This book is part of a large and growing body of work on the observation of analogue gravity effects, such as Hawking radiation, in laboratory systems. The book is highly didactic, skillfully navigating between concepts ranging from quantum field theory on curved space-times, nonlinear fibre optics and the theoretical and experimental foundations in the physics of optical analogues to the Event Horizon. It presents a comprehensive field-theoretical framework for these systems, including the kinematics governing the fields. This allows an analytical calculation of the all-important conversion of vacuum fluctuations into Hawking radiation. Based on this, emission spectra are computed, providing unique insights into the emissions from a highly dispersive system. In an experimental part, the book develops a clear and systematic way to experimentally approach the problem and demonstrates the construction of an experimental setup and measurements of unprecedented sensitivity in the search for stimulation of the Hawking effect.

Application of nuclear magnetic resonance span a wide range of scientific disciplines and for the first time this volume will focus on a rapidly advancing and important theme - NMR applications in industry. Providing a comprehensive yet critical review of the current literature from various industrial sectors including materials, food science, paints and coatings, polymer science, nuclear chemistry, drug discovery and process control, this volume will be an invaluable source of current methods and applications. Essential reading for those wanting to become rapidly acquainted with NMR and for the seasoned practitioner keeping up to date with the literature.

This book provides a comprehensive overview of the main nuclear characterization techniques used to study hydrogen absorption and desorption in materials. The various techniques (neutron scattering, nuclear magnetic resonance, ion-beams, positron annihilation spectroscopy) are explained in detail, and a variety of examples of recent research projects are given to show the unique advantage of these techniques to study hydrogen in materials. Most of these nuclear techniques require very specialized instrumentation, and there are only a handful of these instruments available worldwide. Therefore, the aim of this book is to reach out to a readership with a very diverse background in the physical sciences and engineering and a broad range of hydrogen-related research interests. The same technique can be used by researchers interested in the improvement of the performance of hydrogen storage materials and by those focused on hydrogen ingress causing embrittlement of metals. The emphasis of this book is to provide tutorial material on how to use nuclear characterization techniques for the investigation of hydrogen in materials - information that cannot readily be found in conference and regular research papers. Provides a comprehensive overview of nuclear techniques used for hydrogen-related research Explains all nuclear techniques in detail for the non-expert Covers the whole range of hydrogen-related research Features chapters written by world-renowned experts in nuclear technique and hydrogen-related research

This book gives an overview of recent developments in RS and SERS for sensing and biosensing considering also limitations, possibilities and prospects of this technique. Raman scattering (RS) is a widely used vibrational technique providing highly specific molecular spectral patterns. A severe limitation for the application of this spectroscopic technique lies in the low cross section of RS. Surface-enhanced Raman scattering (SERS) spectroscopy overcomes this problem by 6-11 orders of magnitude enhancement compared with the standard RS for molecules in the close vicinity of certain rough metal surfaces. Thus, SERS combines molecular fingerprint specificity with potential single-molecule sensitivity. Due to the recent development of new SERS-active substrates, labeling and derivatization chemistry as well as new instrumentations, SERS became a very promising tool for many varied applications, including bioanalytical studies and sensing. Both intrinsic and extrinsic SERS biosensing schemes have been employed to detect and identify small molecules, nucleic acids and proteins, and also for cellular and in vivo sensing.

This book presents the first experiment revealing several unexplored non-equilibrium properties of quantum many-body states, and addresses the interplay between the Kondo effect and superconductivity by probing shot noise. In addition, it describes in detail nano-fabrication techniques for carbon nanotube quantum dots, and a measurement protocol and principle that probes both equilibrium and non-equilibrium quantum states of electrons. The book offers various reviews of topics in mesoscopic systems: shot noise measurement, carbon nanotube quantum dots, the Kondo effect in quantum dots, and quantum dots with superconducting leads, which are relevant to probing non-equilibrium physics. These reviews offer particularly valuable resources for readers interested in non-equilibrium physics in mesoscopic systems. Further, the cutting-edge experimental results presented will allow reader to catch up on a vital new trend in the field.

Dealing with the basics, theory and applications of dynamic pulsed-field-gradient NMR NMR (PFG NMR), this book describes the essential theory behind diffusion in heterogeneous media that can be combined with NMR measurements to extract important information of the system being investigated. This information could be the surface to volume ratio, droplet size distribution in emulsions, brine profiles, fat content in food stuff, permeability/connectivity in porous materials and medical applications currently being developed. Besides theory and applications it will provide the readers with background knowledge on the experimental set-ups, and most important, deal with the pitfalls that are numerously present in work with PFG-NMR. How to analyze the NMR data and some important basic knowledge on the hardware will be explained, too.

