The book provides an in-depth understanding of the fundamentals of superconducting electronics and the practical considerations for the fabrication of superconducting electronic structures. Additionally, it covers in detail the opportunities afforded by superconductivity for uniquely sensitive electronic devices and illustrates how these devices (in some cases employing high-temperature, ceramic superconductors) can be applied in analog and digital signal processing, laboratory instruments, biomagnetism, geophysics, nondestructive evaluation and radioastronomy. Improvements in cryocooler technology for application to cryoelectronics are also covered. This is the first book in several years to treat the fundamentals and applications of superconducting electronics in a comprehensive manner, and it is the very first book to consider the implications of high-temperature, ceramic superconductors for superconducting electronic devices. Not only does this new class of superconductors create new opportunities, but recently impressive milestones have been reached in superconducting analog and digital signal processing which promise to lead to a new generation of sensing, processing and computational systems. The 15 chapters are authored by acknowledged leaders in the fundamental science and in the applications of this increasingly active field, and many of the authors provide a timely assessment of the potential for devices and applications based upon ceramic-oxide superconductors or hybrid structures incorporating these new superconductors with other materials. The book takes the reader from a basic discussion of applicable (BCS and Ginzburg-Landau) theories and tunneling phenomena, through the structure and characteristics of Josephson devices and circuits, to applications that utilize the world's most sensitive magnetometer, most sensitive microwave detector, and fastest arithmetic logic unit.

The recent discovery of high-temperature superconductivity in copper based oxides is an event of major importance not only with respect to the physical phenomenon itself but also because it definitely shows that solid state chemistry, and especially the crystal chemistry of oxides, has a crucial place in the synthesis and understanding of new materials for future appli cations. The numerous papers published in the field of high Tc supercon ductors in the last five years demonstrate that the great complexity of these materials necessitates a close collaboration between physicists and solid state chemists. This book is based to a large extent on our experience of the crystal chemistry of copper oxides, which we have been studying in the laboratory for more than twelve years, but it also summarizes the main results which have been obtained for these compounds in the last five years relating to their spectacular superconducting properties. We have focused on the struc ture, chemical bonding and nonstoichiometry of these materials, bearing in mind that redox reactions are the key to the optimization of their supercon ducting properties, owing to the importance of the mixed valence of copper and its Jahn-Teller effect. We have also drawn on studies of extended defects by high-resolution electron microscopy and on their creation by ir radiation effects."

For the last few years astrophysicists and elementary particle physicists have been working jointly on the following fascinating phenomena: 1. The solar neutrino puzzle and the question: What happens to the neutrinos on their way from the sun to the earth? 2. The growing evidence that our universe is filled with about 10 times more matter than is visible and the question: What is dark matter made of? 3. The supernovae explosions and the question: What do neutrinos tell us about such explosions and vice versa? The experimental investigation of these phenomena is difficult and involves unconventional techniques. These are presently under development, and bring together such seemingly disparate disciplines as astrophysics and elementary particle physics on the one hand and superconductivity and solid-state physics on the other. This book contains the proceedings of a workshop held in March 1987 at which the above subjects and their experimental investigation were discussed. The proposed experimental methods are very new. They involve frontier developments in low temperature and solid-state physics. The book should be useful to researchers and students who actively work on these subjects or plan to enter the field. It also offers the non-expert reader with some physics background a good survey of the activities in this field.

