Back Cover Text: This book addresses the study of the gaseous state of granular matter in the conditions of rapid flow caused by a violent and sustained excitation. In this regime, grains only touch each other during collisions and hence, kinetic theory is a very useful tool to study granular flows. The main difference with respect to ordinary or molecular fluids is that grains are macroscopic and so, their collisions are inelastic. Given the interest in the effects of collisional dissipation on granular media under rapid flow conditions, the emphasis of this book is on an idealized model (smooth inelastic hard spheres) that isolates this effect from other important properties of granular systems. In this simple model, the inelasticity of collisions is only accounted for by a (positive) constant coefficient of normal restitution. The author of this monograph uses a kinetic theory description (which can be considered as a mesoscopic description between statistical mechanics and hydrodynamics) to study granular flows from a microscopic point of view. In particular, the inelastic version of the Boltzmann and Enskog kinetic equations is the starting point of the analysis. Conventional methods such as Chapman-Enskog expansion, Grad's moment method and/or kinetic models are generalized to dissipative systems to get the forms of the transport coefficients and hydrodynamics. The knowledge of granular hydrodynamics opens up the possibility of understanding interesting problems such as the spontaneous formation of density clusters and velocity vortices in freely cooling flows and/or the lack of energy equipartition in granular mixtures. Some of the topics covered in this monograph include: Navier-Stokes transport coefficients for granular gases at moderate densities Long-wavelength instability in freely cooling flows Non-Newtonian transport properties in granular shear flows Energy nonequipartition in freely cooling granular mixtures Diffusion in strongly sheared granular mixtures Exact solutions to the Boltzmann equation for inelastic Maxwell models

The study of fluctuations in statistical physics has a long history, and a general theory is well established, connecting fluctuations to response properties of equilibrium systems. Remarkably, this framework fails as soon as some current is flowing across the system, driving it out of equilibrium. The presence of currents is quite common in nature and produces rich phenomena which are far from being included in a general framework. This thesis focuses on this general problem by studying different models such as granular materials and systems exhibiting anomalous diffusion and shows how the generalized response techniques can be successfully used to catch the relevant degrees of freedom that drive the systems out of equilibrium. This study paves the way to the use of the generalized fluctuation relations in an operative way, in order to extract information from a non-equilibrium system and to build the corresponding phenomenological theory.

This book serves as an introduction to the continuum mechanics and mathematical modeling of complex fluids in living systems. The form and function of living systems are intimately tied to the nature of surrounding fluid environments, which commonly exhibit nonlinear and history dependent responses to forces and displacements. With ever-increasing capabilities in the visualization and manipulation of biological systems, research on the fundamental phenomena, models, measurements, and analysis of complex fluids has taken a number of exciting directions. In this book, many of the world's foremost experts explore key topics such as: Macro- and micro-rheological techniques for measuring the material properties of complex biofluids and the subtleties of data interpretation Experimental observations and rheology of complex biological materials, including mucus, cell membranes, the cytoskeleton, and blood The motility of microorganisms in complex fluids and the dynamics of active suspensions Challenges and solutions in the numerical simulation of biologically relevant complex fluid flows This volume will be accessible to advanced undergraduate and beginning graduate students in engineering, mathematics, biology, and the physical sciences, but will appeal to anyone interested in the intricate and beautiful nature of complex fluids in the context of living systems.

This book presents an overview of fundamental aspects of surface-based biosensors and techniques for enhancing their detection sensitivity and speed. It focuses on rapid detection using miniaturized sensors and describes the physical principles of nanoscale transducers, surface modifications, microfluidics and reaction engineering, diffusion and kinetics. A key challenge in the field of bioanalytical sensors is the rapid delivery of target biomolecules to the sensing surface. While various nanostructures have shown great promise in sensitive detection, diffusion-limited binding of analyte molecules remains a fundamental problem. Recently, many researchers have put forward novel schemes to overcome this challenge, such as nanopore channels, electrokinetics, and dielectrophoresis, to name but a few. This book provides the readers an up-to-date account on these technological advances.

