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Books > Science & Mathematics > Physics > Atomic & molecular physics
Covering both theory and applications, this important work provides a comprehensive introduction to the modern theory of X-ray and electronic spectra of free atoms. Romas Karazija discusses methods of angular momenta, irreducible tensorial operators, and coefficients of fractional parentage and their use in determining cross sections and probabilities of elementary processes. In addition, Karazija addresses the structure of electronic shells with inner vacancies and many-body effects.
Condensed-matter physics plays an ever increasing role in photonics, electronic and atomic collisions research. Dispersion (Dynamics and Relaxation) includes scattering/collisions in the gaseous phase. It also includes thermal agitation, tunneling and relaxation in the liquid and solid phases. Classical mechanics, classical statistical mechanics, classical relativity and quantum mechanics are all implicated. 'Semiclassical' essentially means that there is a large or asymptotic real parameter. 'Semiclassical' can also mean 'classical with first-order quantal correction', based on an exponentiated Liouville series commencing with a simple pole in the -plane, being Planck's reduced constant and coming with all the attendant connection problems associated with the singularity at the turning or transition point and with the Stokes phenomenon. Equally,' semiclassical' can mean 'electrons described quantally and the heavy particles classically'. This latter gives rise to the so-called impact parameter method based on a pre-assigned classical trajectory. With evermore sophisticated experiments, it has become equally more important to test theory over a wider range of parameters. For instance, at low impact energies in heavy-particle collisions, the inverse velocity is a large parameter; in single-domain ferromagnetism, thermal agitation (including Brownian motion and continuous-time random walks) is faced with a barrier of height 'sigma', a possibly large parameter. Methods of solution include phase-integral analysis, integral transforms and change-of-dependent variable. We shall consider the Schroedinger time-independent and time-dependent equations, the Dirac equation, the Fokker Planck equation, the Langevin equation and the equations of Einstein's classical general relativity equations. There is an increasing tendency among physicists to decry applied mathematics and theoretical physics in favour of computational blackboxes. One may say applied mathematics concerns hard sums and products (and their inverses) but unless one can simplify and sum infinite series of products of infinite series, can one believe the results of a computer program? The era of the polymath has passed; this book proposal aims to show the relevance to, and impact of theory on, laboratory scientists.
This book describes the coupling between elementary processes, plasma kinetics and electrodynamics in different types of electrical discharges and under non-equilibrium conditions. Analytical methods based on rigorous kinetic theory are developed to interpret the results obtained by numerical methods. Particular emphasis is placed on the kinetics of non-equilibrium N2, O2 and N2-02 plasmas as well as on conditions relevant to atmospheric physics, reentry problems and acoustic and shock waves in non-equilibrium atmospheric gases.
The computational models of physical systems comprise parameters, independent and dependent variables. Since the physical processes themselves are seldom known precisely and since most of the model parameters stem from experimental procedures which are also subject to imprecisions, the results predicted by these models are also imprecise, being affected by the uncertainties underlying the respective model. The functional derivatives (also called "sensitivities") of results (also called "responses") produced by mathematical/computational models are needed for many purposes, including: (i) understanding the model by ranking the importance of the various model parameters; (ii) performing "reduced-order modeling" by eliminating unimportant parameters and/or processes; (iii) quantifying the uncertainties induced in a model response due to model parameter uncertainties; (iv) performing "model validation," by comparing computations to experiments to address the question "does the model represent reality?" (v) prioritizing improvements in the model; (vi) performing data assimilation and model calibration as part of forward "predictive modeling" to obtain best-estimate predicted results with reduced predicted uncertainties; (vii) performing inverse "predictive modeling"; (viii) designing and optimizing the system. This 3-Volume monograph describes a comprehensive adjoint sensitivity analysis methodology, developed by the author, which enables the efficient and exact computation of arbitrarily high-order sensitivities of model responses in large-scale systems comprising many model parameters. The qualifier "comprehensive" is employed to highlight that the model parameters considered within the framework of this methodology also include the system's uncertain boundaries and internal interfaces in phase-space. The model's responses can be either scalar-valued functionals of the model's parameters and state variables (e.g., as customarily