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Books > Science & Mathematics > Physics > Atomic & molecular physics
Dynamics of an open system interacting with theenvironment considered as a thermostate may be formulatedin terms of a master equation with an integral operator allowing for the relaxation process, [Zwanzig 1960]. In some part- ular cases this operator hasashort-lastingkernel that enables one to consider therelaxation as a Markovian process and to obtainthe master equation inthe Lindblad form, [Lindblad 1976 (a)]. In some situations the memory effects become, however, important and the dynamics of thesystem gets much more involved, [Barnett 2001]. A similar situation arises inthe case where a set of consecutive or continuous measurements is performed. The purpose of this article is to consider a situation where some simplification of the generalform of the master equation with memory isstill possibleand the result isasimpler master equation. In particular, we consider the case of a dynamic system c- pled to a measured ancilla via a nondemolition interaction, [Caves 1980]. This simplifies the consideration essentiallywhereas providing an important special case inwhich the energy of the dynamic part is conserved. We consider a composite quantum system consisting of a dynamic part - teracting with an ancillary part, the latter being subject to repeated projective measurements. The entire quantum system is assumed to evolve unitarily d- ing time ? t between the measurements. As a specific example, we analyze a harmonic oscillator coupledtoatwo-level ancillathat issubject to measu- ments.
Mesoporous silica has large-scale industrial applications such as catalysis, drug delivery and bio/chemical absorptions. This book is devoted to all aspects and types of this material, focusing synthesis of mesoporous silica with anionic amphiphilic molecules. Characterization, properties, and applications are also discussed, making the book an essential reference for material scientists, chemists, and chemical Engineer.
This book shows how the study of multi-hadron production phenomena in the years after the founding of CERN culminated in Hagedorn's pioneering idea of limiting temperature, leading on to the discovery of the quark-gluon plasma -- announced, in February 2000 at CERN. Following the foreword by Herwig Schopper -- the Director General (1981-1988) of CERN at the key historical juncture -- the first part is a tribute to Rolf Hagedorn (1919-2003) and includes contributions by contemporary friends and colleagues, and those who were most touched by Hagedorn: Tamas Biro, Igor Dremin, Torleif Ericson, Marek Gazdzicki, Mark Gorenstein, Hans Gutbrod, Maurice Jacob, Istvan Montvay, Berndt Muller, Grazyna Odyniec, Emanuele Quercigh, Krzysztof Redlich, Helmut Satz, Luigi Sertorio, Ludwik Turko, and Gabriele Veneziano. The second and third parts retrace 20 years of developments that after discovery of the Hagedorn temperature in 1964 led to its recognition as the melting point of hadrons into boiling quarks, and to the rise of the experimental relativistic heavy ion collision program. These parts contain previously unpublished material authored by Hagedorn and Rafelski: conference retrospectives, research notes, workshop reports, in some instances abbreviated to avoid duplication of material, and rounded off with the editor's explanatory notes. About the editor: Johann Rafelski is a theoretical physicist working at The University of Arizona in Tucson, USA. Bor n in 1950 in Krakow, Poland, he received his Ph.D. with Walter Greiner in Frankfurt, Germany in 1973. Rafelski arrived at CERN in 1977, where in a joint effort with Hagedorn he contributed greatly to the establishment of the relativistic heavy ion collision, and quark-gluon plasma research fields. Moving on, with stops in Frankfurt and Cape Town, to Arizona, he invented and developed the strangeness quark flavor as the signature of quark-gluon plasma.
A comprehensive review of ion beam application in modern materials research is provided, including the basics of ion beam physics and technology. The physics of ion-solid interactions for ion implantation, ion beam synthesis, sputtering and nano-patterning is treated in detail. Its applications in materials research, development and analysis, developments of special techniques and interaction mechanisms of ion beams with solid state matter result in the optimization of new material properties, which are discussed thoroughly. Solid-state properties optimization for functional materials such as doped semiconductors and metal layers for nano-electronics, metal alloys, and nano-patterned surfaces is demonstrated. The ion beam is an important tool for both materials processing and analysis. Researchers engaged in solid-state physics and materials research, engineers and technologists in the field of modern functional materials will welcome this text.
