This is the physical chemistry textbook for students with an affinity for computers! It offers basic and advanced knowledge for students in the second year of chemistry masters studies and beyond. In seven chapters, the book presents thermodynamics, chemical kinetics, quantum mechanics and molecular structure (including an introduction to quantum chemical calculations), molecular symmetry and crystals. The application of physical-chemical knowledge and problem solving is demonstrated in a chapter on water, treating both the water molecule as well as water in condensed phases. Instead of a traditional textbook top-down approach, this book presents the subjects on the basis of examples, exploring and running computer programs (Mathematica (R)), discussing the results of molecular orbital calculations (performed using Gaussian) on small molecules and turning to suitable reference works to obtain thermodynamic data. Selected Mathematica (R) codes are explained at the end of each chapter and cross-referenced with the text, enabling students to plot functions, solve equations, fit data, normalize probability functions, manipulate matrices and test physical models. In addition, the book presents clear and step-by-step explanations and provides detailed and complete answers to all exercises. In this way, it creates an active learning environment that can prepare students for pursuing their own research projects further down the road. Students who are not yet familiar with Mathematica (R) or Gaussian will find a valuable introduction to computer-based problem solving in the molecular sciences. Other computer applications can alternatively be used. For every chapter learning goals are clearly listed in the beginning, so that readers can easily spot the highlights, and a glossary in the end of the chapter offers a quick look-up of important terms.

Using an applications perspective "Thermodynamic Models for Industrial Applications" provides a unified framework for the development of various thermodynamic models, ranging from the classical models to some of the most advanced ones. Among these are the Cubic Plus Association Equation of State (CPA EoS) and the Perturbed Chain Statistical Association Fluid Theory (PC-SAFT). These two advanced models are already in widespread use in industry and academia, especially within the oil and gas, chemical and polymer industries.

Presenting both classical models such as the Cubic Equations of State and more advanced models such as the CPA, this book provides the critical starting point for choosing the most appropriate calculation method for accurate process simulations. Written by two of the developers of these models, "Thermodynamic Models for Industrial Applications" emphasizes model selection and model development and includes a useful "which model for which application" guide. It also covers industrial requirements as well as discusses the challenges of thermodynamics in the 21st Century.

Small systems are a very active area of research and development due to improved instrumentation that allows for spatial resolution in the range of sizes from one to 100 nm. In this size range, many physical and chemical properties change, which opens up new approaches to the study of substances and their practical application. This affects both traditional fields of knowledge and many other new fields including physics, chemistry, biology, etc. This book highlights new developments in statistical thermodynamics that answer the most important questions about the specifics of small systems - when one cannot apply equations or traditional thermodynamic models.

Prof. Newman is considered one of the great chemical engineers of his time. His reputation derives from his mastery of all phases of the subject matter, his clarity of thought, and his ability to reduce complex problems to their essential core elements. He has been teaching undergraduate and graduate core subject courses at the University of California, Berkeley (UC Berkeley), USA, since joining the faculty in 1966. His method is to write out, in long form, everything he expects to convey to his class on a subject on any given day. He has maintained and updated his lecture notes from notepad to computer throughout his career. This book is an exact reproduction of those notes. The book presents concepts needed to define single- and multi-component systems, starting with the Gibbs function. It helps readers derive concepts of entropy and temperature and the development of material properties of pure substances. It acquaints them with applications of thermodynamics, such as cycles, open systems, and phase transitions, and eventually leads them to concepts of multiple-component systems, in particular, chemical and phase equilibria. It clearly presents all concepts that are necessary for engineers.

Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.

Airbreathing Propulsion covers the physics of combustion, fluid and thermo-dynamics, and structural mechanics of airbreathing engines, including piston, turboprop, turbojet, turbofan, and ramjet engines. End-of-chapter exercises allow the reader to practice the fundamental concepts behind airbreathing propulsion, and the included PAGIC computer code will help the reader to examine the relationships between the performance parameters of different engines. Large amounts of data have on many different piston, turbojet, and turboprop engines have been compiled for this book and are included as an appendix. This textbook is ideal for senior undergraduate and graduate students studying aeronautical engineering, aerospace engineering, and mechanical engineering.

