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Books > Science & Mathematics > Physics > Atomic & molecular physics
Electrostatic forces are essential for the hierarchical structure of matter: electrons are bound to the atomic nucleus by electrostatic forces; atoms carry (partial) charges and ions with opposite charges attract and form (chemical) bonds. Small residual electrostatic forces between molecules allow them to form macroscopic structures such as crystals. Electrostatic interactions explain pseudo-forces used in popular computer programs used to model properties of atoms, molecules, and proteins. By beginning with the basics and then diving deeper into the topic, this book aims to familiarize the reader with electrostatic forces at the atomic and molecular level.
While neutron halos were discovered 30 years ago, this is the first book written on the subject of this exotic form of nuclei that typically contain many more neutrons than stable isotopes of those elements. It provides an introductory description of the halo and outlines the discovery and evidence for its existence. It also discusses different theoretical models of the halo's structure as well as models and techniques in reaction theory that have allowed us to study the halo. This is written at a level accessible to graduate students starting a PhD in nuclear physics. Halo nuclei are an exotic form of atomic nuclei that contain typically many more neutrons than stable isotopes of those elements. To give you a famous example, an atom of the element lithium has three electrons orbiting a nucleus with three protons and, usually, either 3 or 4 neutrons. The difference in the number of neutrons gives us two different isotopes of lithium, Li6 and Li7. But if you keep adding neutrons to the nucleus you will eventually reach Li11, with still 3 protons (that means it's lithium) but with 8 neutrons. This nucleus is so neutron-rich that the last two are very weakly bound to the rest of the nucleus (a Li9 core). What happens is a quantum mechanical effect: the two outer neutrons float around beyond the rest of the nuclear core at a distance that is beyond the range of the force that is holding them to the core. This is utterly counterintuitive. It means the nucleus looks like a core plus extended diffuse cloud of neutron probability: the halo. The author of the book, Jim Al-Khalili, is a theoretician who published some of the key papers on the structure of the halo in the mid and late 90s and was the first to determine its true size. This monograph is based on review articles he has written on the mathematical models used to determine the halo structure and the reactions used to model that structure.
The dynamics of quantum systems exposed to ultrafast (at the femtosecond time-scale) and strong laser radiation has a highly non-linear character, leading to a number of new phenomena, outside the reach of traditional spectroscopy. The current laser technology makes feasible the probing and control of quantum-scale systems with fields that are as strong as the interatomic Coulombic interactions and time resolution that is equal to (or less than) typical atomic evolution times. It is indispensable that any theoretical description of the induced physical processes should rely on the accurate calculation of the atomic structure and a realistic model of the laser radiation as pulsed fields. This book aims to provide an elementary introduction of theoretical and computational methods and by no means is anywhere near to complete. The selection of the topics as well as the particular viewpoint is best suited for early-stage students and researchers; the included material belongs in the mainstream of theoretical approaches albeit using simpler language without sacrificing mathematical accuracy. Therefore, subjects such as the Hilbert vector-state, density-matrix operators, amplitude equations, Liouville equation, coherent laser radiation, free-electron laser, Dyson-chronological operator, subspace projection, perturbation theory, stochastic density-matrix equations, time-dependent SchrAdinger equation, partial-wave analysis, spherical-harmonics expansions, basis and grid wavefunction expansions, ionization, electron kinetic-energy and angular distributions are presented within the context of laser-atom quantum dynamics.
Monte Carlo methods have been very prominent in computer simulation of various systems in physics, chemistry, biology, and materials science. This book focuses on the discussion and path-integral quantum Monte Carlo methods in many-body physics and provides a concise but complete introduction to the Metropolis algorithm and its applications in these two techniques. To explore the schemes in clarity, several quantum many-body systems are analysed and studied in detail. The book includes exercises to help digest the materials covered. It can be used as a tutorial to learn the discussion and path-integral Monte Carlo or a recipe for developing new research in the reader's own area. Two complete Java programs, one for the discussion Monte Carlo of 4^He clusters on a graphite surface and the other for the path-integral Monte Carlo of cold atoms in a potential trap, are ready for download and adoption.
