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Books > Science & Mathematics > Chemistry > Analytical chemistry
This volume offers a careful selection of trend-setting topics in the field. In-depth review articles illustrate current trends in the field. Experienced experts present a comprehensive overview concerning the electrochemical biosensing of glucose for diabetes care from an industrial research and development perspective a survey of bioassay applications for individually addressable electrochemical arrays, focusing on liquid-phase bioanalytical assays a review of recent advances in the development of electronic tongues based on the use of biosensor arrays coupled with advanced chemometric data analysis novel strategies of DNA biosensor development and corresponding applications for studies of DNA damage a survey of recent trends in the electrochemistry of redox proteins, including the increasing diversity of redox proteins used in electrochemical studies, novel immobilization strategies, and biosensor / biofuel cell applications an overview of electrochemical sensing of blood gases with advanced sensor concepts a survey of recent bioelectroanalytical studies with high spatial resolution using scanning electrochemical microscopy with a wide range of applications covering imaging of living cells, studies of metabolic activity, imaging of local enzyme activity, and studies of transport through biolayers This timely collection will be of interest not only for experts in the field, but also to students and their teachers in disciplines that include analytical chemistry, biology, electrochemistry, and various interdisciplinary research areas.
This book is part of a large and growing body of work on the observation of analogue gravity effects, such as Hawking radiation, in laboratory systems. The book is highly didactic, skillfully navigating between concepts ranging from quantum field theory on curved space-times, nonlinear fibre optics and the theoretical and experimental foundations in the physics of optical analogues to the Event Horizon. It presents a comprehensive field-theoretical framework for these systems, including the kinematics governing the fields. This allows an analytical calculation of the all-important conversion of vacuum fluctuations into Hawking radiation. Based on this, emission spectra are computed, providing unique insights into the emissions from a highly dispersive system. In an experimental part, the book develops a clear and systematic way to experimentally approach the problem and demonstrates the construction of an experimental setup and measurements of unprecedented sensitivity in the search for stimulation of the Hawking effect.
Application of nuclear magnetic resonance span a wide range of scientific disciplines and for the first time this volume will focus on a rapidly advancing and important theme - NMR applications in industry. Providing a comprehensive yet critical review of the current literature from various industrial sectors including materials, food science, paints and coatings, polymer science, nuclear chemistry, drug discovery and process control, this volume will be an invaluable source of current methods and applications. Essential reading for those wanting to become rapidly acquainted with NMR and for the seasoned practitioner keeping up to date with the literature.
This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational spectroscopies. The author investigated "individual" NO molecules on Cu surfaces using low-temperature scanning tunneling microscopy (STM). STM not only provides information on the geometric, electronic, and vibrational properties at the single-molecule level; it is also able to manipulate molecules on surfaces to induce chemical reaction. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces and discovered new reaction processes for NO reduction, which provides microscopic insights into the catalytic mechanisms. The author also visualized wave functions of electrons in a valence orbital of NO and demonstrated that the wave functions are modified by the formation of covalent bonding or hydrogen bonding. This is, namely, "the visualization of quantum mechanics in real space," which is certainly worth reading. Furthermore, the book demonstrates that direct observation of valence orbitals helps to elucidate the reactivity of molecules adsorbed onto surfaces. This innovative approach to studying molecular properties will contribute to further development of STM and its related methods.
This book gives an overview of recent developments in RS and SERS for sensing and biosensing considering also limitations, possibilities and prospects of this technique. Raman scattering (RS) is a widely used vibrational technique providing highly specific molecular spectral patterns. A severe limitation for the application of this spectroscopic technique lies in the low cross section of RS. Surface-enhanced Raman scattering (SERS) spectroscopy overcomes this problem by 6-11 orders of magnitude enhancement compared with the standard RS for molecules in the close vicinity of certain rough metal surfaces. Thus, SERS combines molecular fingerprint specificity with potential single-molecule sensitivity. Due to the recent development of new SERS-active substrates, labeling and derivatization chemistry as well as new instrumentations, SERS became a very promising tool for many varied applications, including bioanalytical studies and sensing. Both intrinsic and extrinsic SERS biosensing schemes have been employed to detect and identify small molecules, nucleic acids and proteins, and also for cellular and in vivo sensing.