Atomic Physics is certainly the oldest field in which Quantum Mechanics has been used and has provided the most significant proofs of this new theory. Most of the basic concepts, except those more recently developed in field quantization, have been understood for quite a time. Atomic Physics began to serve as a basis for other fields such as molecu lar, solid state or nuclear physics. A renewal of interest in Atomic Physics began in the sixties, after the discovery of Quantum Electro dynamics, and later when it provided some basic tests of fundamental questions like parity violation, time reversal or Dirac theory. More recently the development of new technologies led to the ex ploration of very extreme cases in which the most secrete aspects of atoms have been observed. - Rydberg states where the atoms are so big that they can be described by classical theories; - Heavy or super-heavy ions or exotic atoms where unknown QED or relativistic effects can be observed (very heavy hydrogenlike or helium like ions, positron production in very violent collisions **. ); - Huge external perturbations as those appearing in super-dense plasmas or ultra-high fields. The aim of this school was to gather atomic physicists from all over the world working in all these areas of Atomic Physics.
This monograph assimilates new research in the field of low-dimensional metals. It provides a detailed overview of the current status of research on quasi-one- and two-dimensional molecular metals, describing normal-state properties, magnetic field effects, superconductivity, and the phenomena of interacting p and d electrons. It includes a number of findings likely to become standard material in future textbooks on solid-state physics.
This third edition of Peter Bernath's successful Spectra of Atoms and Molecules is designed to provide advanced undergraduates and graduate students a working knowledge of the vast field of spectroscopy. Also of interest to chemists, physicists, astronomers, atmospheric scientists, and engineers, this volume emphasizes the fundamental principles of spectroscopy with the primary goal of teaching the interpretation of spectra. Features include a presentation of group theory needed to understand spectroscopy, detailed worked examples and a large number of excellent problems at the end of each chapter. Prof. Bernath provides a large number of diagrams and spectra which have been specifically recorded for this book. Molecular symmetry, matrix representation of groups, quantum mechanics, and group theory are among the topics covered; atomic, rotational, vibrational, electronic and Raman spectra are analyzed. Bernath's clear treatment of the confusing topic of line strengths as needed for quantitative applications is featured. This much-needed new edition has been updated to include the 2010 CODATA revision of physical constants, and a large number of corrections and clarifications. Responding to student requests, the main new feature is the addition of detailed worked examples in each chapter. Spectra of Atoms and Molecules, 3e will help demystify spectroscopy by showing readers the necessary steps in a derivation, as well as the final result.
This book ushers in a new era of experimental and theoretical investigations into collective processes, structure formation, and self-organization of nuclear matter. It reports the results of experiments wherein for the first time the nuclei constituting our world (those displayed in Mendeleev's table as well as the super-heavy ones) have been artificially created. Pioneering breakthroughs are described, achieved at the Proton-21 Laboratory, Kiev, Ukraine, in a variety of new physical and technological directions.A detailed description of the main experiments, their analyses, and the interpretation of copious experimental data are given, along with the methodology governing key measurements and the processing algorithms of the data that empirically confirm the occurrence of macroscopic self-organizing processes leading to the nuclear transformations of various materials.
This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the 'surface science' approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level understanding of physical and chemical processes at surfaces, with particular emphasis on dynamical aspects. This book is a reference in the field.