Progress in Optics, Volume 62, an ongoing series, contains more than 300 review articles by distinguished research workers that have become permanent records for many important developments. In this updated volume, users will find valuable updates on topics such as optical testing, the modern aspects of intensity interferometry with classical light, the generation of partially coherent beams, optical models and symmetries, and more. This book's contributions have become standard references in scientific articles, providing the state-of-the-art to researchers and practitioners who work in the field of optics.
NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications.
Advances in Atomic, Molecular, and Optical Physics provides a comprehensive compilation of recent developments in a field that is in a state of rapid growth, as new experimental and theoretical techniques are used on many problems, both old and new. Topics covered include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics, with timely articles written by distinguished experts that contain relevant review material and detailed descriptions of important developments in the field.
Big on Bk: Current Insights into the Function of Large Conductance Voltage- and Ca2+- Activated K+ Channels at the Molecular, Cellular and Systemic Levels, a volume in the International Review of Neurobiology series, is a comprehensive overview of the state-of-the-art research into this area. It reviews current knowledge and understanding, and also provides a starting point for researchers and practitioners entering the field.
The confocal microscope is appropriate for imaging cells or the measurement of industrial artefacts. However, junior researchers and instrument users sometimes misuse imaging concepts and metrological characteristics, such as position resolution in industrial metrology and scale resolution in bio-imaging. And, metrological characteristics or influence factors in 3D measurement such as height assessment error caused by 3D coupling effect are so far not yet identified. In this book, the authors outline their practices by the working experiences on standardization and system design. This book assumes little previous knowledge of optics, but rich experience in engineering of industrial measurements, in particular with profile metrology or areal surface topography will be very helpful to understand the theoretical concerns and value of the technological advances. It should be useful for graduate students or researchers as extended reading material, as well as microscope users alongside their handbook.
This book presents an overview of the physics of radiation
detection and its applications. It covers the origins and
properties of different kinds of ionizing radiation, their
detection and measurement, and the procedures used to protect
people and the environment from their potentially harmful effects.
It details the experimental techniques and instrumentation used in
different detection systems in a very practical way without
sacrificing the physics content. It provides useful formulae and
explains methodologies to solve problems related to radiation
measurements. With abundance of worked-out examples and
end-of-chapter problems, this book enables the reader to understand
the underlying physical principles and their applications. Detailed
discussions on different detection media, such as gases, liquids,
liquefied gases, semiconductors, and scintillators make this book
an excellent source of information for students as well as
professionals working in related fields. Chapters on statistics,
data analysis techniques, software for data analysis, and data
acquisition systems provide the reader with necessary skills to
design and build practical systems and perform data analysis.
Advances in Atomic, Molecular, and Optical Physics provides a comprehensive compilation of recent developments in a field that is in a state of rapid growth, as new experimental and theoretical techniques are used on many problems, both old and new. Topics covered include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics, with timely articles written by distinguished experts that contain relevant review material and detailed descriptions of important developments in the field.
Volume 3 of this three-part series presents more advanced topics and applications of relativistic quantum field theory. The application of quantum chromodynamics to high-energy particle scattering is discussed with concrete examples for how to compute QCD scattering cross sections. Experimental evidence for the existence of quarks and gluons is then presented both within the context of the naive quark model and beyond. Dr Strickland then reviews our current understanding of the weak interaction, the unified electroweak theory, and the Brout-Higgs-Englert mechanism for the generation of gauge boson masses. The last two chapters contain a self-contained introduction to finite temperature quantum field theory with concrete examples focusing on the high-temperature thermodynamics of scalar field theories, QED, and QCD.
