development of high-sensitivity field-effect terahertz detectors for practical applications.

This book, now in its second edition, introduces readers to quantum rings as a special class of modern high-tech material structures at the nanoscale. It deals, in particular, with their formation by means of molecular beam epitaxy and droplet epitaxy of semiconductors, and their topology-driven electronic, optical and magnetic properties. A highly complex theoretical model is developed to adequately represent the specific features of quantum rings. The results presented here are intended to facilitate the development of low-cost high-performance electronic, spintronic, optoelectronic and information processing devices based on quantum rings. This second edition includes both new and significantly revised chapters. It provides extensive information on recent advances in the physics of quantum rings related to the spin-orbit interaction and spin dynamics (spin interference in Rashba rings, tunable exciton topology on type II InAs/GaAsSb quantum nanostructures), the electron-phonon interaction in ring-like structures, quantum interference manifestations in novel materials (graphene nanoribbons, MoS2), and the effects of electrical field and THz radiation on the optical properties of quantum rings. The new edition also shares insights into the properties of various novel architectures, including coupled quantum ring-quantum dot chains and concentric quantum rings, topologic states of light in self-assembled ring-like cavities, and optical and plasmon m.odes in Moebius-shaped resonators.

The book explores the phenomenon of surface-enhanced Raman scattering (SERS), the huge amplification of Raman signal from molecules in the proximity of a metallic nanostructured surface, allowing readers to gain an in-depth understanding of the mechanisms affecting the spectroscopic response of SERS-active systems for effective applications. SERS spectroscopy is an ultrasensitive analytical technique with great potential for applications in the field of biophysics and nanomedicine. As examples, the author presents the design of nanocolloid-based SERS-active substrates for molecular sensing and of a folate-based SERS-active nanosensor capable of selectively interacting with cancer cells, enabling cancer diagnostics and therapy at the single-cell level. The author also suggests novel paths for the systematization of the SERS nanosystem design and experimental protocols to maximize sensitivity and reproducibility, which is essential when real-world biomedical applications are the goal of the study. With a combined approach, both fundamental and applied, and a detailed analysis of the state of the art, this book provides a valuable overview both for students new to SERS spectroscopy and for experts in the field.

This thesis describes novel approaches and implementation of high-resolution microscopy in the extreme ultraviolet light regime. Using coherent ultrafast laser-generated short wavelength radiation for illuminating samples allows imaging beyond the resolution of visible-light microscopes. Michael Zurch gives a comprehensive overview of the fundamentals and techniques involved, starting from the laser-based frequency conversion scheme and its technical implementation as well as general considerations of diffraction-based imaging at nanoscopic spatial resolution. Experiments on digital in-line holography and coherent diffraction imaging of artificial and biologic specimens are demonstrated and discussed in this book. In the field of biologic imaging, a novel award-winning cell classification scheme and its first experimental application for identifying breast cancer cells are introduced. Finally, this book presents a newly developed technique of generating structured illumination by means of so-called optical vortex beams in the extreme ultraviolet regime and proposes its general usability for super-resolution imaging.

Chemiluminescence (K. Nakashima & K. Imai).

Fluorescent Probes for Evaluation of Local Physical and Structural Parameters (B. Valeur).

Photochemical Fluorometry (J.-J.

Aaron).

Applications of Organized Bile Salt Media for Luminescence Analysis (L. McGown).

Spectral Hole-Burning (K. Holliday & U. Wild).

Near-Infrared Luminescence Spectroscopy (S. Akiyama).

Microspectrofluorometry on Supported Planar Membranes (L. Tamm & E. Kalb).

Clinical Applications of Luminescence Spectroscopy (G. Schenk).

Laser-Excited Molecular Fluorescence in Analytical Sciences (J. Hofstraat, et al.).

Index.

This monograph covers the concept of cartesian tensors with the needs and interests of physicists, chemists and other physical scientists in mind. After introducing elementary tensor operations and rotations, spherical tensors, combinations of tensors are introduced, also covering Clebsch-Gordan coefficients. After this, readers from the physical sciences will find generalizations of the results to spinors and applications to quantum mechanics.