The work in your hand contains three main chapters, covering the chemistry of the condensed phase in the atmosphere, first, the different forms of atmospheric waters (precipitation, fog and clouds, dew), and secondly dust, now mostly termed particulate matter and, more scientifically, atmospheric aerosol. A third section treats the gases in the atmosphere. An introductory chapter covers the roots of the term atmospheric chemistry in its relations to chemistry in general and biogeochemistry as the chemistry of the climate system. Furthermore, a brief overview of understanding chemical reactions in aqueous and gaseous phase is given. It is my aim to pay respect to all persons who studied the substances in the air, to those who made small, and to them who made giant contributions for the progress in atmospheric science. I'm not a historian who is able to present the past from a true perspective of their time - this also would not be my aim. If possible, however, I try to interpret the past - almost limited to experimental fi ndings in the nineteenth century - through current values, without dismissal of the problems and ideas of earlier scientists. In this way it is possible to draw some ideas on the historical chemical state of the air. Hence, I name this voyage critical. However, nowhere in this book it is my attention to express my criticism to colleagues and scientifi c ancestors. Great scientists too were subject to errors; doing science consists from the permanent loop observation, interpretation, conclusion, and again testing against new observation. If this volume can contribute more than to be "a nice story" on atmospheric chemistry, then hopefully it inspires the reader to more critical reading of scientifi c publications, and, not to forget the older one.
Dealing with the basics, theory and applications of dynamic pulsed-field-gradient NMR NMR (PFG NMR), this book describes the essential theory behind diffusion in heterogeneous media that can be combined with NMR measurements to extract important information of the system being investigated. This information could be the surface to volume ratio, droplet size distribution in emulsions, brine profiles, fat content in food stuff, permeability/connectivity in porous materials and medical applications currently being developed. Besides theory and applications it will provide the readers with background knowledge on the experimental set-ups, and most important, deal with the pitfalls that are numerously present in work with PFG-NMR. How to analyze the NMR data and some important basic knowledge on the hardware will be explained, too.
This book serves as a comprehensive, up-to-date reference about this cutting-edge laser technology and its many new and interesting developments. Various aspects and trends of Raman fiber lasers are described in detail by experts in their fields. Raman fiber lasers have progressed quickly in the past decade, and have emerged as a versatile laser technology for generating high power light sources covering a spectral range from visible to mid-infrared. The technology is already being applied in the fields of telecommunication, astronomy, cold atom physics, laser spectroscopy, environmental sensing, and laser medicine. This book covers various topics relating to Raman fiber laser research, including power scaling, cladding and diode pumping, cascade Raman shifting, single frequency operation and power amplification, mid-infrared laser generation, specialty optical fibers, and random distributed feedback Raman fiber lasers. The book will appeal to scientists, students, and technicians seeking to understand the recent developments and future trends of this promising and multifaceted technology.
Many open questions in Theoretical Physics pertain to strongly interacting quantum systems such as the quark-gluon plasma (QGP) produced in heavy-ion collisions or the strange-metal phase observed in many high-temperature superconductors. These systems are notoriously difficult to study using traditional methods such as perturbation theory, but the gauge/gravity duality offers a successful alternative approach, which maps strongly interacting quantum gauge theories to computationally tractable, classical gravity theories. This book begins with a pedagogical introduction to how the duality can be used to extract transport properties of quantum systems from their gravity dual. It then presents new results on hydrodynamic transport in strongly interacting quantum fluids, providing strong evidence that the Haack-Yarom identity between second-order transport coefficients holds for all fluids with a classical gravity dual and may be a universal feature of all strongly coupled quantum fluids such as the QGP. Newly derived Kubo formulae, expressing transport coefficients in terms of quantum correlators, hold independently of the duality. Lastly, the book discusses new results on magnetic impurities in strongly correlated metals, including the first dual gravity description of an inter-impurity coupling, crucial for the quantum criticality underlying the strange-metal phase.
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.
Natural product chemistry covers a fascinating area of organic chemistry and its study has enriched organic chemistry in a myriad of different ways. In recent years the thrust has been in three major directions: advances in stereoselective synthesis of bioactive natural products, developments in structure elucidation of complex natural products through the applications of multidimensional NMR and mass spectroscopy, and the integration of bioassay procedures with the isolation processes leading to the isolation of active principles from the extracts. The present volume reflects these developments, and the growing emphasis on bioactive natural products, chemical constituents of echinoderms, diterpenoids from Rabdosia and Eremophila sp., structural studies on saponins, marine sesquiterpene quinones and antimicrobial activity of amphibian venoms. The reviews on bioactive metabolites of Phomophis, cardenolide detection by ELISA, xenocoumacins and bioactive dihydroisocoumarins, CD studies of carbohydrate-molybdate complexes, oncogene function inhibitors from microbial secondary metabolites and Gelsemium and Lupin alkaloids present frontier developments in several areas of natural product chemistry. It is hoped that the present volume, which contains articles by eminent authorities in each field, will be received with the same enthusiasm as the previous volumes of this series.
