The development of new high-tech applications and devices has created a seemingly insatiable demand for novel functional materials with enhanced and tailored properties. Such materials can be achieved by three-dimensional structuring on the nanoscale, giving rise to a significant enhancement of particular functional characteristics which stems from the ability to access both surface/interface and bulk properties. The highly ordered, bicontinuous double-gyroid morphology is a fascinating and particularly suitable 3D nanostructure for this purpose due to its highly accessible surface area, connectivity, narrow pore diameter distribution and superb structural stability. The presented study encompasses a wide range of modern nanotechnology techniques in a highly versatile bottom-up nanopatterning strategy that splits the fabrication process into two successive steps: the preparation of mesoporous double-gyroid templates utilizing diblock copolymer self-assembly, and their replication with a functional material employing electrochemical deposition and atomic layer deposition. The double-gyroid structured materials discussed include metals, metal oxides, and conjugated polymers, which are applied and characterized in high-performance devices, such as electrochromic displays, supercapacitors, chemical sensors and photovoltaics. This publication addresses a wide range of readers, from researchers and specialists who are professionally active in the field, to more general readers interested in chemistry, nanoscience and physics.

In this book, the author determines that a surface is itself a new material for chemical reaction, and the reaction of the surface provides additional new materials on that surface. The revelation of that peculiarity is what makes this book different from an ordinary textbook, and this new point of view will help to provide a new impetus when graduate students and researchers consider their results. The reaction of surface atoms provides additional new compounds, but these compounds cannot be detached from the surface. Some compounds are passive, but others work as catalysts. One superior feature of the surface is the dynamic cooperation of two or more different functional materials or sites on the same surface. This fact has been well established in the preferential oxidation of CO on platinum supported on a carbon nanotube with Ni-MgO at its terminal end. The Pt and Ni-MgO are perfectly separated, but these two are indispensable for the selective oxidation of CO in H2, where the H2O molecule plays a key role. The reader will understand that the complexity of catalysis is due to the complexity of the dynamic processes on the surface.

This book fills a gap in knowledge between chemistry- and physics-trained researchers about the properties of macroscopic (bulk) material. Although many good textbooks are available on solid-state (or condensed matter) physics, they generally treat simple systems such as simple metals and crystals consisting of atoms. On the other hand, textbooks on solid-state chemistry often avoid descriptions of theoretical background even at the simplest level. This book gives coherent descriptions from intermolecular interaction up to properties of condensed matter ranging from isotropic liquids to molecular crystals. By omitting details of specific systems for which comprehensive monographs are available-on liquid crystals and molecular conductors, for instance-this book highlights the effects of molecular properties, i.e., the presence of the shape and its deformation on the structure and properties of molecular systems.

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A comprehensive review of ion beam application in modern materials research is provided, including the basics of ion beam physics and technology. The physics of ion-solid interactions for ion implantation, ion beam synthesis, sputtering and nano-patterning is treated in detail. Its applications in materials research, development and analysis, developments of special techniques and interaction mechanisms of ion beams with solid state matter result in the optimization of new material properties, which are discussed thoroughly. Solid-state properties optimization for functional materials such as doped semiconductors and metal layers for nano-electronics, metal alloys, and nano-patterned surfaces is demonstrated. The ion beam is an important tool for both materials processing and analysis. Researchers engaged in solid-state physics and materials research, engineers and technologists in the field of modern functional materials will welcome this text.

This book is a status report. It provides a broad overview of the most recent developments in the field, spanning a wide range of topical areas in simulational condensed matter physics. These areas include recent developments in simulations of classical statistical mechanics models, electronic structure calculations, quantum simulations, and simulations of polymers. Both new physical results and novel simulational and data analysis methods are presented. Some of the highlights of this volume include detailed accounts of recent theoretical developments in electronic structure calculations, novel quantum simulation techniques and their applications to strongly interacting lattice fermion models, and a wide variety of applications of existing methods as well as novel methods in the simulation of classical statistical mechanics models, including spin glasses and polymers.

