This book provides the latest technical information on sustainable materials that are feedstocks for additive manufacturing (AM). Topics covered include an up-to-date and extensive overview of raw materials, their chemistry, and functional properties of their commercial versions; a description of the relevant AM processes, products, applications, advantages, and limitations; prices and market data; and a forecast of sustainable materials used in AM, their properties, and applications in the near future. Data included are relative to current commercial products and are presented in easy-to-read tables and charts. Features Highlights up-to-date information and data of actual commercial materials Offers a broad survey of state-of the-art information Forecasts future materials, applications, and areas of R&D Contains simple language, explains technical terms, and minimizes technical lingo Includes over 200 tables, nearly 200 figures, and more than 1,700 references to technical publications, mostly very recent Handbook of Sustainable Polymers for Additive Manufacturing appeals to a diverse audience of students and academic, technical, and business professionals in the fields of materials science and mechanical, chemical, and manufacturing engineering.

A guide to designing safer polymers based on the principles of green chemistry and the EPA’s Polymer Exemption Rule

Green chemistry, the design of chemical products and processes that reduce or eliminate the use and generation of hazardous substances, is a powerful tool in designing safer polymers. By adhering to the principles of green chemistry, manufacturers can produce polymers that are better for the environment, and can do so in an economically sound manner.

The Polymer Exemption Rule delineates types of polymers that are expected to be of reduced risk. By following the guidelines contained within the Polymer Exemption Rule, manufacturers may decrease their regulatory requirements while designing polymers that are environmentally benign.

This valuable guide approaches the manufacture of polymers from two perspectives, incorporating the principles of green chemistry with the guidance of the Polymer Exemption Rule to design environmentally benign polymers. Designing Safer Polymers is an indispensable working resource for polymer scientists and engineers, as well as corporate decision makers working in the polymer and chemical industries.

This book provides a definitive source of information on the chemical reaction engineering aspects of polymer production processes. Recent reviews in the USA by the Chemical Society and the Institute of Chemical Engineers have concluded that polymers will continue to grow in importance as they are tailored to suit specific applications. This book focuses on engineering aspects of reactor design and operation and, in particular, how the properties of polymers are determined by the relationships between chemical kinetics and mechanical design. This book should be of interest to chemical engineers who need to understand reaction engineering concepts and techniques for polymer systems as well as advanced students of polymer science and engineering, materials science and chemistry.

"Handbook of Thermoplastic Elastomers, Second Edition" presents a comprehensive working knowledge of thermoplastic elastomers (TPEs), providing an essential introduction for those learning the basics, but also detailed engineering data and best practice guidance for those already involved in polymerization, processing, and part manufacture.

TPEs use short, cost-effective production cycles, with reduced energy consumption compared to other polymers, and are used in a range of industries including automotive, medical, construction and many more. This handbook provides all the practical information engineers need to successfully utilize this material group in their products, as well as the required knowledge to thoroughly ground themselves in the fundamental chemistry of TPEs. The data tables included in this book assist engineers and scientists in both selecting and processing the materials for a given product or application.

In the second edition of this handbook, all chapters have been reviewed and updated. New polymers and applications have been added- particularly in the growing automotive and medical fields - and changes in chemistry and processing technology are covered.
Provides essential knowledge of the chemistry, processing, properties, and applications for both new and established technical professionals in any industry utilizing TPEsDatasheets provide "at-a-glance" processing and technical information for a wide range of commercial TPEs and compounds, saving readers the need to contact suppliersIncludes data on additional materials and applications, particularly in automotive and medical industries"

Covers principles of Ionic Polymer Metal Composites (IPMC), manufacturing processes, applications and future possibilities in a systematic manner Highlights IPMC practical applicability in biomedical engineering domain Explores single-walled carbon nanotubes (SWNT) based IPMC soft actuators Discusses IPMC applications in underwater areas Includes IPMC application in robotics focussing on special compliant mechanism

Conducting polymers are versatile materials that possess both the unique properties of polymeric materials (elastic behavior, reversible deformation, flexibility, etc.) and the ability to conduct electricity with bulk conductivities comparable to those of metals and semiconductors. Conducting Polymers: Chemistries, Properties and Biomedical Applications provides current, state-of-the-art knowledge of conducting polymers and their composites for biomedical applications. This book covers the fundamentals of conducting polymers, strategies to modify the structure of conducting polymers to make them biocompatible, and their applications in various biomedical areas such as drug/gene delivery, tissue engineering, antimicrobial activities, biosensors, etc. FEATURES Covers the state-of-the-art progress on biodegradable conducting polymers for biomedical applications Presents synthesis, characterization, and applications of conducting polymers for various biomedical research Provides the fundamentals of biodegradation mechanisms and the role of conduction in biomedical devices Offers details of novel methods and advanced technologies used in biomedical applications using conducting polymers Highlights new directions for scientists, researchers, and students to better understand the chemistry, technologies, and applications of conducting polymers This book is essential reading for all academic and industrial researchers working in the fields of materials science, polymers, nanotechnology, and biomedical technology.

