In this book, we have attempted to produce a reference on high resolution focused ion beams (FIBs) that will be useful for both the user and the designer of FIB instrumentation. We have included a mix of theory and applications that seemed most useful to us.
The field of FIBs has advanced rapidly since the application of the first field emission ion sources in the early 1970s. The development of the liquid metal ion source (LMIS) in the late 1960s and early 1970s and its application for FIBs in the late 1970s have resulted in a powerful tool for research and for industry. There have been hundreds of papers written on many aspects of LMIS and FIBs, and a useful and informative book on these subjects was published in 1991 by Phil Prewett and Grame Mair. Because there have been so many new applications and uses found for FIBs in the last ten years we felt that it was time for another book on the subject.

This book contains the transcripts of the lectures presented at the NATO Advanced study Institute on "Computational Techniques in Quantum Chemistry and Molecular Physics," held at Ramsau, Germany, 4th - 21st Sept. 1974. Quantum theory was developed in the early decades of this century and was first applied to problems in chemistry and molecular physics as early as 1927. It soon emerged however, that it was impossible to con sider any but the simplest systems in any quantita tive detail because of the complexity of Schrodinger's equation which is the basic equation for chemical and molecular physics applications. This remained the si tuation until the development, after 1950, of elec tronic digital computers. It then became possible to attempt approximate solutions of Schrodinger's equa tion for fairly complicated systems, to yield results which were sufficiently accurate to make comparison with experiment meaningful. Starting in the early nineteen sixties in the United States at a few centres with access to good computers an enormous amount of work went into the development and implementation of schemes for approximate solu tions of Schrodinger's equation, particularly the de velopment of the Hartree-Fock self-consistent-field scheme. But it was soon found that the integrals needed for application of the methods to molecular problems are far from trivial to evaluate and cannot be easily approximated."

The three articles of the present volume pertain to very different subjects, all ofconsiderable current interest. The first reviews the fascinating history ofthe search for nucleon substructure in the nucleus using the strength ofGamow- Teller excitations. The second deals with deep inelastic lepton scattering as a probe ofthe non-perturbative structure of the nucleon. The third describes the present state ofaffairs for muon catalyzed fusion, an application of nuclear physics which many new experiments have helped to elucidate. This volume certainly illustrates the broad range ofphysics within our field. The article on Nucleon Charge-Exchange Reactions at Intermediate Energy, by Parker Alford and Brian Spicer, reviews recent data which has clarified one of the greatest puzzles of nuclear physics during the past two decades, namely, the "missing strength" in Gamow-Teller (GT) transitions. The nucleon-nucleon interaction contains a GT component which has a low-lying giant resonance. The integrated GT strength is subject to a GT sum rule. Early experiments with (n, p) charge exchange reactions found only about half of the strength, required by the sum rule, in the vicinity of the giant resonance. At the time, new theoretical ideas suggested that the GT strength was especially sensitive to renormalization from effects pertaining to nucleon substructure, particularly the delta excitation of the nucleon in the nucleus.

Stars are born and die in clouds of gas and dust, opaque to most types of radiation, but transparent in the infrared. Requiring complex detectors, space missions and cooled telescopes, infrared astronomy is the last branch of this discipline to come of age. After a very successful sky survey performed in the eighties by the IRAS satellite, the Infrared Space Observatory, in the nineties, brought spectacular advances in the understanding of the processes giving rise to powerful infrared emission by a great variety of celestial sources.

Outstanding results have been obtained on the bright comet Hale-Bopp, and in particular of its water spectrum, as well as on the formation, chemistry and dynamics of planetary objects in the solar system. Ideas on the early stages of stellar formation and on the stellar initial mass function have been clarified.

ISO is the first facility in space able to provide a systematic diagnosis of the physical phenomena and the chemistry in the close environment of pre-main sequence stars, in the interstellar medium, and in the final stages of stellar life, using, among other indicators, molecular hydrogen, ubiquitous crystalline silicates, water and ices.

ISO has dramatically increased our ability to investigate the power production, excitation and fuelling mechanism of galaxies of every type, and has discovered a new very cold dust component in galaxies.

ISO has demonstrated that luminous infrared galaxies were brighter and much more numerous in the past, and that they played a dominant role in shaping present day galaxies and in producing the cosmic infrared background.

