This book deals with the new and now-expanding field of friction, wear, and other surface-related mechanical phenomena for polymers. Polymers have been used in various forms such as bulk, films, and composites in applications where their friction, wear resistance, and other surface-related properties have been effectively utilized. There are also many examples in which polymers have performed extremely well, such as in tyres, shoes, brakes, gears, bearings, small moving parts in electronics and MEMS, cosmetics/hair products, and artificial human joints. Around the world, much research is currently being undertaken to develop new polymers, in different forms, for further enhancing tribological performance and for finding novel applications. Keeping in view the importance of tribology of polymers for research and technology as well as the vast literature that is now available in research papers and review articles, this timely book brings together a wealth of research data for an understanding of the basic principles of the subject.

Globally, fire retardants are needed to satisfy a multibillion dollar market. Fire retardancy of polymeric materials is an important component of fire safety. Fire retardants either reduce the likelihood of ignition and/or reduce the rate of flame spread and hence, escalation of fire. The need to comply with safety legislations forces industry to use fire retardants in materials in order to save lives. With growing consumer demands and new legislations, the development of new systems is an on-going process, which also involves understanding their mechanisms of action. This book covers the latest developments in fire retardant strategies including: " new fire retardant systems (including nanoparticulate fillers, sometimes combined with conventional fire retardants) " intumescent formulations and their recent applications in bulk polymers, fibres and textiles " test-methods for material flammability " material-specific aspects of combustion, smoke and toxicity. Fire retardant strategies covered, include the use of synergistic combinations of alumina with organoclay, organophosphorus compunds, silica and organosilicones, clay-phosphate combinations and a novel tecnhique for investigating fire rerardant behaviour. The section on nanoparticulate fillers includes an investigation on the effect of filler shape, the use of carbon nanofibres and nanotubes, the interpretation of nanocomposite behaviour in the cone calorimeter, and groundbreaking new research on the influence of rheological properties on burning behaviour. The coverage of fibres and textiles includes a discussion on trends in textile fire retardancy and flammability regulations, and some novel halogen-free approaches to fire retardancy of cellulose, acrylic and polypropylene textiles. Finally, the influence of fire retardants on fire toxicity is discussed in detail, followed by an investigation of the toxic products from burning fire retarded polymer nanocomposites. This book will update fire retardant materials' developers with latest in research and design of new fire retardant materials. It will also provide a snapshot of the state-of-the-art for a range of other groups including environmentalists looking for alternatives to brominated flame retardants and engineers needing to use fire safe materials in their projects.

This book focuses on exciting new research in polymer science. The first section of the book deals with new advancements in polymer technology, which includes polymers that are responsible for progress in the field of energy, electronics, and medical sciences. It focuses on the most promising polymer nanocomposites and nanomaterials. Composites are becoming more important because they can help to improve quality of life. The second section of the book highlights this aspect of macromolecules, while the third section emphasizes biopolymers, their development, and applications.

Elastomer-Based Composite Materials: Mechanical, Dynamic, and Microwave Properties and Engineering Applications is focused on elastomer-based composite materials comprising different types of reinforcing fillers. The book provides an informative examination of the possibilities for broadening the engineering applications of elastomer composites through using various types of hybrid fillers, ferrites, and ceramics, and also examines their synthesis and characterization. It discusses new hybrid fillers that have been synthesized by different techniques, e.g. impregnation of different substrates (carbon black, conductive carbon black, activated carbons, etc.) with silica or magnetite. These new fillers have been thoroughly characterized by standard techniques and by up-to-date methods, such as energy dispersive X-ray spectroscopy in scanning transmission electron microscopy (STEM-EDX), atomic absorption spectroscopy (AAS), and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The effect of those fillers upon the curing properties, mechanical and dynamic parameters, electrical conductivity, and dielectric and microwave characteristics of elastomer-based composites is discussed in detail in this volume. The book also covers the influence of various types of ceramics (SiC, B4C, and TiB2) and barium and strontium hexaferrites upon the aforementioned properties of rubber composites in conjunction with a view toward solutions for environmental problems caused by waste tires. The book shows that pyrolysis-cum-water vapor is a suitable and environmentally friendly method for the conversion of the waste green tires into useful carbon-silica hybrid fillers. The properties of elastomer-based composites comprising different types of nanostructures (fullerenes, carbon nanotubes, graphene nanoplatelets), modified activated carbons, and calcined kaolin are also discussed. Special attention is paid to composites with lower levels of zinc oxide. The volume provides an abundance of knowledge on the detailed characterization of these fillers and on the curing, mechanical, dynamic mechanical, and dielectric and microwave properties of the elastomeric composites. The book surveys the most recent research activities of the authors, which will make it a vital reference source for scientists in both the academic and industrial sectors, as well as for individuals who are interested in rubber materials. It will be very useful for students, especially PhD students, scientists, lecturers, and engineers working or doing research in the field of polymer materials science, elastomer-based composites and nanocomposites and their engineering applications in the production of microwave absorbers and electromagnetic waves shielding materials, materials for electronics devices and telecommunications.