Written in the perspective of an experimental chemist, this book puts together some fundamentals from chemistry, solid state physics and quantum chemistry, to help with understanding and predicting the electronic and optical properties of organic semiconductors, both polymers and small molecules. The text is intended to assist graduate students and researchers in the field of organic electronics to use theory to design more efficient materials for organic electronic devices such as organic solar cells, light emitting diodes and field effect transistors. After addressing some basic topics in solid state physics, a comprehensive introduction to molecular orbitals and band theory leads to a description of computational methods based on Hartree-Fock and density functional theory (DFT), for predicting geometry conformations, frontier levels and energy band structures. Topological defects and transport and optical properties are then addressed, and one of the most commonly used transparent conducting polymers, PEDOT:PSS, is described in some detail as a case study.
The present theme concerns the forces of nature, and what investigations of these forces can tell us about the world we see about us. The story of these forces is long and complex, and contains many episodes that are not atypical of the bulk of scientific research, which could have achieved greater acclaim 'if only...'.The intention of this book is to introduce ideas of how the visible world, and those parts of it that we cannot observe, either because they are too small or too large for our scale of perception, can be understood by consideration of only a few fundamental forces. The subject in these pages will be the authority of the commonly termed, laws of physics, which arise from the forces of nature, and the corresponding constants of nature (for example, the speed of light, c, the charge of the electron, e, or the mass of the electron, me).
The first version of quantum theory, developed in the mid 1920's, is what is called nonrelativistic quantum theory; it is based on a form of relativity which, in a previous volume, was called Newton relativity. But quickly after this first development, it was realized that, in order to account for high energy phenomena such as particle creation, it was necessary to develop a quantum theory based on Einstein relativity. This in turn led to the development of relativistic quantum field theory, which is an intrinsically many-body theory. But this is not the only possibility for a relativistic quantum theory. In this book we take the point of view of a particle theory, based on the irreducible representations of the Poincare group, the group that expresses the symmetry of Einstein relativity. There are several ways of formulating such a theory; we develop what is called relativistic point form quantum mechanics, which, unlike quantum field theory, deals with a fixed number of particles in a relativistically invariant way. A central issue in any relativistic quantum theory is how to introduce interactions without spoiling relativistic invariance. We show that interactions can be incorporated in a mass operator, in such a way that relativistic invariance is maintained. Surprisingly for a relativistic theory, such a construction allows for instantaneous interactions; in addition, dynamical particle exchange and particle production can be included in a multichannel formulation of the mass operator. For systems of more than two particles, however, straightforward application of such a construction leads to the undesirable property that clusters of widely separated particles continue to interact with one another, even if the interactions between the individual particles are of short range. A significant part of this volume deals with the solution of this problem. Since relativistic quantum mechanics is not as well-known as relativistic quantum field theory, a chapter is devoted to applications of point form quantum mechanics to nuclear physics; in particular we show how constituent quark models can be used to derive electromagnetic and other properties of hadrons.
"Applications of Quantum and Classical Connections in Modeling Atomic, Molecular and Electrodynamical Systems" is a reference on the new field of relativistic optics, examining topics related to relativistic interactions between very intense laser beams and particles. Based on 30 years of research, this unique book connects the properties of quantum equations to corresponding classical equations used to calculate the energetic values and the symmetry properties of atomic, molecular and electrodynamical systems. In addition, it examines applications for these methods, and for the calculation of properties of high harmonics in interactions between very intense electromagnetic fields and electrons. This resource is the only one of its kind, a valuable tool for
scientists and graduate students interested in the foundations of
quantum mechanics, as well as applied scientists interested in
accurate atomic and molecular models.