This book is a comprehensive exposition of the thermodynamic properties of the van der Waals fluid, which evolved out of a course on thermodynamics and statistical mechanics at Iowa State University in the US.

This corrected and updated second edition of "Scattering Theory" presents a concise and modern coverage of the subject. In the present treatment, special attention is given to the role played by the long-range behaviour of the projectile-target interaction, and a theory is developed, which is well suited to describe near-threshold bound and continuum states in realistic binary systems such as diatomic molecules or molecular ions. It is motivated by the fact that experimental advances have shifted and broadened the scope of applications where concepts from scattering theory are used, e.g. to the field of ultracold atoms and molecules, which has been experiencing enormous growth in recent years, largely triggered by the successful realization of Bose-Einstein condensates of dilute atomic gases in 1995. The book contains sections on special topics such as near-threshold quantization, quantum reflection, Feshbach resonances and the quantum description of scattering in two dimensions. The level of abstraction is kept as low as at all possible and deeper questions related to the mathematical foundations of scattering theory are passed by. It should be understandable for anyone with a basic knowledge of nonrelativistic quantum mechanics. The book is intended for advanced students and researchers, and it is hoped that it will be useful for theorists and experimentalists alike.

The aim of this book is to provide the reader with a coherent and updated comprehensive treatise that covers the central subjects of the field. The style and content is suitable both for students and researchers. Highlights of the book include (among many others) the Ion-Sphere model, statistical models, Average-Atom model, emission spectrum, unresolved transition arrays, supertransition arrays, radiation transport, escape factors and x-ray lasers.

Molecular behaviour, which is no less than magical, holds the key to the understanding, not only of chemistry, but of all biology and of life itself. It is a mystery why molecular behaviour should remain poorly understood and why the authoritative theories of physics have produced no more than superficial models to elucidate this vital issue. An interdisciplinary international team of experts came together to document and to probe various aspects of these fundamental questions and their startling conclusions confirm the need for a fresh look at the physical sciences with a view to better understand the mysteries and magic of molecules. This book explores the common ground to guide chemists, biologists, crystallographers, spectroscopists and theorists into a deeper recognition of their individual relevance towards painting a holistic picture of scientific endeavour. This effort to stimulate interest in multidisciplinary research is rare, if not unique.

Flux quantization experiments indicate that the carriers, Cooper pairs (pairons), in the supercurrent have charge magnitude 2e, and that they move independently. Josephson interference in a Superconducting Quantum Int- ference Device (SQUID) shows that the centers of masses (CM) of pairons move as bosons with a linear dispersion relation. Based on this evidence we develop a theory of superconductivity in conventional and mate- als from a unified point of view. Following Bardeen, Cooper and Schrieffer (BCS) we regard the phonon exchange attraction as the cause of superc- ductivity. For cuprate superconductors, however, we take account of both optical- and acoustic-phonon exchange. BCS started with a Hamiltonian containing "electron" and "hole" kinetic energies and a pairing interaction with the phonon variables eliminated. These "electrons" and "holes" were introduced formally in terms of a free-electron model, which we consider unsatisfactory. We define "electrons" and "holes" in terms of the cur- tures of the Fermi surface. "Electrons" (1) and "holes" (2) are different and so they are assigned with different effective masses: Blatt, Schafroth and Butler proposed to explain superconductivity in terms of a Bose-Einstein Condensation (BEC) of electron pairs, each having mass M and a size. The system of free massive bosons, having a quadratic dispersion relation: and moving in three dimensions (3D) undergoes a BEC transition at where is the pair density.

This volume presents five pedagogical articles spanning frontier developments in contemporary nuclear physics ranging from the physics of a single nucleon to nucleosynthesis in the Big Bang. Although the objectives of Advances in Nuclear Physics have been and will continue to be quite distinct from those of conventional conference proceedings, the articles in this volume are carefully edited and expanded manuscripts based on an outstanding series of lectures delivered at the VI J. A. Swieca Summer School in Brazil. Starting at the smallest scale, the first article by Dan Olof Riska addresses realistic chiral symmetric models of the nucleon. Since the analytic tools are not yet developed to solve nonperturbative QCD directly, significant effort has been devoted in recent years to the development of models which incorporate and are constrained by the approximate chiral symmetry manifested in QCD. This article provides a clear introduction to chiral symmetry and the Skyrme model, and discusses the Skyrme model's relation to the chiral bag model, its extensions, and its application to nucleons and hyperons.

