It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.

This book provides a brief exposition of the principles of beam physics and particle accelerators with an emphasis on numerical examples employing readily available computer tools. However, it avoids detailed derivations, instead inviting the reader to use general high-end languages such as Mathcad and Matlab, as well as specialized particle accelerator codes (e.g. MAD, WinAgile, Elegant, and others) to explore the principles presented. This approach allows readers to readily identify relevant design parameters and their scaling. In addition, the computer input files can serve as templates that can be easily adapted to other related situations. The examples and computer exercises comprise basic lenses and deflectors, fringe fields, lattice and beam functions, synchrotron radiation, beam envelope matching, betatron resonances, and transverse and longitudinal emittance and space charge. The last chapter presents examples of two major types of particle accelerators: radio frequency linear accelerators (RF linacs) and storage rings. Lastly, the appendix gives readers a brief description of the computer tools employed and concise instructions for their installation and use in the most popular computer platforms (Windows, Macintosh and Ubuntu Linux). Hyperlinks to websites containing all relevant files are also included. An essential component of the book is its website (actually part of the author's website at the University of Maryland), which contains the files that reproduce results given in the text as well as additional material such as technical notes and movies.

The effect which now bears his name, was discovered in 1958 by Rudolf Moessbauer at the Technical University of Munich. At first, this appeared to be a phenomenon related to nuclear energy levels that provided some information about excited state lifetimes and quantum properties. However, it soon became apparent that Moessbauer spectroscopy had applications in such diverse fields as general relativity, solid state physics, chemistry, materials science, biology, medical physics, archeology and art. It is the extreme sensitivity of the effect to the atomic environment around the probe atom as well as the ability to apply the technique to some interesting and important elements, most notably iron, that is responsible for the Moessbauer effect's extensive use. The present volume reviews the historical development of the Moessbauer effect, the experimental details, the basic physics of hyperfine interactions and some of the numerous applications of Moessbauer effect spectroscopy.

While neutron halos were discovered 30 years ago, this is the first book written on the subject of this exotic form of nuclei that typically contain many more neutrons than stable isotopes of those elements. It provides an introductory description of the halo and outlines the discovery and evidence for its existence. It also discusses different theoretical models of the halo's structure as well as models and techniques in reaction theory that have allowed us to study the halo. This is written at a level accessible to graduate students starting a PhD in nuclear physics. Halo nuclei are an exotic form of atomic nuclei that contain typically many more neutrons than stable isotopes of those elements. To give you a famous example, an atom of the element lithium has three electrons orbiting a nucleus with three protons and, usually, either 3 or 4 neutrons. The difference in the number of neutrons gives us two different isotopes of lithium, Li6 and Li7. But if you keep adding neutrons to the nucleus you will eventually reach Li11, with still 3 protons (that means it's lithium) but with 8 neutrons. This nucleus is so neutron-rich that the last two are very weakly bound to the rest of the nucleus (a Li9 core). What happens is a quantum mechanical effect: the two outer neutrons float around beyond the rest of the nuclear core at a distance that is beyond the range of the force that is holding them to the core. This is utterly counterintuitive. It means the nucleus looks like a core plus extended diffuse cloud of neutron probability: the halo. The author of the book, Jim Al-Khalili, is a theoretician who published some of the key papers on the structure of the halo in the mid and late 90s and was the first to determine its true size. This monograph is based on review articles he has written on the mathematical models used to determine the halo structure and the reactions used to model that structure.

Electrostatic forces are essential for the hierarchical structure of matter: electrons are bound to the atomic nucleus by electrostatic forces; atoms carry (partial) charges and ions with opposite charges attract and form (chemical) bonds. Small residual electrostatic forces between molecules allow them to form macroscopic structures such as crystals. Electrostatic interactions explain pseudo-forces used in popular computer programs used to model properties of atoms, molecules, and proteins. By beginning with the basics and then diving deeper into the topic, this book aims to familiarize the reader with electrostatic forces at the atomic and molecular level.

Monte Carlo methods have been very prominent in computer simulation of various systems in physics, chemistry, biology, and materials science. This book focuses on the discussion and path-integral quantum Monte Carlo methods in many-body physics and provides a concise but complete introduction to the Metropolis algorithm and its applications in these two techniques. To explore the schemes in clarity, several quantum many-body systems are analysed and studied in detail. The book includes exercises to help digest the materials covered. It can be used as a tutorial to learn the discussion and path-integral Monte Carlo or a recipe for developing new research in the reader's own area. Two complete Java programs, one for the discussion Monte Carlo of 4^He clusters on a graphite surface and the other for the path-integral Monte Carlo of cold atoms in a potential trap, are ready for download and adoption.

