Diffuse interface (D.I.) model for muliphase flows.- Phase separation of viscous ternary liquid mixtures.- Dewetting and decomposing films of simple and complex liquids.- Phase-field models.

Multiphase flows are typically described assuming that the different phases are separated by a sharp interface, with appropriate boundary conditions. This approach breaks down whenever the lengthscale of the phenomenon that is being studied is comparable with the real interface thickness, as it happens, for example, in the coalescence and breakup of bubbles and drops, the wetting and dewetting of solid surfaces and, in general, im micro-devices. The diffuse interface model resolves these problems by assuming that all quantities can vary continuously, so that interfaces have a non-zero thickness, i.e. they are "diffuse." The contributions in this book review the theory and describe some relevant applications of the diffuse interface model for one-component, two-phase fluids and for liquid binary mixtures, to model multiphase flows in confined geometries.

"Interfacial Fluid Mechanics: A Mathematical Modeling Approach" provides an introduction to mathematical models of viscous flow used in rapidly developing fields of microfluidics and microscale heat transfer. The basic physical effects are first introduced in the context of simple configurations and their relative importance in typical microscale applications is discussed. Then, several configurations of importance to microfluidics, most notably thin films/droplets on substrates and confined bubbles, are discussed in detail. Topics from current research on electrokinetic phenomena, liquid flow near structured solid surfaces, evaporation/condensation, and surfactant phenomena are discussed in the later chapters."

Applied Chemical Engineering Thermodynamics provides the undergraduate and graduate student of chemical engineering with the basic knowledge, the methodology and the references he needs to apply it in industrial practice. Thus, in addition to the classical topics of the laws of thermodynamics, pure component and mixture thermodynamic properties as well as phase and chemical equilibria the reader will find: - history of thermodynamics - energy conservation - internmolecular forces and molecular thermodynamics - cubic equations of state - statistical mechanics. A great number of calculated problems with solutions and an appendix with numerous tables of numbers of practical importance are extremely helpful for applied calculations. The computer programs on the included disk help the student to become familiar with the typical methods used in industry for volumetric and vapor-liquid equilibria calculations.

In September 2000, the University of Bayreuth, Germany, hosted the Fourth International Meeting on Thermodi?usion (IMT4). TheIMTconferenceswerebornfromtheideaofbringingtogetherresearchers in the ?eld of thermodi?usion. Under the auspices of the European Group of Research in Thermodi?usion(EGRT)theconferenceseriesstartedin1994with IMT1 in Toulouse and has been continued every other year with IMT2 (Pau, 1996), IMT3 (Mons, 1998), and IMT4 (Bayreuth, 2000). The next conference, IMT5, will be held in 2002 in Lyngby, Denmark. Thermodi?usion, alsocalledthermaldi?usionortheLudwig-Sorete?ect, - scribes the coupling between a temperature gradient and a resulting mass ?ux. Although the e?ect was already discovered in the 19th century by Ludwig and Soret, it has gained growing interest during the last years due to improved - perimentaltechniqueslikestate-of-the-artthermogravitationalcolumns, modern opticalmethods, ?owchannels, andmicrogravityexperiments, tomentiononlya few. We are still far from a detailed microscopic picture, but analytical theories have been improved and the availability of fast computers and e?cient al- rithmsfornonequilibriummoleculardynamicssimulationshasprovidedvaluable input from the theoretical side. TheIMTconferencescoverallaspectsofthermodi?usionfromfundamentals to new applications. Traditionally, the focus has been on the ?uid state, ra- ing from mixtures of simple liquids to more complex systems such as critical mixtures, electrolytes, polymers, colloidal dispersions, or magnetic ?uids. IMT4 tried to widen the scope by including a plenary lecture about thermodi?usion in ionic solids. Scienti?c input comes from diverse disciplines such as physics, chemistry, engineering, and geophysics. Sadly, Leo Kempers passed away while this book was being prepared. Many ofushavelostafriendandrespectedcolleague.Hismanuscripthasbeenbrought into its ?nal state by A. Shapiro, whom we want to thank