Fiber-reinforced polymer composites exhibit better damping characteristics than conventional metals due to the viscoelastic nature of the polymers. There has been a growing interest among research communities and industries in the use of natural fibers as reinforcements in structural and semi-structural applications, given their environmental advantages. Knowledge of the vibration and damping behavior of biocomposites is essential for engineers and scientists who work in the field of composite materials. Vibration and Damping Behavior of Biocomposites brings together the latest research developments in vibration and viscoelastic behavior of composites filled with different natural fibers. Features: Reviews the effect of various types of reinforcements on free vibration behavior Emphasizes aging effects, influence of compatibilizers, and hybrid fiber reinforcement Explores the influence of resin type on viscoelastic properties Covers the use of computational modeling to analyze dynamic behavior and viscoelastic properties Discusses viscoelastic damping characterization through dynamic mechanical analysis. This compilation will greatly benefit academics, researchers, advanced students, and practicing engineers in materials and mechanical engineering and related fields who work with biocomposites. Editors Dr. Senthil Muthu Kumar Thiagamani, Kalasalinagam Academy of Research and Education (KARE), India Dr. Md Enamul Hoque, Military Institute of Science and Technology (MIST), Bangladesh Dr. Senthilkumar Krishnasamy, King Mongkut's University of Technology North Bangkok KMUTNB, Thailand Dr. Chandrasekar Muthukumar, Hindustan Institute of Technology & Science (HITS), India Dr. Suchart Siengchin, King Mongkut's University of Technology North Bangkok KMUTNB, Thailand

Biopolymers are attracting immense attention of late because of their diverse applications that can address growing environmental concerns and energy demands. The development of various biomaterials creates significant advancements in the medical field as well, and many biopolymers are used for the fabrication of biomaterials. Together, biopolymers and biomaterials create great potential for new materials, applications, and uses. This new volume, Biopolymers and Biomaterials, covers the science and application of biopolymers and biomaterials. It presents an array of different studies on biopolymers and biomaterials, along with their results, interpretation, and the conclusions arrived at through investigations. It includes biopolymer synthesis, their characterizations, and their potential applications. The book begins with an explanation of the different biopolymers used in the textile industry, their advantages and disadvantages, and their applications.

This informative volume discusses recent advancements in the research and development in synthesis, characterization, processing, morphology, structure, and properties of advanced polymeric materials. With contributions from leading international researchers and professors in academic, government and industrial institutions, Advanced Polymeric Materials for Sustainability and Innovations has a special focus on eco-friendly polymers, polymer composites, nanocomposites, and blends and materials for traditional and renewable energy. In this book the relationship between processing-morphology-property applications of polymeric materials is well established. Recent advances in the synthesis of new functional monomers has shown strong potential in generating better property polymers from renewable resources. Fundamental advances in the field of nanocomposite blends and nanostructured polymeric materials in automotive, civil, biomedical and packaging/coating applications are the highlights of this book.

This volume highlights the latest developments and trends in advanced polyblends and their structures. It presents the developments of advanced polyblends and respective tools to characterize and predict the material properties and behavior. The book provides important original and theoretical experimental results that use non-routine methodologies often unfamiliar to many readers. Furthermore chapters on novel applications of more familiar experimental techniques and analyses of composite problems are included, which indicate the need for the new experimental approaches that are presented. Technical and technological development demands the creation of new materials that are stronger, more reliable, and more durable-materials with new properties. Up-to-date projects in creation of new materials go along the way of nanotechnology. With contributions from experts from both the industry and academia, this book presents the latest developments in the identified areas. This book incorporates appropriate case studies, explanatory notes, and schematics for more clarity and better understanding. The book is designed as a textbook for postgraduate students, as a teaching support for the faculty, as a reference book for early research career beginners, and as a reference book for the scientific community at large for understanding the significance of modern materials and chemical engineering. This book will be useful for chemists, chemical engineers, technologists, and students interested in advanced nano-polymers with complex behavior and their applications This new book: * Gives an up-to-date and thorough exposition of the present state of the art of polyblends and composites * Familiarizes the reader with new aspects of the techniques used in the examination of polymers, including chemical, physicochemical, and purely physical methods of examination * Describes the types of techniques now available to the polymer chemist and technician and discusses their capabilities, limitations, and applications * Provides a balance between materials science and mechanics aspects, basic and applied research, and high-technology and high-volume (low-cost) composite development

