The present volume presents six chapters, two of them fairly brief, covering both fundamental and applied electrochemistry. The latter aspect has, of course, historical significance in the subject as well as a major technological profile in recent decades, while intimate connections between these complementary facets of the subject have always been a driving force for its earlier and continu ing development. In the Modern Aspects of Electrochemistry series we have periodically included contributions from the several schools of Russi n electrochemistry. This approach is continued in the present volume by inclusion of the chapter by Benderskii, Brodskii, Daikhin, and Velichko from the Frumkin Institute, Moscow, on phase transitions among molecules adsorbed in the double-layer interphase at electrodes. This topic has attracted attention for some years through the works of the Russian school and of Gierst and Buess-Herman. Such behavior is also related to the important phenomenon of self-assembly of molecules in films at interfaces. In Chapter 1, these authors give an account of the factors associated with two-dimensional phase transitions and associated orientation effects with polar adsorbates at electrode interfaces. The theoretical interpretation of these effects are also treated in some detail. Chapter 2, by Rusling, deals with electrochemistry and electro catalysis in microemulsions, thus connecting aspects of electrode kinetics, adsorption at electrode interfaces, and colloid chemistry."

Covers the broad area of nano-optical spectroscopy from the perspective of putting the concepts and innovations in the field to use Discusses entire spectra of near-field optics and spectroscopy using light Includes dielectric nanophotonics and optical confinement Studies acoustic phonon confinement for analysis of chemical, biological, and other materials Explores gas/chemical sensing using surface plasmon resonance (SPR) in the Kretschmann configuration

This book summarizes recent progress in cellulose chemistry. The last 10 years have witnessed important developments, because sustainability is a major concern. Biodegradable cellulose derivatives, in particular esters and ethers, are employed on a large scale. The recent developments in cellulose chemistry include unconventional methods for the synthesis of derivatives, introduction of novel solvents, e.g. ionic liquids, novel approaches to regioselective derivatization of cellulose, preparation of nano-particles and nano-composites for specific applications. These new developments are discussed comprehensively. This book is aimed at researchers and professionals working on cellulose and its derivatives. It fills an important gap in teaching, because most organic chemistry textbooks concentrate on the relatively simple chemistry of mono- and disaccharides. The chemistry and, more importantly, the applications of cellulose are only concisely mentioned.

Details all recently developed methods for palladium and platinum determination using spectrophotometry in a single source. Organized so that given so that anyone interested in a particular method using a specific reagent can go directly to those details. Facilitates the development of better methods for specific conditions of a sample.

How do you describe an analytical method, measure the purity of the new chemical that you have just synthesized, or report the proper units of measurement? For analytical chemists, the principal tool of the trade, or source of terms, is this book - the so-called Orange Book. First published in 1978, this latest edition takes into account the explosion of new analytical procedures and, at the same time, the diversity of techniques and the quality and performance characteristics of the procedures that are the focus of interest. The scope of analytical chemistry has widened, new types of instrumental techniques have emerged and automation has taken over. Answers can now be shared, not only on the chemical composition and structure of the sample, but also changes in composition and structure in space and time. New chapters on chemometrics, bio-analytical methods of analysis, and sample treatment and preparation have been added. The terminology of metrology and quality assurance is now up to date with the latest ISO and JCGM standards. This new volume will be an indispensable reference resource for the coming decade, revising and updating accepted terminology, and providing the official language of analytical chemistry.

Characterization and Analysis of Microplastics, Volume 75 presents the latest information on new and published analytical methodologies for the identification and quantification of microplastics. This series focuses on a variety of interesting topics surrounding the field of microplastics, with this new release in the series covering sampling and sample handing, the characterization of microplastics by raman spectroscopy, and techniques for assessing the chemical compounds related to microplastics. Users will find a variety of useful information that includes morphological, physical and chemical characterizations, along with analytical techniques and future perspectives of analytical methodologies in this rapidly advancing field.