This monograph describes mathematical models that enable prediction of phase compositions for various technological processes, as developed on the base of a complex physico-chemical analysis of reaction. It studies thermodynamics and kinetics of specific stages of complex pyrometallurgical processes involving boron, carbon, sulfur, tungsten, phosphorus, and many more, as well as their exposure to all sorts of factors.

First and foremost, this enables to optimize processes and technologies at the stage of design, while traditional empirical means of development of new technologies are basically incapable of providing an optimal solution. Simulation results of metals and alloys production, welding and coating technologies allow obtaining materials with pre-given composition, structure and properties in a cost-saving and conscious manner. Moreover, a so-called "inverse problem," i.e., selecting source materials which would ensure the required results, cannot be solved by any other means.

This book discusses recent progress in endohedral fullerenes - their production and separation techniques, as well as their characterization and properties. Furthermore, the book delves into the all-important issue of stability by investigating electron transfer between the encapsulated metal species and the carbon cage. It also reviews spin-based phenomena caused by the shielding of endohedral spin by the fullerene, and analyzes formation of the spin states by charge transfer as studied by electron spin resonance. Tuning of charge states of endohedral species and of spin states of both the cage and the cluster are explained. Finally, the book considers the recent discovery of magnetism in some endohedral fullerenes, and the potential for quantum computing.

This is the third Selecta of publications of Elliott Lieb, the first two being Stabil ity of Matter: From Atoms to Stars, edited by Walter Thirring, and Inequalities, edited by Michael Loss and Mary Beth Ruskai. A companion fourth Selecta on Statistical Mechanics is also edited by us. Elliott Lieb has been a pioneer of the discipline of mathematical physics as it is nowadays understood and continues to lead several of its most active directions today. For the first part of this selecta we have made a selection of Lieb's works on Condensed Matter Physics. The impact of Lieb's work in mathematical con densed matter physics is unrivaled. It is fair to say that if one were to name a founding father of the field, Elliott Lieb would be the only candidate to claim this singular position. While in related fields, such as Statistical Mechanics and Atomic Physics, many key problems are readily formulated in unambiguous mathematical form, this is less so in Condensed Matter Physics, where some say that rigor is "probably impossible and certainly unnecessary." By carefully select ing the most important questions and formulating them as well-defined mathemat ical problems, and then solving a good number of them, Lieb has demonstrated the quoted opinion to be erroneous on both counts. What is true, however, is that many of these problems turn out to be very hard. It is not unusual that they take a decade (even several decades) to solve."

Fuel Cells have become a potentially highly efficient sustainable source of energy and electricity for an ever-demanding power hungry world. The two main types of fuel cells ripe for commercialisation are the high temperature solid oxide fuel cell (SOFC) and the low temperature polymer electrolyte membrane fuel cell (PEM). The commercial uses of which include, but are not limited to, military, stand-by power, commercial and industrial, and remoter power. However, all aspects of the electricity market are being considered.

This book has brought together a team of world-renowned experts in all aspects of fuel cell development for both SOFC and PEM in a workshop environment. The workshop held between June 6-10, 2004 was held in the capital city of the Ukraine, Kiev. The reason for the venue was that Ukraine is the third largest resource of zircon sands, a major source of material for the solid oxide fuel cell. Ukraine is looking at undertaking a very large effort in the solid oxide fuel cell arena, and hopes, one day, to be an international player in this market, and this book is an outcome from the workshop. The book focuses on the issues related to fuel cells, particularly the state-of-the-art internationally, the issues that were of particular interest for getting fuel cells fully commercialized, and advances in fuel cell materials and technology. The focus was on all types of fuel cells, but the emphasis was particularly on solid oxide fuel cells (SOFC), due to their importance to the host country. The book is an essential reference to researchers, academics and industrialists interested in up-to-date information on SOFC and PEM development.