This book focuses on the recent trends in micro- and nano-structured polymer systems, particularly natural polymers, biopolymers, biomaterials, and their composites, blends, and IPNs. This valuable volume covers the occurrence, synthesis, isolation, production, properties and applications, modification, as well as the relevant analysis techniques to reveal the structures and properties of polymer systems. Biobased polymer blends and composites occupy a unique position in the dynamic world of new biomaterials. The growing need for lubricious coatings and surfaces in medical devices-an outcome of the move from invasive to noninvasive medicines and procedures-is playing a major role in the advancement of biomaterials technology. Natural polymers have attained their cutting-edge technology through various platforms, and this book presents a multitude of information about them. Topics include biopolymer-synthetic systems, nanomaterial-polymer structures, multi-characterization techniques, polymer blends and composites, polymer gels and polyelectrolytes, and many other interesting aspects of interests to researchers. This book will be valuable to scientists, physicians, pharmacists, engineers, and other specialists in a variety of disciplines, both academic and industrial.

This new volume explores the latest research on the use of alginate as a biopolymer in various biomedical applications and therapeutics. The uses of alginates and modified alginates discussed in this book include tissue regeneration, encapsulation and delivery of drugs, nucleic acid materials, proteins and peptides, genes, herbal therapeutic agents, nutraceuticals, and more. This book also describes the synthesis and characterizations of various alginate and modified alginate systems, such as hydrogels, gels, composites, nanoparticles, scaffolds, etc., used for the biomedical applications and therapeutics. Alginate, a biopolymer of natural origin, is of immense interest for its variety of applications in pharmaceuticals (as medical diagnostic aids) and in materials science. It is the one of the most abundant natural biopolymers and is considered an excellent excipient because of its non-toxic, stable, and biodegradable properties. Several research innovations have been made on applications of alginate in drug delivery and biomedicines. There needs to be a thorough understanding of the synthesis, purification, and characterization of alginates and its derivatives for their utility in healthcare fields, and this volume offers an abundance of information toward that end.

Natural Fiber Textile Composite Engineering sheds light on the area of the natural fiber textile composites with new research on their applications, the material used, the methods of preparation, the different types of polymers, the selection of raw materials, the elements of design the natural fiber textile polymer composites for a particular end use, their manufacturing techniques, and finally their life cycle assessments (LCA). The volume also addresses the important issue in the materials science of how to utilize natural fibers as an enhancement to composite materials. Natural fiber-reinforced polymer composites have been proven to provide a combination of superior mechanical property, dielectric property, and environmental advantages such as renewability and biodegradability. Natural fibers, some from agricultural waste products, can replace existing metallic and plastic parts and help to alleviate the environmental problem of increasing amounts of agriculture residual. The book is divided into four sections, covering: applications of natural fiber polymer composites design of natural fiber polymer composites composite manufacturing techniques and agriculture waste manufacturing composite material testing methods The first section of the book deals with the application of textile composites in the industry and the properties of the natural fibers, providing an understanding of the history of natural fiber composites as well as an analysis of the different properties of different natural fibers. The second section goes on to explain the textile composites, their classification, different composite manufacturing techniques, and the different pretreatment methods for the natural fibers to be used in composite formation. It also analyzes the composite material design under different types of loading and the mechanism of failure of the natural fiber composite. The effect of the fiber volume fraction of different textile structures is explained. The third section of the book, on composite manufacturing techniques and agriculture waste manufacturing, concerns the natural fiber composite manufacturing techniques, agricultural waste, and the methods of their preparation to be used successfully in the composite, either in the form of fibers particles or nanoparticles. The book then considers the testing methods of the different composite components as well as the final composite materials, giving the principle of the testing standards, either distractive or nondestructive. This book attempts to fill the gap between the role of the textile engineer and the role of the designer of composites from natural fibers. It provides important information on the application of textile composites for textile engineers, materials engineers, and researchers in the area of composite materials.

