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Books > Science & Mathematics > Chemistry > General
CALCULATIONS OF ANALYTICAL CHEMISTRY by LEICESTER F. HAMILTON, S.
B. and STEPHEN G. SIMPSON. Originally published in 1922. PREFACE:
The title of this book has been clfanged from Calculations of
Quantitative Chemical Analysis to Calculations of Analytical Chem
istry because the subject matter has been expanded to cover the
stoichiometry of both qualitative and quantitative analysis. In
order to include calculations usually covered in courses in
qualitative analysis, some rearrangements of material have been
made, new sections have been added, and chapters dealing with
equilibrium constants and with the more elementary aspects of
analytical . calculations have been considerably expanded. Al
together, the number of sections has been increased from 78 to 114
and the number of problems from 766 to 1,032. The greater part of
the book is still devoted to the calculations of quantitative
analysis. Short chapters on conductometric and amperometric
titrations and a section on calibration of weights have been added,
and many other changes and additions have been made at various
points in the text. A section reviewing the use of logarithms has
been inserted, and a table of molecular weights covering most of
the problems in the book is included in the Appendix. It is felt
that every phase of general analytical chemistry is adequately
covered by problems, both with and without answers, and that most
of the problems require reasoning on the part of the student and
are not solved by simple substitution in a formula. LEICESTER F.
HAMILTON STEPHEN G. SIMPSON CAMBRIDGE, MASS., February, 1947.
Contents include: PREFACE v PART I. GENERAL ANALYSIS CHAPTER I.
MATHEMATICAL, OPERATIONS 1. Factors Influencingthe Reliability of
Analytical Results 1 2. Deviation Measures as a Means of Expressing
Reliability ... . 2 3. Significant Figures as a Means of Expressing
Reliability 3 4. Rules Governing the Use of Significant Figures in
Chemical Com putations 3 5. Conventions Regarding the Solution of
Numerical Problems .... 6 Problems 1-18 7 6. Rules Governing the
Use of Logarithms .... 9 7. Method of Using Logarithm Tables . . 13
8. Use of the Slide Rule 14 Problems 19-24 15 CHAPTER II. CHEMICAL,
EQUATIONS 9. Purpose of Chemical Equations 16 10. Types of Chemical
Equations 16 11. lonization of Acids, Bases, and Salts 17 12. Ionic
Equations Not Involving Oxidation 18 13. Oxidation Number 20 14.
Ionic Oxidation and Reduction Equations 21 Problems 25-43 24
CHAPTER III. CALCULATIONS BASED ON FORMULAS AND EQUATIONS 15.
Mathematical Significance of a Chemical P ormula . 28 16. Formula
Weights 28 17. Mathematical Significance of a Chemical Equation 29
Problems 44-70 32 CHAPTER IV. CONCENTRATION OF SOLUTIONS 18.
Methods of Expressing Concentration 36 19. Grains per Unit Volume
3f> vii CONTENTS 20. Percentage Composition. . . . . 36 21.
Specific Gravity 36 22. Volume Ratios 37 23. Molar and Formal
Solutions 37 24. Equivalent Weight and Normal Solution 38 25.
Simple Calculations Involving Equivalents, Milliequivalents, and
Normality 39 Problems 71-86 43 CHAPTER V. P] quiLiBRiUM CONSTANTS
26. Law of Mass Action 46 27. Ion Product Constant of Water 47 28.
pll Value 48 Problems 87-94 49 29. lonization Constant 50 30.
Common Ion Effect. Buffered Solution 52 31. lonization of Polybasic
Acids 53 32.
Advancing the experimental study of superfluids relies on
increasingly sophisticated techniques. We develop and demonstrate
the loading of Bose-Einstein condensates (BECs) into nearly
arbitrary trapping potentials, with a resolution improved by a
factor of seven when compared to reported systems. These advanced
control techniques have since been adopted by several cold atoms
labs around the world. How this BEC system was used to study 2D
superfluid dynamics is described. In particular, negative
temperature vortex states in a two-dimensional quantum fluid were
observed. These states were first predicted by Lars Onsager 70
years ago and have significance to 2D turbulence in quantum and
classical fluids, long-range interacting systems, and defect
dynamics in high-energy physics. These experiments have established
dilute-gas BECs as the prototypical system for the experimental
study of point vortices and their nonequilibrium dynamics. We also
developed a new approach to superfluid circuitry based on classical
acoustic circuits, demonstrating its conceptual and quantitative
superiority over previous lumped-element models. This has
established foundational principles of superfluid circuitry that
will impact the design of future transport experiments and new
generation quantum devices, such as atomtronics circuits and
superfluid sensors.