Awarded the 2009 Olle Prize! The field of coordination polymer research has undergone rapid expansion in recent years. No longer are these materials the vaguely defined 'insoluble material' at the bottom of your vessel that spell death for your reaction. They have gone from 'polymeric rubbish' to 'materials of the future'. Great leaps in the deliberate design of coordination polymers were made in the 1990s. These were allied with similar advances in related areas such as organic crystal engineering, metallosupramolecular chemistry and X-ray diffraction. No longer did we assemble things atom by atom. Whole molecules were used as building blocks and new materials were made. This is the first book to provide a broad overview of all the major facets of coordination polymer research in one place. It combines chapters on nets and interpenetration with wide-ranging surveys of transition metal and lanthanoid coordination polymers and their properties. The aim is to provide a flavour of each aspect whilst introducing the important concepts and developments using carefully selected examples. After an introduction, the text is split into three sections: -Design (nets, interpenetration, malleability) -Analysis (transition metal coordination polymers, lanthanoid coordination polymers, organometallic networks, organic-inorganic hybrids) -Application (magnetic properties, porosity, acentric and chiral networks, reactive coordination polymers, other properties). Written in the style of a tutorial review, the book is suitable for both senior specialists and new postgraduate students taking their first steps in the field. It also provides an authoritative and detailed reference source.

Derived from the fourth edition of the well-known "Plastics Technology Handbook," Industrial Polymers, Specialty Polymers, and Their Applications covers a wide range of general and special types of polymers, along with a wealth of information about their applications.

The book first focuses on commonly used industrial polymers, including polypropylenes, low- and high-density polyethylenes, and poly(vinyl chloride), as well as less widely used polymer types, such as acrylics, ether polymers, cellulosics, sulfide polymers, silicones, polysulfones, polyether ether ketones, and polybenzimidazoles. It then explores polymer derivatives and polymeric combinations that play special and often critical roles in diverse fields of human activities. The polymers covered include liquid crystal, electroactive, ionic, and shape memory polymers; hydrogels; and nanocomposites. The volume concludes with a comprehensive overview of new developments in the use of polymers in a variety of areas.

Scientific principles of design and fabrication of packaging materials for food purposes are described in this book, as well as methods for structural modification and other techniques. The main practical properties and applications of polymer materials are described. Great attention is paid to the analysis of all processes taking place during formations and destruction of polymer packaging materials. Methods such as electron microscopy, infrared microscopy and optical polarization were used to describe the behaviour of polymer materials and their composition.

Derived from the fourth edition of the well-known "Plastics Technology Handbook," Plastics Fundamentals, Properties, and Testing covers the behavior, characterization, and evaluation of polymers. With a lucid approach and wealth of valuable information, this volume looks at the remarkable versatility of this nonmetallic class of materials.

Examining polymers at the molecular level, the book first discusses their inherent properties and how their end-use properties can be influenced through changes in the molecular architecture or incorporation of various fillers and additives. The authors coherently present a wide spectrum of topics by sequentially introducing structural aspects, properties, and applications. They then proceed to explore the mechanical, electrical, optical, and thermal properties of polymers, providing theoreticalderivations where necessary as well as explanations on molecular and structural features. To identify the principles involved, the book also furnishes the bases of many standard test methods according to ASTM and BS 2782 specifications.