encountered in optimization problems) or general function-valued responses. Since linear operators admit bona-fide adjoint operators, responses of models that are linear in the state functions (i.e., dependent variables) can depend simultaneously on both the forward and the adjoint state functions. Hence, the sensitivity analysis of such responses warrants the treatment of linear systems in their own right, rather than treating them as particular cases of nonlinear systems. This is in contradistinction to responses for nonlinear systems, which can depend only on the forward state functions, since nonlinear operators do not admit bona-fide adjoint operators (only a linearized form of a nonlinear operator may admit an adjoint operator). Thus, Volume 1 of this book presents the mathematical framework of the nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Response-Coupled Forward/Adjoint Linear Systems (abbreviated as "nth-CASAM-L"), which is conceived for the most efficient computation of exactly obtained mathematical expressions of arbitrarily-high-order (nth-order) sensitivities of a generic system response with respect to all of the parameters underlying the respective forward/adjoint systems. Volume 2 of this book presents the application of the nth-CASAM-L to perform a fourth-order sensitivity and uncertainty analysis of an OECD/NEA reactor physics benchmark which is representative of a large-scale model comprises many (21,976) uncertain parameters, thereby amply illustrating the unique potential of the nth-CASAM-L to enable the exact and efficient computation of chosen high-order response sensitivities to model parameters. Volume 3 of this book presents the "nth-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Nonlinear Systems" (abbreviation: nth-CASAM-N) for the practical, efficient, and exact computation of arbitrarily-high order sensitivities of responses to model parameters for systems that are also nonlinear in their underlying state functions. Such computations are not feasible with any other methodology. The application of the nth-CASAM-L and the nth-CASAM-N overcomes the so-called "curse of dimensionality" in sensitivity and uncertainty analysis, thus revolutionizing all of the fields of activities which require accurate computation of response sensitivities. Since this monograph includes many illustrative, fully worked-out, paradigm problems, it can serve as a textbook or as supplementary reading for graduate courses in academic departments in the natural sciences and engineering.
This book presents physical units and widely used physical formulas, which are given together with conversion factors in various units. It includes frequently used atomic spectra and data for atoms, ions and molecules, as well as potential curves for diatomic molecules, and provides numerical parameters for transport phenomena in gases and plasmas. Further, the rate constants of a number of processes in atmospheric ionized air have been added to this second edition of the book. The numerical data has been selected from the information on atoms, atomic systems, atomic processes and models for atomic physics in this area, and the numerical parameters of atoms, ions and atom systems are included in periodical tables of elements.
This volume contains papers presented at the 6th International Workshop on Application of Lasers in Atomic Nuclei Research, LASER 2006, held in Poznan, Poland, May 29-June 01, 2006. Researchers and PhD students interested in recent results in the nuclear structure investigation by laser spectroscopy, the progress of the experimental technique and the future developments in the field will find this volume indispensable.
This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride-water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
A large range of symmetries in art is presented through clear and aesthetically outstanding examples of historical ornaments. Compendious comments illustrate the selected photographic material by addressing the interested and specialist reader alike. Contents: Introduction Fundamental categories The convenient start: Plane groups of symmetry Intertwined patterns: Layer groups of symmetry Two-colored periodic ornamentation Polychromatic patterns Beyond 2D groups: Hypersymmetry, superstructures, two symmetries in one pattern, the "order-disorder" patterns, homothety and similarity, inversion and nonlinear patterns Quasiperiodic patterns Fractals and fractal character Style and symmetry - symmetry and style References Index
Powerful new techniques, including heavy ion and exotic beams, are pushing the frontiers of nuclear physics and opening up a wealth of new fields of research. After introductory chapters on theoretical and experimental aspects of nuclear collisions and beams, Exotic Nuclear Physics'' offers articles by experienced lecturers on forefront topics in nuclear physics, such as the conquest of the neutron and the proton drip-lines, nuclear astrophysics, the equation of state of hypernuclear matter, nuclear supersymmetry and chaotic motion in nuclei. This volume continues the successful tradition of published lecture notes from the Hispalensis International Summer School. It will benefit graduate students and lecturers in search of advanced material for self-study and courses as will as researchers in search of a modern and comprehensive source of reference.