This thesis reports on the use of scanning tunnelling microscopy to elucidate the atomic-scale electronic structure of a charge density wave, revealing that it has a d-symmetry form factor, hitherto unobserved in nature. It then details the development of an entirely new class of scanned probe: the scanning Josephson tunnelling microscope. This scans the Josephson junction formed between a cuprate superconducting microscope tip and the surface of a cuprate sample, thereby imaging the superfluid density of the sample with nanometer resolution. This novel method is used to establish the existence of a spatially modulated superconducting condensate, something postulated theoretically over half a century ago but never previously observed.

This application-oriented book introduces readers to the associations and relationships between contact mechanics and friction, providing them with a deeper understanding of tribology. It addresses the related phenomena of contacts, adhesion, capillary forces, friction, lubrication, and wear from a consistent point of view. The author presents (1) methods for rough estimates of tribological quantities, (2) simple and general methods for analytical calculations, and (3) the crossover into numerical simulation methods, the goal being to convey a consistent view of tribological processes at various scales of magnitude (from nanotribology to earthquake research). The book also explores the system dynamic aspects of tribological systems, such as squeal and its suppression, as well as other types of instabilities and spatial patterns. It includes problems and worked-out solutions for the respective chapters, giving readers ample opportunity to apply the theory to practical situations and to deepen their understanding of the material discussed. The second edition has been extended with a more detailed exposition of elastohydrodynamic lubrication, an updated chapter on numerical simulation methods in contact mechanics, a new section on fretting in the chapter on wear, as well as numerous new exercises and examples, which help to make the book an excellent reference guide.

This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.

This book illustrates the practical workings of environmental transmission electron microscopy (ETEM) from history and instrument design through to solving practical problems. Aspects of instrument design, performance, and operating procedures are covered, together with common problems and pitfalls of the technique. Not only will a properly operated instrument and a carefully set up experiment provide new insight into your specimen, but the ability to observe the specimen in its natural habitat will be essential to meeting specific design criteria for the development of the next generation of materials. Over the past five decades, transmission electron microscopy (TEM) under environmental conditions relevant to a particular sample has been of increasing interest. Symposia dealing with the topic are now among the best attended at international microscopy conferences. Since typical operating modes for the ETEM require the sample be subjected to a harsh environment consisting of corrosive gases and high temperatures, the challenges of adapting and operating the instrument for observation under dynamic operating conditions are numerous. However, careful consideration of the interaction of the electrons with the gases and sample, as well as the gases with the microscope components, can lead to highly rewarding results. In Controlled Atmosphere Transmission Electron Microscopy, leading experts help you to perform successful experiments using the ETEM, and to interpret and understand the results.

This volume describes the application of fluorescence spectroscopy in polymer research. The first chapters outline the basic principles of the conformational and dynamic behavior of polymers and review the problems of polymer self-assembly. Subsequent chapters introduce the theoretical principles of advanced fluorescence methods and typical examples of their application in polymer science. The book closes with several reviews of various fluorescence applications for studying specific aspects of polymer-solution behavior. It is a useful resource for polymer scientists and experts in fluorescence spectroscopy alike, facilitating their communication and cooperation.

Many open questions in Theoretical Physics pertain to strongly interacting quantum systems such as the quark-gluon plasma (QGP) produced in heavy-ion collisions or the strange-metal phase observed in many high-temperature superconductors. These systems are notoriously difficult to study using traditional methods such as perturbation theory, but the gauge/gravity duality offers a successful alternative approach, which maps strongly interacting quantum gauge theories to computationally tractable, classical gravity theories. This book begins with a pedagogical introduction to how the duality can be used to extract transport properties of quantum systems from their gravity dual. It then presents new results on hydrodynamic transport in strongly interacting quantum fluids, providing strong evidence that the Haack-Yarom identity between second-order transport coefficients holds for all fluids with a classical gravity dual and may be a universal feature of all strongly coupled quantum fluids such as the QGP. Newly derived Kubo formulae, expressing transport coefficients in terms of quantum correlators, hold independently of the duality. Lastly, the book discusses new results on magnetic impurities in strongly correlated metals, including the first dual gravity description of an inter-impurity coupling, crucial for the quantum criticality underlying the strange-metal phase.

This book presents the latest developments in noncontact atomic force microscopy. It deals with the following outstanding functions and applications that have been obtained with atomic resolution after the publication of volume 2: (1) Pauli repulsive force imaging of molecular structure, (2) Applications of force spectroscopy and force mapping with atomic resolution, (3) Applications of tuning forks, (4) Applications of atomic/molecular manipulation, (5) Applications of magnetic exchange force microscopy, (6) Applications of atomic and molecular imaging in liquids, (7) Applications of combined AFM/STM with atomic resolution, and (8) New technologies in dynamic force microscopy. These results and technologies are now expanding the capacity of the NC-AFM with imaging functions on an atomic scale toward making them characterization and manipulation tools of individual atoms/molecules and nanostructures, with outstanding capability at the level of molecular, atomic, and subatomic resolution. Since the publication of vol. 2 of the book Noncontact Atomic Force Microscopy in 2009 the noncontact atomic force microscope, which can image even insulators with atomic resolution, has achieved remarkable progress. The NC-AFM is now becoming crucial for nanoscience and nanotechnology.