This book illustrates the practical workings of environmental transmission electron microscopy (ETEM) from history and instrument design through to solving practical problems. Aspects of instrument design, performance, and operating procedures are covered, together with common problems and pitfalls of the technique. Not only will a properly operated instrument and a carefully set up experiment provide new insight into your specimen, but the ability to observe the specimen in its natural habitat will be essential to meeting specific design criteria for the development of the next generation of materials. Over the past five decades, transmission electron microscopy (TEM) under environmental conditions relevant to a particular sample has been of increasing interest. Symposia dealing with the topic are now among the best attended at international microscopy conferences. Since typical operating modes for the ETEM require the sample be subjected to a harsh environment consisting of corrosive gases and high temperatures, the challenges of adapting and operating the instrument for observation under dynamic operating conditions are numerous. However, careful consideration of the interaction of the electrons with the gases and sample, as well as the gases with the microscope components, can lead to highly rewarding results. In Controlled Atmosphere Transmission Electron Microscopy, leading experts help you to perform successful experiments using the ETEM, and to interpret and understand the results.
Forensic odontology refers to the science and practice of dentistry which may be applied to help solve litigation in both criminal and civil cases. It is a specialist branch of dentistry that assists the legal system in the handling, analysis and interpretation of dental evidence. Forensic Odontology: Principles and Practice pulls together the very latest research findings and advice on best practice and essential skills, including aspects of forensic science that provide a well-rounded educational experience for the reader. Chapters provide coverage of anatomy and morphology, mortuary techniques, physical anthropology, applied forensic sciences, child and elder abuse, and facial approximation. The text introduces the various topics and discusses underpinning philosophies without being an exhaustive historical treatise. Appropriate case studies are used to highlight issues, and references to current research are provided to stimulate further reading and research. Written by experienced practitioners in the field, this informative introductory text is invaluable to graduate and undergraduate students, as well as experienced dentists, wishing to gain experience or pursue a career in forensic odontology. This text will be a welcome addition to the forensic odontological libraries of all practicing forensic odontologists.
This volume provides a detailed overview of water pollution and control of several selected Chinese reservoirs. It explores sediment contamination as well as algal blooms and their impact on water quality. Several chapters also discuss various methods of quality control, such as mixing-oxygenation combined with microbial remediation technologies. Due to their broad geographical distribution and different nutrition levels, the investigated reservoirs, the Jinpen, Shibianyu, Fenhe, Zhelin and Zhoucun reservoirs, can be regarded as representative for China. This comprehensive work will appeal to researchers, advanced students and reservoir managers.
This book offers a theoretical description of topological matter in terms of effective field theories, and in particular topological field theories, focusing on two main topics: topological superconductors and topological insulators.Even though there is vast literature on these subjects, the book fills an important gap by providing a concise introduction to both topological order and symmetry-protected phases using a modern mathematical language, and developing the theoretical concepts by highlighting the physics and the physical properties of the systems. Further, it discusses in detail the topological interactions for topologically ordered matter, and the response to smooth external fields for symmetry protected matter. The book also covers more specialized topics that cannot be found elsewhere. Specifically, the response of superconductors to geometry, including the newly discovered geo-Meissner effect; and a correction to the usual Meissner effect, only present in the topologically interesting chiral superconductors.
This thesis reports on the use of scanning tunnelling microscopy to elucidate the atomic-scale electronic structure of a charge density wave, revealing that it has a d-symmetry form factor, hitherto unobserved in nature. It then details the development of an entirely new class of scanned probe: the scanning Josephson tunnelling microscope. This scans the Josephson junction formed between a cuprate superconducting microscope tip and the surface of a cuprate sample, thereby imaging the superfluid density of the sample with nanometer resolution. This novel method is used to establish the existence of a spatially modulated superconducting condensate, something postulated theoretically over half a century ago but never previously observed.