This volume chronicles the proceedings of the Third Symposium on Metallized Plastics: Fundamental and Applied Aspects held under the auspices of the Dielectric Science and Technology Division of the Electrochemical Society in Phoenix, Arizona, October 13-18, 1991. This series of symposia to address the subject of metallized plastics was initiated in 1988 and the premier symposium was held in Chicago, October 10-12, 1988, followed by the second event in Montreal, Canada, May 7-10, 1990. The rroceedings of these two symposia have been properly documented ,2. The third symposium was a huge success like the previous two events, and all this is testimonial to the brisk interest and high tempo of R&D activity in the fie14 of metallized plastics. This further bolsters our earlier thinking that there was a conspicuous need to hold symposia on this topic on a regular basis and the fourth is planned for May 16-21, 1993 in Honolulu, Hawaii. The study of metallized plastics constitutes an important human endeavor l and as pointed out earlier there are myriad applications of metallized plastics ranging from very commonplace to exotic. Also a survey of the recent literature will reveal that both the fundamental and applied aspects of metallized plastics are being pursued with great vigor.

Written and edited by experts on specialty elastomers applications in the mechanical and automotive products industries, the Handbook of Specialty Elastomers provides a single source reference for the design of compounds using specialty elastomers.

This book defines specialty elastomers as heat-, oil-, fuel-, and solvent-resistant polymers. Each chapter examines individual elastomers in terms of development history, chemical composition, structure, and properties as well as processing methods, applications, and commercially available products. Covering their applications in the rubber, energy, chemicals, and oil industries, the book also discusses the use of antioxidants, antiozonants, vulcanization agents, plasticizers, and process aids for specialty elastomers. The concluding chapter details considerations and relevant processes-such as molding operations-involved in designing application-specific rubber components.

The Handbook of Specialty Elastomers provides comprehensive insight into the processes and challenges of designing rubber formulations and specialty elastomeric components.

Analytical pyrolysis allows scientists to use routine laboratory instrumentation for analyzing complex, opaque, or insoluble samples more effectively than other analytical techniques alone. Analytical Pyrolysis Handbook, Third Edition is a practical guide to the application of pyrolysis techniques to various samples and sample types for a diversity of fields including microbiology, forensic science, industrial research, and environmental analysis. The much-anticipated third edition incorporates recent technological advances that increase the technique's sensitivity to trace elements, improve its reproducibility, and expand its applicability. The book reviews the types of instrumentation available to perform pyrolysis and offers guidance for interfacing instruments and integrating other analytical techniques, including gas chromatography and mass spectrometry. Fully updated with new sample pyrograms, figures, references, and real-world examples, this edition also highlights new areas of application including cultural materials, forensic analysis, and environmental studies. This book illustrates how the latest advances make pyrolysis a practical, cost-effective, reliable, and flexible alternative for increasingly complex sample analyses. Analytical Pyrolysis Handbook, Third Edition is an essential, one-stop guide for determining if pyrolysis meets application-specific needs as well as performing pyrolysis and handling the data obtained.

Hydrogels are crosslinked, macromolecular polymeric materials arranged in a three-dimensional network, which can absorb and retain large amounts of water. Hydrogels are commonly used in clinical practice and experimental medicine for a wide range of applications, including drug delivery, tissue engineering and regenerative medicine, diagnostics, cellular immobilization, separation of biomolecules or cells, and barrier materials to regulate biological adhesions. This book elucidates the underlying concepts and emerging applications of hydrogels and will provide key case studies and critical analysis of the existing research.

This book presents the chemical properties of lignocellulosic fibers, knowledge of which is essential for innovation and sustainable development of their transformation. Thermochemical transformation of wood and other lignocellulosics is presented to highlight its volatile, liquid and solid products and their novel applications. Forest biorefinery is described to emphasize the new products from lignocellulosic constituents, both structural (cellulose, hemicelluloses and lignins) and those extraneous to cell walls-extractives. New developments in cellulose technology related to nanocellulose are discussed in relation to new applications. Industrial lignins are presented in detail, both in terms of extraction procedures from spent liquors and structural characterization of the isolated lignins. Application of lignocellulosic biopolymers in new composite materials, or in biomaterials for medicinal purposes, and in solid wood preservation, are described. The example of an industrial biorefinery installed in southwestern France more than 40 years ago is presented.