Scientists and researchers are looking for new smart materials to replace old or conventional materials for better performance and for new applications. The use of polymeric materials and nanomaterials is increasing due to their wide-spectrum tunability and many properties. It is now easier to formulate materials for special purposes using these materials than using conventional materials and methods. Many commercial products made from polymeric materials and nanomaterials are now in use and on the market. This book presents a diverse selection of cutting-edge research on the development of polymeric materials and nanomaterials for new and different applications. These include electrical applications, biomedical applications, sensing applications, coating applications, and others. A few chapters dedicated to materials for construction applications are also included. Discussions include the properties, behavior, preparation, processing, and characterization of various polymeric materials, nanomaterials, and their composites. Some of the chapter authors present theoretical studies of these systems, which can help readers to develop a better understanding in this area.

With chapters by the editors and other experts in the field of polymer science, this book covers a broad selection of important research advances in the field, including updates on enzymatic destruction and photoelectric characteristics, studies on the changes in the polymer molecular mass during hydrolysis and a new type of bioadditive for motor fuel, and an exploration of the interrelation of viscoelastic and electromagnetic properties of densely cross-linked polymers. Also included are chapters that discuss the problems of mechanics of textile performance, new aspects of polymeric nanofibers, a mathematical model of nanofragment cross-linked polymers, and much more.

This book presents some fascinating phenomena associated with the remarkable features of high performance polymers and also provides an update on applications of modern polymers. It offers new research on structure-property relationships, synthesis and purification, and potential applications of high performance polymers. The collection of topics in this book reflects the diversity of recent advances in modern polymers with a broad perspective that will be useful for scientists as well as for graduate students and engineers. The book opens with a presentation of classical models, moving on to increasingly more complex quantum mechanical and dynamical theories. Coverage and examples are drawn from modern polymers. Topics include high performance polymers and computer science integration in biochemical, green polymers, molecular nanotechnology, and industrial chemistry.

Engineering design teams sometimes have need of a material that may not exist because the combination of required properties is difficult to achieve. One solution is to develop a new material having the required set of properties needed in the application. During the author's 40-year career he has successfully worked on many such problems. The uniquely useful and valuable book, Polymeric Thermosetting Compounds: Innovative Aspects of Their Formulation Technology, presents twenty of those design problems and the solutions, which resulted in patents and spin-off applications. Author Ralph Hermansen, with years of experience of hands-on experience, is an expert in formulating epoxies, polyurethanes, and other polymers into compounds that have unique properties, and here he shares his knowledge and experience of attaining novel solutions to very challenging problems. He covers polymeric compounds such as coatings, adhesives, encapsulants, transparent plastics, and others. Chapters describe the design problem and define which key properties are sought in the new material. The author shares his thinking about how to approach the formulating problem and describes the experimental procedures used to eventually solve the problem. Patent information is shared as well. Once a new family of polymeric compounds is developed, that technology can be used to attack new unsolved materials problems, or "spin-offs," and real-life examples are provided to help readers see new applications of the technologies described in the earlier chapters. The book will be of interest to a diverse group of people. Industry professionals already in the business of selling specialty compounds may be able to add new products to their catalogs with little research cost or time by using the information in the book. Formulators, trying to develop a new compound to challenging requirements, may gain insight into how to make a breakthrough. The information in the book will be very valuable to companies needing these novel solutions. And younger people wondering what a career in materials science would be like get a first-hand commentary from someone who has done it.

Much data has been collected from experiments on the kinetios of radical reactions in different solids, but to date, this has not been presented in book format in a thorough and comprehensive way. This book makes the experimental data accessible for all chemists involved in these reactions. Various models of the tunnel atom transfer are analyzed in order to explain the kinetic isotope effect in solid phase reactions and photoinitiated radical reactions are inspected for the kinetic non-equivalence of particles and factors affecting their reactivity. Topics covered include:
* kinetic description of reactions with dispersion particles in reactivity
* the influence of space-orientation factors on reactivity in cage reactions
* the influence of molecular dynamics on the kinetics of elementary reactions
* the effect of structural-physical modification on kinetics of cage radical reactions

Biopolymers represent a carbon emission solution: they are green and eco-friendly with a variety of uses in biomedical engineering, the automotive industry, the packaging and paper industries, and for the development of new building materials. This book describes the various raw materials of biopolymers and their chemical and physical properties, the polymerization process, and the chemical structure and properties of biopolymers. Furthermore, this book identifies the drawbacks of biopolymers and how to overcome them through modification methods to enhance the compatibility, flexibility, physicochemical properties, thermal stability, impact response, and rigidity.