-Effects of Electric Fields on Block Copolymer Nanostructures By H. G. Schoberth, V. Olszowka, K. Schmidt, and A. Boeker -Nanopattern Evolution in Block Copolymer Films: Experiment, Simulations and Challenges By L. Tsarkova, G.J. Agur Sevink, and G. Krausch -Controlled Wrinkling as a Novel Method for the Fabrication of Patterned Surfaces By A. Schweikart, A. Horn, A. Boeker, and A. Fery -Layered Systems Under Shear Flow By D. Svensek and H. R. Brand -Thermal Diffusion in Polymer Blends: Criticality and Pattern Formation By W. Koehler, A. Krekhov, and W. Zimmermann -Foaming of Microstructured and Nanostructured Polymer Blends By H. Ruckdaschel, P. Gutmann, V. Altstadt, H. Schmalz, and A.H.E. Muller

The emission of electrons from solid surfaces bombarded by slow neutral and ionized heavy particles (atoms, molecules) is reviewed both theoretically and in the light of recent experimental studies by leading groups in the field. The book integrates physics of ion beams, surfaces and chemical physics, and serves both as a reference work for researchers and a textbook for graduate students.

In conventional metals, various transport coefficients are scaled according to the quasiparticle relaxation time, \tau, which implies that the relaxation time approximation (RTA) holds well. However, such a simple scaling does not hold in many strongly correlated electron systems, reflecting their unique electronic states. The most famous example would be cuprate high-Tc superconductors (HTSCs), where almost all the transport coefficients exhibit a significant deviation from the RTA results. To better understand the origin of this discrepancy, we develop a method for calculating various transport coefficients beyond the RTA by employing field theoretical techniques. Near the magnetic quantum critical point, the current vertex correction (CVC), which describes the electron-electron scattering beyond the relaxation time approximation, gives rise to various anomalous transport phenomena. We explain anomalous transport phenomena in cuprate HTSCs and other metals near their magnetic or orbital quantum critical point using a uniform approach. We also discuss spin related transport phenomena in strongly correlated systems. In many d- and f-electron systems, the spin current induced by the spin Hall effect is considerably greater because of the orbital degrees of freedom. This fact attracts much attention due to its potential application in spintronics. We discuss various novel charge, spin and heat transport phenomena in strongly correlated metals.

With its many beautiful colour pictures, this book gives fascinating insights into the unusual forms and behaviour of matter under extremely high pressures and temperatures. These extreme states are generated, among other things, by strong shock, detonation and electric explosion waves, dense laser beams, electron and ion beams, hypersonic entry of spacecraft into dense atmospheres of planets and in many other situations characterized by extremely high pressures and temperatures. Written by one of the world's foremost experts on the topic, this book will inform and fascinate all scientists dealing with materials properties and physics and also serve as an excellent introduction to plasma-, shock-wave and high-energy-density physics for students and newcomers seeking an overview. This second edition is thoroughly revised and expanded, in particular with new material on high energy-density physics, nuclear explosions and other nuclear transformation processes.

This book gives a theoretical description of linear and nonlinear optical responses of matter with special emphasis on the microscopic and "nonlocal" nature of resonant response. The response field and induced polarization are determined self-consistently in terms of simultaneous linear or nonlinear polynomial equations. This scheme is a general one situated between QED and macroscopic response theory, but is most appropriate for determining the dependence of optical signals on the size, shape, and internal structure of a nanostructure sample. As a highlight of the scheme, the multi-resonant enhancement of the DFWM signal is described together with its experimental verification.

Discovered in 1880, piezoelectric materials play a key role in an innovative market of several billions of dollars. Recent advances in applications derive from new materials and their development, as well as to new market requirements. With the exception of quartz, ferroelectric materials are used for they offer both high efficiency and sufficient versatility to meet adequately the multidimensional requirements for application. Consequently, strong emphasis is placed on tailoring materials and technology, whether one deals with single crystals, ceramics or plastic materials. Tailoring requires a basic understanding of both physical principles and technical possibilities and limitations. This report elucidates these developments by a broad spectrum of examples, comprising ultrasound in medicine and defence industry, frequency control, signal processing by SAW-devices, sensors, actuators, including novel valves for modern motor management. It delivers a mutual fertilization of technology push and market pull that should be of interest not only to materials scientists or engineers but also to managers who dedicate themselves to a sound future-oriented R&D policy.