Progress in Optics, Volume 62, an ongoing series, contains more than 300 review articles by distinguished research workers that have become permanent records for many important developments. In this updated volume, users will find valuable updates on topics such as optical testing, the modern aspects of intensity interferometry with classical light, the generation of partially coherent beams, optical models and symmetries, and more. This book's contributions have become standard references in scientific articles, providing the state-of-the-art to researchers and practitioners who work in the field of optics.

NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds. Since the previous edition of this book was published, there have been many advancements in the field of paramagnetic NMR spectroscopy. This completely updated and expanded edition contains the latest fundamental theory and methods for mastery of this analytical technique. Users will learn how to interpret the NMR spectra of paramagnetic molecules, improve experimental techniques, and strengthen their understanding of the underlying theory and applications.

The confocal microscope is appropriate for imaging cells or the measurement of industrial artefacts. However, junior researchers and instrument users sometimes misuse imaging concepts and metrological characteristics, such as position resolution in industrial metrology and scale resolution in bio-imaging. And, metrological characteristics or influence factors in 3D measurement such as height assessment error caused by 3D coupling effect are so far not yet identified. In this book, the authors outline their practices by the working experiences on standardization and system design. This book assumes little previous knowledge of optics, but rich experience in engineering of industrial measurements, in particular with profile metrology or areal surface topography will be very helpful to understand the theoretical concerns and value of the technological advances. It should be useful for graduate students or researchers as extended reading material, as well as microscope users alongside their handbook.

Advances in Atomic, Molecular, and Optical Physics provides a comprehensive compilation of recent developments in a field that is in a state of rapid growth, as new experimental and theoretical techniques are used on many problems, both old and new. Topics covered include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics, with timely articles written by distinguished experts that contain relevant review material and detailed descriptions of important developments in the field.

Big on Bk: Current Insights into the Function of Large Conductance Voltage- and Ca2+- Activated K+ Channels at the Molecular, Cellular and Systemic Levels, a volume in the International Review of Neurobiology series, is a comprehensive overview of the state-of-the-art research into this area. It reviews current knowledge and understanding, and also provides a starting point for researchers and practitioners entering the field.

Advances in Atomic, Molecular, and Optical Physics provides a comprehensive compilation of recent developments in a field that is in a state of rapid growth, as new experimental and theoretical techniques are used on many problems, both old and new. Topics covered include related applied areas, such as atmospheric science, astrophysics, surface physics, and laser physics, with timely articles written by distinguished experts that contain relevant review material and detailed descriptions of important developments in the field.

Written in the perspective of an experimental chemist, this book puts together some fundamentals from chemistry, solid state physics and quantum chemistry, to help with understanding and predicting the electronic and optical properties of organic semiconductors, both polymers and small molecules. The text is intended to assist graduate students and researchers in the field of organic electronics to use theory to design more efficient materials for organic electronic devices such as organic solar cells, light emitting diodes and field effect transistors. After addressing some basic topics in solid state physics, a comprehensive introduction to molecular orbitals and band theory leads to a description of computational methods based on Hartree-Fock and density functional theory (DFT), for predicting geometry conformations, frontier levels and energy band structures. Topological defects and transport and optical properties are then addressed, and one of the most commonly used transparent conducting polymers, PEDOT:PSS, is described in some detail as a case study.

Volume 3 of this three-part series presents more advanced topics and applications of relativistic quantum field theory. The application of quantum chromodynamics to high-energy particle scattering is discussed with concrete examples for how to compute QCD scattering cross sections. Experimental evidence for the existence of quarks and gluons is then presented both within the context of the naive quark model and beyond. Dr Strickland then reviews our current understanding of the weak interaction, the unified electroweak theory, and the Brout-Higgs-Englert mechanism for the generation of gauge boson masses. The last two chapters contain a self-contained introduction to finite temperature quantum field theory with concrete examples focusing on the high-temperature thermodynamics of scalar field theories, QED, and QCD.

The first version of quantum theory, developed in the mid 1920's, is what is called nonrelativistic quantum theory; it is based on a form of relativity which, in a previous volume, was called Newton relativity. But quickly after this first development, it was realized that, in order to account for high energy phenomena such as particle creation, it was necessary to develop a quantum theory based on Einstein relativity. This in turn led to the development of relativistic quantum field theory, which is an intrinsically many-body theory. But this is not the only possibility for a relativistic quantum theory. In this book we take the point of view of a particle theory, based on the irreducible representations of the Poincare group, the group that expresses the symmetry of Einstein relativity. There are several ways of formulating such a theory; we develop what is called relativistic point form quantum mechanics, which, unlike quantum field theory, deals with a fixed number of particles in a relativistically invariant way. A central issue in any relativistic quantum theory is how to introduce interactions without spoiling relativistic invariance. We show that interactions can be incorporated in a mass operator, in such a way that relativistic invariance is maintained. Surprisingly for a relativistic theory, such a construction allows for instantaneous interactions; in addition, dynamical particle exchange and particle production can be included in a multichannel formulation of the mass operator. For systems of more than two particles, however, straightforward application of such a construction leads to the undesirable property that clusters of widely separated particles continue to interact with one another, even if the interactions between the individual particles are of short range. A significant part of this volume deals with the solution of this problem. Since relativistic quantum mechanics is not as well-known as relativistic quantum field theory, a chapter is devoted to applications of point form quantum mechanics to nuclear physics; in particular we show how constituent quark models can be used to derive electromagnetic and other properties of hadrons.