This book provides a comprehensive and updated insight into dielectric elastomers; one of the most promising classes of polymer-based smart materials and technologies. This technology can be used in a very broad range of applications, from robotics and automation to the biomedical field.
The need for improved transducer performance has resulted in considerable efforts towards the development of devices relying on materials with intrinsic transduction properties. These materials, often termed as "smart" or "intelligent," include improved piezoelectrics and magnetostrictive or shape-memory materials. Emerging electromechanical transduction technologies, based on so-called ElectroActive Polymers (EAP), have gained considerable attention. EAP offer the potential for performance exceeding other smart materials, while retaining the cost and versatility inherent to polymer materials. Within the EAP family, "dielectric elastomers," are of particular interest as they show good overall performance, simplicity of structure and robustness. Dielectric elastomer transducers are rapidly emerging as high-performance "pseudo-muscular" actuators, useful for different kinds of tasks. Further, in addition to actuation, dielectric elastomers have also been shown to offer unique possibilities for improved generator and sensing devices.
Dielectric elastomer transduction is enabling an enormous range of new applications that were precluded to any other EAP or smart-material technology until recently.
This book provides a comprehensive and updated insight into dielectric elastomer transduction, covering all its fundamental aspects. The book deals with transduction principles, basic materialsproperties, design of efficient device architectures, material and device modelling, along with applications.
* Concise and comprehensive treatment for practitioners and academics
* Guides the reader through the latest developments in electroactive-polymer-based technology
* Designed for ease of use with sections on fundamentals, materials, devices, models and applications

The first book to tackle the application of smart polymers in bioseparation and bioprocessing, Smart Polymers: Applications in Biotechnology and Biomedicine broke new ground in this challenging field. Completely revised, updated, and following in the footsteps of its predecessor, the second edition is poised to take its place as a premier reference in this field. This new edition considers those polymers in which a highly nonlinear response of a smart polymer to small changes in the external medium is of critical importance for the successful functioning of the system. The systems discussed are based on soluble/insoluble transition of smart polymers in aqueous solution, on conformational transitions of the macromolecules physically attached or chemically grafted to a surface and on the shrinking/swelling of covalently cross-linked networks of macromolecules, i.e. smart hydrogels.

The book focuses on the theory describing the behavior of smart polymers in solution, as gels, and when grafted to surfaces. It provides solid, quantitative descriptions and reliable guidelines, reflecting the maturation of the field and the demand for the development of new smart polymer systems. The coverage highlights smart gels and especially fast responding and macroporous gels, as these gels pave the way to different applications of smart polymers in the areas ofbioseparation, drug release, and microfluidics. With contributions from leading researchers as well as extensive end-of-chapter references, this volume offers a comprehensive overview of the current state-of-the-art in the field and the potential for future developments.

Dendrimers are a new class of macromolecule increasingly used in the fields of synthetic organic chemistry, biology, medicine and biotechnology. Dendrimers in Medicine and Biotechnology: New Molecular Tools looks at this exciting and rapidly growing area of science. Using an interdisciplinary approach with particular emphasis on biological applications, the book discusses the relationship between the dendrimer molecular motif and its biological properties. A general introduction to the subject of dendrimers, including definitions of terms and symbols, is provided. Subsequent sections discuss topics including dendrimers in biological systems, dendrimers as drug delivery devices, dendrimers in diagnostics and dendrimer drugs. Throughout the book examples from current research are also provided. This book will appeal to a wide range of scientists, including non specialists who require an introduction to dendrimers, as well as those wishing to know more about the application of dendrimers in the field of biology and medicine.

New fields of science and technology call for new materials with valuable performance characteristics. Long-term resistance to such temperatures can be found only in polymers with chains made up of thermostable fragments. Particularly interesting in this respect are elementorganic polymers with inorganic and organo-inorganic molecular chains. Elementorganic polymers are not only highly thermostable, but also perform well under low temperatures, sunlight, humidity, weather, etc. Thus, these polymers (especially silicones) are widely and effectively used in the electrical, radio, coal, mechanical rubber, aircraft, metallurgical, textile and other industries. They are of great utility not only in industry, but also in households and in medicine, where their merits can hardly be overestimated. The need to publish this book arose with the scientific and technical developments of the last decade, the reconstruction and technical renovation of existing factories, as well as fundamental changes in some syntheses of elementorganic monomers and polymers. Moreover, nowadays it is essential to train highly-skilled chemical engineers with a comprehensive knowledge of current chemistry, of the production technology of elementorganic monomers and polymers, and of their characteristics and applications.