Designed to cover the fundamental concepts of thermodynamics used in engineering, the book introduces topics such as the laws of thermodynamics, exergy analysis, thermodynamic cycles, measurement theory, and applications. Using step by step examples and numerous illustrations, the book is designed with a "self-teaching" methodology, including a variety of exercises with corresponding answers to enhance mastery of the content. The book provides an engineer with a basic understanding or review of thermodynamic principles. Features Designed to cover the fundamental concepts of thermodynamics used in engineering Introduces topics such as the laws of thermodynamics, exergy analysis, thermodynamic cycles, measurement theory, and applications Includes a variety of exercises such as conceptual questions for review, and numerical exercises(with answers) to enhance mastery of the content

Natural fires can be considered as scale-dependant, non-linear processes of mass, momentum and heat transport, resulting from a turbulent reactive and radiative fluid medium flowing over a complex medium, the vegetal fuel. In natural outdoor conditions, the experimental study of natural fires at real scale needs the development of an original metrology, one able to capture the large range of time and length scales involved in its dynamic nature and also able to resist the thermal, mechanical and chemical aggression of flames on devices. Robust, accurate and poorly intrusive tools must be carefully set-up and used for gaining very fluctuating data over long periods. These signals also need the development of original post-processing tools that take into account the non-steady nature of their stochastic components. Metrology for Fire Experiments in Outdoor Conditions closely analyzes these features, and also describes measurements techniques, the thermal insulation of fragile electronic systems, data acquisition, measurement errors and optimal post-processing algorithms. This book is intended for practitioners as a reference guide for optimizing measurements techniques in an outdoor environment. Advanced-level students and researchers will also find the book invaluable.

Thermodynamic degradation science is a new and exciting discipline. This book merges the science of physics of failure with thermodynamics and shows how degradation modeling is improved and enhanced when using thermodynamic principles. The author also goes beyond the traditional physics of failure methods and highlights the importance of having new tools such as Mesoscopic noise degradation measurements for prognostics of complex systems, and a conjugate work approach to solving physics of failure problems with accelerated testing applications. Key features: Demonstrates how the thermodynamics energy approach uncovers key degradation models and their application to accelerated testing. Demonstrates how thermodynamic degradation models accounts for cumulative stress environments, effect statistical reliability distributions, and are key for reliability test planning. Provides coverage of the four types of Physics of Failure processes describing aging: Thermal Activation Processes, Forced Aging, Diffusion, and complex combinations of these. Coverage of numerous key topics including: aging laws; Cumulative Accelerated Stress Test (CAST) Plans; cumulative entropy fatigue damage; reliability statistics and environmental degradation and pollution. Thermodynamic Degradation Science: Physics of Failure, Accelerated Testing, Fatigue and Reliability Applications is essential reading for reliability, cumulative fatigue, and physics of failure engineers as well as students on courses which include thermodynamic engineering and/or physics of failure coverage.

Modern thermodynamics is a unique but still not a logically self-consistent field of knowledge. It has a proven universal applicability and significance but its actual potential is still latent. The development of the foundations of thermodynamics was in effect non-stop but absolutely no one has any idea about this. This book is the first of its kind that will motivate researchers to build up a logically consistent field of thermodynamics. It greatly appreciates the actual depth and potential of thermodynamics which might also be of interest to readers in history and philosophy of scientific research. The book presents the life stories of the protagonists in detail and allows readers to cast a look at the whole scene of the field by showcasing a significant number of their colleagues whose works have fittingly complemented their achievements. It also tries to trigger a detailed analysis of the reasons why the actual work in this extremely important field has in effect gone astray. It comprises five chapters and introduces three scientists in the first two chapters, which are specifically devoted to the Scandinavian achievements in macroscopic thermodynamics. These introductions are novel and call for a detailed reconsideration of the field. The third chapter acquaints the readers with their fourth colleague in Germany who was working on the proper link between the macroscopic thermodynamics, kinetics, and the atomistic representation of matter. The fourth chapter brings in their fifth colleague in the United States who could formally infer the famous formula S = k * ln(W), ingeniously guessed by Ludwig Boltzmann, and thus clarify the physical sense of the entropy notion. The last chapter summarizes the above-mentioned discourses.