Focusing on the purely theoretical aspects of strongly correlated electrons, this volume brings together a variety of approaches to models of the Hubbard type – i.e., problems where both localized and delocalized elements are present in low dimensions. The chapters are arranged in three parts. The first part deals with two of the most widely used numerical methods in strongly correlated electrons, the density matrix renormalization group and the quantum Monte Carlo method. The second part covers Lagrangian, Functional Integral, Renormalization Group, Conformal, and Bosonization methods that can be applied to one-dimensional or weakly coupled chains. The third part considers functional derivatives, mean-field, self-consistent methods, slave-bosons, and extensions. Taken together, the contributions to this volume represent a comprehensive overview of current problems and developments.

Transient problems in transport phenomena have a variety of applications, ranging from drug delivery systems in chemotherapy in bioengineering to heat transfer to surfaces in fluidized bed combustion (FBC) boilers in mechanical engineering. However, the attention given to transient problems is disproportionate with its occurrence in the industry. Damped Wave Transport and Relaxation looks at transient problems in heat, mass and momentum transfer: including non-Fourier effects of conduction and relaxation; non-Fick effects of mass diffusion and relaxation; and non-Newtonian effects of viscous momentum transfer and relaxation. The author also reviews applications to current problems of interest and uses worked examples and illustrations to describe the manifestations of using generalized transport equations. This book is intended for graduate students in transport phenomena and is an ideal reference source for industrial engineers.
* Provides a connection with molecular phenomena
* Separate sections are devoted to heat, mass and momentum transfer
* Includes exercises and examples of applications

This invaluable book explores the delicate interplay between geometry and statistical mechanics in materials such as microemulsions, wetting and growth interfaces, bulk lyotropic liquid crystals, chalcogenide glasses and sheet polymers, using tools from the fields of polymer physics, differential geometry, field theory and critical phenomena. Several chapters have been updated relative to the classic 1989 edition. Moreover, there are now three entirely new chapters - on effects of anisotropy and heterogeneity, on fixed connectivity membranes and on triangulated surface models of fluctuating membranes.

Mesoscopic physics deals with effects at submicron and nanoscales where the conventional wisdom of macroscopic averaging is no longer applicable. A wide variety of new devices have recently evolved, all extremely promising for major novel directions in technology, including carbon nanotubes, ballistic quantum dots, hybrid mesoscopic junctions made of different type of normal, superconducting and ferromagnetic materials. This, in turn, demands a profound understanding of fundamental physical phenomena on mesoscopic scales. As a result, the forefront of fundamental research in condensed matter has been moved to the areas where the interplay between electron-electron interactions and quantum interference of phase-coherent electrons scattered by impurities and/or boundaries is the key to such understanding. An understanding of decoherence as well as other effects of the interactions is crucial for developing future electronic, photonic and spintronic devices, including the element base for quantum computation.

This thesis explores the dispersion stability, microstructure and phase transitions involved in the nanoclay system. It describes the recently discovered formation of colloidal gels via two routes: the first is through phase separation and second is by equilibrium gelation and includes the first reported experimental observation of a system with high aspect ratio nanodiscs. The phase behavior of anisotropic nanodiscs of different aspect ratio in their individual and mixed states in aqueous and hydrophobic media is investigated. Distinct phase separation, equilibrium fluid and equilibrium gel phases are observed in nanoclay dispersions with extensive aging. The work then explores solution behavior, gelation kinetics, aging dynamics and temperature-induced ordering in the individual and mixed states of these discotic colloids. Anisotropic ordering dynamics induced by a water-air interface, waiting time and temperature in these dispersions were studied in great detail along with aggregation behavior of nanoplatelets in hydrophobic environment of alcohol solutions.