The novel coronavirus 2019 (COVID-19) has caused a serious global
pandemic in just eight months. Nearly every country and territory
in the world has been affected by the virus. The virulence and
infection rate of the virus are profound, and has required extreme
social distancing measures across the globe in order to prevent
overwhelming the healthcare services and hospitals. COVID-19
appears to have the greatest effects on elderly individuals and
those who have co-morbid diseases, such as heart disease, asthma,
and diabetes. As the peak begins to slow in many countries, the
death rates remain high amidst justified fears of a second wave. A
rapid worldwide mobilization has begun to identify effective
treatments and develop vaccines. This new volume will increase
readers' understanding of the ongoing COVID-19 pandemic through a
series of chapters that address these concerns. Leading experts
will discuss the effects of the virus in cases of co-morbidities,
new treatment approaches, mental health aspects of the pandemic,
and convey the results of survey studies. The book will be an
excellent resource for researchers studying virology, metabolic
diseases, respiratory disorders, and clinical scientists,
physicians, drug companies, and healthcare services and workers.
In the post-genome era, questions concerning gene products,
enzymes, and metabolism are returning to the forefront of life
science research. Genetic information on its own does not fully
account for an enzyme's kinetic and regulatory properties or for
the behavior of the enzymes within its particular cellular milieu.
Unanswered questions about the regulation, integration, and
adaptation of metabolism have led to a resurgence of interest in
protein, enzymological, and metabolic research for understanding
biological processes.
Functional Metabolism: Regulation and Adaptation provides a
comprehensive survey of metabolism. It includes an in-depth
examination of the regulation of carbohydrates, lipids, and amino
acids, and approaches to the study of enzyme regulation, signal
transduction, and control of transcription and translation. The
contributors-an internationally recognized group of
researchers-also cover:
- The metabolic basis of diabetes, obesity, and blood
disorders
- Oxidative stress and antioxidant defenses in health and
disease
- Novel perspectives on biochemical adaptation to environmental
stress
- Application of metabolic knowledge to developments in organ
preservation and understanding the origin of life
From the basics of metabolic regulation and adaptation to the
latest relevant advances in the genetic, proteomic, and enzymatic
basis of how cells regulate their functions, Functional Metabolism:
Regulation and Adaptation offers the most exhaustive treatment of
the subject currently available. It is an essential text for
students and practitioners in biochemistry, cell and molecular
biology, and biomedicine.
The continued greening of the energy sector, with inroads being
made through numerous sources of materials that can produce energy,
is the main focus of this, Green Chemical Processing, Volume 8. It
includes contributions from area experts in widely different
fields, all involved in energy production, and makes connections to
the 12 Principles of Green Chemistry.
Remediation of wastewater is important to ensure that pollutants
generated in industry do not effect our environment negatively.
Traditional wastewater remediation is not a sustainable process,
however by using biological means the sustainability can be
improved. This book explores how bioremediation biotechnology is
used to remove pollutants in wastewater. Both conventional methods
bioremediation technologies are discussed.
Were you looking for the book with access to MasteringChemistry?
This product is the book alone and does NOT come with access to
MasteringChemistry. Buy the book and access card package to save
money on this resource. With an expanded focus on critical thinking
and problem solving, the new Seventh Edition of Introductory
Chemistry: Concepts and Critical Thinking prepares students for
success in Introductory Chemistry courses. Unlike other
introductory chemistry texts, all materials -the textbook, student
solutions manual, laboratory manual, instructor's manual and test
item file - are written by the author and tightly integrated to
work together most effectively. Math and problem solving are
covered early in the text; Corwin builds student confidence and
ability through innovative pedagogy and technology formulated to
meet the needs of today's learners. By presenting chemistry in a
clear and interesting way, students to leave their first chemistry
course with a positive impression, a set of new skills, and the
desire to learn more.
Superfluid helium is a quantum liquid that exhibits a range of
counter-intuitive phenomena such as frictionless flow. Quantized
vortices are a particularly important feature of superfluid helium,
and all superfluids, characterized by a circulation that can only
take prescribed integer values. However, the strong interactions
between atoms in superfluid helium prohibit quantitative theory of
vortex behaviour. Experiments have similarly not been able to
observe coherent vortex dynamics. This thesis resolves this
challenge, bringing microphotonic techniques to bear on
two-dimensional superfluid helium, observing coherent vortex
dynamics for the first time, and achieving this on a silicon chip.