Continuum mechanics deals with the stress, deformation, and mechanical behaviour of matter as a continuum rather than a collection of discrete particles. The subject is interdisciplinary in nature, and has gained increased attention in recent times primarily because of a need to understand a variety of phenomena at different spatial scales. The second edition of Principles of Continuum Mechanics provides a concise yet rigorous treatment of the subject of continuum mechanics and elasticity at the senior undergraduate and first-year graduate levels. It prepares engineer-scientists for advanced courses in traditional as well as emerging fields such as biotechnology, nanotechnology, energy systems, and computational mechanics. The large number of examples and exercise problems contained in the book systematically advance the understanding of vector and tensor analysis, basic kinematics, balance laws, field equations, constitutive equations, and applications. A solutions manual is available for the book.

Textbook concisely introduces engineering thermodynamics, covering concepts including energy, entropy, equilibrium and reversibility * Novel explanation of entropy and the second law of thermodynamics * Presents abstract ideas in an easy to understand manner * Includes solved examples and end of chapter problems * Accompanied by a website hosting a solutions manual

MA1/4ssen Sie sich mit Thermodynamik beschAftigen, fA1/4rchten sich aber davor und wissen nicht genau, wo und wie Sie anfangen sollen? Dann ist dies das richtige Buch fA1/4r Sie. Zuerst werden Stoffeigenschaften der Materie verstAndlich vermittelt. Dann folgen das Energieprinzip, die berA1/4hmten HauptsAtze, das Spezialwissen und die Anwendungen. Anschauliche Beispiele aus der Praxis mit vollstAndigen LAsungen erweitern Ihr VerstAndnis. Die dort vorgestellten LAsungsstrategien sind universal und befAhigen Sie, auch andere Aufgaben zu lAsen. Dieses Buch wird Sie der Thermodynamik nAherbringen und Ihre Sicht auf das Fach positiv verAndern.

This book comprehensively discusses diesel combustion phenomena like ignition delay, fuel-air mixing, rate of heat release, and emissions of smoke, particulate and nitric oxide. It enables quantitative evaluation of these important phenomena and parameters. Most importantly, it attempts to model them with constants that are independent of engine types and hence they could be applied by the engineers and researchers for a general engine. This book emphasizes the importance of the spray at the wall in precisely describing the heat release and emissions for most of the engines on and off-road. It gives models for heat release and emissions. Every model is thoroughly validated by detailed experiments using a broad range of engines. The book describes an elegant quasi-one-dimensional model for heat release in diesel engines with single as well as multiple injections. The book describes how the two aspects, namely, fuel injection rate and the diameter of the combustion bowl in the piston, have enabled meeting advanced emission, noise, and performance standards. The book also discusses the topics of computational fluid dynamics encompassing RANS and LES models of turbulence. Given the contents, this book will be useful for students, researchers and professionals working in the area of vehicle engineering and engine technology. This book will also be a good professional book for practising engineers in the field of combustion engines and automotive engineering.