Using the nano metric resolution of atomic force microscopy techniques, this work explores the rich fundamental physics and novel functionalities of domain walls in ferroelectric materials, the nano scale interfaces separating regions of differently oriented spontaneous polarization. Due to the local symmetry-breaking caused by the change in polarization, domain walls are found to possess an unexpected lateral piezoelectric response, even when this is symmetry-forbidden in the parent material. This has interesting potential applications in electromechanical devices based on ferroelectric domain patterning. Moreover, electrical conduction is shown to arise at domain walls in otherwise insulating lead zirconate titanate, the first such observation outside of multiferroic bismuth ferrite, due to the tendency of the walls to localize defects. The role of defects is then explored in the theoretical framework of disordered elastic interfaces possessing a characteristic roughness scaling and complex dynamic response. It is shown that the heterogeneous disorder landscape in ferroelectric thin films leads to a breakdown of the usual self-affine roughness, possibly related to strong pinning at individual defects. Finally, the roles of varying environmental conditions and defect densities in domain switching are explored and shown to be adequately modelled as a competition between screening effects and pinning.

Deniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term "orthogonal supramolecular interactions" refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics. The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology.

This book describes hydration structures of proteins by combining experimental results with theoretical considerations. It is designed to introduce graduate students and researchers to microscopic views of the interactions between water and biological macromolecules and to provide them with an overview of the field. Topics on protein hydration from the past 25 years are examined, most of which involve crystallography, fluorescence measurements, and molecular dynamics simulations. In X-ray crystallography and molecular dynamics simulations, recent advances have accelerated the study of hydration structures over the entire surface of proteins. Experimentally, crystal structure analysis at cryogenic temperatures is advantageous in terms of visualizing the positions of hydration water molecules on the surfaces of proteins in their frozen-hydrated crystals. A set of massive data regarding hydration sites on protein surfaces provides an appropriate basis, enabling us to identify statistically significant trends in geometrical characteristics. Trajectories obtained from molecular dynamics simulations illustrate the motion of water molecules in the vicinity of protein surfaces at sufficiently high spatial and temporal resolution to study the influences of hydration on protein motion. Together with the results and implications of these studies, the physical principles of the measurement and simulation of protein hydration are briefly summarized at an undergraduate level. Further, the author presents recent results from statistical approaches to characterizing hydrogen-bond geometry in local hydration structures of proteins. The book equips readers to better understand the structures and modes of interaction at the interface between water and proteins. Referred to as "hydration structures", they are the subject of much discussion, as they may help to answer the question of why water is indispensable for life at the molecular and atomic level.

This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the 'surface science' approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level understanding of physical and chemical processes at surfaces, with particular emphasis on dynamical aspects. This book is a reference in the field.

The book deals with the development of continual models of turbulent natural media. Such models serve as a ground for the statement and numerical evaluation of the key problems of the structure and evolution of the numerous astrophysical and geophysical objects. The processes of ordering (self-organization) in an originally chaotic turbulent medium are addressed and treated in detail with the use of irreversible thermodynamics and stochastic dynamics approaches which underlie the respective models. Different examples of ordering set up in the natural environment and outer space are brought and thoroughly discussed, the main focus being given to the protoplanetary discs formation and evolution.

Micro/nano-mechanical systems are a crucial part of the modern world providing a plethora of sensing and actuation functionalities used in everything from the largest cargo ships to the smallest hand-held electronics; from the most advanced scientific and medical equipment to the simplest household items. Over the past few decades, the processes used to produce these devices have improved, supporting dramatic reductions in size, but there are fundamental limits to this trend that require a new production paradigm. The 2004 discovery of graphene ushered in a new era of condensed matter physics research, that of two-dimensional materials. Being only a few atomic layers thick, this new class of materials exhibit unprecedented mechanical strength and flexibility and can couple to electric, magnetic and optical signals. Additionally, they can be combined to form van der Waals heterostructures in an almost limitless number of ways. They are thus ideal candidates to reduce the size and extend the capabilities of traditional micro/nano-mechanical systems and are poised to redefine the technological sphere. This thesis attempts to develop the framework and protocols required to produce and characterise micro/nano-mechanical devices made from two-dimensional materials. Graphene and its insulating analogue, hexagonal boron nitride, are the most widely studied materials and their heterostructures are used as the test-bed for potential device architectures and capabilities. Interlayer friction, electro-mechanical actuation and surface reconstruction are some of the key phenomena investigated in this work.

Fullerene Polymers and Fullerene Polymer Composites is an in-depth experimental and theoretical account of polymers and composites whose unusual properties, such as, photophysical phenomena, electrical transport, phase transitions and magnetic properties, stem from the incorporation of C60 in the material. Each chapter is written by an internationally renowned expert who has published extensively in this sub-field of fullerene materials. Introductory chapters on the fundamental properties of fullerenes (C60, C70) and photophysical phenomena in fullerenes and polymers are also included.