This Topics in Current Physics (TCP) Volume 34 is concerned primarily with super- conductivity and magnetism, and the mutual interaction of these two phenomena in ternary rare earth compounds. It is the companion of TCP Volume 32 - Superconduc- tivity in Ternary Compounds: Structural, Electronic and Lattice Properties. The interplay between superconductivity and magnetism has intrigued theoreticians and experimentalists alike for more than two decades. V. L. Ginzburg first addressed the question of whether or not superconductivity and ferromagnetism could coexist in 1957, and B. T. Matthias and coworkers carried out the first experimental inves- tigations on this problem in 1959. The early experiments were made on systems that consisted of a superconducting element or compound into which small concentrations of rare earth impurities with partially-filled 4f electron shells had been intro- duced. These dilute impurity systems were chosen because the scattering of conduc- tion electrons by parama9. netic rare earth impurity ions usually has a strong de- structive "pa i r breaking" effect on superconducti vity, typi ca lly drivi ng the super- conducting transition temperature to zero at impurity concentrations of only a few atomic percent. Unfortunately, analysis of these early experiments was complicated by clustering and/or the formation of short range or "glassy" types of magnetic order so that definitive conclusions regarding the coexistence of superconductivity and magnetism could not be reached.

The structural. electronic and lattice properties of superconducting ternary com pounds are the subject of this Topics volume. Its companion volume (Topics in Cur rent Physics. Volume 34) deals primarily with the mutual interaction of supercon ductivity and magnetism in ternary compounds. These two volumes are the culmination of a project. started nearly two years ago. that was inspired by the intense re search effort. both experimental and theoretical. then being expended to explore and develop an understanding of the remarkable physical properties of ternary super conductors. Research activity on this subject has increased in the meantime. The interest in ternary superconductors originated in 1972. when B.T. Matthias and his co-workers first discovered superconductivity in several ternary molybdenum sulfide compounds that had been synthesized in 1971 by R. Chevrel. M. Sergent. and J. Prigent. The superconducting critical temperature Tc of one of the compounds. PbMo S * was reported to be ~ 15 K. This value is sufficiently high that there was g 6 (and still is) reason to expect that other ternary compounds would be found with superconducting transition temperatures rivaling those of the A15 compounds. of which Nb Ge has the record high Tc of 23 K. The interest in ternary superconductors 3 received further impetus when several of the ternary molybdenum sulfides were found to have exceptionally high upper critical magnetic fields. some of them in the neighborhood of 50 Tesla or more. An immense amount of research on ternary molybdenum chalcogenides then followed.

The characterization of epitaxial layers and their surfaces has benefitted a lot from the enormous progress of optical analysis techniques during the last decade. In particular, the dramatic improvement of the structural quality of semiconductor epilayers and heterostructures results to a great deal from the level of sophistication achieved with such analysis techniques. First of all, optical techniques are nondestructive and their sensitivity has been improved to such an extent that nowadays the epilayer analysis can be performed on layers with thicknesses on the atomic scale. Furthermore, the spatial and temporal resolution have been pushed to such limits that real time observation of surface processes during epitaxial growth is possible with techniques like reflectance difference spectroscopy. Of course, optical spectroscopies complement techniques based on the inter action of electrons with matter, but whereas the latter usually require high or ultrahigh vacuum conditions, the former ones can be applied in different environments as well. This advantage could turn out extremely important for a rather technological point of view, i.e. for the surveillance of modern semiconductor processes. Despite the large potential of techniques based on the interaction of electromagnetic waves with surfaces and epilayers, optical techniques are apparently moving only slowly into this area of technology. One reason for this might be that some prejudices still exist regarding their sensitivity."

Single-electron tunneling (SET) and related phenomena have recently come to be considered as "hot topics." This also became apparent when we organized the 4th International Conference on Superconducting and Quantum Effect Devices and Their Applications, SQUID'91, which was held June 18-21, 1991, in Berlin, Germany. Impressed by the number of contributions dedicated to the new physics of ultrasmall devices, we deemed it appropriate to devote this volume of the Springer Series in Electronics and Photonics to these specialized proceedings. The other contributions presented at SQUID'91, which are more conventional in character but nevertheless contain excitingly innovative results, are published separately as Volume 64 of the series Springer Proceedings in Physics. At first glance it seems strange that a conference abbreviated SQUID'91 should attract so many papers on non-superconducting devices, and in fact the first SQUID'XX conferences dealt exclusively with the physics and technology of Josephson junctions, SQUIDs and other superconducting devices and their ap plications. However, many concepts developed for superconducting devices, like tunneling, flux quantization, and flux-charge conjugation, appeared to be suitable for ultrasmall non-superconducting structures as well, and many researchers in the field of superconducting devices extended their activities accordingly. Thus the extension of the conference programme evolved quite informally. Meanwhile, the meetings established themselves as well-known conference series tradition ally appreciated by the SQUID community for its balanced mixture of physics and technology, review and preview. SQUID'XX became a kind of a trademark."