This book provides a comprehensive review of established, cutting-edge, and future trends in the exponentially growing field of nanomaterials and their applications in biosensors and bioanalyses. Part I focuses on the key principles and transduction approaches, reviewing the timeline featuring the important historical milestones in the development and application of nanomaterials in biosensors and bioanalyses. Part II reviews various architectures used in nanobiosensing designs focusing on nanowires, one- and two-dimensional nanostructures, and plasmonic nanobiosensors with interferometric reflectance imaging. Commonly used nanomaterials, functionalization of the nanomaterials, and development of nanobioelectronics are discussed in detail in Part III with examples from screen-printed electrodes, nanocarbon films, and semiconductor quantum dots. Part IV reviews the current applications of carbon nanotubes, nanoneedles, plasmonic sensors, electrochemical scanning microscopes, and field-effect transistors with the future outlook for emerging technologies. Attention is also given to potential challenges, in particular, of taking these technologies at the point-of-need. The book concludes by providing a condensed summary of the contents, with emphasis on future directions. Nanomaterials have become an essential part of biosensors and bioanalyses in the detection and monitoring of medical, pharmaceutical, and environmental conditions, from cancer to chemical warfare agents. This book, with its distinguished editors and international team of expert contributors, will be an essential guide for all those involved in the research, design, development, and application of nanomaterials in biosensors and bioanalyses.

This volume summarises recent developments and possible future directions for small molecule X-ray crystallography. It reviews specific areas of crystallography which are rapidly developing and places them in a historical context. The interdisciplinary nature of the technique is emphasised throughout. It introduces and describes the chemical crystallographic and synchrotron facilities which have been at the cutting edge of the subject in recent decades. The introduction of new computer-based algorithms has proved to be very influential and stimulated and accelerated the growth of new areas of science. The challenges which will arise from the acquisition of ever larger databases are considered and the potential impact of artificial intelligence techniques stressed. Recent advances in the refinement and analysis of X-ray crystal structures are highlighted. In addition the recent developments in time resolved single crystal X-ray crystallography are discussed. Recent years have demonstrated how this technique has provided important mechanistic information on solid-state reactions and complements information from traditional spectroscopic measurements. The volume highlights how the prospect of being able to routinely "watch" chemical processes as they occur provides an exciting possibility for the future. Recent advances in X-ray sources and detectors that have also contributed to the possibility of dynamic single-crystal X-ray diffraction methods are presented. The coupling of crystallography and quantum chemical calculations provides detailed information about electron distributions in crystals and has resulted in a more detailed understanding of chemical bonding. The volume will be of interest to chemists and crystallographers with an interest in the synthesis, characterisation and physical and catalytic properties of solid-state materials. Postgraduate students entering the field will benefit from a historical introduction to the subject and a description of those techniques which are currently used. Since X-ray crystallography is used so widely in modern chemistry it will serve to alert senior chemists to those developments which will become routine in coming decades. It will also be of interest to the broad community of computational chemists who study chemical systems.

Stability is one of the most important performances required for silver halide photographic materials. In 1935, Dr. E. 1. Birr introduced the concept of the stabilization ofphotographic emulsions for the first time by inventing a most effective stabilizer, 4-oxo-6-methyl-l,3,3a,7-tetraazaindene (TAl). Dr. Birr's monograph Stabilization ofPhotographic Silver Halide Emulsions was published in 1974, and accepted as a reliable reference book by many photographic scientists and engineers. Since then, silver halide photographic materials have been greatly improved and expanded through active and continual development of various kinds of technologies. Especially, extensive efforts have been made to develop photographic materials with high sensitivity and rapid processing, which rely upon the stability ofphotographic emulsions under various conditions. Thus, the concept and technologies of stabilization ofphotographic silver halide materials have been expanded so extensively that many photographic scientists and engineers eagerly want a reliable, new reference book on the stabilization of photographic emulsions. Dr. Gunther Fischer is one of the most experienced and eminent scientists and engineers in the field of the stabilization of photographic materials with expanded concept. He has been involved in research on the stabilization of pho tographic emulsions since 1964 when he joined the Technical Scientific Laboratory in the Research and Development Department of the Photo Film Company Agfa Wolfen formerly headed by Dr. Birr, whom he succeeded in that position. I was deeply impressed by his fruitful and elaborate achievements in these fields."