The current book, Advanced Fluid Mechanics and Heat Transfer is based on author's four decades of industrial and academic research in the area of thermofluid sciences including fluid mechanics, aero-thermodynamics, heat transfer and their applications to engineering systems. Fluid mechanics and heat transfer are inextricably intertwined and both are two integral parts of one physical discipline. No problem from fluid mechanics that requires the calculation of the temperature can be solved using the system of Navier-Stokes and continuity equations only. Conversely, no heat transfer problem can be solved using the energy equation only without using the Navier-Stokes and continuity equations. The fact that there is no book treating this physical discipline as a unified subject in a single book that considers the need of the engineering and physics community, motivated the author to write this book. It is primarily aimed at students of engineering, physics and those practicing professionals who perform aero-thermo-heat transfer design tasks in the industry and would like to deepen their knowledge in this area. The contents of this new book covers the material required in Fluid Mechanics and Heat Transfer Graduate Core Courses in the US universities. It also covers the major parts of the Ph.D-level elective courses Advanced Fluid Mechanics and Heat Transfer that the author has been teaching at Texas A&M University for the past three decades.

Supercritical pressure fluids have been exploited in many engineering fields, where binary mixtures are frequently encountered. This book focuses on the coupled heat and mass transfer in them, where the coupling comes from cross-diffusion effects (i.e., Soret and Dufour effects) and temperature-dependent boundary reactions. Under this configuration, three main topics are discussed: relaxation and diffusion problems, hydrodynamic stability, and convective heat and mass transfer. This book reports a series of new phenomena, novel mechanisms, and an innovative engineering design in hydrodynamics and transport phenomena of binary mixtures at supercritical pressures. This book covers not only current research progress but also basic knowledge and background. It is very friendly to readers new to this field, especially graduate students without a deep theoretical background.

This book presents select proceedings of Conference on Recent Trends in Fluid Dynamics Research (RTFDR-21). It signifies the current research trends in fluid dynamics and convection heat transfer for both laminar and turbulent flow structures. The topics covered include fluid mechanics and applications, microfluidics and nanofluidics, numerical methods for multiphase flows, cavitation, combustion, fluid-particle interactions in turbulence, biological flows, CFD, experimental fluid mechanics, convection heat transfer, numerical heat transfer, fluid power, experimental heat transfer, heat transfer, non-newtonian rheology, and boundary layer theory. The book also discusses various fundamental and application-based research of fluid dynamics, heat transfer, combustion, etc., by theoretical and experimental approaches. The book will be a valuable reference for beginners, researchers, and professionals interested in fluid dynamics research and allied fields.

A step-by-step guide for students (and faculty) on the use of Aspen in teaching thermodynamics Easily-accessible modern computational techniques opening up new vistas in teaching thermodynamics A range of applications of Aspen Plus in the prediction and calculation of thermodynamic properties and phase behavior using the state-of-the art methods Encourages students to develop engineering insight by doing repetitive calculations with changes in parameters and/or models Calculations and application examples in a step-by-step manner designed for out-of-classroom self study Makes it possible to easily integrate Aspen Plus into thermodynamics courses without using in-class time Stresses the application of thermodynamics to real problems

< p=""> This highly informative book offers a comprehensive overview of the fundamentals of propulsion. The book focuses on foundational topics in propulsion, namely gas dynamics, turbomachinery, and combustion to more complex subjects such as practical design aspects of aircraft engines and thermodynamic aspects and analysis. It also includes pedagogical aspects such as end-of-chapter problems and worked examples to augment learning and self-testing. This book is a useful reference for students in the area of mechanical and aerospace engineering. Also, scientists and engineers working in the areas of aerospace propulsion and gas dynamics find this book a valuable addition. ^

This book presents the operational aspects of the rocket engine on a test facility. It will be useful to engineers and scientists who are in touch with the test facility. To aerospace students it shall provide an insight of the job on the test facility. And to interested readers it shall provide an impression of this thrilling area of aerospace.