During the last 20 years interest in high-resolution x-ray diffractometry and reflectivity has grown as a result of the development of the semiconductor industry and the increasing interest in material research of thin layers of magnetic, organic, and other materials. For example, optoelectronics requires a subsequent epitaxy of thin layers of different semiconductor materials. Here, the individuallayer thicknesses are scaled down to a few atomic layers in order to exploit quantum effects. For reasons of electronic and optical confinement, these thin layers are embedded within much thicker cladding layers or stacks of multilayers of slightly different chemical composition. It is evident that the interface quality of those quantum weHs is quite important for the function of devices. Thin metallic layers often show magnetic properties which do not ap pear for thick layers or in bulk material. The investigation of the mutual interaction of magnetic and non-magnetic layers leads to the discovery of colossal magnetoresistance, for example. This property is strongly related to the thickness and interface roughness of covered layers."

Polymers are essential to biology because they can have enough stable degrees of freedom to store the molecular code of heredity and to express the sequences needed to manufacture new molecules. Through these they perform or control virtually every function in life. Although some biopolymers are created and spend their entire career in the relatively large free space inside cells or organelles, many biopolymers must migrate through a narrow passageway to get to their targeted destination. This suggests the questions: How does confining a polymer affect its behavior and function? What does that tell us about the interactions between the monomers that comprise the polymer and the molecules that confine it? Can we design and build devices that mimic the functions of these nanoscale systems? The NATO Advanced Research Workshop brought together for four days in Bikal, Hungary over forty experts in experimental and theoretical biophysics, molecular biology, biophysical chemistry, and biochemistry interested in these questions. Their papers collected in this book provide insight on biological processes involving confinement and form a basis for new biotechnological applications using polymers. In his paper Edmund DiMarzio asks: What is so special about polymers? Why are polymers so prevalent in living things? The chemist says the reason is that a protein made of N amino acids can have any of 20 different kinds at each position along the chain, resulting in 20 N different polymers, and that the complexity of life lies in this variety.

The IFIP World Computer Congress (WCC) is one of the most important conferences in the area of computer science and a number of related Human and Social Science disciplines at the worldwide level and it has a federated structure, which takes into account the rapidly growing and expanding interests in this area. Human-Computer Interaction is now a mature and still dynamically evolving part of this area, which is represented in IFIP by the Technical Committee 13 on HCI. We are convinced that in this edition of WCC, which takes place for the first time in Italy, it will be interesting and useful to have a Symposium on Human- Computer Interaction in order to present and discuss a number of contributions in this field. There has been increasing awareness among designers of interactive systems of the importance of designing for usability, but we are still far from having products that are really usable, and usability can mean different things depending on the application domain. We are all aware that too many users of current technology feel often frustrated because computer systems are not compatible with their abilities and needs with existing work practices. As designers of tomorrow technology, we have the responsibility of creating computer artefacts that would permit better user experience with the various computing devices, so that users may enjoy more satisfying experiences with information and communications technologies.

This work represents one of the first comprehensive attempts to seamlessly integrate two highly active interdisciplinary domains in soft matter science - microfluidics and liquid crystals (LCs). Motivated by the lack of fundamental experiments, Dr. Sengupta initiated systematic investigation of LC flows at micro scales, gaining new insights that are also suggestive of novel applications. By tailoring the surface anchoring of the LC molecules and the channel dimensions, different topological constraints were controllably introduced within the microfluidic devices. These topological constraints were further manipulated using a flow field, paving the way for Topological Microfluidics. Harnessing topology on a microfluidic platform, as described in this thesis, opens up capabilities beyond the conventional viscous-dominated microfluidics, promising potential applications in targeted delivery and sorting systems, self-assembled motifs, and novel metamaterial fabrications.

The rare earth elements form a fascinating group, resembling each other very closely in both physical and chemical properties. The close similarity of the behaviour of the elements led to difficulties in isolation of the elements in a state of high purity. Now that the separation and purification of these elements have been achieved, the chemistry and the industrial applications of the rare earth elements are drawing the attention of many scientists in the world, especially countries which possess vast reserves of rare earth minerals. Some of the applications of mixed rare earths are as metallurgical additives for ferrous and non-ferrous metals, fluid cracking catalysts, lighter flints, polishing compounds in glasses, carbon arc cores for lighting and hydrogen absorbing alloys for rechargeable batteries. Some of the salient applications of high-purity rare earth elements are cathode ray tubes, automotive catalytic converters, permanent magnets in computer technology and sound systems, lasers, phosphors, electric motors, optical fibres, and possible future applications such as in coloured pigments for plastics and paints, new catalysts, refrigeration systems and solid oxide fuel cells.