This monograph presents an integrated perspective of the wide range of phenomena and processes applicable to the study of transport of species in porous materials. In order to formulate the entire range of porous media and their uses, this book gives the basics of continuum mechanics, thermodynamics, seepage and consolidation and diffusion, including multiscale homogenization methods. The particular structure of the book has been chosen because it is essential to be aware of the true properties of porous materials particularly in terms of nano, micro and macro mechanisms. This book is of pedagogical and practical importance to the fields covered by civil, environmental, nuclear and petroleum engineering and also in chemical physics and geophysics as it relates to radioactive waste disposal, geotechnical engineering, mining and petroleum engineering and chemical engineering.

The high temperatures generated in gases by shock waves give rise to physical and chemical phenomena such as molecular vibrational excitation, dissociation, ionization, chemical reactions and inherently related radiation. In continuum regime, these processes start from the wave front, so that generally the gaseous media behind shock waves may be in a thermodynamic and chemical non-equilibrium state. This book presents the state of knowledge of these phenomena. Thus, the thermodynamic properties of high temperature gases, including the plasma state are described, as well as the kinetics of the various chemical phenomena cited above. Numerous results of measurement and computation of vibrational relaxation times, dissociation and reaction rate constants are given, and various ionization and radiative mechanisms and processes are presented. The coupling between these different phenomena is taken into account as well as their interaction with the flow-field. Particular points such as the case of rarefied flows and the inside of the shock wave itself are also examined. Examples of specific non-equilibrium flows are given, generally corresponding to those encountered during spatial missions or in shock tube experiments.

The analysis of the reliability and availability of power plants is frequently based on simple indexes that do not take into account the criticality of some failures used for availability analysis. This criticality should be evaluated based on concepts of reliability which consider the effect of a component failure on the performance of the entire plant. System reliability analysis tools provide a root-cause analysis leading to the improvement of the plant maintenance plan. Taking in view that the power plant performance can be evaluated not only based on thermodynamic related indexes, such as heat-rate, Thermal Power Plant Performance Analysis focuses on the presentation of reliability-based tools used to define performance of complex systems and introduces the basic concepts of reliability, maintainability and risk analysis aiming at their application as tools for power plant performance improvement, including: * selection of critical equipment and components, * definition of maintenance plans, mainly for auxiliary systems, and * execution of decision analysis based on risk concepts. The comprehensive presentation of each analysis allows future application of the methodology making Thermal Power Plant Performance Analysis a key resource for undergraduate and postgraduate students in mechanical and nuclear engineering.

This is a work in four parts, dealing with the mechanics and thermodynamics of materials with memory, including properties of the dynamical equations which describe their evolution in time under varying loads. The first part is an introduction to Continuum Mechanics with sections dealing with classical Fluid Mechanics and Elasticity, linear and non-linear. The second part is devoted to Continuum Thermodynamics, which is used to derive constitutive equations of materials with memory, including viscoelastic solids, fluids, heat conductors and some examples of non-simple materials. In part three, free energies for materials with linear memory constitutive relations are comprehensively explored. The new concept of a minimal state is also introduced. Formulae derived over the last decade for the minimum and related free energies are discussed in depth. Also, a new single integral free energy which is a functional of the minimal state is analyzed in detail. Finally, free energies for examples of non-simple materials are considered. In the final part, existence, uniqueness and stability results are presented for the integrodifferential equations describing the dynamical evolution of viscoelastic materials. A new approach to these topics, based on the use of minimal states rather than histories, is discussed in detail. There are also chapters on the controllability of thermoelastic systems with memory, the Saint-Venant problem for viscoelastic materials and on the theory of inverse problems.