This book introduces the recent development in Japan of diamond electrodes, which has attracted much attention in the world. For example, electrochemical sensors using diamond electrodes are now being utilized commercially. Newly developing applications such as electrochemical organic synthesis including CO2 reduction are also expected to form an important future technology. Those emerging applications to various fields which are receiving increasing attention are described in detail here. This book is useful not only for students who would like to begin their study of diamond electrodes but also for industries that are exploring novel electrochemical applications.

Olive Mill Waste: Recent Advances for Sustainable Management addresses today's most relevant topics in olive oil industry sustainable management. Emphasizing recent advisable practices, the book explores the potential of reutilizing OMW to power the mill itself, the reuse of OMW as soil amendment, aerobic biological treatment of OMW and compost production, the case study of OMW within the biorefinery concept, the recovery of bioactive compounds from OMW, and their applications in food products and cosmetics. Recent research efforts have concluded that the successful management of OMW focuses on three main routes: (a) reuse of water, (b) reuse of polyphenols, and (c) reuse of nutrients. Following this consideration, the book covers sustainable practices in the olive oil industry, revealing opportunities for reutilizing the water of OMW within the process or as s soil amendment. At the same time, it explores all the possibilities of recovering polyphenols and reutilizing them in target products, such as foods and cosmetics. In addition, the book presents successful cases of industrial OMW valorization through real world experiences.

The book describes the theoretical principles of nonstatistical methods of data analysis but without going deep into complex mathematics. The emphasis is laid on presentation of solved examples of real data either from authors' laboratories or from open literature. The examples cover wide range of applications such as quality assurance and quality control, critical analysis of experimental data, comparison of data samples from various sources, robust linear and nonlinear regression as well as various tasks from financial analysis. The examples are useful primarily for chemical engineers including analytical/quality laboratories in industry, designers of chemical and biological processes. Features: Exclusive title on Mathematical Gnostics with multidisciplinary applications, and specific focus on chemical engineering. Clarifies the role of data space metrics including the right way of aggregation of uncertain data. Brings a new look on the data probability, information, entropy and thermodynamics of data uncertainty. Enables design of probability distributions for all real data samples including smaller ones. Includes data for examples with solutions with exercises in R or Python. The book is aimed for Senior Undergraduate Students, Researchers, and Professionals in Chemical/Process Engineering, Engineering Physics, Stats, Mathematics, Materials, Geotechnical, Civil Engineering, Mining, Sales, Marketing and Service, and Finance.

Resolving Spectral Mixtures: With Applications from Ultrafast Time-Resolved Spectroscopy to Superresolution Imaging offers a comprehensive look into the most important models and frameworks essential to resolving the spectral unmixing problem-from multivariate curve resolution and multi-way analysis to Bayesian positive source separation and nonlinear unmixing. Unravelling total spectral data into the contributions from individual unknown components with limited prior information is a complex problem that has attracted continuous interest for almost four decades. Spectral unmixing is a topic of interest in statistics, chemometrics, signal processing, and image analysis. For decades, researchers from these fields were often unaware of the work in other disciplines due to their different scientific and technical backgrounds and interest in different objects or samples. This led to the development of quite different approaches to solving the same problem. This multi-authored book will bridge the gap between disciplines with contributions from a number of well-known and strongly active chemometric and signal processing research groups. Among chemists, multivariate curve resolution methods are preferred to extract information about the nature, amount, and location in time (process) and space (imaging and microscopy) of chemical constituents in complex samples. In signal processing, assumptions are usually around statistical independence of the extracted components. However, the chapters include the complexity of the spectral data to be unmixed as well as dimensionality and size of the data sets. Advanced spectroscopy is the key thread linking the different chapters. Applications cover a large part of the electromagnetic spectrum. Time-resolution ranges from femtosecond to second in process spectroscopy and spatial resolution covers the submicronic to macroscopic scale in hyperspectral imaging.