Compound semiconductor devices form the foundation of solid-state microwave and optoelectronic technologies used in many modern communication systems. In common with their low frequency counterparts, these devices are often represented using equivalent circuit models, but it is often necessary to resort to physical models in order to gain insight into the detailed operation of compound semiconductor devices. Many of the earliest physical models were indeed developed to understand the 'unusual' phenomena which occur at high frequencies. Such was the case with the Gunn and IMPATI diodes, which led to an increased interest in using numerical simulation methods. Contemporary devices often have feature sizes so small that they no longer operate within the familiar traditional framework, and hot electron or even quantum mechanical models are required. The need for accurate and efficient models suitable for computer aided design has increased with the demand for a wider range of integrated devices for operation at microwave, millimetre and optical frequencies. The apparent complexity of equivalent circuit and physics-based models distinguishes high frequency devices from their low frequency counterparts . . Over the past twenty years a wide range of modelling techniques have emerged suitable for describing the operation of compound semiconductor devices. This book brings together for the first time the most popular techniques in everyday use by engineers and scientists. The book specifically addresses the requirements and techniques suitable for modelling GaAs, InP. ternary and quaternary semiconductor devices found in modern technology."

In this text experts review experimental studies that directly reveal the relationship between the atomic structure and physical behavior of high-Tc superconductors. The thorough discussion centers on twins, twin boundaries, the vortex lattice, and magnetic and mechanical properties in connection with structural imperfections. Particular attention is paid to the role of the oxygen atom in the Y-Ba-Cu-O and La-Cu-O species. The experimental methods evaluated include electron and X-ray diffraction, electron microscopy, and M-ssbauer spectroscopy. This book makes extraordinarily valuable data obtained at the Institute of Solid State Physics at Chernogolovka accessible to the wider international community of researchers in superconductivity.

During the past thirty years considerable efforts have been made to design the synthesis and the study of molecular semiconductors. Molecular semiconductors - and more generally molecular materials - involve interactions between individual subunits which can be separately synthesized. Organic and metallo-organic derivatives are the basis of most of the molecular materials. A survey of the literature on molecular semiconductors leaves one rather confused. It does seem to be very difficult to correlate the molecular structure of these semiconductors with their experimental electrical properties. For inorganic materials a simple definition delimits a fairly homogeneous family. If an inorganic material has a conductivity intermediate between that of an 12 1 1 3 1 1 insulator " 10- n- cm- ) and that of a metal (> 10 n- cm- ), then it is a semiconductor and will exhibit the characteristic properties of this family, such as junction formation, photoconductivity, and the photovoltaic effect. For molecular compounds, such simplicity is certainly not the case. A huge number of molecular and macromolecular systems have been described which possess an intermediate conductivity. However, the various attempts which have been made to rationalize their properties have, more often than not, failed. Even very basic electrical properties such as the mechanism of the charge carrier formation or the nature and the density ofthe dopants are not known in detail. The study of molecular semiconductor junctions is very probably the most powerful approach to shed light on these problems.

