Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers which contain metal cations and the structure-building organic "linker" units. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. Thousands of organic compounds and, in particular, aromatic and heterocyclic compounds are widely used as feedstock for industrial chemical synthesis, as fine chemicals, major components of liquid fossil fuels, dyestuffs, industrial solvents, agricultural chemicals, medicinal drugs, pharmaceuticals and personal care products (PPCPs), and active pharmaceutical ingredients (APIs). There is a strong interest towards synthesis, characterization and studies of both known and newly synthesized mesoporous MOFs for adsorption in solution to achieve the high adsorption capacity, selectivity, and the possibility of multiple regeneration of "spent" sorbent. This book covers experimental fundamental research on using mesoporous MOFs in emerging applications of major industrial, environmental and academic importance, especially purification of water and liquid fossil fuels and in advanced biomedical technologies.

Due to their unique properties, chitosan-based materials have emerged as useful resources in a variety of medicines, drug controlled-release carriers, tissue engineering scaffolds, and immobilized enzymes. But many of these materials have yet to reach the commercial market. Therefore, more work must be completed to fill the gap between research and production. Exploring the state of the field, Chitosan-Based Hydrogels: Functions and Applications details the latest progress in the research and development of chitosan-based biomaterials. The book introduces the formation and chemical structure of chitosan-based hydrogels. It also discusses the relationship between their structure and functions, which provides a theoretical basis for the design of biomaterials. In addition, many real-world examples illustrate the potential application of chitosan-based hydrogels in various areas, including materials science, biotechnology, pharmaceuticals, regenerative medicine, and cell engineering. By examining the structure and functions of chitosan-based hydrogels in living systems, this book provides the foundation for future research. It encourages readers to contribute to further research and development of these unique biomaterials.

In a carefully crafted, multidisciplinary, skillfully focused format, Polymers for Vascular and Urogenital Applications covers attributes of polymers used for vascular, urological, and gynecological materials. It provides a brief analysis of how the use of polymers in vascular and urogenital applications has evolved in the past five decades and outlines their common and specific functional requirements. The book provides a brief description of the evolving role of a particular family of materials and presents topics in highly integrated, well-balanced, authoritatively prepared segments on materials processing and in vitro and in vivo evaluation, complete with case studies. Features Includes contributions from authors representing a diverse technical group of clinicians with strong science or engineering backgrounds and research interests Supplies a comprehensive link between polymeric biomaterials and their application Provides a brief description of the evolving role of a particular family of materials Discusses recent developments in applications and the rationale for present and future clinical significance This book not only integrates clinical needs with current and future research responses but also provides a comprehensive overview to foster future innovation. It illustrates how two important and dissimilar areas in medicine can be interrelated by shared biomaterials and explores the clinical paradigm that establishes the driving force for innovation.

Rheology is applied extensively in polymer, chemical, food processing, and related industries. This book combines the basic concepts and applications by presenting a balanced overview of the principles. With simplified analysis of complex problems, the textbook format provides easy understanding for both students and practicing professionals. There is no competing book with such a wide scope, including unique topics such as diffusion, flows about particles, and liquid mixing. This second edition is abundantly updated throughout. Highlights include elongational flow measurements, POM-POM modeling, diffusion and rheology of polymer nanocomposites, new results based on CFD simulations, and much more.

This book aims to utilize the principles that have been developed for composite materials in the aircraft industry and apply these principles for the analysis for design of fiber reinforced plastic vessels and piping in the chemical processing industry.

This new book covers the synthetic as well application aspects of functional polymers. It highlights modern trends in the field and showcases the recent characterization techniques that are being employed in the field of polymer science. The chapters are written by top-notch scientists who are internationally recognized in the field. The chapters will highlight the modern trend in the field.

An explanation for engineers and chemists working in such industries as paper, paint, and textiles, of the operating mechanisms involved in the physics and chemistry of polymers and colloids as they apply to emulsion polymer manufacture and use. Outlines the various available materials, how they are

Science and Applications of Conducting Polymers emphasizes potential industrial applications of conducting polymers. The papers presented discuss the basic physics and chemistry of conducting polymers, followed by an in-depth examination of applications. The book is ideal for researchers in polymer physics, electronics, optics, and semiconductor physics.

This volume focuses on the developments in theory and materials science of conjugated materials for nonlinear optics, and on the processing of conjugated polymers. It describes the microscopic origin and mechanism of the nonlinear optical susceptibilities in the framework of quantum field theory.