In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitledHandbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications.

The present title consists of twelve chapters. The first chapter is an introduction covering definition, classification, properties, world reserves, methods of processing from ores, methods of separation both classical and modern, and analytical chemistry of rare earths, including classical and modern methods.

The second chapter deals with quantum chemical considerations, s, p, d and f orbitals, electronic configurations, Pauli's principle, spin-orbit coupling and levels, energy level diagrams, Hund's rules, Racah parameters, oxidation states, HSAB principle, coordination number, lanthanide contraction, interconfiguration fluctuations. This is followed by a chapter dealing with methods of determination of stability constants, stability constants of complexes, thermodynamic consideration, double-double effect, inclined w plot, applications of stability constant data.

The fourth chapter deals with complexes of rare earth elements with a variety of complexing agents, such as monocarboxylic acids, dicarboxylic acids, polycarboxylic acids like citric, nitrilotriacetic, ethylenediamine tetraacetic; beta diketones, ligands with nitrogen donors, macrocyclic ligands, ligands with sulphur donors, phosphines, cyanate, thiocyanate, selenocyanate, perchlorate, decaborates, acyclic and macrocyclic Schiff's bases, carboranes, selenides and tellurides.

Structural chemistry of lanthanide complexes dealing with low coordination numbers, 6-, -7 and -8 coordination, dodecahedra, square antiprisms, hexagonal bipyramids, cubes and other structures, 9-coordination, high coordination numbers and organometallic structures is discussed in the fifth chapter.

Organometallic complexes such as tris, bis and monocylopentadienyl complexes, cyclooctatetraenyl complexes, cyclopentadienyl-cyclooctatetraenyl complexes, indenyl complexes, fluorenyl complexes, complexes with other aromatic _ ligands, callixerene complexes, NMR spectroscopy of organometallic complexes, vibrational spectra, and catalytic applications form the theme of the sixth chapter.

Kinetics and mechanisms complex formation involving rate expressions, rate laws, dissociative and associative pathways, techniques used in probing reaction mechanisms, crystal field effects are discussed in the following chapter.

Crystal field theory, intensities of 4f-4f transitions, Judd-Ofelt theory of electric-dipole transitions, covalency model of hypersensitivity, dynamic coupling mechanism, solution spectra, spectral data for complexes, solvent effects, fluorescence and photochemistry of lanthanide complexes are dealt with in spectroscopy of lanthanide complexes.

Photoelectron spectroscopy of rare earths involving typical spectra, core levels, splitting due to exchange, spin-orbit coupling, binding energies, states arising due to ionization of fn configuration, interconfiguration fluctuation and surface oxidation phenomena are discussed in the next chapter. The following chapter deals with the important topic of lanthanide NMR shift reagents and their applications in elucidating structures. The penultimate topic deals with ecological, physiological and environmental aspects along withsome interesting biological applications.

In the final chapter, applications such as in metallurgy of steels, corrosion inhibition, catalysis, paints, cinema arc carbon and search light electrodes, polishing powders in optics, permanent magnets, ceramic superconductors, lasers, garnet films for magnetic bubble memory applications, nuclear applications, x-ray phosphors for medical radiology, fiber optics, photonics, electronics, magnetic resonance imaging (MRI) high-tech applications and fuel cells are elucidated.

The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.

Leading scientists discuss the most recent physical and experimental results in the physics of Bose-Einstein condensate theory, the theory of nonlinear lattices (including quantum and nonlinear lattices), and nonlinear optics and photonics. Classical and quantum aspects of the dynamics of nonlinear waves are considered. The contributions focus on the Gross-Pitaevskii equation and on the quantum nonlinear Schr dinger equation. Recent experimental results on atomic condensates and hydrogen bonded systems are reviewed. Particular attention is given to nonlinear matter waves in periodic potential.