Springer-Verlag, Berlin Heidelberg, in conjunction with Springer-Verlag New York, is pleased to announce a new series: CRYSTALS Growth, Properties, and Applications The series presents critical reviews of recent developments in the field of crystal growth, properties, and applications. A substantial portion of the new series will be devoted to the theory, mechanisms, and techniques of crystal growth. Occasionally, clear, concise, complete, and tested instructions for growing crystals will be published, particularly in the case of methods and procedures that promise to have general applicability. Responding to the ever-increasing need for crystal substances in research and industry, appropriate space will be devoted to methods of crystal characterization and analysis in the broadest sense, even though reproducible results may be expected only when structures, microstructures, and composition are really known. Relations among procedures, properties, and the morphology of crystals will also be treated with reference to specific aspects of their practical application. In this way the series will bridge the gaps between the needs of research and industry, the pos sibilities and limitations of crystal growth, and the properties of crystals. Reports on the broad spectrum of new applications - in electronics, laser tech nology, and nonlinear optics, to name only a few - will be of interest not only to industry and technology, but to wider areas of applied physics as well and to solid state physics in particular. In response to the growing interest in and importance of organic crystals and polymers, they will also be treated."

In less than two decades the concept of supercon In every field of science there are one or two ductivity has been transformed from a laboratory individuals whose dedication, combined with an innate curiosity to usable large-scale applications. In the understanding, permits them to be able to grasp, late 1960's the concept of filamentary stabilization condense, and explain to the rest of us what that released the usefulness of zero resistance into the field is all about. For the field of titanium alloy marketplace, and the economic forces that drive tech superconductivity, such an individual is Ted Collings. nology soon focused on niobium-titanium alloys. They His background as a metallurgist has perhaps given him are ductile and thus fabricable into practical super a distinct advantage in understanding superconduc conducting wires that have the critical currents and tivity in titanium alloys because the optimization of fields necessary for large-scale devices. More than superconducting parameters in these alloys has been 90% of all present-day applications of superconductors almost exclusively metallurgical. Advantages in use titanium alloys. The drive to optimize these training and innate abilities notwithstanding, it is alloys resulted in a flood of research that has been the author's dedication that is the essential com collected, condensed, and analyzed in this volume."

During a century, from the Van der Waals mean field description (1874) of gases to the introduction of renormalization group (RG techniques 1970), thermodynamics and statistical physics were just unable to account for the incredible universality which was observed in numerous critical phenomena. The great success of RG techniques is not only to solve perfectly this challenge of critical behaviour in thermal transitions but to introduce extremely useful tools in a wide field of daily situations where a system exhibits scale invariance. The introduction of scaling, scale invariance and universality concepts has been a significant turn in modern physics and more generally in natural sciences. Since then, a new "physics of scaling laws and critical exponents", rooted in scaling approaches, allows quantitative descriptions of numerous phenomena, ranging from phase transitions to earthquakes, polymer conformations, heartbeat rhythm, diffusion, interface growth and roughening, DNA sequence, dynamical systems, chaos and turbulence. The chapters are jointly written by an experimentalist and a theorist. This book aims at a pedagogical overview, offering to the students and researchers a thorough conceptual background and a simple account of a wide range of applications. It presents a complete tour of both the formal advances and experimental results associated with the notion of scaling, in physics, chemistry and biology.

Recent experimental and theoretical progress has elucidated the tunable crossover, in ultracold Fermi gases, from BCS-type superconductors to BEC-type superfluids.

"The BCS-BEC Crossover and the Unitary Fermi Gas" is a collaborative effort by leading international experts to provide an up-to-date introduction and a comprehensive overview of current research in this fast-moving field.

It is now understood that the unitary regime that lies right in the middle of the crossover has remarkable universal properties, arising from scale invariance, and has connections with fields as diverse as nuclear physics and string theory.

This volume will serve as a first point of reference for active researchers in the field, and will benefit the many non-specialists and graduate students who require a self-contained, approachable exposition of the subject matter.