Telechelic polymers have garnered a great deal of scientific interest due to their reactive chain-end functions. This comprehensive book compiles and details the basic principles of and cutting-edge research in telechelic polyesters, polycarbonates, and polyethers, ranging from synthesis to applications. It discusses general strategies toward telechelic polymers, centered on the fundamental aspects of polycondensation reactions, of cationic, anionic, coordination-insertion, and activated monomer mechanisms of the metal-, enzyme-, or otherwise organocatalyzed ring-opening polymerization of cyclic monomers, and of postpolymerization chemical modification methods of polymer precursors. All main classes of polymers are covered separately, comprising polyhydroxyalkanoates, poly( -caprolactone)s, poly(lactic acid)s, polylactides, polycarobnates, and polyethers, including synthetic approaches as well as some illustrative, up-to-date examples and uses. The book also addresses applications of hydroxyl, thiol, amino, or acrylate/methacrylate end-capped polymers as starting materials for the preparation of diverse polymer architectures ranging from block, graft, and star-shaped polymers and micelles to precursors for ATRP macroinitiators, polyurethane copolymers, shape-memory polymers, or nanosized drug delivery systems. The book will appeal to advanced undergraduate- and graduate-level students of polymer science; researchers in macromolecular science, especially those with an interest in functional and reactive polymers; and polymer chemists in academia and industry.

A comprehensive treatment of a large family of polymers useful in a wide range of applications in such fields as automotive, pharmaceutical, cosmetic, metal-working, mining, industrial coating, textile, construction, and home furnishings. Summarizes the chemistry and mechanisms; provides basic prepa

Now available for the first time, this valuable reference presents polymer solubility parameters and various polymer-liquid interaction parameters in an easy-to-use form. It critically evaluates and comprehensively compiles data from original sources. It presents these quantities polymer-by-polymer, alphabetically by polymer common chemical name, fully cross-referenced by systematic chemical names, alternative names and trade names. This one-of-a-kind handbook summarizes the relationship between the various quantities and their methods of determination. This resource is an absolute must for all who are interested in the chemical industry, specifically polymer chemistry, chemical engineering, applied chemistry, and physical chemistry.

This handbook focuses on physical, structural, and compositional properties of elastomeric materials and plastics. It provides a broad overview of the physical and physicochemical properties of synthetic rubbers that are used in conventional cured applications.

Polymers have been used as dielectric materials owing to their light weight, great flexibility, and processability as well as high insulation properties. To enhance their performance for various desired dielectric applications, fabrication of polymeric nanocomposites is believed to be one of the most effective approaches. By controlling the nanomaterial dispersion and interfacial structures with the polymer matrices in nanocomposites, dielectric properties can be tailored for specific applications. This book reviews representative polymer nanocomposite systems, focusing on the roles of nanodispersion, interfacial structures, and properties of polymer matrix materials in the dielectric properties and energy storage performance. The book reviews various dielectric relaxation models applicable to the analysis of polymer nanocomposites. It compiles the recent progress in new dielectric polymer nanocomposites based on biomaterials and hybrid nanomaterial systems for advanced dielectric applications.

Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science. New to the Third Edition Part I This first part covers newer developments in polymer synthesis, including 'living' radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements. Part II In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory-Huggins theory for polymer solutions and their phase separation is treated more rigorously. Part III A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology. Part IV The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded. While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.

This book provides an overview of the state of the art of several of the subfields of electroresponsive polymer science. It also provides a sufficiently broad perspective to stimulate development in new direction and to bring researchers up to date on the fields as a whole.

First Published in 1996. Routledge is an imprint of Taylor & Francis, an informa company.

This book reflects understanding of property enhancement through development of molecular structure. It focuses on liquid crystalline and semicrystalline polymers that provide a state of the art knowledge of the molecular organizations.

Addressing the two major unit operations-mixing and extrusion-fundamental toprocessing elastomers and plastic materials, this reference summarizes design equationsthat can be employed effectively in scaling up product performance parameters, andcontains a thorough survey of rheological principles. In addition, the book provides awealth of practical information, relating molecular and compositional properties ofpolymers to processing characteristics and end-use properties so that engineers can selectpolymers suitable for specific equipment as well as products.Polymer Mixing and Extrusion Technology examines viscometric techniquesand demonstrates their importance to product quality assurance ... reviews design-relatedliterature/correlations and calculation procedures for mixing and extrusion ... definesneeds and precision standards for setting up a polymer processing laboratory so thatproduct quality control can be implemented in physical testing and processing research.. . plus more.Illustrated with over 200 diagrams, tables, and photographs that facilitate readers'understanding of the processes, Polymer Mixing and Extrusion Technology isan authoritative source for plastics, polymer, and chemical engineers, manufacturers ofplastics processing equipment, and advanced undergraduate and graduate students in thesedisciplines.