Volume 16 marks the beginning of a special topic series devoted to modern techniques in protein NMR, under the Biological Magnetic Resonance series. This volume is being followed by Volume 17 with the subtitle Structure Computation and Dynamics in Protein NMR. Volumes 16 and 17 present some of the recent, significant advances in biomolecular NMR field with emphasis on developments during the last five years. We are honored to have brought together in these volumes some of the world's foremost experts who have provided broad leadership in advancing this field. Volume 16 contains advances in two broad categories: the first, Large Proteins, Complexes, and Membrane Proteins, and second, Pulse Methods. Volume 17, which will follow covers major advances in Computational Methods, and Structure and Dynamics. In the opening chapter of Volume 16, Marius Clore and Angela Gronenborn give a brief review of NMR strategies including the use of long range restraints in the structure determination of large proteins and protein complexes. In the next two chapters, Lewis Kay and Ron Venters and their collaborators describe state-of-t- art advances in the study of perdeuterated large proteins. They are followed by Stanley Opella and co-workers who present recent developments in the study of membrane proteins. (A related topic dealing with magnetic field induced residual dipolar couplings in proteins will appear in the section on Structure and Dynamics in Volume 17).

Combining incisive experiments with the latest theoretical advances, this book presents an extensive study of transfer-triggered breakup, the dominant process by which breakup occurs in reactions involving light, weakly bound nuclei. It demonstrates not only that lifetimes of resonant states shorter than a zeptosecond are crucially important for these reactions to suppress complete fusion, but also that such short lifetimes are experimentally accessible. By making quantitative predictions of the effect of breakup from short-lived resonant states on incomplete fusion at above-barrier energies, the book suggests that the extent to which near-target breakup can suppress complete fusion is much more limited than previously thought. With an impressive amount of complex data and state-of-the-art models, which were developed, modified, and tested over course of the Ph.D., it examines all aspects of nuclear reactions - nuclear models, modern detectors and spectrometers, as well as data analysis, and offers a detailed discussion of experimental results and technical developments like new radioactive beams. This excellent and beautifully written book presents outstanding quality experimental work that establishes a cornerstone in our understanding of the reaction dynamics of light weakly bound nuclei at energies around the Coulomb barrier.

Molecular Physics and Hypersonic Flows bridges the gap between the fluid dynamics and molecular physics communities, emphasizing the role played by elementary processes in hypersonic flows. In particular, the work is primarily dedicated to filling the gap between microscopic and macroscopic treatments of the source terms to be inserted in the fluid dynamics codes. The first part of the book describes the molecular dynamics of elementary processes both in the gas phase and in the interaction with surfaces by using quantum mechanical and phenomenological approaches. A second group of contributions describes thermodynamics and transport properties of air components, with special attention to the transport of internal energy. A series of papers is devoted to the experimental and theoretical study of the flow of partially ionized gases. Subsequent contributions treat modern computational techniques for 3-D hypersonic flow. Non-equilibrium vibrational kinetics are then described, together with the coupling of vibration-dissociation processes as they affect hypersonic flows. Special emphasis is given to the interfacing of non-equilibrium models with computational fluid dynamics methods. Finally, the last part of the book deals with the application of direct Monte Carlo methods in describing rarefied flows.

Strangeness nuclear physics bears a broad impact on contemporary physics. This set of extensive lectures presents a balanced theoretical and experimental introduction to, and survey of, the field. It addresses topics such as the production and spectroscopy of strange nuclear systems, modern approaches to the hyperon-nucleon interaction, and weak decays of hypernuclei. This burgeoning research field is well served by this tutorial primer.

A thorough exploration of the atomic structures and properties of the essential engineering interfaces—an invaluable resource for students, teachers, and professionals

The most up-to-date, accessible guide to solid-vapor, solid-liquid, and solid-solid phase transformations, this innovative book contains the only unified treatment of these three central engineering interfaces. Employing a simple nearest-neighbor broken-bond model, Interfaces in Materials focuses on metal alloys in a straightforward approach that can be easily extended to all types of interfaces and materials. Enhanced with nearly 300 illustrations, along with extensive references and suggestions for further reading, this book provides:

• A simple, cohesive approach to understanding the atomic structure and properties of interfaces formed between solid, liquid, and vapor phases
• Self-contained discussions of each interface—allowing separate study of each phase transformation
• A comparative look at the different interfaces, including atomic structure and crystallography; anisotropy, roughening, and melting; interfacial stability and segregation; continuous and ledge growth models; and atomistic modeling
• An analysis of nearest-neighbor broken-bond results against thermodynamic and kinetic descriptions of the interfaces
• Problem sets at the end of each chapter, emphasizing the key concepts detailed in the text

Spanning the fields of chemical, electrical and computer engineering, materials science, solid-state physics, and microscopy, Interfaces in Materials bridges a major gap in the literature of surface and interface science.