"

This book should fill a gap which has existed in the literature on supercon ductivity. There have been a number of excellent textbooks available on the phenomenon of superconductivity, which describe in detail the variety of ef fects connected with it and the mathematical techniques to deal with them properly. However, until now there has not been a textbook available in English which concentrates on the mate ial aspects of superconductivity. This is a major shortcoming since most physicists working in the field of superconduc tivity are mainly concerned with specific materials and subsequently often need to know more about the interplay of superconductivity and material prop erties. On the other hand, people working in the field know that a competent and well-written book by S. V. Vonsovsky, V. A. Izyumov, and E. Z. Kurmaev has been available in Russian. It presents a thorough discussion of superconducting transition-metal alloys and compounds. This volume is a translation of an updated version of the Russian edition. The translation was done by A. P. Zavarnitsyn of the authors' institution and by Dr. E. H. Brandt of the Max-Planck-Institut fur Metallforschung in Stuttgart. The master manuscript was ably typed by Mrs. C. Pendl. I would like to take this opportunity to thank each of them. I sincerely hope that the book will turn out to be useful to physicists working in the field of superconductivity as well as to nonspecialists and interested graduate students."

One of the most exciting developments in modern physics has been the discovery of the new class of oxide materials with high superconducting transition temperature. Systems with Tc well above liquid nitrogen temperature are already a reality and higher Tc's are anticipated. Indeed, the idea of a room-temperature superconductor, which just a short time ago was considered science fiction, appears to be a distinctly possible outcome of materials research. To address the need to train students and scientists for research in this exciting field, Jeffrey W. Lynn and colleagues at the University of Maryland, College Park, as well as other superconductivity experts from around the U.S., taught a graduate-level course in the fall of 1987, from which the chapters in this book were drawn. Subjects included are: Survey of superconductivity (J. Lynn).- The theory of type-II superconductivity (D. Belitz).- The Josephson effect (P. Ferrell).- Crystallography (A. Santoro).- Electronic structure (C.P. Wang).- Magnetic properties and interactions (J. Lynn).- Synthesis and diamagnetic properties (R. Shelton).- Electron pairing (P. Allen).- Superconducting devices (F. Bedard).- Superconducting properties (J. Crow, N.-P. Ong).

Lead-free solders are used extensively as interconnection materials in electronic assemblies and play a critical role in the global semiconductor packaging and electronics manufacturing industry. Electronic products such as smart phones, notebooks and high performance computers rely on lead-free solder joints to connect IC chip components to printed circuit boards." Lead Free Solder: Mechanics and Reliability" provides in-depth design knowledge on lead-free solder elastic-plastic-creep and strain-rate dependent deformation behavior and its application in failure assessment of solder joint reliability. It includes coverage of advanced mechanics of materials theory and experiments, mechanical properties of solder and solder joint specimens, constitutive models for solder deformation behavior; numerical modeling and simulation of solder joint failure subject to thermal cycling, mechanical bending fatigue, vibration fatigue and board-level drop impact tests.

Life-Cycle Assessment of Semiconductors presents the first and thus far only available transparent and complete life cycle assessment of semiconductor devices. A lack of reliable semiconductor LCA data has been a major challenge to evaluation of the potential environmental benefits of information technologies (IT). The analysis and results presented in this book will allow a higher degree of confidence and certainty in decisions concerning the use of IT in efforts to reduce climate change and other environmental effects. Coverage includes but is not limited to semiconductor manufacturing trends by product type and geography, unique coverage of life-cycle assessment, with a focus on uncertainty and sensitivity analysis of energy and global warming missions for CMOS logic devices, life cycle assessment of flash memory and life cycle assessment of DRAM. The information and conclusions discussed here will be highly relevant and useful to individuals and institutions.

This thesis details the significant progress made in improving the performance of organic transistors and the network conductivity of carbon nanotubes. The first section investigates organic semiconductor nucleation and growth on the most common dielectric surface used to fabricate organic thin film transistors. The nucleation and growth of the semiconductor was determined to be a critical factor affecting the device performance. Excellent dielectric modification layers, which promote desirable semiconductor growth leading to high conductivity were identified, and a technologically relevant deposition technique was developed to fabricate high quality dielectric modification layers over large areas. This may represent an important step towards the realization of large area organic circuity. In the final section, lessons learned from studying organic semiconductor nucleation and growth were utilized to improve the conductivity of carbon nanotube networks. Selective nucleation of materials at the junctions between nanotubes in the network significantly decreased the network's sheet resistance. The resulting networks may be promising candidates for transparent electrodes with a variety of optoelectronic applications.