Overthe nearly 20 years of Kelvin probe force microscopy, an increasing interest in the technique and its applications has developed. This book gives a concise introduction into the method and describes various experimental techniques. Surface potential studies on semiconductor materials, nanostructures and devices are described, as well as application to molecular and organic materials. The current state of surface potential at the atomic scale is also considered. This book presents an excellent introduction for the newcomer to this field, as much as a valuable resource for the expert."

This book, "Heat and Mass Transfer in Porous Media," presents a set of new developments in the field of basic and applied research work on the physical and chemical aspects of heat and mass transfer phenomena in a porous medium domain, as well as related material properties and their measurements. The book contents include both theoretical and experimental developments, providing a self-contained major reference that is appealing to both the scientists and the engineers. At the same time, these topics will encounter of a variety of scientific and engineering disciplines, such as chemical, civil, agricultural, mechanical engineering, etc. The book is divided in several chapters that intend to be a short monograph in which the authors summarize the current state of knowledge for benefit of professionals.

This book provides a profound understanding, which physical processes and mechanisms cause the heat transfer in composite and cellular materials. It shows models for all important classes of composite materials and introduces into the latest advances.

In three parts, the book covers Composite Materials (Part A), Porous and Cellular Materials (Part B) and the appearance of a conjoint solid phase and fluid aggregate (Part C).

Thermal Separation Technology is a key discipline for many industries and lays the engineering foundations for the sustainable and economic production of high-quality materials. This book provides fundamental knowledge on this field and may be used both in university teaching and in industrial research and development. Furthermore, it is intended to support professional engineers in their daily efforts to improve plant efficiency and reliability. Previous German editions of this book have gained widespread recognition. This first English edition will now make its content available to the international community of students and professionals. In the first chapters of the book the fundamentals of thermodynamics, heat and mass transfer, and multiphase flow are addressed. Further chapters examine in depth the different unit operations distillation and absorption, extraction, evaporation and condensation, crystallization, adsorption and chromatography, and drying, while the closing chapter provides valuable guidelines for a conceptual process development.

Nanofins Science and Technology describes the heat transfer effectiveness of polymer coolants and their fundamental interactions with carbon nanotube coatings that act as nanofins. Heat transfer at micro/nano-scales has attracted significant attention in contemporary literature. This has been primarily driven by industrial requirements where significant decrease in the size of electronic devices/chips with concomitant enhancement in the heat flux have caused challenging needs for cooling of these platforms. With quantum effects kicking in, traditional cooling techniques need to be replaced with more effective technologies. A promising technique is to enhance heat transfer by surface texturing using nanoparticle coatings or engineered nanostructures. These nanostructures are termed as nanofins because they augment heat transfer by a combination of surface area enhancement as well as liquid-solid interactions at the molecular scale.

This monograph describes mathematical models that enable prediction of phase compositions for various technological processes, as developed on the base of a complex physico-chemical analysis of reaction. It studies thermodynamics and kinetics of specific stages of complex pyrometallurgical processes involving boron, carbon, sulfur, tungsten, phosphorus, and many more, as well as their exposure to all sorts of factors.

First and foremost, this enables to optimize processes and technologies at the stage of design, while traditional empirical means of development of new technologies are basically incapable of providing an optimal solution. Simulation results of metals and alloys production, welding and coating technologies allow obtaining materials with pre-given composition, structure and properties in a cost-saving and conscious manner. Moreover, a so-called "inverse problem," i.e., selecting source materials which would ensure the required results, cannot be solved by any other means.

This short primer provides a concise and tutorial-style introduction to transport phenomena in Newtonian fluids , in particular the transport of mass, energy and momentum. The reader will find detailed derivations of the transport equations for these phenomena, as well as selected analytical solutions to the transport equations in some simple geometries. After a brief introduction to the basic mathematics used in the text, Chapter 2, which deals with momentum transport, presents a derivation of the Navier-Stokes-Duhem equation describing the basic flow in a Newtonian fluid. Also provided at this stage are the derivations of the Bernoulli equation, the pressure equation and the wave equation for sound waves. The boundary layer, turbulent flow and flow separation are briefly reviewed. Chapter 3, which addresses energy transport caused by thermal conduction and convection, examines a derivation of the heat transport equation. Finally, Chapter 4, which focuses on mass transport caused by diffusion and convection, discusses a derivation of the mass transport equation.