The search for examples of proton radioactivity has resulted in the discovery of a large number of proton emitters in the region 50 < Z < 84 [1]. Many of these proton emitters and their daughters are also a-emitters, and in some cases the a-decay chain from the daughter terminates on a nuclide closer to stability whose mass excess is known. This opens up the possibility of using a-and proton-decay Q-values to determine the mass excesses of a large group of nuclei connected by particle decay. The Q-values are derived from the measured kinetic energies of the emitted protons or a-particles. Where the decay chains are not connected to nuclei with known mass excesses, proton separation energies can be measured in some cases and derived in others. For the a-decay ofthe parent nucleus (Z, A) to the daughter (Z - 2, A - 4), the energy and momentum relations used to convert between Q-value, mass (M) and mass excess (ME) are: M(4He)E", (1) M(Z - 2, A - 4)Erecoil, (2) Q", E", + Erecoi\, ME(Z, A) Q", + ME(Z - 2, A - 4) + ME(4He). (3) In practice, one uses M(4He) ~ 4 and M(Z - 2, A - 4) (A - 4), so that Equation (3) becomes ME(Z, A) = E", (_A_) + ME(Z - 2, A - 4) + ME(4He). (4) A -4 Similarly, for protons, we have ME(Z, A) = Ep(_A_) +ME(Z - 1, A-I) +ME(lH).
This thesis explores the physics of non-equilibrium quantum dynamics in homogeneous two-dimensional (2D) quantum gases. Ultracold quantum gases driven out of equilibrium have been prominent platforms for studying quantum many-body physics. However, probing non-equilibrium dynamics in conventionally trapped, inhomogeneous atomic quantum gases has been a challenging task because coexisting mass transport and spreading of quantum correlations often complicate experimental analyses. In this work, the author solves this technical hurdle by producing ultracold cesium atoms in a quasi-2D optical box potential. The exquisite optical trap allows one to remove density inhomogeneity in a degenerate quantum gas and control its dimensionality. The author also details the development of a high-resolution, in situ imaging technique to monitor the evolution of collective excitations and quantum transport down to atomic shot-noise, and at the length scale of elementary collective excitations. Meanwhile, tunable Feshbach resonances in ultracold cesium atoms permit precise and dynamical control of interactions with high temporal and even spatial resolutions. By employing these state-of-the-art techniques, the author performed interaction quenches to control the generation and evolution of quasiparticles in quantum gases, presenting the first direct measurement of quantum entanglement between interaction quench generated quasiparticle pairs in an atomic superfluid. Quenching to attractive interactions, this work shows stimulated emission of quasiparticles, leading to amplified density waves and fragmentation, forming 2D matter-wave Townes solitons that were previously considered impossible to form in equilibrium due to their instability. This thesis unveils a set of scale-invariant and universal quench dynamics and provides unprecedented tools to explore quantum entanglement transport in a homogenous quantum gas.
The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).
This thesis describes the application of the collinear resonance laser spectroscopy to sensitively measure the electromagnetic nuclear observables of the neutron-rich indium isotopes 115-131In. This entailed a systematic study of the efficiency of resonant ionization schemes to extract the hyperfine structure of the isotopes, the atomic charge exchange process and benchmarking of modern atomic calculations with a laser ablation ion source. This allowed determination of the root-mean-square nuclear charge radii, nuclear magnetic dipole moments, nuclear electric quadrupole moments and nuclear spins of the 113-131In isotopes with high accuracy. With a proton hole in the Z = 50 nuclear shell closure of tin and several nuclear isomer states, these measurements of the indium (Z = 49) isotope chain provided an efficient probe of the evolution of nuclear structure properties towards and at the doubly-magic nuclear shell closure of 132Sn (N = 82) - revealing unpredicted changes.
Over the years, many leading European graduate schools in the field of astrophysical and space plasmas have operated within the framework of the research network, "Theory, Observations, and Simulations in Turbulence in Space Plasmas." This text is a set of lectures and tutorial reviews culled from the relevant work of all those schools. It emphasizes applications on solar coronae, solar flares, and the solar wind. In bridging the gap between standard textbook material and state-of-the-art research, this text offers a broad flavor to postgraduate and postdoctoral students just coming to the field. And because of its unique mix, it will also be useful to lecturers looking for advanced teaching material for their seminars and courses.
This book presents the proceedings of The International Workshop on Frontiers in High Energy Physics (FHEP 2019), held in Hyderabad, India. It highlights recent, exciting experimental findings from LHC, KEK, LIGO and several other facilities, and discusses new ideas for the unified treatment of cosmology and particle physics and in the light of new observations, which could pave the way for a better understanding of the universe we live in. As such, the book provides a platform to foster collaboration in order to provide insights into this important field of physics.