This open access book introduces and explains machine learning (ML) algorithms and techniques developed for statistical inferences on a complex process or system and their applications to simulations of chemically reacting turbulent flows. These two fields, ML and turbulent combustion, have large body of work and knowledge on their own, and this book brings them together and explain the complexities and challenges involved in applying ML techniques to simulate and study reacting flows. This is important as to the world's total primary energy supply (TPES), since more than 90% of this supply is through combustion technologies and the non-negligible effects of combustion on environment. Although alternative technologies based on renewable energies are coming up, their shares for the TPES is are less than 5% currently and one needs a complete paradigm shift to replace combustion sources. Whether this is practical or not is entirely a different question, and an answer to this question depends on the respondent. However, a pragmatic analysis suggests that the combustion share to TPES is likely to be more than 70% even by 2070. Hence, it will be prudent to take advantage of ML techniques to improve combustion sciences and technologies so that efficient and "greener" combustion systems that are friendlier to the environment can be designed. The book covers the current state of the art in these two topics and outlines the challenges involved, merits and drawbacks of using ML for turbulent combustion simulations including avenues which can be explored to overcome the challenges. The required mathematical equations and backgrounds are discussed with ample references for readers to find further detail if they wish. This book is unique since there is not any book with similar coverage of topics, ranging from big data analysis and machine learning algorithm to their applications for combustion science and system design for energy generation.

This book provides state-of-the-art advances in several areas of importance in energy, combustion, power, propulsion, environment using fossil fuels and alternative fuels, and biofuels production and utilization. Availability of clean and sustainable energy is of greater importance now than ever before in all sectors of energy, power, mobility and propulsion. Written by internationally renowned experts, the latest fundamental and applied research innovations on cleaner energy production as well as utilization for a wide range of devices extending from micro scale energy conversion to hypersonic propulsion using hydrocarbon fuels are provided. The tailored technical tracks and contributions from the world renowned technical experts are portrayed in the respective field to highlight different but complementary views on fuels, combustion, power and propulsion and air toxins with special focus on current and future R&D needs and activities. The energy and environment sustainability require a multi-pronged approach involving development and utilization of new and renewable fuels, design of fuel-flexible combustion systems that can be easily operated with the new fuels, and develop novel and environmentally friendly technologies for improved utilization of all kinds of gas, liquid and solid fuels. This volume is a useful book for practicing engineers, research engineers and managers in industry and research labs, academic institutions, graduate students, and final year undergraduate students in Mechanical, Chemical, Aerospace, Energy and Environmental Engineering.

This textbook provides students studying thermodynamics for the first time with an accessible and readable primer on the subject. The book is written in three parts: Part I covers the fundamentals of thermodynamics, Part II is on gas dynamics, and Part III focuses on combustion. Chapters are written clearly and concisely and include examples and problems to support the concepts outlined in the text. The book begins with a discussion of the fundamentals of thermodynamics and includes a thorough analysis of engineering devices. The book moves on to address applications in gas dynamics and combustion to include advanced topics such as two-phase critical flow and blast theory. Written for use in Introduction to Thermodynamics, Advanced Thermodynamics, and Introduction to Combustion courses, this book uniquely covers thermodynamics, gas dynamics, and combustion in a clear and concise manner, showing the integral connections at an advanced undergraduate or graduate student level.

This book presents a theoretical analysis of the modern methods used for modeling various chemical engineering processes. Currently, the two primary problems in the chemical industry are the optimal design of new devices and the optimal control of active processes. Both of these problems are often solved by developing new methods of modeling. These methods for modeling specific processes may be different, but in all cases, they bring the mathematical description closer to the real processes by using appropriate experimental data. In this book, the authors detail a new approach for the modeling of chemical processes in column apparatuses. Further, they describe the types of neural networks that have been shown to be effective in solving important chemical engineering problems. Readers are also presented with mathematical models of integrated bioethanol supply chains (IBSC) that achieve improved economic and environmental sustainability. The integration of energy and mass processes is one of the most powerful tools for creating sustainable and energy efficient production systems. This book defines the main approaches for the thermal integration of periodic processes, direct and indirect, and the recent integration of small-scale solar thermal dryers with phase change materials as energy accumulators. An exciting overview of new approaches for the modeling of chemical engineering processes, this book serves as a guide for the important innovations being made in theoretical chemical engineering.

This book covers historical aspects and future directions of mechanical and industrial engineering. Chapters of this book include applied mechanics and design, tribology, machining, additive manufacturing and management of industrial technologies.