Shape memory materials are immensely useful because of their capability to recover their original shapes upon exposure to an external stimulus such as heat, moisture, light or a magnetic field. This book reviews key recent research in shape memory polymers, their properties and applications. Topics include the relationship between morphological structures and shape memory properties; high performance Tg and Tm type shape memory polymers; structures of shape memory polymers with supramolecular switches; and the thermally-active and moisture-active shape memory effect of supermolecular shape memory polymers.
Advances in shape memory polymers is an essential reference for polymer and textile material students, scientists, designers, engineers and manufacturers. It is also an invaluable guide for professionals in the biomedical, electronics and engineering industries.
Reviews key recent research in shape-memory polymers, their properties and applicationsOpening chapters address the relationship between morphological structures and shape memory properties and high performance Tg and Tm type shape memory polymersChapters cover thermally-active and moisture-active shape memory effect of supermolecular shape memory polymers, among other topics

This reference guide brings together a wide range of essential data on the effect of long term thermal exposure on plastics and elastomers, enabling engineers to make optimal material choices and design decisions. The data is supported by explanations of how to make use of the data in real-world engineering contexts.

High heat environments are common in automotive, oil and gas, household appliances, coatings, space and aeronautics and many more end uses. As a result, thermal stability data are critically important to engineers designing parts particularly that replace metals, work that is common today as they look for ways to reduce weight. The data tables in this book enable engineers and scientists to select the right materials for a given product or application across a wide range of sectors.

Several polymer classes are covered, including polyolefins, polyamides, polyesters, elastomers, fluoropolymers, biodegradable plastics and more, saving readers the need to contact suppliers. The book also includes introductory sections to provide background on plastic/polymer chemistry and formulation and plastic testing methods, providing the knowledge required to make best use of the data.
Essential data and practical guidance for engineers and scientists working with plastics for use in high temperature environmentsIncludes introductory chapters on polymer chemistry and its effect on thermal stability, providing the underpinning knowledge required to utilize the dataCovers a wide range of commercial polymer classes, saving readers the need to contact suppliers

The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid ate the complex chemistry that leads to the formation of the antioxidant -active agents.

Chitin is the second most abundant natural polymer in the world after cellulose, mainly derived from the food waste of shrimp and crabs. Chitosan is the most important derivative of chitin. Thanks to their biodegradability, non-toxicity, biocompatibility, bioactivity, and versatile chemical and physical properties, chitin and chitosan derivatives are used in a wide variety of applications, including water treatment, cosmetics and toiletries, food and beverages, healthcare/medical, and agrochemicals. Chitin and Chitosans in the Bioeconomy covers all major aspects of chitin and chitosan, including structure, biosynthesis, biodegradation, properties of chitin and derivatives, applications, and market. It offers a special focus on the bioeconomy, which is the renewable segment of the circular economy. Describes the structure, biosynthesis, and biodegradation of chitin and chitosan Covers chitin- and chitosan-based products Details valorization of these materials Presents information on shell biorefineries Chitin and Chitosans in the Bioeconomy serves as a reference for polymer scientists and engineers and is also accessible to economists and advanced students.

Mineral-filled polymer composites are increasingly used for various applications, including automotive, construction, biomedical, maritime, sport and ballistic, due to the advantages of low cost, light weight, excellent rigidity and high mechanical strength. One of two volumes comprising the Mineral-Filled Polymer Composites Handbook, this volume provides an overview of the latest research, trends, applications and future directions of advanced mineral fiber-reinforced polymer composites. It focuses specifically on material selection, processing and applications. This book: Emphasizes the principles governing the behavior of mineral-filled composite materials in the field of engineering and their applications Covers systematic material selection tools such as analytical hierarchy process (AHP), analytical network process (ANP), and technique of ranking preferences by similarity of the ideal solution (TOPSIS) Reviews the use of these materials for various engineering applications Features chapters looking at fabrication techniques and frictional properties Details current research in polymer nanocomposites and particulate polymer composites This book serves as an excellent reference guide for researchers, advanced students, academics and industry professionals interested in the synthesis of mineral-filled polymer and biopolymer composites, as well as those pursuing research in the broad fields of composite materials, polymers, organic/inorganic hybrid materials and nano-assembly.