This textbook introduces the molecular and quantum chemistry needed to understand the physical properties of molecules and their chemical bonds. It follows the authors' earlier textbook "The Physics of Atoms and Quanta" and presents both experimental and theoretical fundamentals for students in physics and physical and theoretical chemistry. The new edition treats new developments in areas such as high-resolution two-photon spectroscopy, ultrashort pulse spectroscopy, photoelectron spectroscopy, optical investigation of single molecules in condensed phase, electroluminescence, and light-emitting diodes.

This book provides an advanced introduction to extended theories of quantum field theory and algebraic topology, including Hamiltonian quantization associated with some geometrical constraints, symplectic embedding and Hamilton-Jacobi quantization and Becci-Rouet-Stora-Tyutin (BRST) symmetry, as well as de Rham cohomology. It offers a critical overview of the research in this area and unifies the existing literature, employing a consistent notation. Although the results presented apply in principle to all alternative quantization schemes, special emphasis is placed on the BRST quantization for constrained physical systems and its corresponding de Rham cohomology group structure. These were studied by theoretical physicists from the early 1960s and appeared in attempts to quantize rigorously some physical theories such as solitons and other models subject to geometrical constraints. In particular, phenomenological soliton theories such as Skyrmion and chiral bag models have seen a revival following experimental data from the SAMPLE and HAPPEX Collaborations and these are discussed. The book describes how these model predictions were shown to include rigorous treatments of geometrical constraints because these constraints affect the predictions themselves. The application of the BRST symmetry to the de Rham cohomology contributes to a deep understanding of Hilbert space of constrained physical theories. Aimed at graduate-level students in quantum field theory, the book will also serve as a useful reference for those working in the field. An extensive bibliography guides the reader towards the source literature on particular topics.

This book elaborates on the acceleration of charged particles with ultrafast terahertz electromagnetic radiation. It paves the way for new, and improves many aspects of current, accelerator applications. These include providing shorter electron bunches for ultrafast time-resolved pump-probe spectroscopy, enabling complex longitudinal profiles to be imparted onto charged particle bunches and significantly improving the ability to synchronise an accelerator to an external laser. The author has developed new sources of terahertz radiation with attractive properties for accelerator-based applications. These include a radially biased large-area photoconductive antenna (PCA) that provided the largest longitudinally polarised terahertz electric field component ever measured from a PCA. This radially biased PCA was used in conjunction with an energy recovery linear accelerator for electron acceleration experiments at the Daresbury Laboratory. To achieve even higher longitudinally polarised terahertz electric field strengths, and to be able to temporally tune the terahertz radiation, the author investigated generation within non-linear optical crystals. He developed a novel generation scheme employing a matched pair of polarity inverted magnesium-oxide doped stoichiometric lithium niobate crystals, which made it possible to generate longitudinally polarised single-cycle terahertz radiation with an electric field amplitude an order of magnitude larger than existing sources.

The world faces serious difficulties in obtaining the energy that will be needed in coming decades for a growing population, especially given the problem of climate change caused by fossil fuel use. This book presents a view of nuclear energy as an important carbon-free energy option. It discusses the nuclear fuel cycle, the types of reactors used today and proposed for the future, nuclear waste disposal, reactor accidents and reactor safety, nuclear weapon proliferation, and the cost of electric power. To provide background for these discussions, the book begins with chapters on the history of the development and use of nuclear energy, the health effects of ionizing radiation, and the basic physics principles of reactor operation.

The text has been rewritten and substantially expanded for this edition, to reflect changes that have taken place in the eight years since the publication of the first edition and to provide greater coverage of key topics. These include the Yucca Mountain repository plans, designs for next-generation reactors, weapons proliferation and terrorism threats, the potential of alternatives to nuclear energy, and controversies about low-level radiation.

Acclaim for the first edition:

"a ]The book provides a superb background for scientists and those in technical fields. It provides probably all the information that many people, including government policy makers, will ever need...[a] well-written and balanced book. This book is recommended for anyone who wants a broad technical background on nuclear energy."
-American Journal of Physics

This series, established in 1965, is concerned with recent developments in the general area of atomic, molecular, and optical physics. The field is in a state of rapid growth, as new experimental and theoretical techniques are used on many old and new problems. Topics covered also include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics. Articles are written by distinguished experts who are active in their research fields. The articles contain both relevant review material and detailed descriptions of important recent developments.