This book reviews the current state-of-the art of single layer silicene up to thicker silicon nanosheets, and their structure, properties and potential applications. Silicene is a newly discovered material that is one atomic layer think. It is a two-dimensional (2D) nanomaterial that is classified as a nanosheet, which has large lateral dimensions up to micrometres, but thicknesses of only nanometres or less. Silicon nanosheets are currently a very 'hot' area of research. The unique properties and morphology of such materials make them ideal for a variety of applications, including electronic devices, batteries and sensors. 2D nanosheets of silicon can be considered as analogues of graphene. As silicon is already the major component of electronic devices, the significance of nanosheets composed of silicon is that they can be more easily integrated into existing electronic devices. Furthermore, if 2D nanostructured Si can be implemented into such devices, then their size could be reduced into the nano-regime, providing unique properties different from bulk Si that is currently employed. The book is written for researchers and graduate students.

My intent in writing this book is to present an introduction to the thermo- chanical theory required to conduct research and pursue applications of shock physics in solid materials. Emphasis is on the range of moderate compression that can be produced by high-velocity impact or detonation of chemical exp- sives and in which elastoplastic responses are observed and simple equations of state are applicable. In the interest of simplicity, the presentation is restricted to plane waves producing uniaxial deformation. Although applications often - volve complex multidimensional deformation fields it is necessary to begin with the simpler case. This is also the most important case because it is the usual setting of experimental research. The presentation is also restricted to theories of material response that are simple enough to permit illustrative problems to be solved with minimal recourse to numerical analysis. The discussions are set in the context of established continuum-mechanical principles. I have endeavored to define the quantities encountered with some care and to provide equations in several convenient forms and in a way that lends itself to easy reference. Thermodynamic analysis plays an important role in continuum mechanics, and I have included a presentation of aspects of this subject that are particularly relevant to shock physics. The notation adopted is that conventional in expositions of modern continuum mechanics, insofar as possible, and variables are explained as they are encountered. Those experienced in shock physics may find some of the notation unconventional.

A reference and text, Dissipative Phenomena treats the broadly applicable area of nonequilibrium statistical physics and concentrates the modelling and characterization of dissipative phenomena. A variety of examples from diverse disciplines, such as condensed matter physics, materials science, metallurgy, chemical physics, are discussed. Dattagupta employs a broad framework of stochastic processes and master equation techniques to obtain models for a range of experimentally relevant phenomena such as classical and quantum Brownian motion, spin dynamics, kinetics of phase ordering, relaxation in glasses, and dissipative tunnelling. This book will serve as a graduate/research level textbook since it offers considerable utility to experimentalists, computational physicists and theorists.

Written by leading experts in the field of band-ferromagnetism, this book is intended to give a status report on our understanding of this complicated and fascinating problem of solid state physics. Modern developments are presented and explained in a tutorial style, emphasizing the decisive ideas and the hot topics of current and future research on band-ferromagnetism. The authors include experimentalists and theoreticians working on different aspects of magnetism and employing a variety of techniques. In particular, they treat the following five central themes: Ground-State Properties, Finite-Temperature Electronic Structure, Models of Band-Ferromagnetism, Low-Dimensional Systems, Understanding Spectroscopies. The book will be of benefit to students and researchers alike.

This book presents a comprehensive description of phonons and their interactions in systems with different dimensions and length scales. Internationally-recognized leaders describe theories and measurements of phonon interactions in relation to the design of materials with exotic properties such as metamaterials, nano-mechanical systems, next-generation electronic, photonic, and acoustic devices, energy harvesting, optical information storage, and applications of phonon lasers in a variety of fields.

The emergence of techniques for control of semiconductor properties and geometry has enabled engineers to design structures in which functionality is derived from controlling electron behavior. As manufacturing techniques have greatly expanded the list of available materials and the range of attainable length scales, similar opportunities now exist for designing devices whose functionality is derived from controlling phonon behavior. However, progress in this area is hampered by gaps in our knowledge of phonon transport across and along arbitrary interfaces, the scattering of phonons with crystal defects, interface roughness and mass-mixing, delocalized electrons/collective electronic excitations, and solid acoustic vibrations when these occur in structures with small physical dimensions. This book providesa comprehensive description of phonons and their interactions in systems with different dimensions and length scales. Theories and measurements of phonon interactions are described in relation to the design of materials with exotic properties such as metamaterials, nano-mechanical systems, next-generation electronic, photonic, and acoustic devices, energy harvesting, optical information storage, and applications of phonon lasers in a variety of fields."