Shale oil and gas have altered the energy landscape, possibly permanently. They burst upon the fossil energy scene with a suddenness that initially defied prediction. Even the political balance of the world has changed. But, with the methods employed, the vast majority of the oil and gas remains in the ground. At the same time, serious environmental impact issues have been raised. A new volume in the Emerging Issues in Analytical Chemistry series, Sustainable Shale Oil and Gas: Analytical Chemistry, Geochemistry, and Biochemistry Methods was written on the premise that analytical methods to inform these areas were wanting. While not attempting to be comprehensive, it describes important analytical methods, some still in development. These methods are underpinned primarily by chemistry, but geochemistry and even biochemistry play significant roles. The book has a solutions flavor; problems are posed together with approaches to ameliorate them.

This is an expanded and revised second edition, presenting accurate and comprehensive information about our leading thermal scientists to current and future generations. In our globalized world, most researchers in thermal analysis do not know each other in person and are not familiar with each other's achievements. This volume provides the reader with an up-to-date list of the prominent members in this community. The publication contains only living scientists. The selection is based partly on several decades of the editors' personal professional experience and also partly on the opinion of the Regional Editors of the Journal of Thermal Analysis and Calorimetry.

This book presents the reader with a story-based narrative of discovery and development of radiation-induced graft polymerization. The report presented here accomplishes this by relating the inspiring account of research and development based on long-term collaboration among a professor, an engineer, and an entrepreneur. Their goal, ultimately successful, was to come up with a method for grafting functional polymer chains onto existing trunk polymers. The desired outcome was to produce feasible forms for practical use as adsorbents such as porous hollow-fiber membranes, porous sheets, nonwoven fabrics, and fibers. Adsorbents that specifically and efficiently bind to target ions and molecules are essential for capturing uranium species in seawater and antibody drugs in biological fluids and for removing metal ions from ultrapure water and radioactive cesium ions from contaminated water. This unique volume, with its clearly written text and many illustrative figures and diagrams, demonstrates the advantages of the high-adsorption capacity and rate and the easy handling of new polymeric adsorbents over conventional adsorbents. The dynamic behavior of graft chains as described here is certain to appeal especially to chemists, physicists, and material scientists as well as to other readers with an interest in this valuable subject.

High-pressure Molecular Spectroscopy describes examples of the applications of several spectroscopic methods to investigate the behavior of various chemical systems under high pressures, including guest-host interactions, chemical reactions, molecule-based multiferroics, lanthanide ion-doped glasses, and organic, inorganic and organometallic materials. The techniques involved include: Luminescence studies Inelastic neutron scattering Infrared and Raman studies Synchrotron X-ray diffraction

In this unique textbook and reference source, the authors integrate theoretical and applied research from a host of disciplines, including materials science, plasma physics, and advanced transport phenomena. Volume 1, the first of two, covers the fundamentals of plasma physics and gaseous electronics, thermodynamics, and transport properties of plasma.

Polycyclic aromatic hydrocarbons (PAHs) are the first type of chemicals that were ever discovered to cause cancer in humans. They are found in cigarette smoke, in barbecued and smoked foods, in automobile and Diesel engine exhaust, fireplace smoke, and many other common things that people are exposed to. Analyzing for PAHs in the environment is important in identifying potential sources of cancer exposure and eliminating these as risks. The smaller PAHs, those of lower than 300 molecular weight, have been the most studied and have also been covered in several books. No books have dealt with the analysis of the larger PAHs. These compounds are not only important for the health concerns, but they are also of current technological and scientific interest.

The Quality of Air discusses the topic from both the environmental and human health points-of-view. As today's policymakers, academic, government, industrial researchers, and the general public are all concerned about air pollution in both indoor and outdoor scenarios, this book presents the advances in the analytical tools available for air quality control within social, political, and legal frameworks. With its multi-author approach, there is a wide range of expertise in tackling the topic.

This book describes the importance of heat transfer in heat exchangers, and fluids properties play a vital role to increase heat transfer rate translating the size of the equipment and cuts in the capital and running cost in the long term. Nanofluids applications in heat exchangers will help to improve the thermophysical properties of the fluid and therefore heat transfer. And, this book explains the enhancing mechanisms of heat transfer by employing nanofluids in heat exchangers. A critical discussion will enable to estimate the pros and cons of such fluids in different types of heat exchangers. Prevailing working conditions for short- and long-term implementation of various types of nanofluids will be discussed and introduced to the readers. This book helps the researchers, scientist and academicians working in the domain to be able to get a comprehensive knowledge at one place regarding the preparation, properties, measurements, data reduction, characteristics and applications of nanofluids in heat exchangers.