This Brief addresses two issues of interest of turbulent Rayleigh-Benard convection. The first issue is the characterization and understanding of the statistics of the velocity and temperature fluctuations in the system. The second issue is the revelation and understanding of the nature of the scaling behavior of the velocity temperature structure functions. The problem under the Oberbeck-Boussinesq approximation is formulated. The statistical tools, including probability density functions (PDF) and conditional statistics, for studying fluctuations are introduced, and implicit PDF formulae for fluctuations obeying certain statistical symmetries are derived. Applications of these PDF formulae to study the fluctuations in turbulent Rayleigh-Benard convection are then discussed. The phenomenology of the different types of scaling behavior: the Bolgiano-Obhukov scaling behavior when buoyancy effects are significant and the Kolmogorov-Obukhov-Corrsin scaling behavior when they are not, is introduced. A crossover between the two types of scaling behavior is expected to occur at the Bolgiano length scale above which buoyancy is important. The experimental observations are reviewed. In the central region of the convective cell, the Kolmogorov-Obukhov-Corrsin scaling behavior has been observed. On the other hand, the Bolgiano-Obukhov scaling remains elusive only until recently. By studying the dependence of the conditional temperature structure functions on the locally averaged thermal dissipation rate, evidence for the Bolgiano-Obukhov scaling has recently been found near the bottom plate. The different behaviors observed in the two regions could be attributed to the different size of the Bolgiano scale. What physics determines the relative size of the Bolgiano scale remains to be understood. The Brief is concluded by a discussion of these outstanding issues.

This book provides a comprehensive analysis of various solar based hydrogen production systems. The book covers first-law (energy based) and second-law (exergy based) efficiencies and provides a comprehensive understanding of their implications. It will help minimize the widespread misuse of efficiencies among students and researchers in energy field by using an intuitive and unified approach for defining efficiencies. The book gives a clear understanding of the sustainability and environmental impact analysis of the above systems. The book will be particularly useful for a clear understanding of second law (exergy) efficiencies for various systems. It may serve as a reference book to the researchers in energy field. The definitions and concepts developed in the book will be explained through illustrative examples.

Thermomechanics and Infra-Red Imaging represents one of eight volumes of technical papers presented at the Society for Experimental Mechanics Annual Conference on Experimental and Applied Mechanics, held at Uncasville, Connecticut, June 13-16, 2011. The full set of proceedings also includes volumes on Dynamic Behavior of Materials, Mechanics of Biological Systems and Materials, Mechanics of Time-Dependent Materials and Processes in Conventional and Multifunctional Materials, MEMS and Nanotechnology; Optical Measurements, Modeling and, Metrology; Experimental and Applied Mechanics, and Engineering Applications of Residual Stress.

"Flow Boiling in Microgap Channels: Experiment, Visualization and Analysis" presents an up-to-date summary of the details of the confined to unconfined flow boiling transition criteria, flow boiling heat transfer and pressure drop characteristics, instability characteristics, two phase flow pattern and flow regime map and the parametric study of microgap dimension. Advantages of flow boiling in microgaps over microchannels are also highlighted. The objective of this Brief is to obtain a better fundamental understanding of the flow boiling processes, compare the performance between microgap and conventional microchannel heat sinks, and evaluate the microgap heat sink for instabilities and hotspot mitigation.