The present theme concerns the forces of nature, and what investigations of these forces can tell us about the world we see about us. The story of these forces is long and complex, and contains many episodes that are not atypical of the bulk of scientific research, which could have achieved greater acclaim 'if only...'.The intention of this book is to introduce ideas of how the visible world, and those parts of it that we cannot observe, either because they are too small or too large for our scale of perception, can be understood by consideration of only a few fundamental forces. The subject in these pages will be the authority of the commonly termed, laws of physics, which arise from the forces of nature, and the corresponding constants of nature (for example, the speed of light, c, the charge of the electron, e, or the mass of the electron, me).

"Applications of Quantum and Classical Connections in Modeling Atomic, Molecular and Electrodynamical Systems" is a reference on the new field of relativistic optics, examining topics related to relativistic interactions between very intense laser beams and particles. Based on 30 years of research, this unique book connects the properties of quantum equations to corresponding classical equations used to calculate the energetic values and the symmetry properties of atomic, molecular and electrodynamical systems. In addition, it examines applications for these methods, and for the calculation of properties of high harmonics in interactions between very intense electromagnetic fields and electrons.

This resource is the only one of its kind, a valuable tool for scientists and graduate students interested in the foundations of quantum mechanics, as well as applied scientists interested in accurate atomic and molecular models.
Features detailed explanations of the theories of atomic and molecular systems, as well as wave properties of stationary atomic and molecular systemsProvides periodic solutions of classical equations, semi-classical methods, and theories of systems composed of very intense electromagnetic fields and particles Offers models and methods based on 30 years of research

The progress in nuclear magnetic resonance (NMR) spectroscopy that took place during the last several decades is observed in both experimental capabilities and theoretical approaches to study the spectral parameters. The scope of NMR spectroscopy for studying a large series of molecular problems has notably broadened. However, at the same time, it requires specialists to fully use its potentialities. This is a notorious problem and it is reflected in the current literature where this spectroscopy is typically only used in a routine way. Also, it is seldom used in several disciplines in which it could be a powerful tool to study many problems. The main aim of this book is to try to help reverse these trends.

This book is divided in three parts dealing with 1) high-resolution NMR parameters; 2) methods for understanding high-resolution NMR parameters; and 3) some experimental aspects of high-resolution NMR parameters for studying molecular structures. Each part is divided into chapters written by different specialists who use different methodologies in their work. In turn, each chapter is divided into sections. Some features of the different sections are highlighted: it is expected that part of the readership will be interested only in the basic aspects of some chapters, while other readers will be interested in deepening their understanding of the subject dealt with in them.
Shows how NMR parameters are useful for structure assignment as well as to obtain insight on electronic structuresEmphasis on conceptual aspects

Contributions by specialists who use the discussed methodologies in their everyday work

Our understanding of subatomic particles developed over many years, although a clear picture of the different particles, their interactions and their inter-relationships only emerged in the latter part of the twentieth century. The first ""subatomic particles"" to be investigated were those which exhibit readily observable macroscopic behavior, specifically these are the photon, which we observe as light and the electron, which is manifested as electricity. The true nature of these particles, however, only became clear within the last century or so. The development of the Standard Model provided clarification of the way in which various particles, specifically the hadrons, relate to one another and the way in which their properties are determined by their structure. The final piece, perhaps, of the final model, that is the means by which some particles acquire mass, has just recently been clarified with the observation of the Higgs boson. Since the 1970s it has been known that the measured solar neutrino flux was inconsistent with the flux predicted by solar models. The existence of neutrinos with mass would allow for neutrino flavor oscillations and would provide an explanation for this discrepancy. Only in the past few years, has there been clear experimental evidence that neutrinos have mass. The description of particle structure on the basis of the Standard Model, along with recent discoveries concerning neutrino properties, provides us with a comprehensive picture of the properties of subatomic particles. Part I of the present book provides an overview of the Standard Model of particle physics including an overview of the discovery and properties of the Higgs boson. Part II of the book summarizes the important investigations into the physics of neutrinos and provides an overview of the interpretation of these studies.