This represents a major scientific contribution, as it opens the
door not only to providing a better understanding of this esoteric
quantum state of matter, but also to building new quantum
technologies based upon it, and to understanding the dynamics of
astrophysical superfluids such as those thought to exist in the
core of neutron stars.
This book focuses on the possible interactions that might occur
between carbon materials and molten salts, and discusses the
mechanisms involved in detail, highlighting possible future
developments in the field. Carbon materials can be exposed to
molten salts in various technologically important applications,
such as in molten salt-nuclear reactors and aluminum production
electrolysis cells. As such, numerous studies have investigated the
possible interactions between carbon and molten salts. In addition,
various interesting carbon nanostructures have recently been
produced in molten salts, including carbon nanotubes, graphene and
nanodiamonds with a number of attractive applications. With
abundant images and graphs supporting the discussion, this book
appeals to researchers working in the field of carbon
nanostructures, carbon capture and conversion, nuclear reactors,
energy storage, molten salts and related areas of science and
technology.
Advances in Energy, Environment and Chemical Engineering collects
papers resulting from the conference on Energy, Environment and
Chemical Engineering (AEECE 2022), Dali, China, 24-26 June, 2022.
The primary goal is to promote research and developmental
activities in energy technology, environment engineering and
chemical engineering. Moreover, it aims to promote scientific
information interchange between scholars from the top universities,
business associations, research centers and high-tech enterprises
working all around the world. The conference conducts in-depth
exchanges and discussions on relevant topics such as energy
engineering, environment technology and advanced chemical
technology, aiming to provide an academic and technical
communication platform for scholars and engineers engaged in
scientific research and engineering practice in the field of saving
technologies, environmental chemistry, clean production and so on.
By sharing the research status of scientific research achievements
and cutting-edge technologies, it helps scholars and engineers all
over the world comprehend the academic development trend and
broaden research ideas. So as to strengthen international academic
research, academic topics exchange and discussion, and promote the
industrialization cooperation of academic achievements.
This book reviews the assessment of industrial biotechnology
products and processes from a sustainable perspective. Industrial
Biotechnology is a comparably young field which comes along with
high expectations with regard to sustainability issues. These stem
from the promise of reducing greenhouse gas emissions and replacing
fossil resources in the near or later future and using green
technology, i.e. more environmentally friendly technologies. The
intended economic, ecological and social benefits, however, need to
be proven, resulting in a variety of challenges, both from a
methodological and application point of view. In this book,
specific assessment and application topics of industrial
biotechnology are addressed, highlighting challenges and solutions
for both developers and users of assessment methods. In twelve
chapters, experts in their particular fields define the scope,
characterize industrial biotechnology and show in their
contributions the state of the art, challenges and prospects of
assessing industrial biotechnology products and processes. The
chapter 'Societal and Ethical Aspects of Industrial Biotechnology'
of this book is available open access under a CC BY 4.0 license at
link.springer.com
As a byproduct of historical development, there are different,
unrelated systems of nomenclature for "inorganic chemistry,"
"organic chemistry," "polymer chemistry," "natural products
chemistry," etc. With each new discovery in the laboratory, as well
as each new theoretical proposal for a chemical, the lines that
traditionally have separated these "distinct" subsets of matter
continually grow more blurred. This lack of uniformity in
characterizing and naming chemicals increases the communication
difficulties between differently trained chemists, as well as other
scientists, and greatly impedes progress. With the set of known
chemicals numbering over 42,000,000 (in Chemical Abstracts' data
base) and continually growing (about 2,000 new additions every
day), the desirability for a unified system for naming all
chemicals simultaneously grows. Moreover, in order to meet the
requirements of disparate groups of scientists, and of society in
general, the name assigned to a given chemical should, not only
uniquely describe that substance, but also should be a part of a
readily recognizable order for the entire field. For these
purposes, a topology-based "bi-parametric" system of nomenclature
is herein proposed.
- In this book, a new nomenclature system is proposed
- The new nomenclature is applicable to a three dimensional world,
and is internally consistent
- This nomenclature unifies ALL branches of chemistry, removing the
need for various presently existing sets of rules
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