This volume describes the application of fluorescence spectroscopy in polymer research. The first chapters outline the basic principles of the conformational and dynamic behavior of polymers and review the problems of polymer self-assembly. Subsequent chapters introduce the theoretical principles of advanced fluorescence methods and typical examples of their application in polymer science. The book closes with several reviews of various fluorescence applications for studying specific aspects of polymer-solution behavior. It is a useful resource for polymer scientists and experts in fluorescence spectroscopy alike, facilitating their communication and cooperation.
This book presents the first experiment revealing several unexplored non-equilibrium properties of quantum many-body states, and addresses the interplay between the Kondo effect and superconductivity by probing shot noise. In addition, it describes in detail nano-fabrication techniques for carbon nanotube quantum dots, and a measurement protocol and principle that probes both equilibrium and non-equilibrium quantum states of electrons. The book offers various reviews of topics in mesoscopic systems: shot noise measurement, carbon nanotube quantum dots, the Kondo effect in quantum dots, and quantum dots with superconducting leads, which are relevant to probing non-equilibrium physics. These reviews offer particularly valuable resources for readers interested in non-equilibrium physics in mesoscopic systems. Further, the cutting-edge experimental results presented will allow reader to catch up on a vital new trend in the field.
This book presents the latest developments in noncontact atomic force microscopy. It deals with the following outstanding functions and applications that have been obtained with atomic resolution after the publication of volume 2: (1) Pauli repulsive force imaging of molecular structure, (2) Applications of force spectroscopy and force mapping with atomic resolution, (3) Applications of tuning forks, (4) Applications of atomic/molecular manipulation, (5) Applications of magnetic exchange force microscopy, (6) Applications of atomic and molecular imaging in liquids, (7) Applications of combined AFM/STM with atomic resolution, and (8) New technologies in dynamic force microscopy. These results and technologies are now expanding the capacity of the NC-AFM with imaging functions on an atomic scale toward making them characterization and manipulation tools of individual atoms/molecules and nanostructures, with outstanding capability at the level of molecular, atomic, and subatomic resolution. Since the publication of vol. 2 of the book Noncontact Atomic Force Microscopy in 2009 the noncontact atomic force microscope, which can image even insulators with atomic resolution, has achieved remarkable progress. The NC-AFM is now becoming crucial for nanoscience and nanotechnology.
This application-oriented book introduces readers to the associations and relationships between contact mechanics and friction, providing them with a deeper understanding of tribology. It addresses the related phenomena of contacts, adhesion, capillary forces, friction, lubrication, and wear from a consistent point of view. The author presents (1) methods for rough estimates of tribological quantities, (2) simple and general methods for analytical calculations, and (3) the crossover into numerical simulation methods, the goal being to convey a consistent view of tribological processes at various scales of magnitude (from nanotribology to earthquake research). The book also explores the system dynamic aspects of tribological systems, such as squeal and its suppression, as well as other types of instabilities and spatial patterns. It includes problems and worked-out solutions for the respective chapters, giving readers ample opportunity to apply the theory to practical situations and to deepen their understanding of the material discussed. The second edition has been extended with a more detailed exposition of elastohydrodynamic lubrication, an updated chapter on numerical simulation methods in contact mechanics, a new section on fretting in the chapter on wear, as well as numerous new exercises and examples, which help to make the book an excellent reference guide.
This book describes selected problems in contemporary spectroscopy in the context of quantum mechanics and statistical physics. It focuses on elementary radiative processes involving atomic particles (atoms, molecules, ions), which include radiative transitions between discrete atomic states, the photoionization of atoms, photorecombination of electrons and ions, bremsstrahlung, photodissociation of molecules, and photoattachment of electrons to atoms. In addition to these processes, the transport of resonant radiation in atomic gases and propagation of infrared radiation in molecular gases are also considered. The book subsequently addresses applied problems such as optical pumping, cooling of gases via laser resonance radiation, light-induced drift of gas atoms, photoresonant plasma, reflection of radio waves from the ionosphere, and detection of submillimeter radiation using Rydberg atoms. Lastly, topical examples in atmospheric and climate change science are presented, such as lightning channel glowing, emission of the solar photosphere, and the greenhouse phenomenon in the atmospheres of the Earth and Venus. Along with researchers, both graduate and undergraduate students in atomic, molecular and atmospheric physics will find this book a useful and timely guide. |
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