All living matter is comprised of cells, small compartments isolated from the environment by a cell membrane and filled with concentrated solutions of various organic and inorganic compounds. Some organisms are single-cell, where all life functions are performed by that cell. Others have groups of cells, or organs, specializing in one particular function. The survival of the entire organism depends on all of its cells and organs fulfilling their roles. While the cells are studied by different sciences, they are seen differently by biologists, chemists, or physicists. Biologists concentrate their attention on cell structure and function. What the cells consists of? Where are its organelles? What function each organelle fulfils? From a chemists' point of view, a cell is a complex chemical reaction chamber where various molecules are synthesized or degraded. The main question is how these, sometimes very complicated chains of reactions are controlled. Finally, from a physics standpoint, some of the fundamental questions are about the physical movement of all these molecules between organelles within the cell, their exchange with the extracellular medium, as well as electrical phenomena resulting from such transport. The aim of this book is to look into the basic physical phenomena occurring in cells. These physical transport processes facilitate chemical reactions in the cell and various electrical effects, and that in turn leads to biological functions necessary for the cell to satisfy its role in the mother organism. Ultimately, the goals of every cell are to stay alive and to fulfill its function as a part of a larger organ or organism. The first volume of this book is an inventory of physical transport processes occurring in cells while this second volume provides a closer look at how complex biological and physiological cell phenomena result from these very basic physical processes.
This thesis explores two distinct applications of laser spectroscopy: the study of nuclear ground state properties, and element selective radioactive ion beam production. It also presents the methods and results of an investigation into isotope shifts in the mercury isotopic chain. These Resonance Ionization Laser Ion Source (RILIS) developments are detailed, together with an RILIS ionization scheme that allowed laser ionized ion beams of chromium, germanium, radium and tellurium to be generated at the Isotope Mass Separator On-Line (ISOLDE) facility. A combination of laser spectroscopy with decay spectroscopy and mass spectrometry unambiguously demonstrated a cessation of the extreme shape staggering first observed in the 1970s and revealed the characteristic kink at the crossing of the N=126 shell closure. A series of RILIS developments were required to facilitate this experiment, including mercury "ionization scheme" development and the coupling of the RILIS with an arc discharge ion source. Laser spectroscopy has since become a powerful tool for nuclear physics and the Resonance Ionization Laser Ion Source (RILIS), of the ISOLDE facility at CERN, is a prime example. Highlighting important advances in this field, the thesis offers a unique and revealing resource.
Our understanding of subatomic particles developed over many years, although a clear picture of the different particles, their interactions and their inter-relationships only emerged in the latter part of the twentieth century. The first ""subatomic particles"" to be investigated were those which exhibit readily observable macroscopic behavior, specifically these are the photon, which we observe as light and the electron, which is manifested as electricity. The true nature of these particles, however, only became clear within the last century or so. The development of the Standard Model provided clarification of the way in which various particles, specifically the hadrons, relate to one another and the way in which their properties are determined by their structure. The final piece, perhaps, of the final model, that is the means by which some particles acquire mass, has just recently been clarified with the observation of the Higgs boson. Since the 1970s it has been known that the measured solar neutrino flux was inconsistent with the flux predicted by solar models. The existence of neutrinos with mass would allow for neutrino flavor oscillations and would provide an explanation for this discrepancy. Only in the past few years, has there been clear experimental evidence that neutrinos have mass. The description of particle structure on the basis of the Standard Model, along with recent discoveries concerning neutrino properties, provides us with a comprehensive picture of the properties of subatomic particles. Part I of the present book provides an overview of the Standard Model of particle physics including an overview of the discovery and properties of the Higgs boson. Part II of the book summarizes the important investigations into the physics of neutrinos and provides an overview of the interpretation of these studies.
On July 4, 2012, physicists at the Large Hadron Collider in Geneva madehistory when they discovered an entirely new type of subatomic particle that many scientists believe is the Higgs boson. For forty years, physicists searched for this capstone to the Standard Model of particle physics--the theory that describes both the most elementary components that are known in matter and the forces through which they interact. This particle points to the Higgs field, which provides the key to understanding why elementary particles have mass. In Higgs Discovery, Lisa Randall explains the science behind this monumental discovery, its exhilarating implications, and the power of empty space. |
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