Nuclear spins are highly coherent quantum objects that were featured in early ideas and demonstrations of quantum information processing. In silicon, the high-fidelity coherent control of a single phosphorus (31-P) nuclear spin I=1/2 has demonstrated record-breaking coherence times, entanglement, and weak measurements. In this thesis, we demonstrate the coherent quantum control of a single antimony (123-Sb) donor atom, whose higher nuclear spin I = 7/2 corresponds to eight nuclear spin states. However, rather than conventional nuclear magnetic resonance (NMR), we employ nuclear electric resonance (NER) to drive nuclear spin transitions using localized electric fields produced within a silicon nanoelectronic device. This method exploits an idea first proposed in 1961 but never realized experimentally with a single nucleus, nor in a non-polar crystal such as silicon. We then present a realistic proposal to construct a chaotic driven top from the nuclear spin of 123-Sb. Signatures of chaos are expected to arise for experimentally realizable parameters of the system, allowing the study of the relation between quantum decoherence and classical chaos, and the observation of dynamical tunneling. These results show that high-spin quadrupolar nuclei could be deployed as chaotic models, strain sensors, hybrid spin-mechanical quantum systems, and quantum-computing elements using all-electrical controls.
Written by a former International Atomic Energy Agency (IAEA) nuclear inspector and nuclear security expert, this book provides a comprehensive and authentic overview of current global nuclear developments. The author provides detailed insights into current and past nuclear crises and reveals the technical capabilities, political strategies and motives of nuclear weapon owners. By analyzing the nuclear programs and strategies of various countries, including the USA, Russia, China, Great Britain and France, this book highlights the existing global nuclear threat and the risks it entails for humanity. It also describes the current blockades and suggests possible ways out. Given its scope, the book will appeal to scholars and policymakers interested in gaining new insights into sensitive or complex nuclear programs in various countries.
Nuclear isomers are the long-lived excited states of nuclei. Therefore, they constitute the meta-stable landscape of nuclei. The first isomer was probably identified as early as 1921. Since then, the number of isomers has been growing steadily picking up pace in recent times. Interest in nuclear isomers has grown in recent years for many reasons. The experimental capabilities to observe isomers have been expanding to cover a wider time scale. This has opened up new windows to observe and decipher the underlying nuclear structure and interactions. Further, the isomers are beginning to be seen as potential energy storage devices and nuclear clocks with a host of applications. Possible discovery of a gamma ray laser has also ignited many researches in this area. Isomers now cover the full nuclear landscape with structural peculiarities specific to each region of the nuclear chart. Exploring the nuclear isomers, therefore, provides a novel insight into the nuclear structure properties of that region. There could be many different reasons for the long lives of excited nuclear states, which lead to the classification of isomers. Isomers are broadly classified in to four classes: Spin isomers, shape isomers, fission isomers and K-isomers. Seniority isomers have also been identified which are often clubbed with the spin isomers. We discuss this classification and the underlying causes in detail. Many examples are considered to highlight the large variety of isomers. The range of half-lives covered by the isomers varies from billions of years to nano-seconds and even small. To understand this vast variation is a fascinating endeavor in itself. The angular momentum couplings, nuclear shapes, pairing etc. conspire together to give this vast range of half-lives. We go through these aspects in detail, highlighting the various selection rules at work. It is interesting that the nuclear shapes play an important role in many types of isomers. The spin isomers, which occur in spherical or, near-spherical nuclei, are generally confined to the magic numbers. Seniority isomers are largely found in semi-magic nuclei and should be explored in conjunction with the spin isomers. New developments in seniority and generalized seniority isomers are discussed in detail. As the nuclei deform; the nature of isomers changes. We take a close look into the decay properties of isomers in deformed nuclei, particularly the K isomers, the shape isomers and the fission isomers. While doing so, the theoretical and experimental developments of isomers are also addressed. A number of open questions are posed for possible new experiments and better understanding of the isomers.