This outstanding reference presents an up-to-date account of investigations during the last10 years in the area of injection and compression molding of polymers.Injection and Compression Molding Fundamentals considers simulation andexperimentation of flow dynamics in the cavity and delivery system . . . discussesrheology and viscoelastic modeling ... clarifies fiber orientation ... delineates residualstresses and processing-property relationships in molded parts ... and details computeraideddesign and manufacture of the mold.In addition, the book highlights specific features and problems related to the molding ofthermoplastics, rubbers, and thermosets ... and reveals the current status of the sciencebasedtechnology related to injection and compression molding.The most detailed and authoritative reference of its type, Injection and CompressionMolding Fundamentals is an invaluable resource for plastics, mechanical, andchemical engineers; colloid, oil, and color chemists; polymer engineers and scientists;mold designers and manufacturers; rheologists; and materials scientists. The book willalso be of value for use in graduate-level courses in plastics, mechanical, chemical, andpolymer engineering, and in short courses and seminars offered by professional societies.

The process of cryogelation has been vigorously studied over the past two decades, with recent research focussing on applications of these polymer systems in various biomedical and biotechnological fields. While there is significant literature available as research publications, limited reviews, and book chapters, Supermacroporous Cryogels: Biomedical and Biotechnological Applications is the first dedicated book on the subject. It thoroughly explores all aspects of cryogels from synthesis to applications in medical and biotechnological research and practice. Presenting the work of researchers from around the globe, this book addresses three key components of cryogelation, starting with an overview of the unique inherent properties of cryogels and their synthesis and optimization from various natural and synthetic polymers. It also focusses on the surface modification of cryogels as well as factors that affect their properties. The second component is a discussion of the biomedical aspects of cryogels, categorically describing their biocompatible nature and their recent usage in medical imaging by creating phantoms of various tissues and using tissue engineering to regenerate various tissues. The third reviews a wide range of applications of cryogels in biotechnology, including biocatalysis, cell separation, wastewater treatment, high throughput processes, and bioreactors. A comprehensive look at the process of cryogelation and an up-to-date account of significant developments in cryogel research, Supermacroporous Cryogels provides a single source of information beneficial to unacquainted readers as well as experts wanting to know about current research and practice regarding cryogels in medicine, technology, chemistry, and materials science and engineering.

"Volume 1 of this outstanding resource concentrates on safety and environmental concerns in the manufacture and use of resins, and thoroughly discusses theories of degradation, plasticization, solvation, and stabilization. "

This book provides solutions to many vital questions on the important property differences and advantages of individual engineering thermoplastics. It is useful for executives; managers; design, materials, and sales engineers; researchers; materials and product manufacturers; and compounders.

This comprehensive, long-needed reference provides the thorough understanding required tomodify and manipulate rigid PVC's thermal/shear sensitivity and rheological properties, helpingyou utilize rigid PVC most effectively in manufacturing applications as diverse as pipes,house siding, bottles , window frames, and packaging films.With complete, up-to-the-minute coverage in one convenient source, Engineering with RigidPVC encompasses rheological principles, resin properties, and additive modification, as wellas polymer preparation, melt processing, and forming techniques ... major conversion operationsand their manufacturing applications-including actual commercial formulations andprocesses .. . quality control procedures necessary to monitor compounding processes ...aspects of processability critical for product development and improvement .. . and muchmore.International in scope, this time- and money-saver is an eseential daily resource for all professionalsinvolved in Engineering with Rigid PVC, including plastics engineers, polymer chemists,process engineers, and plastics processors and technicians. Furthermore, the volume isideal for training programs and professional seminars, and is an outstanding supplement forstudents in polymer chemistry , materials science , and plastics engineering.

Inorganic-Whisker-Reinforced Polymer Composites: Synthesis, Properties and Applications gives a comprehensive presentation of inorganic microcrystalline fibers, or whiskers, a polymer composite filler. It covers whisker synthesis, surface modification, applications for reinforcing polymer-matrix composites, and analysis of resulting filled polymer composites. It focuses on calcium carbonate whiskers as a primary case study, introducing surface treatment methods for calcium carbonate whiskers and factors that influence them. Along with calcium carbonate, the book discusses potassium titanate and aluminum borate whiskers, which also comprise the new generation of inorganic whiskers. According to research results, composites filled by inorganic whiskers show improved strength, wear-resistance, thermal conductivity, and antistatic properties. It explains the importance of modifying polymer materials for use with inorganic whiskers and describes preparation and evaluation methods of polymers filled with inorganic whiskers. The book also considers possible challenges and solutions in synthesis and applications of polymers filled with inorganic whiskers. It summarizes the latest practices and research progress in China and elsewhere. With much of its information being new outside of China, Inorganic-Whisker-Reinforced Polymer Composites calls attention to the excellent promise displayed by applications of inorganic whiskers. They have the potential for wide and durable application and also for further development. This book demonstrates their potential and presents current and future directions in polymer science and inorganic whiskers.