Provides clear instructions and step-by-step exercises to make learning the material easier for students. Emphasizes fundamental laboratory skills which prepare a student for the industry. Builds students' skills through an organized and systematic presentation of materials, procedures, and tasks. Updates reflect recent innovations and regulatory requirements to ensure students stay up to date. Supplies skills suitable for careers in forensic, clinical, quality control, environmental, and other testing laboratories.

A comprehensive review of the latest fingerprint development and imaging techniques With contributions from leading experts in the field, Fingerprint Development Techniques offers a comprehensive review of the key techniques used in the development and imaging of fingerprints. It includes a review of the properties of fingerprints, the surfaces that fingerprints are deposited on, and the interactions that can occur between fingerprints, surfaces and environments. Comprehensive in scope, the text explores the history of each process, the theory behind the way fingerprints are either developed or imaged, and information about the role of each of the chemical constituents in recommended formulations. The authors explain the methodology employed for carrying out comparisons of effectiveness of various development techniques that clearly demonstrate how to select the most effective approaches. The text also explores how techniques can be used in sequence and with techniques for recovering other forms of forensic evidence. In addition, the book offers a guide for the selection of fingerprint development techniques and includes information on the influence of surface contamination and exposure conditions. This important resource: Provides clear methodologies for conducting comparisons of fingerprint development technique effectiveness Contains in-depth assessment of fingerprint constituents and how they are utilized by development and imaging processes Includes background information on fingerprint chemistry Offers a comprehensive history, the theory, and the applications for a broader range of processes, including the roles of each constituent in reagent formulations Fingerprint Development Techniques offers a comprehensive guide to fingerprint development and imaging, building on much of the previously unpublished research of the Home Office Centre for Applied Science and Technology.

Regarded as a seminal work in chemometrics, Information Theory as Applied to Chemical Analysis by Karel Eckscklager and Vladimir Stepanek shed light on the importance of information theory, stressing that the very mechanisms of information gathering are key to the quality of the analytical data collected. Continuing that examination, this new volume, Information Theory in Analytical Chemistry, looks at the practical applications of information theory, especially as a tool for optimizing chemical analysis. Complete with up-to-date examples from diverse areas such as toxicology, environmental science, and metallurgy, the book provides a workable framework for developing, optimizing, and assessing analytical procedures. Layer by layer, the analytical process is dismantled - and reassembled - so the reader develops a genuine, practice-oriented grasp of just how information theory shapes the chemical analysis process. Beginning with the fundamentals of information theory and analytical chemistry, the book then considers the systemic nature of chemical analysis, examining each of its facets: identification of components, trace analysis, qualitative analysis, quantitative analysis, multicomponent analysis, microanalysis, and surface or structure analysis. Up-to-date, detailed discussion includes: identification of an individual component or a group of compounds; effect of a priori knowledge of the sample on the information gain of the result; importance of calibration methods and reference material and their net effect on the precision and accuracy of results; choice of the optimum analytical method, criteria of selection; quality control, external and internal quality assurance; chemicalhomogeneity testing. Particularly important in trace and multivariate analysis, the book also sheds light on the information content inherent in analytical instrumentation, contrasting it with the true information gains of the analysis. Essential to understanding the individual steps of analytical process, this distinction allows for better evaluation and optimization of each step, including calibration and signal processing. The book also assesses the information contribution of key chemometric methods, such as cluster analysis, pattern recognition, and factorial data analysis, useful in multivariate or multicomponent analysis. This discussion, in turn, provides insight into the true character of multivariate data analysis, revealing it as not simply a string of single-component analyses done simultaneously, but rather a fragile, potentially bias-ridden mechanism with unique interpretive potential of its own. Complete with tables, diagrams, and examples, Information Theory in Analytical Chemistry is a practical handbook of enhanced analytical techniques that can sharply improve the quality of data collection as well as a user's understanding of the significance of information theory in each step of the entire chemical analysis process.