Caustics are natural phenomena, forming light patterns in rainbows or through drinking glasses, and creating light networks at the bottom of swimming pools. Only in recent years have scientists started to artificially create simple caustics with laser light. However, these realizations have already contributed to progress in advanced imaging, lithography, and micro-manipulation. In this book, Alessandro Zannotti pioneers caustics in many ways, establishing the field of artificial caustic optics. He employs caustic design to customize high-intensity laser light. This is of great relevance for laser-based machining, sensing, microscopy, and secure communication. The author also solves a long standing problem concerning the origin of rogue waves which appear naturally in the sea and can have disastrous consequences. By means of a far-reaching optical analogy, he identifies scattering of caustics in random media as the origin of rogue waves, and shows how nonlinear light-matter interaction increases their probability.
This book reports on the latest developments in the field of Superfluidity. The phenomenon has had a tremendous impact on the fundamental sciences as well as a host of technologies. It began with the discovery of superconductivity in mercury in 1911, which was ultimately described theoretically by the theory of Bardeen Cooper and Schriever (BCS) in 1957. The analogous phenomena, superfluidity, was discovered in helium in 1938 and tentatively explained shortly thereafter as arising from a Bose-Einstein Condensation (BEC) by London. But the importance of superfluidity, and the range of systems in which it occurs, has grown enormously. In addition to metals and the helium liquids the phenomena has now been observed for photons in cavities, excitons in semiconductors, magnons in certain materials, and cold gasses trapped in high vacuum. It very likely exist for neutrons in a neutron star and, possibly, in a conjectured quark state at their center. Even the Universe itself can be regarded as being in a kind of superfluid state. All these topics are discussed by experts in the respective subfields.
Taking an individual approach, this book focuses on the concepts underlying chemical physics. It presents the essence of a connected theory rather than mere explanations of apparently unrelated facts, helping readers to understand chemical phenomena in terms of the most fundamental laws of physics.
This book introduces readers to basic approaches in and principles of marine nuclear power design, including overall reactor design, in-core design, coolant systems and devices, I&C system design, safety system design, and dynamic analysis assessment. It comprehensively reviews both the fundamentals of and latest trends in nuclear-powered devices, covering their entire lifespan, from design and testing to operation and decommissioning. Further, it explores in detail various real-world conditions in the marine context - such as insufficient space for equipment deployment and frequently changing operating conditions as well as swinging and tilting. Offering extensive information on the design and operation of marine nuclear power systems, the book is a valuable resource for researchers and professionals in the area of marine science and nuclear engineering, and graduate students intending to embark on a career in the field.
Using a selection of key experiments performed over the past 30 years or so, we present a discussion of the strikingly counter-intuitive phenomena of the quantum world that defy explanation in terms of everyday "common sense" reasoning, and we provide the corresponding quantum mechanical explanations with a very elementary use of associated formalism. Most, but certainly not all, of the experiments we describe are optical experiments involving a very small number of photons (particles of light). We begin with experiments on the wave-particle duality of electrons, proceed to experiments on the particle nature of light and single photon interference, delayed choice experiments and interaction-free detection, then go on to experiments involving the interference of two photons, quantum entanglement and Bell's Theorem, quantum teleportation, large-scale quantum effects and the divide between the classical and quantum worlds, addressing the question as to whether or not there is such a divide.
In 1954, Charles Townes invented the laser's microwave cousin, the maser. The next logical step was to extend the same physical principles to the shorter wavelengths of light, but the idea did not catch fire until October 1957, when Townes asked Gordon Gould about Gould's research on using light to excite thallium atoms. Each took the idea and ran with it. The independent-minded Gould sought the fortune of an independent inventor; the professorial Townes sought the fame of scientific recognition. Townes enlisted the help of his brother-in-law, Arthur Schawlow, and got Bell Labs into the race. Gould turned his ideas into a patent application and a million-dollar defense contract. They soon had company. Ali Javan, one of Townes's former students, began pulling 90-hour weeks at Bell Labs with colleague Bill Bennett. And far away in California a bright young physicist named Ted Maiman became a very dark horse in the race. While Schawlow proclaimed that ruby could never make a laser, Maiman slowly convinced himself it would. As others struggled with recalcitrant equipment and military secrecy, Maiman built a tiny and elegant device that fit in the palm of his hand. His ruby laser worked the first time he tried it, on May 16, 1960, but afterwards he had to battle for acceptance as the man who made the first laser. Beam is a fascinating tale of a remarkable and powerful invention that has become a symbol of modern technology.
Researchers, postgraduate and undergraduate students of high energy physics |
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