Seven review articles and original papers provide a representative overview of the research work done in hydrogen bond research at Austrian universities. The topics covered by the contributions are: state-of-the-art of understanding hydrogen bonding in biopolymers; recent NMR techniques for studying hydrogen bonding in aqueous solutions; intramolecular hydrogen bonding and proton transfer in a class of Mannich bases derived from substituted phenols and naphthols; competition between intramolecular hydrogen bonds in ortho-disubstituted phenols; molecular dynamic simulations on proton transfer in 5,8-dihydroxynaphthoquinone and in the formic acid dimer; accurate calculations of the intermolecular interactions in cyanoacetylen dimers; correlation between OH...O bond distances and OH stretching frequencies as derived from structural and spectroscopic data of minerals.
Fullerene Polymers and Fullerene Polymer Composites is an in-depth experimental and theoretical account of polymers and composites whose unusual properties, such as, photophysical phenomena, electrical transport, phase transitions and magnetic properties, stem from the incorporation of C60 in the material. Each chapter is written by an internationally renowned expert who has published extensively in this sub-field of fullerene materials. Introductory chapters on the fundamental properties of fullerenes (C60, C70) and photophysical phenomena in fullerenes and polymers are also included.
Highly charged ions are the most chemically reactive species known
to mankind. This reactivity is due to the extremely large potential
energy they posses. This textbook deals with the wide range of
interactions which occur when such ions interact with other forms
of matter, especially solid surfaces and gasses. Particular
emphasis is placed on situations where the kinetic energy
associated with the interactions is small so that the effects of
the high potential energy are most apparent. Experimental and
theoretical techniques of investigation are covered in addition to
the findings they produce.
Recent advances in scanning-probe technology, in optical technology (optical "tweezers"), and in solution-phase chemistry now enable us to manipulate individual atoms and molecules. It is thus becoming possible not only to build machines at the scale of integrated electronic circuits and circuits with "wires" no thicker than an atom, but also to manipulate biological tissues and materials at the scale of individual cells, organelles, and even molecules. The implications of this technology are profound: for computer technology, for electromechanical sensors and actuators, for materials science and manufacturing, and for biomedical engineering.||The molecular machines of living organisms provide the paradigm for the discussion in this text. It thus emphasizes chemical physics, particularly solution-phase chemistry, as a basis for understanding the assembly of molecular machines. In addition, the book discusses the proximity-probe methods and bioengineering associated with understanding and designing devices at nanometer scales.||"Molecular Nantechnology " will be of interest to physicists, chemists, materials scientists, biological physicists, computer scientists, and manufacturing engineers.||From the reviews:||¿[Provides] an intuitive, scientific framework for understanding nanoscale systems . . . Rietman had organized the book around his precept that ¿solution-phase chemistry and protein engineering will bootstrap us into the first phase of nanotechnology.¿ . . . Useful for those who might need a basic introduction to some of the important issues in nanotechnology and the influence of the chemical and biological science on the nanotechnology revolution . . . Those seeking a qualitative picture of nanoscale systems engineering will find it a useful reference.¿|-Physics Today
Since the early days of modem physics spectroscopic techniques have been employed as a powerful tool to assess existing theoretical models and to uncover novel phenomena that promote the development of new concepts. Conventionally, the system to be probed is prepared in a well-defined state. Upon a controlled perturbation one measures then the spectrum of a single particle (electron, photon, etc.) emitted from the probe. The analysis of this single particle spectrum yields a wealth of important information on the properties of the system, such as optical and magnetic behaviour. Therefore, such analysis is nowadays a standard tool to investigate and characterize a variety of materials. However, it was clear at a very early stage that real physical compounds consist of many coupled particles that may be excited simultaneously in response to an external perturbation. Yet, the simultaneous (coincident) detection of two or more excited species proved to be a serious technical obstacle, in particular for extended electronic systems such as surfaces. In recent years, however, coincidence techniques have progressed so far as to image the multi-particle excitation spectrum in an impressive detail. Correspondingly, many-body theoretical concepts have been put forward to interpret the experimental findings and to direct future experimental research. This book gives a snapshot of the present status of multi-particle coincidence studies both from a theoretical and an experimental point of view. It also includes selected topical review articles that highlight the achievements and the power of coincident techniques.