Relativity plays an important role in atomic nuclei, and, since the early 1970s, there has been increasing interest in, and literature on, the nucleus as a relativistic system. In fact, the relativistic treatment provides a powerful method to describe nuclear structure and reactions. It is thus an ideal time to collect and review the important landmarks in this book. Directed to advanced students and researchers, it explains both the underlying relativistic theory and compares predictions with actual experiments.

This volume contains papers based on the workshop "Energy and Information Transfer in Biological Systems: How Physics Could Enrich Biological Understanding," held in Italy in 2002. The meeting was a forum aimed at evaluating the potential and outlooks of a modern physics approach to understanding and describing biological processes, especially regarding the transition from the microscopic chemical scenario to the macroscopic functional configurations of living matter. In this frame some leading researchers presented and discussed several basic topics, such as the photon interaction with biological systems also from the viewpoint of photon information processes and of possible applications; the influence of electromagnetic fields on the self-organization of biosystems including the nonlinear mechanism for energy transfer and storage; and the influence of the structure of water on the properties of biological matter.

How much knowledge can we gain about a physical system and to what degree can we control it? In quantum optical systems, such as ion traps or neutral atoms in cavities, single particles and their correlations can now be probed in a way that is fundamentally limited only by the laws of quantum mechanics. In contrast, quantum many-body systems pose entirely new challenges due to the enormous number of microscopic parameters and their small length- and short time-scales.
This thesis describes a new approach to probing quantum many-body systems at the level of individual particles: Using high-resolution, single-particle-resolved imaging and manipulation of strongly correlated atoms, single atoms can be detected and manipulated due to the large length and time-scales and the precise control of internal degrees of freedom. Such techniques lay stepping stones for the experimental exploration of new quantum many-body phenomena and applications thereof, such as quantum simulation and quantum information, through the design of systems at the microscopic scale and the measurement of previously inaccessible observables.

Volume II/26 supplements the previous compilations II/l, II/9 and II/17 of the magnetic properties of free radicals which were published in 1965, 1977-1980 and 1986-90. In the form of books and CD ROM it covers the literature from about 1985 to 2001. Due to the still rapid growth of the field and the necessary inclusion of new subjects the volume is divided into subvolumes which will appear in fast succession. Together with the earlier publications volume II/26 offers an up-to-date and comprehensive survey and collection of structures and data on the important chemical intermediates, namely radicals, polyradicals and related species such as carbenes, nitrenes, etc. As before the species have been grouped according to chemical aspects. The contents of the individual subvolumes are indicated on the inside of the front covers. For each group of substances the literature has been compiled and extracted by experts in the fields. A small overlap between the chapters is intentional and allows a maximum of coherence and comprehensiveness of the display. For the reader's convenience an index of substances follows in the last subvolume. Data retrieval is also facilitated by helpful links in the CD ROM version. We wish to thank all the authors for their careful and experienced work and the most agreeable cooperation, the Landolt- Boernstein office, especially Mrs. A.

This series, established in 1965, is concerned with recent developments in the general area of atomic, molecular, and optical physics. The field is in a state of rapid growth, as new experimental and theoretical techniques are used on many old and new problems. Topics covered also include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics. Articles are written by distinguished experts who are active in their research fields. The articles contain both relevant review material and detailed descriptions of important recent developments.

This book provides the first comprehensive description of time crystals which have a repeating structure in time. It introduces the fundamental concepts behind time crystals and explores the many different branches of this new research area. The book starts with the original idea of the time crystallization in quantum systems as introduced by Wilczek and follows the development of the field up to the present day. Both spontaneous formation of crystalline structures in time and concepts of the condensed matter physics in the time domain, ranging from Anderson localization in time to many-body systems with exotic interactions, are described. The prospect of creation of novel objects by means of time engineering is also presented. The book assumes knowledge of quantum mechanics to the graduate level. It serves as a valuable reference with pointers to future research directions for graduate students and senior scientists alike.