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students

This book suggests a new common approach to the study of resonance energy transport based on the recently developed concept of Limiting Phase Trajectories (LPTs), presenting applications of the approach to significant nonlinear problems from different fields of physics and mechanics. In order to highlight the novelty and perspectives of the developed approach, it places the LPT concept in the context of dynamical phenomena related to the energy transfer problems and applies the theory to numerous problems of practical importance. This approach leads to the conclusion that strongly nonstationary resonance processes in nonlinear oscillator arrays and nanostructures are characterized either by maximum possible energy exchange between the clusters of oscillators (coherence domains) or by maximum energy transfer from an external source of energy to the chain. The trajectories corresponding to these processes are referred to as LPTs. The development and the use of the LPTs concept a re motivated by the fact that non-stationary processes in a broad variety of finite-dimensional physical models are beyond the well-known paradigm of nonlinear normal modes (NNMs), which is fully justified either for stationary processes or for nonstationary non-resonance processes described exactly or approximately by the combinations of the non-resonant normal modes. Thus, the role of LPTs in understanding and analyzing of intense resonance energy transfer is similar to the role of NNMs for the stationary processes. The book is a valuable resource for engineers needing to deal effectively with the problems arising in the fields of mechanical and physical applications, when the natural physical model is quite complicated. At the same time, the mathematical analysis means that it is of interest to researchers working on the theory and numerical investigation of nonlinear oscillations.

This book presents developments of techniques for detection and analysis of two electrons resulting from the interaction of a single incident electron with a solid surface. Spin dependence in scattering of spin-polarized electrons from magnetic and non-magnetic surfaces is governed by exchange and spin-orbit effects. The effects of spin and angular electron momentum are shown through symmetry of experimental geometries: (i) normal and off normal electron incidence on a crystal surface, (ii) spin polarization directions within mirror planes of the surface, and (iii) rotation and interchange of detectors with respect to the surface normal. Symmetry considerations establish relationships between the spin asymmetry of two-electron distributions and the spin asymmetry of Spectral Density Function of the sample, hence providing information on the spin-dependent sample electronic structure. Detailed energy and angular distributions of electron pairs carry information on the electron-electron interaction and electron correlation inside the solid. The "exchange - correlation hole" associated with Coulomb and exchange electron correlation in solids can be visualized using spin-polarized two-electron spectroscopy. Also spin entanglement of electron pairs can be probed. A description of correlated electron pairs generation from surfaces using other types of incident particles, such as photons, ions, positrons is also presented.

The 6th International Conference on Laser Probing (LAP2012) had been held in Paris at the Institut Henri Poincare. It highlighted the state of the art in Laser Probing and reinforced the common ground and synergies among the different actors in the field. The Institut de Physique Nucleaire d Orsay and the Grand Accelerateur National d Ions Lourds in Caen had been in charge of the organization of this event, co-sponsored by the Institut National de Physique Nucleaire et de Physique des Particules (IN2P3) and the Laboratory Physique des 2 Infinis et des Origines (P2IO).
Previously published as special issue of Hyperfine Interactions, vol. 216, 1-3."

This book provides a detailed review of power amplifiers, including classes and topologies rarely covered in books, and supplies sufficient information to allow the reader to design an entire amplifier system, and not just the power amplification stage. A central aim is to furnish readers with ideas on how to simplify the design process for a preferred power amplifier stage by introducing software-based routines in a programming language of their choice. The book is in two parts, the first focusing on power amplifier theory and the second on EDA concepts. Readers will gain enough knowledge of RF and microwave transmission theory, principles of active and passive device design and manufacturing, and power amplifier design concepts to allow them to quickly create their own programs, which will help to accelerate the transceiver design process. All circuit designers facing the challenge of designing an RF or microwave power amplifier for frequencies from 2 to 18 GHz will find this book to be a valuable asset.

In this thesis the author presents the results of extensive spectroscopy experiments beyond the bounds of each transition element to clarify the origins of characteristic spectral features and charge dynamics in charge-spin-orbital coupled phenomena in Mott-transition oxides. Several counterpart 3d transition-metal oxides were adopted as model systems suitable for examining the mechanisms involved, and their electronic structures were systematically investigated using three main spectroscopy methods.