Molecular Materials with Specific Interactions: Modeling and Design has a very interdisciplinary character and is intended to provide basic information as well as the details of theory and examples of its application to experimentalists and theoreticians interested in modeling molecular properties and putting into practice rational design of new materials. One of the first requirements to initiate the molecular modeling of molecular materials is an accurate and realistic description of the electronic structure, intermolecular interactions and chemical reactions at microscopic and macroscopic scale. Therefore the first four chapters contain an extensive introduction into the latest theories of intermolecular interactions, functional density techniques, microscopic and mezoscopic modeling techniques as well as first-principle molecular dynamics.
a ~Soft Matter Under Exogenic Impactsa (TM) is fairly unique in supplying a comprehensive presentation of high pressures, negative pressures, random constraints and strong electric field exogenic (external) impacts on various soft matter systems. These are: (i) critical liquids, (ii) glass formers, such as supercooled liquids including water, polymers and resins, (iii) liquid crystals and (iv) bio-liquids. It is, because of this, an excellent guide in this novel and still puzzling research area. Besides new results, the identification of new types of physical behavior, new technological materials, ultimate verification of condensed and soft matter physics models, new applications in geophysics, biophysics, biotechnology, are all discussed in this book. a ~Soft Matter Under Exogenic Impactsa (TM) comes as a result from the ARW NATO brainstorming discussion in Odessa, Ukraine (8-12 Oct. 2005). It contains 31 papers prepared by key specialists in the field, which include amongst others: H. E. Stanley (USA), K. L. Ngai (USA), C. M. Roland (USA), M. A. Anisimov (USA), G. P. Johari (Canada), M.-C. Bellisent (France), A. R. Imre (Hungary), G. Floudas (Greece), Th. Kraska (Germany), A. Chalyi (Ukraine), E. E. Ustjuzhanin (Russia), J. L. Tamarit (Spain) and S. Kralj (Slovenia).
The first presentation of the novel interdisciplinary optical remote sensing technique for various ionized diluted media, based on the collisional polarization of the spectoral emission. The book provides a methodology of the impact spectropolarimetic sensing of many solutions to many practical diagnostic problems.
This book reports on a new result from the KL 0 search at the J-PARC KOTO experiment, which sets an upper limit of 3x10-9 for the branching fraction of the decay at the 90% confidence level, improving the previous best limit by an order of magnitude. To explain the matter-antimatter asymmetry in the universe, still unknown new physics beyond the standard model (SM) that breaks CP symmetry is necessary. The rare decay of a long-lived neutral K meson, KL 0 , is a CP-violating decay. It is an excellent probe to search for new physics because new physics can contribute to the decay and change its branching fraction, while the SM is as small as 3x10-11. However, it is extremely difficult to search for because all of the decay products are neutral and two neutrinos are undetectable. The KL 0 signal is identified by measuring two photons from a 0 with a calorimeter and confirming the absence of any other detectable particles with hermetic veto counters. The book contributes to the analysis of neutron-induced backgrounds which were the dominant background sources in the search. For the background caused by two consecutive hadronic showers in the calorimeter due to a neutron, the author evaluated the background yield using a data-driven approach. For another background caused by an meson production- decays two photons-by a neutron that hits a veto counter near the calorimeter, the author developed an original analysis technique to reduce it. The book also contributes to the analysis of the normalization modes (KL 3 0, KL 2 0, KL 2 ) to measure KL yield, the estimation of the signal acceptance based on a simulation, and the evaluation of the trigger efficiency. As a result, significant improvements in the measurement were achieved, and this is an important step in the continuing higher sensitivity search, which can reach new physics with the energy scales up to O(100-1000 TeV).
An understanding of the collisions between micro particles is of
great importance for the number of fields belonging to physics,
chemistry, astrophysics, biophysics etc. The present book, a theory
for electron-atom and molecule collisions is developed using
non-relativistic quantum mechanics in a systematic and lucid
manner.