This second volume of the "Handbook of Polyhydroxyalkanoates (PHA): Kinetics, Bioengineering and Industrial Aspects" focusses on thermodynamic and mathematical considerations of PHA biosynthesis, bioengineering aspects regarding bioreactor design and downstream processing for PHA recovery from microbial biomass. It covers microbial mixed culture processes and includes a strong industry-focused section with chapters on the economics of PHA production, industrial-scale PHA production from sucrose, next generation industrial biotechnology approaches for PHA production based on novel robust production strains, and holistic techno-economic and sustainability considerations on PHA manufacturing. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this book Provides an insight into microbial thermodynamics to reveal the central domain governing in PHA formation, both aerobically and anaerobically. Includes systematic overview of mathematical modelling approaches, starting from low-structured and formal kinetic models until modern tools like metabolic models, cybernetic models and so forth Discusses challenges during scale up of PHA production processes and on development of non-sterile processes and contamination-resistant strains Presents a holistic picture of the current state of PHA research by mixed cultures Reviews the industry-related point of view about current and future trends in PHA production and processing

This books studies syntax of NPIs and their interaction with sentential negatives in Hindi. It outlines the clause structure of Hindi and locates the syntactic position of sentential negatives as well as constituent negatives within the structure. It is argued that sentential negative in Hindi negation marker heads its own maximal projection, NegP, which is immediately dominated by TP. In addition to locating the position of negation markers in the clause structure, it outlines the distribution of negative polarity items (NPIs) in Hindi and the structural constraints on their licensing by sentential negative. The book argues that an NPI in Hindi is licensed overtly in the course of derivation by a c-commanding negative marker. The bulk of the evidence presented in this book argues against previous theoretical accounts that claim that NPI licensing involves covert syntactic operations such as LF movement or reconstruction. With respect to the classification of NPIs, this book also shows the existence of two different types of NPIs in Hindi; namely, strong NPIs and weak NPIs. Strong NPIs require a clause mate c-commanding negative licensor, whereas weak NPIs are quantifiers and are similar to free choice 'any' in English that are interpreted as NPIs in the presence of a c-commanding negative licensor.

The Handbook of Polyhydroxyalkanoates (PHA) focusses on and addresses varying facets of PHA biosynthesis and processing, spread across three volumes. The first volume discusses feedstock aspects, enzymology, metabolism and genetic engineering of PHA biosynthesis. It addresses better understanding the mechanisms of PHA biosynthesis in scientific terms and profiting from this understanding in order to enhance PHA biosynthesis in bio-technological terms and in terms of PHA microstructure. It further discusses making PHA competitive for outperforming established petrol-based plastics on industrial scale and obstacles for market penetration of PHA. This second volume focusses on thermodynamic and mathematical considerations of PHA biosynthesis, bioengineering aspects regarding bioreactor design and downstream processing for PHA recovery from microbial biomass. It covers microbial mixed culture processes and includes a strong industry-focused section with chapters on the economics of PHA production, industrial-scale PHA production from sucrose, next generation industrial biotechnology approaches for PHA production based on novel robust production strains, and holistic techno-economic and sustainability considerations on PHA manufacturing. Third volume is on the production of functionalized PHA bio-polyesters, the post-synthetic modification of PHA, processing and additive manufacturing of PHA, development and properties of PHA-based (bio)composites and blends, the market potential of PHA and follow-up materials, different bulk- and niche applications of PHA, and the fate and use of spent PHA items. Divided into fourteen chapters, it describes functionalized PHA and PHA modification, processing and their application including degradation of spent PHA-based products and fate of these bio-polyesters during compositing and other disposal strategies. Aimed at professionals and graduate students in Polymer (plastic) industry, wastewater treatment plants, food industry, biodiesel industry, this set: Presents comprehensive and holistic consideration of these microbial bioplastics in the volumes. Enables reader to learn about microbiological, enzymatic, genetic, synthetic biology, and metabolic aspects of PHA biosynthesis based on the latest scientific discoveries. Discusses design and operate a PHA production plant. Strong focus on post-synthetic modification, preparation of functional PHA and follow-up products, and PHA processing. Covers all related engineering considerations