Comparative studies on the charge dynamics and Mott transition features of transition-metal oxides were performed: Charge dynamics and thermoelectricity in a typical Mott transition system La1 xSrxVO3, charge dynamics in a doped valence-bond solid system (Ti1 xVx)2O3 and in layered nickelates R2-xSrxNiO4 with charge-ordering instability are investigated thoroughly. The results obtained successfully provide a number of novel insights into the emergent phenomena near the Mott transition.

"

Raman spectroscopy is now well established as one of the most versatile techniques for the chemical analysis of molecular species. Major advances have been made in a number of areas in the field in recent years which enable the researcher and practising analytical scientist to solve the complex chemical problems of today. The ten chapters in Modern Techniques in Raman Spectroscopy cover some of the most exciting fields of research in modern Raman techniques, and illustrate the power of modern Raman spectroscopy for molecular analysis in both theoretical and practical problems. The volume opens with chapters on signal expressions and instrumentation in Raman spectroscopy, and then goes on to discuss in detail Fourier and Hadamard Transform Raman spectroscopies, micro-Raman spectroscopy, surface-enhanced Raman spectroscopy, Raman optical activity, coherent and time-resolved techniques and the use of optical fibres in Raman spectroscopy. The chapters are written by leading researchers from a broad range of disciplines. Throughout, applications of the various techniques are discussed. Modern Techniques in Raman Spectroscopy will be of great interest to all those involved in molecular spectroscopy, in both industry and academia. The inclusion of a wide range of modern techniques in a single volume will make this a particularly valuable work to researchers across the whole field of Raman spectroscopy.

This multi-author contributed volume contains chapters featuring the development of the DV-X method and its application to a variety of problems in Materials Science and Spectroscopy written by leaders of the respective fields. The volume contains a Foreword written by the Chairs of Japanese and Korea DV-X alpha Societies. This book is aimed at individuals working in Quantum Chemistry.

This book reviews various aspects of molecular spectroscopy and its application in materials science, chemistry, physics, medicine, the arts and the earth sciences. Written by an international group of recognized experts, it examines how complementary applications of diverse spectroscopic methods can be used to study the structure and properties of different materials. The chapters cover the whole spectrum of topics related to theoretical and computational methods, as well as the practical application of spectroscopic techniques to study the structure and dynamics of molecular systems, solid-state crystalline and amorphous materials, surfaces and interfaces, and biological systems. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in the latest developments in the theory, experimentation, measurement and application of various advanced spectroscopic methods for the study of materials.

This thesis focuses on the fundamental problem of characterising partially coherent beams. The book describes several non-interferometric methods based on phase-space tomography for recovering the spatial coherence information of optical beams. In the context of optical beams, partially coherent light provides numerous advantages over coherent light. From microscopy to optical communications, there are many disciplines that benefit from using partially coherent beams. However, their range of applications currently remains limited due to the complexity of extracting information. In addition to providing a feasible experimental solution for the general case, the book explores several situations in which beam symmetries are exploited to simplify the information extraction process. Each characterisation method is accompanied by a corresponding theoretical explanation and a thorough description of experimental examples.

This book review series presents current trends in modern biotechnology. The aim is to cover all aspects of this interdisciplinary technology where knowledge, methods and expertise are required from chemistry, biochemistry, microbiology, genetics, chemical engineering and computer science. Volumes are organized topically and provide a comprehensive discussion of developments in the respective field over the past 3-5 years. The series also discusses new discoveries and applications. Special volumes are dedicated to selected topics which focus on new biotechnological products and new processes for their synthesis and purification. In general, special volumes are edited by well-known guest editors. The series editor and publisher will however always be pleased to receive suggestions and supplementary information. Manuscripts are accepted in English.