This monograph represents a critical survey of the outstanding
capabilities of X-ray
Experiments since 1911 prove that the distance between nuclear particles constituting atomic bodies is a hundred thousand times larger than the diameters of these particles. Hence the volumes of all atomic bodies including ourselves are space-like empty, a hundred times more empty than the volume of the solar system. Scores of experiments also prove that space contains electrons and positrons bound to each other by energies of a million electron volts per pair, and form a cubic lattice, named the epola.Based on the epola model of space, this book reveals the physical nature of inertia, gravitation, the spreading of electromagnetic and gravitational actions in space with the velocity of light, and derives their laws. The postulates of quantum and relativity theories are also derived and turned into explainable physical laws. Thus physics is restored as the natural science it had been before it was turned into a science of axiomatic statements and calculations.The book will appeal both to serious scientists and students as well as the general reader interested in scientific explanations of the physical world. Since as a natural science physics deals with the simplest and most basic natural phenomena, this book will be as accessible to the general public as biology books.
This thesis presents results crucial to the emerging field of indirect excitons. These specially designed quasiparticles give the unique opportunity to study fundamental properties of quantum degenerate Bose gases in semiconductors. Furthermore, indirect excitons allow for the creation of novel optoelectronic devices where excitons are used in place of electrons. Excitonic devices are explored for the development of advanced signal processing seamlessly coupled with optical communication. The thesis presents and describes the author's imaging experiments that led to the discovery of spin transport of excitons. The many firsts presented herein include the first studies of an excitonic conveyer, leading to the discovery of the dynamical localization-delocalization transition for excitons, and the first excitonic ramp and excitonic diode with no energy-dissipating voltage gradient.
"Paradox" conjures up arrows and tortoises. But it has a speculative, gedanken ring: no one would dream of really conjuring up Achilles to confirm that he catches the tortoise. The paradox of Einstein, Podolsky, and Rosen, however, is capable of empirical test. Attempted experimental resolutions have involved photons, but these are not detected often enough to settle the matter. Kaons are easier to detect and will soon be used to discriminate between quantum mechanics and local realism. The existence ofan objective physical reality, which had disappeared behind the impressive formalism of quantum mechanics, was originally intended to be the central issue of the paradox; locality, like the mathematics used, was just assumed to hold. Quantum mechanics, with its incompatible measurements, was born rather by chance in an atmosphere of great positivistic zeal, in which only the obviously measurable had scientific respectability. Speculation about occult "unobservable" quantities was viewed as vacuous metaphysics, which should surely form no part of a mature scientific attitude. Soon the "unmeasurable, " once only disreputable, vanished altogether. One had first been told not to worry about it; then, as dogma got more carefully defined, one was assured that the unobserved was just not there. This made it easier not to think about it and to avoid hazardous metaphysical temptation.
The four articles of the present volume address very different topics in nuclear physics and, indeed, encompass experiments at very different kinds of exp- imental facilities. The range of interest of the articles extends from the nature of the substructure of the nucleon and the deuteron to the general properties of the nucleus, including its phase transitions and its rich and unexpected quantal properties. The first article by Fillipone and Ji reviews the present experimental and theoretical situation pertaining to our knowledge of the origin of the spin of the nucleon. Until about 20 years ago the half-integral spin of the neutron and p- ton was regarded as their intrinsic property as Dirac particles which were the basic building blocks of atomic nuclei. Then, with the advent of the Standard Model and of quarks as the basic building blocks, the substructure of the - cleon became the subject of intense interest. Initial nonrelativistic quark m- els assigned the origin of nucleon spin to the fundamental half-integral spin of its three constituent quarks, leaving no room for contributions to the spin from the gluons associated with the interacting quarks or from the orbital angular momentum of either gluons or quarks. That naive understanding was shaken, about fifteen years ago, by experiments involving deep-inelastic scattering of electrons or muons from nucleons. |
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