Density functional theory (DFT) has become the standard workhorse for quantum mechanical simulations as it offers a good compromise between accuracy and computational cost.
However, there are many important systems for which DFT performs very poorly, most notably strongly-correlated materials, resulting in a significant recent growth in interest in 'beyond DFT' methods. The widely used DFT+U technique, in particular, involves the addition of explicit Coulomb repulsion terms to reproduce the physics of spatially-localised electronic subspaces.
The magnitude of these corrective terms, measured by the famous Hubbard U parameter, has received much attention but less so for the projections used to delineate these subspaces.
The dependence on the choice of these projections is studied in detail here and a method to overcome this ambiguity in DFT+U, by self-consistently determining the projections, is introduced.
The author shows how nonorthogonal representations for electronic states may be used to construct these projections and, furthermore, how DFT+U may be implemented with a linearly increasing cost with respect to system size.
The use of nonorthogonal functions in the context of electronic structure calculations is extensively discussed and clarified, with new interpretations and results, and, on this topic, this work may serve as a reference for future workers in the field."

Physics and Chemistry of Transition-Metal Oxides includes both theoretical and experimental approaches to the variety of phenomena found in the transition-metal oxides, including high-temperature superconductivity, colossal magnetoresistance, and metal-insulator transition. These are the central issues in materials science and condensed matter physics/chemistry, and readers can obtain up-to-date information on what is happening in this field of research.

Technology computer-aided design, or TCAD, is critical to today's semiconductor technology and anybody working in this industry needs to know something about TCAD. This book is about how to use computer software to manufacture and test virtually semiconductor devices in 3D. It brings to life the topic of semiconductor device physics, with a hands-on, tutorial approach that de-emphasizes abstract physics and equations and emphasizes real practice and extensive illustrations. Coverage includes a comprehensive library of devices, representing the state of the art technology, such as SuperJunction LDMOS, GaN LED devices, etc.

Various experimental techniques for point contact production are described. Examples of point-contact spectra are presented for pure metals, alloys and compounds, as well as for semimetals and semiconductors, heavy fermion systems, Kond-lattices, mixed valence compounds and more. Superconducting point contacts are considered in respect to Andreev reflection and Josephson effects. Special attention is paid to contact conductance fluctuation, and new trends of research are outlined.

The expansion of the application of ferroelectric crystals in engineering as well as of a number of fundamental problems of solid-state physics, which have not yet been solved and which bear a direct relation to ferro electricity, has lately stimulated much interest in the problem of ferroelectricity. In courses of solid-state physics ferroelectricity is studied today along with traditional disciplines, such as magnetism, superconductivity, and 'semiconducting phe nomena. Moreover, new specialities have been born concerned directly with the development and utilization of ferroelectric material in optics, acous tics, computer technology, and capacitor engineering. Special courses in the physics of ferroelectrics are read in a number of colleges and universities. The study of the nature of ferro electricity has currently reached such a level of development that we may speak of having gained a rather deep insight into the physical essence of a number of phenomena, which contribute to the generation of a spontaneous electric polarization in crystals. It is exactly at this level that it has become possible to single out that part of the problem, the physical picture of which can be depicted in a rather unsophisticated manner and which is the foundation for the construction of a building of "complete understanding.""

Second-Generation High-Temperature Superconducting Coils and Their Applications for Energy Storage addresses the practical electric power applications of high-temperature superconductors. It validates the concept of a prototype energy storage system using newly available 2G HTS conductors by investigating the process of building a complete system from the initial design to the final experiment. It begins with a clear introduction of the related background and then presents a comprehensive design of a superconducting energy storage system that can store maximum energy using a limited length of superconductors. The author has created a modeling environment for analysis of the system and also presents experimental results that are highly consistent with his theoretical calculations.