This well-organized volume begins with a breakdown of the dynamic properties of composites and a complete look at various testing methods and data derived from each technique. Next is a discussion of wave motion in fiber-reinforced composites, including an investigation of effective modulus theory, an examination of wave motions in composite plates under impact loading, and a series of experimental studies conducted on inspected composite plates. The book then discusses non-destructive testing, including the applications and limitations of currently available non-destructive evaluation (NDE) techniques, and covers a variety of factors that affect the damage tolerance of composites. Important information on impact damage modeling, along with a classification of model types, is also presented.

First Published in 2006. This volume introduces and provides a semantic analysis of Discourse Adjectives, a natural class of adjectives that the author argues includes apparent, clear, evident, and obvious among its prototypical members. With a main claim that Discourse Adjectives do not provide information about the facts of the world. Rather, they are used by interlocutors to negotiate the status of propositions in a discourse.

International law is often manipulated in the debate about humanitarian intervention. The Liberian case provides an opportunity to challenge UN and the Economic Community of West African States' (ECOWAS') new approach. ECOWAS and the UN's justifications for moving away from the current norms are flawed. No enlightened person would disagree with the values of peace, democracy, human rights, and economic development. But should these goals be pursued within the current framework or outside it? Deme is an international lawyer educated at the University of Bordeaux, France. He received his Ph.D at Boston University. Deme teaches at the university of Rhodes Island and is a research fellow for the International Consortium for Law and Development at Boston University. He currently is an independent consultant for various international agencies in Washington DC and New York.

Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science.

New to the Third Edition

Part I

This first part covers newer developments in polymer synthesis, including ‘living’ radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements.

Part II

In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory–Huggins theory for polymer solutions and their phase separation is treated more rigorously.

Part III

A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology.

Part IV

The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded.

While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.

Table of Contents

CONCEPTS, NOMENCLATURE AND SYNTHESIS OF POLYMERS

Concepts and Nomenclature

The Origins of Polymer Science and the Polymer Industry

Basic Definitions and Nomenclature

Molar Mass and Degree of Polymerization

Principles of Polymerization

Introduction

Classification of Polymerization Reactions

Monomer Functionality and Polymer Skeletal Structure

Functional Group Reactivity and Molecular Size: The Principle of Equal Reactivity

Step Polymerization

Introduction

Linear Step Polymerization

Non-Linear Step Polymerization

Radical Polymerization

Introduction to Radical Polymerization

The Chemistry of Conventional Free-Radical Polymerization

Kinetics of Conventional Free-Radical Polymerization

Free-Radical Polymerization Processes

Reversible-Deactivation (‘Living’) Radical Polymerizations

Non-Linear Radical Polymerizations

Ionic Polymerization

Introduction to Ionic Polymerization

Cationic Polymerization

Anionic Polymerization

Group-Transfer Polymerization

Stereochemistry and Coordination Polymerization

Introduction to Stereochemistry of Polymerization

Tacticity of Polymers

Geometric Isomerism in Polymers Prepared from Conjugated Dienes

Ziegler–Natta Coordination Polymerization

Metallocene Coordination Polymerization

Ring-Opening Polymerization

Introduction to Ring-Opening Polymerization

Cationic Ring-Opening Polymerization

Anionic Ring-Opening Polymerization

Free-Radical Ring-Opening Polymerization

Ring-Opening Metathesis Polymerization

Specialized Methods of Polymer Synthesis

Introduction

Solid-State Topochemical Polymerization

Polymerization by Oxidative Coupling

Precursor Routes to Intractable Polymers

Supramolecular Polymerization (Polyassociation)