Leading scientists discuss the most recent physical and experimental results in the physics of Bose-Einstein condensate theory, the theory of nonlinear lattices (including quantum and nonlinear lattices), and nonlinear optics and photonics. Classical and quantum aspects of the dynamics of nonlinear waves are considered. The contributions focus on the Gross-Pitaevskii equation and on the quantum nonlinear Schr dinger equation. Recent experimental results on atomic condensates and hydrogen bonded systems are reviewed. Particular attention is given to nonlinear matter waves in periodic potential.

Neutron spin echo (NSE) spectroscopy is the highest energy resolution neutron scattering technique available for examining a large area (in time and space) in condensed matter physics. This broad dynamic and spatial range is extensively exploited in the study of a wide range of scientific problems ranging from the dynamics of glasses, polymer melts, complex fluids and microemulsions to the elementary excitations in superfluid 4He and to ferromagnets and spin glasses. This book reviews the current status and future prospects in NSE spectroscopy describing the method, latest instrumentation and also the use of NSE in fundamental, hard- and soft-matter science. It provides first-hand information for researchers working in the fields touched by NSE. In addition, young researchers, PhD students and graduates interested in the method will obtain a comprehensive overview and guidelines to implementing the NSE technique.

Intended for advanced undergraduates and beginning graduates with some basic knowledge of optics and quantum mechanics, this text begins with a review of the relevant results of quantum mechanics, before turning to the electromagnetic interactions involved in slowing and trapping atoms and ions, in both magnetic and optical traps. The concluding chapters discuss a broad range of applications, from atomic clocks and studies of collision processes, to diffraction and interference of atomic beams at optical lattices and Bose-Einstein condensation.

Simulation of materials at the atomistic level is an important tool in studying microscopic structures and processes. The atomic interactions necessary for the simulations are correctly described by Quantum Mechanics, but the size of systems and the length of processes that can be modelled are still limited. The framework of Gaussian Approximation Potentials that is developed in this thesis allows us to generate interatomic potentials automatically, based on quantum mechanical data. The resulting potentials offer several orders of magnitude faster computations, while maintaining quantum mechanical accuracy. The method has already been successfully applied for semiconductors and metals.

In this book the characteristics of synchrotron radiation, including insertion device radiation, are described and derived from first principles. The reader is first introduced to the subject in an intuitive way in order to gain familiarity with the underlying physical processes. A rigorous mathematical derivation of the theory then follows. Since the characteristics of synchrotron radiation are intimately connected with the parameters of the electron beam and its accelerator, a basic introduction to electron beam dynamics and accelerator design is included. The book is aimed at graduate students and scientists working with synchrotron radiation and is designed to serve both as a textbook and as a reference work. It includes numerous exercises, some with solutions.

Soon after she became involved in the didactics of physics, the author of this book realized that the transfer of new discoveries in physics into schools and to undergraduate programs is almost non-existent.

This book covers high-transition temperature (Tc) s-wave superconductivity and the neighboring Mott insulating phase in alkali-doped fullerides. The author presents (1) a unified theoretical description of the phase diagram and (2) a nonempirical calculation of Tc. For these purposes, the author employs an extension of the DFT+DMFT (density-functional theory + dynamical mean-field theory). He constructs a realistic electron-phonon-coupled Hamiltonian with a newly formulated downfolding method. The Hamiltonian is analyzed by means of the extended DMFT. A notable aspect of the approach is that it requires only the crystal structure as a priori knowledge. Remarkably, the nonempirical calculation achieves for the first time a quantitative reproduction of the experimental phase diagram including the superconductivity and the Mott phase. The calculated Tc agrees well with the experimental data, with the difference within 10 K. The book provides details of the computational scheme, which can also be applied to other superconductors and other phonon-related topics. The author clearly describes a superconducting mechanism where the Coulomb and electron -phonon interactions show an unusual cooperation in the superconductivity thanks to the Jahn-Teller nature of the phonons.

This book contains important contributions from top international scientists on the-state-of-the-art of femtochemistry and femtobiology at the beginning of the new millennium. It consists of reviews and papers on ultrafast dynamics in molecular science.The coverage of topics highlights several important features of molecular science from the viewpoint of structure (space domain) and dynamics (time domain). First of all, the book presents the latest developments, such as experimental techniques for understanding ultrafast processes in gas, condensed and complex systems, including biological molecules, surfaces and nanostructures. At the same time it stresses the different ways to control the rates and pathways of reactive events in chemistry and biology. Particular emphasis is given to biological processes as an area where femtodynamics is becoming very useful for resolving the structural dynamics from techniques such as electron diffraction, and X-ray and IR spectroscopy. Finally, the latest developments in quantum control (in both theory and experiment) and the experimental pulse-shaping techniques are described.