An (e,2e) experiment is the measurement of an electron impact ionization process where both the exiting electrons are detected in coincidence. Such measurements are almost at the limit of what can be known, in quantum mechanical terms, and its description presents a substantial theoretical challenge. There are at least two very good reasons for studying (e,2e) and related processes. In the first place we are now only beginning to understand the dynamics of the collision process. The range and sophistication of present experiments allow us to identify kinematic regimes where delicate and subtle effects can be observed, stretching current theories to their limit. Secondly, the multiple coincident technique offers us the possibility of an analytical tool that could be used to probe the structure of the target, be it atom, molecule, thin film or surface. Measurements are now being performed at threshold on H, on the inner shell levels of Au and Ag using projectiles at relativistic energies, with spin-polarized electrons on Li, on a myriad of molecules in symmetric, noncoplanar kinematics, and on He in a multitude of different geometries. The technique has recently been extended to excitation ionization (e,3e) and (gamma,2e) experiments. Major theoretical advances have also been made, but much still remains to be done. This volume contains the invited papers that were presented at the Workshop on (e,2e) and related processes which took place in September/October 1992 in Cambridge, UK. The three major review papers which it contains together form an excellent introduction to this new and rapidly expanding area of physics and set the scene for the wide range of research contributions, both experimental and theoretical, from the leading scientists in the field.

This book takes a "bottom-up" approach, beginning with atoms and molecules - molecular building blocks - and assembling them to build nanostructured materials. Coverage includes Carbon Nanotubes, Nanowires, and Diamondoids. The applications presented here will enable practitioners to design and build nanometer-scale systems. These concepts have far-reaching implications: from mechanical to chemical processes, from electronic components to ultra-fine sensors, from medicine to energy, and from pharmaceuticals to agriculture and food.

This book, devoted to the study of quantum effects in atomic systems, reviews the state of the art in the fields of Bose--Einstein condensation, quantum information processing, and the problems of propagation of matter waves in complex media. The specific topics include: theory and experiments in Bose--Einstein condensation, theory and experiments on decoherence phenomena in simple quantum systems and the connection to quantum measurement, atom interferometry, quantum computing, multiple scattering problems in atomic physics, quantum and nonlinear optics in a photonic band gap and quantum chaos and atomic physics. Pedagogical in style, the articles address PhD students as well as researchers.

This book is targeted mainly to the undergraduate students of USA, UK and other European countries, and the M. Sc of Asian countries, but will be found useful for the graduate students, Graduate Record Examination (GRE), Teachers and Tutors. This is a by-product of lectures given at the Osmania University, University of Ottawa and University of Tebrez over several years, and is intended to assist the students in their assignments and examinations. The book covers a wide spectrum of disciplines in Modern Physics, and is mainly based on the actual examination papers of UK and the Indian Universities. The selected problems display a large variety and conform to syllabi which are currently being used in various countries. The book is divided into ten chapters. Each chapter begins with basic concepts containing a set of formulae and explanatory notes for quick reference, followed by a number of problems and their detailed solutions. The problems are judiciously selected and are arranged section-wise. The so- tions are neither pedantic nor terse. The approach is straight forward and step-- step solutions are elaborately provided. More importantly the relevant formulas used for solving the problems can be located in the beginning of each chapter. There are approximately 150 line diagrams for illustration. Basic quantum mechanics, elementary calculus, vector calculus and Algebra are the pre-requisites.