This thesis deals with topological orders from two different perspectives: from a condensed matter point of view, where topological orders are considered as breakthrough phases of matter; and from the emerging realm of quantum computation, where topological quantum codes are considered the most appealing platform against decoherence. The thesis reports remarkable studies from both sides. It thoroughly investigates a topological order called the double semion model, a counterpart of the Kitaev model but exhibiting richer quasiparticles as excitations. A new model for symmetry enriched topological order is constructed, which adds an onsite global symmetry to the double semion model. Using this topological phase, a new example of topological code is developed, the semion code, which is non-CSS, additive, non-Pauli and within the stabiliser formalism. Furthermore, the thesis analyses the Rashba spin-orbit coupling within topological insulators, turning the helical edge states into generic edges modes with potential application in spinstronics. New types of topological superconductors are proposed and the novel properties of the correspondingly created Majorana fermions are investigated. These Majorana fermions have inherent properties enabling braiding and the performance of logical gates as fundamental blocks for a universsal quantum computator.

This thesis combines highly accurate optical spectroscopy data on the recently discovered iron-based high-temperature superconductors with an incisive theoretical analysis. Three outstanding results are reported: (1) The superconductivity-induced modification of the far-infrared conductivity of an iron arsenide with minimal chemical disorder is quantitatively described by means of a strong-coupling theory for spin fluctuation mediated Cooper pairing. The formalism developed in this thesis also describes prior spectroscopic data on more disordered compounds. (2) The same materials exhibit a sharp superconductivity-induced anomaly for photon energies around 2.5 eV, two orders of magnitude larger than the superconducting energy gap. The author provides a qualitative interpretation of this unprecedented observation, which is based on the multiband nature of the superconducting state. (3) The thesis also develops a comprehensive description of a superconducting, yet optically transparent iron chalcogenide compound. The author shows that this highly unusual behavior can be explained as a result of the nanoscopic coexistence of insulating and superconducting phases, and he uses a combination of two complementary experimental methods - scanning near-field optical microscopy and low-energy muon spin rotation - to directly image the phase coexistence and quantitatively determine the phase composition. These data have important implications for the interpretation of data from other experimental probes.

This thesis addresses the evolving field of measurement science, specifically that of mass spectrometry (MS) and ion mobility spectrometry (IMS) based techniques. It focuses on the design, construction and implementation of low-cost, easy-to-manufacture measurement tools that are used in modern settings such as airport security screening. Advances in these technologies often involve minimal performance enhancement at ever-increasing cost, which in turn limits accessibility to versatile measurement tools. This problem is addressed using desktop 3D printers along with widely available materials for the production of novel ion lenses and an IMS instrument with a performance comparable to that of many commercial systems. Bairds findings are a source of inspiration for scientists exploring this emerging field.

Topological Insulators (TIs) are insulators in the bulk, but have exotic metallic states at their surfaces. The topology, associated with the electronic wavefunctions of these systems, changes when passing from the bulk to the surface. This work studies, by means of infrared spectroscopy, the low energy optical conductivity of Bismuth based TIs in order to identify the extrinsic charge contribution of the bulk and to separate it from the intrinsic contribution of the surface state carriers. The extensive results presented in this thesis definitely shows the 2D character of the carriers in Bismuth-based topological insulators. The experimental apparatus and the FTIR technique, the theory of optical properties and Surface Plasmon Polaritons, as well as sample preparation of both crystals and thin films, and the analysis procedures are thoroughly described.

Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications provides a unique source of information in an important area of chemistry. Since Volume 40 the nature and ethos of this series have been altered to reflect a change of emphasis towards 'Techniques, Materials and Applications'. Researchers will now find up-to-date critical reviews which provide in-depth analyses of the leading papers in the field, with authors commenting of the quality and value of the work in a wider context. Focus areas will include structure-function relationships, photochemistry and spectroscopy of inorganic complexes, and catalysis; materials such as ceramics, cements, pigments, glasses and corrosion products; techniques such as advanced laser spectroscopy and theoretical methods.

This book focuses on the widely used experimental techniques available for the structural, morphological, and spectroscopic characterization of materials. Recent developments in a wide range of experimental techniques and their application to the quantification of materials properties are an essential side of this book. Moreover, it provides concise but thorough coverage of the practical and theoretical aspects of the analytical techniques used to characterize a wide variety of functional nanomaterials. The book provides an overview of widely used characterization techniques for a broad audience: from beginners and graduate students, to advanced specialists in both academia and industry.