"Instrumental Thin-Layer Chromatography" delivers comprehensive coverage of this separation tool with particular emphasis on how this tool can be used in advanced laboratories and integrated into problem-solving scenarios. Significant improvements in instrumentation have outpaced the development of information resources that describe the latest state-of-the-art and demonstrate the full capabilities of TLC. This book provides a contemporary picture of the fundamentals and practical applications of TLC at a level suitable for the needs of professional scientists with interests in project management where TLC is a common tool. Compact, highly focused chapters convey essential information that defines modern TLC and how it can be effectively implemented in most areas of laboratory science. Numerous figures and tables provide access to material not normally found in a single source yet are required by working scientists.
Contributions written by recognized authoritative and visionary expertsFocuses on state-of-the-art instrumental thin-layer chromatography and advanced applications across many areasProvides guidance on the analysis of complex, dirty mixtures of compoundsOffers a cost-effective analytic technique for laboratories working under strict budgets

This book describes selected problems in contemporary spectroscopy in the context of quantum mechanics and statistical physics. It focuses on elementary radiative processes involving atomic particles (atoms, molecules, ions), which include radiative transitions between discrete atomic states, the photoionization of atoms, photorecombination of electrons and ions, bremsstrahlung, photodissociation of molecules, and photoattachment of electrons to atoms. In addition to these processes, the transport of resonant radiation in atomic gases and propagation of infrared radiation in molecular gases are also considered. The book subsequently addresses applied problems such as optical pumping, cooling of gases via laser resonance radiation, light-induced drift of gas atoms, photoresonant plasma, reflection of radio waves from the ionosphere, and detection of submillimeter radiation using Rydberg atoms. Lastly, topical examples in atmospheric and climate change science are presented, such as lightning channel glowing, emission of the solar photosphere, and the greenhouse phenomenon in the atmospheres of the Earth and Venus. Along with researchers, both graduate and undergraduate students in atomic, molecular and atmospheric physics will find this book a useful and timely guide.

This book explores the mechanism of alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rate, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI and SIMS and topics of IAR-based direct analysis mass spectrometry.

This thesis presents various characteristics of 122-type iron pnictide (FeSC) such as crystal and electronic structure, carrier-doping effect, and impurity-scattering effect, using transport, magnetization, specific heat, single-crystal X-ray diffraction, and optical spectral measurements. Most notably the measurement on the magnetic fluctuation in the material successfully explains already known unusual electronic properties, i.e., superconducting gap symmetry, anisotropy of in-plane resistivity in layered structure, and charge dynamics; and comparing them with those of normal phase, the controversial problems in FeSCs are eventually settled. The thesis provides broad coverage of the physics of FeSCs both in the normal and superconducting phase, and readers therefore benefit from the efficient up-to-date study of FeSCs in this thesis. An additional attraction is the detailed description of the experimental result critical for the controversial problems remaining since the discovery of FeSC in 2008, which helps readers follow up recent developments in superconductor research.

Nuclear Magnetic Resonance (NMR) has proved to be a uniquely powerful and versatile tool for analyzing and characterizing chemicals and materials of all kinds. This book focuses on the latest developments and applications for 'solid-state' NMR, which has found new uses from archaeology to crystallography to biomaterials and pharmaceutical science research. The book provides materials engineers, analytical chemists, and physicists, in and out of laboratories, a survey of the techniques and the essential tools of solid-state NMR, together with a practical guide on applications. In this concise introduction to the growing field of solid-state nuclear magnetic resonance spectroscopy, the reader will find: * Basic NMR concepts for solids, including guidance on the spin-1/2 nuclei concept * Coverage of the quantum mechanics aspects of solid state NMR and an introduction to the concept of quadrupolar nuclei * An understanding relaxation, exchange and quantitation in NMR * An analysis and interpretation of NMR data, with examples from crystallography studies * Appendices covering spin properties of spin-1/2 nuclides as well as NMR simulation procedures

Our understanding of the rheological and seismic properties of the Earth's interior relies on interpreting geophysical observations using mineral physics data. The complexity of natural materials complicates these interpretations, but here the key features of such materials in controlling the attenuation of seismic waves are determined by a set of careful experiments. This thesis clearly explains how dynamic mechanical spectroscopy has been used to determine the visco-elastic properties of igneous and sedimentary rocks containing geological fluids. These experiments highlight, for the first time, the importance of mineral and rock microstructures as controls on geophysical properties of solids, particularly near the melting point. The results have impacts in areas ranging from volcanic processes, through the structure of the deep Earth, to fluid-saturated porous media.