This book deals with the acceleration and storage of polarized proton beams in cyclic accelerators. Basic equations of spin motion are reviewed, the invariant spin field is introduced, and an adiabatic invariant of spin motion is derived. These modern concepts contribute to the optimization of high energy accelerators for polarized beams. It also allows the analysis of high order depolarizing resonances. Several numerical methods for computing the invariant spin field are presented and results are displayed in numerous illustrations. The reader will gain a much clearer view of spin dynamics at high energy than has hitherto been available.

Crystal growth and nucleation are treated in the specialized literature in different ways depending on the discipline in question (physics, physical chemistry, chemical engineering) and on the theoretical approaches (atomistic vs continuum approach as regards crystal growth, phase vs chemical concept as regards nucleation). This book relates the different approaches to one another, giving preference to atomistic treatments by the methods of statistical thermodynamics and chemical kinetics. This unified approach also facilitates an understanding of some related phenomena of surface physics, such as adsorption, wetting etc. The book allows research novices and graduate students to get an insight into the physics of the phenomena and to interpret some of the experimental results.

Mesoporous silica has large-scale industrial applications such as catalysis, drug delivery and bio/chemical absorptions. This book is devoted to all aspects and types of this material, focusing synthesis of mesoporous silica with anionic amphiphilic molecules. Characterization, properties, and applications are also discussed, making the book an essential reference for material scientists, chemists, and chemical Engineer.

Not only was E.P. Wigner one of the most active creators of 20th century physics, he was also always interested in expressing his opinion in philosophical, political or sociological matters. This volume of his collected works covers a wide selection of his essays about science and society, about himself and his colleagues. Annotated by J. Mehra, this volume will become an important source of reference for historians of science, and it will be pleasant reading for every physicist interested in forming ideas in modern physics.

This book is an interdisciplinary introduction to optical collapse of laser beams, which is modelled by singular (blow-up) solutions of the nonlinear Schroedinger equation. With great care and detail, it develops the subject including the mathematical and physical background and the history of the subject. It combines rigorous analysis, asymptotic analysis, informal arguments, numerical simulations, physical modelling, and physical experiments. It repeatedly emphasizes the relations between these approaches, and the intuition behind the results. The Nonlinear Schroedinger Equation will be useful to graduate students and researchers in applied mathematics who are interested in singular solutions of partial differential equations, nonlinear optics and nonlinear waves, and to graduate students and researchers in physics and engineering who are interested in nonlinear optics and Bose-Einstein condensates. It can be used for courses on partial differential equations, nonlinear waves, and nonlinear optics. Gadi Fibich is a Professor of Applied Mathematics at Tel Aviv University. "This book provides a clear presentation of the nonlinear Schrodinger equation and its applications from various perspectives (rigorous analysis, informal analysis, and physics). It will be extremely useful for students and researchers who enter this field." Frank Merle, Universite de Cergy-Pontoise and Institut des Hautes Etudes Scientifiques, France

Although introduced30 years ago, the J-matrix method has witnessed a resurgence of interest in the last few years. In fact, the interest never ceased, as some authors have found in this method an effective way of handling the continuous spectrum of scattering operators, in addition to other operators. The motivation behind the introduction of the J-matrix method will be presented in brief. The introduction of fast computing machines enabled theorists to perform cal- lations, although approximate, in a conveniently short period of time. This made it possible to study varied scenarios and models, and the effects that different possible parameters have on the ?nal results of such calculations. The ?rst area of research that bene?ted from this opportunity was the structural calculation of atomic and nuclear systems. The Hamiltonian element of the system was set up as a matrix in a convenient, ?nite, bound-state-like basis. A matrix of larger size resulted in a better con?guration interaction matrix that was subsequently diagonalized. The discrete energy eigenvalues thus obtained approximated the spectrum of the system, while the eigenfunctions approximated the wave function of the resulting discrete state. Structural theorists were delighted because they were able to obtain very accurate values for the lowest energy states of interest.