Sonochemistry is studied primarily by chemists and sonoluminescence mainly by physicists, but a single physical phenomenon - acoustic cavitation - unites the two areas. The physics of cavitation bubble collapse, is relatively well understood by acoustical physicists but remains practically unknown to the chemists. By contrast, the chemistry that gives rise to electromagnetic emissions and the acceleration of chemical reactions is familiar to chemists, but practically unknown to acoustical physicists. It is just this knowledge gap that the present volume addresses. The first section of the book addresses the fundamentals of cavitation, leading to a more extensive discussion of the fundamentals of cavitation bubble dynamics in section two. A section on single bubble sonoluminescence follows. The two following sections address the new scientific discipline of sonochemistry, and the volume concludes with a section giving detailed descriptions of the applications of sonochemistry. The mixture of tutorial lectures and detailed research articles means that the book can serve as an introduction as well as a comprehensive and detailed review of these two interesting and topical subjects.

Commencing with a self-contained overview of atomic collision theory, this monograph presents recent developments of R-matrix theory and its applications to a wide-range of atomic molecular and optical processes. These developments include the electron and photon collisions with atoms, ions and molecules which are required in the analysis of laboratory and astrophysical plasmas, multiphoton processes required in the analysis of superintense laser interactions with atoms and molecules and positron collisions with atoms and molecules required in antimatter studies of scientific and technologial importance. Basic mathematical results and general and widely used R-matrix computer programs are summarized in the appendices.

All living matter is comprised of cells, small compartments isolated from the environment by a cell membrane and filled with concentrated solutions of various organic and inorganic compounds. Some organisms are single-cell, where all life functions are performed by that cell. Others have groups of cells, or entire organs, specializing in one particular function. The survival of the entire organism depends on all of its cells and organs fulfilling their roles.While the cells are studied by different sciences, they are seen differently by biologists, chemists, or physicists. Biologists concentrate their attention on cell structure and function. What does the cell consist of? Where are its organelles? What function does each organelle fulfil? From a chemists' point of view, a cell is a complex chemical reaction chamber where various molecules are synthesized or degraded. The main question is how these, sometimes very complicated chains of reactions are controlled. Finally, from a physics standpoint, one of the main questions is the physical movement of all these molecules between organelles within the cell, as well as their exchange with the extracellular medium. The aim of this book is to look into the basic physical phenomena occurring in cells. These physical transport processes facilitate chemical reactions in the cell and that in turn leads to the biological functions necessary for the cell to satisfy its role in the mother organism. Ultimately, the goals of every cell are to stay alive and to fulfil its function as a part of a larger organ or organism. This book is an inventory of physical transport processes occurring in cells while the second volume will be a closer look at how complex biological and physiological cell phenomena result from these very basic physical processes.

This dissertation focuses on the calculation of transport coefficients in the matter created in a relativistic heavy-ion collision after chemical freeze-out. This matter can be well approximated using a pion gas out of equilibrium. We describe the theoretical framework needed to obtain the shear and bulk viscosities, the thermal and electrical conductivities and the flavor diffusion coefficients of a meson gas at low temperatures. To describe the interactions of the degrees of freedom, we use effective field theories with chiral and heavy quark symmetries. We subsequently introduce the unitarization methods in order to obtain a scattering amplitude that satisfies the unitarity condition exactly, then go on to calculate the transport properties of the low-temperature phase of quantum chromodynamics - the hadronic medium - which can be used in hydrodynamic simulations of a relativistic heavy-ion collision and its subsequent evolution. We show that the shear viscosity over entropy density exhibits a minimum in a phase transition by studying this coefficient in atomic Argon (around the liquid-gas phase transition) and in the linear sigma model in the limit of a large number of scalar fields (which presents a chiral phase transition). Finally, we provide an experimental method for estimating the bulk viscosity in relativistic heavy-ion collisions by performing correlations of the fluctuating components of the stress-energy tensor.

This collection of papers will address the question "What is the Magnetospheric Cusp?" and what is its role in the coupling of the solar wind to the magnetosphere as well as its role in the processes of particle transport and energization within the magnetosphere. The cusps have traditionally been described as narrow funnel-shaped regions that provide a focus of the Chapman-Ferraro currents that flow on the magnetopause, a boundary between the cavity dominated by the geomagnetic field (i.e., the magnetosphere) and the external region of the interplanetary medium. Measurements from a number of recent satellite programs have shown that the cusp is not confined to a narrow region near local noon but appears to encompass a large portion of the dayside high-latitude magnetosphere. It appears that the cusp is a major source region for the production of energetic charged particles for the magnetosphere. This book will be of great interest to scientists in Space Physics as well as to those working in research organizations in governments and industries, university departments of physics, astronomy, space physics, and geophysics. Part of this book has already been published in a journal.