Copolymerization

Introduction

Step Copolymerization

Chain Copolymerization

Block Copolymer Synthesis

Graft Copolymer Synthesis

CHARACTERIZATION OF POLYMERS

Theoretical Description of Polymers in Solution

Introduction

Thermodynamics of Polymer Solutions

Chain Dimensions

Frictional Properties of Polymer Molecules in Dilute Solution

Number-Average Molar Mass

Introduction to Measurements of Number-Average Molar Mass

Membrane Osmometry

Vapour Pressure Osmometry

Ebulliometry and Cryoscopy

End-Group Analysis

Effects of Low Molar Mass Impurities upon Mn

Scattering Methods

Introduction

Static Light Scattering

Dynamic Light Scattering

Small-Angle X-Ray and Neutron Scattering

Frictional Properties of Polymers in Solution

Introduction

Dilute Solution Viscometry

Ultracentrifugation

Molar Mass Distribution

Introduction

Fractionation

Gel Permeation Chromatography

Field-Flow Fractionation

Mass Spectroscopy

Chemical Composition and Molecular Microstructure

Introduction

Principles of Spectroscopy

Ultraviolet and Visible Light Absorption Spectroscopy

Infrared Spectroscopy

Raman Spectroscopy

Nuclear Magnetic Resonance Spectroscopy

Mass Spectroscopy

PHASE STRUCTURE AND MORPHOLOGY OF BULK POLYMERS

The Amorphous State

Introduction

The Glass Transition

Factors Controlling the Tg

Macromolecular Dynamics

The Crystalline State

Introduction

Determination of Crystal Structure

Polymer Single Crystals

Semi-Crystalline Polymers

Liquid Crystalline Polymers

Defects in Crystalline Polymers

Crystallization

Melting

Multicomponent Polymer Systems

Introduction

Polymer Blends

Block Copolymers

PROPERTIES OF BULK POLYMERS

Elastic Deformation

Introduction

Elastic Deformation

Elastic Deformation of Polymers

Viscoelasticity

Introduction

Viscoelastic Mechanical Models

Boltzmann Superposition Principle

Dynamic Mechanical Testing

Frequency Dependence of Viscoelastic Behaviour

Transitions and Polymer Structure

Time–Temperature Superposition

Effect of Entanglements

Non-Linear Viscoelasticity

Elastomers

Introduction

Thermodynamics of Elastomer Deformation

Statistical Theory of Elastomer Deformation

Stress–Strain Behaviour of Elastomers

Factors Affecting Mechanical Behaviour

Yield and Crazing

Introduction

Phenomenology of Yield

Yield Criteria

Deformation Mechanisms

Crazing

Fracture and Toughening

Introduction

Fundamentals of Fracture

Mechanics of Fracture

Fracture Phenomena

Toughened Polymers

Polymer Composites

Introduction to Composite Materials

Matrix Materials

Types of Reinforcement

Composite Composition

Particulate Reinforcement

Fibre Reinforcement

Nanocomposites

Electrical Properties

Introduction to Electrical Properties

Dielectric Properties

Conduction in Polymers

Polymer Electronics

Answers to Problems

Index

Problems and Further Reading appear at the end of each chapter.

The improvement of strength and durability in polymers has implications relevant to industrial, medical, and household applications. Enhanced by the improved knowledge of the interactions between complex hierarchical structures and functional requirements, Mechanical Properties of Polymers Based on Nanostructure and Morphology focuses on new polymer materials that possess a combination of improved mechanical and other physical properties. This book specifies techniques used in structural and morphological characterization, discusses crazing and molecular variables of fracture behavior, and clarifies various modes of deformation mechanisms and orientation processes for semicrystalline polymers, block copolymers, and composites. The volume examines microindentation hardness studies and mechanisms of toughness enhancement for particle modified, amorphous and semicrystalline polymers and blends using model analysis. Experts in the field present innovations that illustrate new aspects of manufacturing, structure development, and properties of practical relevance in nanoparticle-filled thermoplastic polymers and the applications of carbon nanotube and nanofiber reinforced polymer systems. Other topics discussed in the book include alternative methods of polymer modification based on micro- and nanolayered polymers and hot compaction of oriented fibers and tapes. This book reflects the continuing research of mechanisms contributing to the structure-function relationship of nanostructured polymers and nanocomposites. Mechanical Properties of Polymers Based on Nanostructure and Morphology presents effective ways to combine improved mechanical and physical properties in polymers and form new, performance-enhanced composite materials.