This book highlights the symmetry properties of acoustic fields and describes the gauge invariance approach, which can be used to reveal those properties. Symmetry is the key theoretical framework of metamaterials, as has been demonstrated by the successful fabrication of acoustical metamaterials. The book first provides the necessary theoretical background, which includes the covariant derivative, the vector potential, and invariance in coordinate transformation. This is followed by descriptions of global gauge invariance (isotropy), and of local gauge invariance (anisotropy). Sections on time reversal symmetry, reflection invariance, and invariance of finite amplitude waves round out the coverage.

This book offers a theoretical description of topological matter in terms of effective field theories, and in particular topological field theories, focusing on two main topics: topological superconductors and topological insulators.Even though there is vast literature on these subjects, the book fills an important gap by providing a concise introduction to both topological order and symmetry-protected phases using a modern mathematical language, and developing the theoretical concepts by highlighting the physics and the physical properties of the systems. Further, it discusses in detail the topological interactions for topologically ordered matter, and the response to smooth external fields for symmetry protected matter. The book also covers more specialized topics that cannot be found elsewhere. Specifically, the response of superconductors to geometry, including the newly discovered geo-Meissner effect; and a correction to the usual Meissner effect, only present in the topologically interesting chiral superconductors.

Chemiluminescence (K. Nakashima & K. Imai).

Fluorescent Probes for Evaluation of Local Physical and Structural Parameters (B. Valeur).

Photochemical Fluorometry (J.-J.

Aaron).

Applications of Organized Bile Salt Media for Luminescence Analysis (L. McGown).

Spectral Hole-Burning (K. Holliday & U. Wild).

Near-Infrared Luminescence Spectroscopy (S. Akiyama).

Microspectrofluorometry on Supported Planar Membranes (L. Tamm & E. Kalb).

Clinical Applications of Luminescence Spectroscopy (G. Schenk).

Laser-Excited Molecular Fluorescence in Analytical Sciences (J. Hofstraat, et al.).

Index.

This book examines the electronic structure of earth-abundant and environmentally friendly materials for use as absorber layers within photovoltaic cells. The corroboration between high-quality photoemission measurements and density of states calculations yields valuable insights into why these materials have demonstrated poor device efficiencies in the vast literature cited. The book shows how the materials' underlying electronic structures affect their properties, and how the band positions make them unsuitable for use with established solar cell technologies. After explaining these poor efficiencies, the book offers alternative window layer materials to improve the use of these absorbers. The power of photoemission and interpretation of the data in terms of factors generally overlooked in the literature, such as the materials' oxidation and phase impurity, is demonstrated. Representing a unique reference guide, the book will be of considerable interest and value to members of the photoemission community engaged in solar cell research, and to a wider materials science audience as well.

This book discusses the development of various reliable scanning electrochemical microscopy (SECM) imaging techniques for studying the distribution of biomarkers and nanomaterials in thin and thick animal samples, plant antioxidant (AO) defense systems, as well as human melanoma. The authors demonstrate that SECM could improve the diagnosis and understanding of different melanoma stages on the basis of highly resolved maps of the tyrosinase distribution. Tyrosinase is the key enzyme involved in fruit maturation and is a biomarker for melanoma. As such the book presents various tyrosinase SECM detection strategies developed for the analysis of the spatial distribution of tyrosinase in melanoma and in banana samples. It describes the first imaging of the redox active proteins within the entire mouse heart with an SECM system using a spider probe composed of eight independent microelectrodes. Further, it investigates distributions of injected graphene nanoribbons (GONRs) for drug delivery by Soft-Probe-SECM. Lastly, the book outlines a non-invasive electrochemical strategy for mapping the AO activity of apple peel using Soft-Probe-SECM.

A comprehensive device model considering both spatial distributions of the terahertz field and the field-effect self-mixing factor has been constructed for the first time in the thesis. The author has found that it is the strongly localized terahertz field induced in a small fraction of the gated electron channel that plays an important role in the high responsivity. An AlGaN/GaN-based high-electron-mobility transistor with a 2-micron-sized gate and integrated dipole antennas has been developed and can offer a noise-equivalent power as low as 40 pW/Hz1/2 at 900 GHz. By further reducing the gate length down to 0.2 micron, a noise-equivalent power of 6 pW/Hz1/2 has been achieved. This thesis provides detailed experimental techniques and device simulation for revealing the self-mixing mechanism including a scanning probe technique for evaluating the effectiveness of terahertz antennas. As such, the thesis could be served as a valuable introduction towards further development of high-sensitivity field-effect terahertz detectors for practical applications.