If a Writer would know how to behave himself with relation to Posterity; let him consider in old Books, what he finds, that he is glad to know; and what Omissions he most laments. Jonathan Swift This book emerges from a long story of teaching. I taught chemical engineering thermodynamics for about ten years at the University of Naples in the 1960s, and I still remember the awkwardness that I felt about any textbook I chose to consider-all of them seemed to be vague at best, and the standard of logical rigor seemed immensely inferior to what I could find in books on such other of the students in my first class subjects as calculus and fluid mechanics. One (who is now Prof. F. Gioia of the University of Naples) once asked me a question which I have used here as Example 4. 2-more than 20 years have gone by, and I am still waiting for a more intelligent question from one of my students. At the time, that question compelled me to answer in a way I didn't like, namely "I'll think about it, and I hope I'll have the answer by the next time we meet. " I didn't have it that soon, though I did manage to have it before the end of the course.

Fundamentals of Combustion Processes is designed as a textbook for an upper-division undergraduate and graduate level combustion course in mechanical engineering. The authors focus on the fundamental theory of combustion and provide a simplified discussion of basic combustion parameters and processes such as thermodynamics, chemical kinetics, ignition, diffusion and pre-mixed flames. The text includes exploration of applications, example exercises, suggested homework problems and videos of laboratory demonstrations

The term transport phenomena is used to describe processes in which mass, momentum, energy and entropy move about in matter. Advances in Transport Phenomena provide state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. The annual review series intends to fill the information gap between regularly published journals and university-level textbooks by providing in-depth review articles over a broader scope than in journals. The authoritative articles, contributed by internationally-leading scientists and practitioners, establish the state of the art, disseminate the latest research discoveries, serve as a central source of reference for fundamentals and applications of transport phenomena, and provide potential textbooks to senior undergraduate and graduate students. This review book provides state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. This new volume of the annual review "Advances in Transport Phenomena" series provides in-depth review articles covering the fields of mass transfer, fluid mechanics, heat transfer and thermodynamics. This review book provides state-of-the-art expositions of major advances by theoretical, numerical and experimental studies from a molecular, microscopic, mesoscopic, macroscopic or megascopic point of view across the spectrum of transport phenomena, from scientific enquiries to practical applications. This new volume of the annual review "Advances in Transport Phenomena" series provides in-depth review articles covering the fields of mass transfer, fluid mechanics, heat transfer and thermodynamics.

This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.

The Sixth International Cryogenic Materials Conference (ICMC) was held on the campus of Massachusetts Institute of Technology in Cambridge in col laboration with the Cryogenic Engineering Conference (CEC) on August 12-16, 1985. The complementary program and the interdependence of these two dis ciplines foster the conference. Its manifest purpose is sharing the latest advances in low temperature materials science and technology. Equally im portant, areas of needed research are identified, prioriti-es for new research are set, and an increased appreciation of interdisciplinary, interlaboratory, and international cooperation ensues. The success of the conference is the result of the. able leadership and hard work of many people: S. Foner of M.I.T. coordinated ICMC efforts as its Conference Chairman. A. I. Braginski of Westinghouse R&D Center planned the program with the assistance of Cochairmen E. N. C. Dalder of Lawrence Livermore National Laboratory, T. P. Orlando of M.I.T., D. O. Welch of Brookhaven National Laboratory, and numerous other committee members. A. M. Dawson of M.I.T., Chairman of Local Arrangements, and G. M. Fitzgerald, Chairman of Special Events, skillfully managed the joint conference. The contributions of the CEC Board, and particularly its conference chairman, J. L. Smith, Jr. of M.I.T., to the organization of the joint conference are also gratefully acknm.ledged.

A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the thermodynamics developed for interfaces by Gibbs can be applied also away from equilibrium, which is typically the case in reality. A description of phase transitions is of great importance for the understanding of both natural and industrial processes. For example, it is relevant for the understanding of the increase of CO2 concentration in the atmosphere, or improvements of efficiency in distillation columns. This excellent work of luminescent scientific novelty has brought this area a significant step forward. The systematic documentation of the approach will facilitate further applications of the theoretical framework to important problems.