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High Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water (Hardcover, 1st ed. 2018)
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High Resolution Imaging, Spectroscopy and Nuclear Quantum Effects of Interfacial Water (Hardcover, 1st ed. 2018)
Series: Springer Theses
Expected to ship within 10 - 15 working days
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This thesis presents a series of experimental techniques based on
scanning probe microscopy, which make it possible access the degree
of freedom of protons both in real and energy space. These novel
techniques and methods allow direct visualization of the concerted
quantum tunneling of protons within the hydrogen-bonded network and
quantification of the quantum component of a single hydrogen bond
at a water-solid interface for the first time. Furthermore, the
thesis demonstrates that the anharmonic quantum fluctuations of
hydrogen nuclei further weaken the weak hydrogen bonds and
strengthen the strong ones. However, this trend was reversed when
the hydrogen bond coupled to the local environment. These
pioneering findings substantially advance our understanding of the
quantum nature of H bonds at the molecular level.
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