This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.

The book considers the main growth-related phenomena occurring during epitaxial growth, such as thermal etching, doping, segregation of the main elements and impurities, coexistence of several phases at the crystal surface and segregation-enhanced diffusion.
It is complete with tables, graphs and figures, which allow fast determination of suitable growth parameters for practical applications.

This book gives an account of state-of-the-art investigations of properties and processes at solid-liquid interfaces with the same precision as it is standard in ultrahigh vacuum based surface science. Using combinations of in-situ and ex-situ experimental methods fundamental and relevant phenomena such as adsorption and desorption of ions and molecules, restructuring of surfaces, thin film and nanocluster growth, and electrochemical reactions on the micrometer scale are addressed. The overview includes a wide range of experimental techniques and examples of solid-liquid interfaces and aims at stimulating an expansion of this type of important Interface Science.

Lithium niobate, LiNbO , is an oxide ferroelectric with various kinds of pro- 3 nouncedphysicalproperties. Thisversatilityhaspromoteditscareerinscience anddevices. Ithasbeenparticularlyfruitfulintheopticalregime,wheremany e?ects have been found in LiNbO and devices introduced using it as a host. 3 One of the few big drawbacks, namely the low level laser damage threshold based on photorefraction due to extrinsic defects was discovered very early. A relatively new topic, not involved so far in any general description, is a fundamental dependence of the optical properties of LiNbO on intrinsic de- 3 fects. Their importance has been realised out due to the development of varies growthtechniquesintherecentpast. Theprogressinthegrowthandstudiesof LiNbO crystals with di?erent composition, particularly almost stoichiomet- 3 ric ones, has revealed a signi?cant and sometimes decisive role of the intrinsic defects. For example, the photoinduced charge transport, and therefore the photorefractive properties governing the recording of the phase gratings in LiNbO , are strongly controlled by the content of intrinsic defects. The re- 3 cently found impact of intrinsic defects on the coercive ?eld in LiNbO is 3 of fundamental importance for the creation of periodically poled structures (PPLN) aimed at the optical-frequency conversion in the quasi-phase mat- ing (QPM) mode of operation. As a consequence of these results, an idea of the intrinsic defects in LiNbO has been developed during the last decade 3 and involves microscopic studies on defects, photorefraction and ferroelectric switching using spectroscopic and structure methods.

Historical Overview of (Mini)emulsion Polymerizations and Preparation of Hybrid Latex Particles, by A.M. van Herk;
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Physical Methods for the Preparation of Hybrid Nanocomposite Polymer Latex Particles, by R. F.A. Teixeira and S. A.F. Bon;
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Organic/Inorganic Composite Latexes: The Marriage of Emulsion Polymerization and Inorganic Chemistry, by Elodie Bourgeat-Lami and Muriel Lansalot;
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Preparation of Hybrid Latex Particles and Core Shell Particles Through the Use of Controlled Radical Polymerization Techniques in Aqueous Media, by Bernadette Charleux, Franck D Agosto, and Guillaume Delaittre;
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Miniemulsion Polymerization as a Means to Encapsulate Organic and Inorganic Materials, by Clemens K.Weiss and Katharina Landfester;
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Organic Inorganic Hybrid Magnetic Latex, by Md Mahbubor Rahman and Abdelhamid Elaissari

Quasielastic neutron scattering has made many important contributions to the atomistic elucidation of diffusion processes in solids. The aim of this book is to inform researchers in solid state physics, solid state chemistry, and inorganic materials science of the potential of quasielastic neutron scattering. The book has been written for experimentalists and contains in its first part the theoretical background on neutrons, neutron scattering, and solid state diffusion, which is essential for the proper use of quasielastic neutron scattering. This general part should be useful for non-experts in the field of neutron scattering and diffusion as well. The second part of the book addresses the experts in this vivid field of research. It summarizes the scientific applications of quasielastic neutron scattering to special solid state materials systems, as for example to hydrogen in metals or to diffusion in solid state ionic conductors.

Experiments since 1911 prove that the distance between nuclear particles constituting atomic bodies is a hundred thousand times larger than the diameters of these particles. Hence the volumes of all atomic bodies including ourselves are space-like empty, a hundred times more empty than the volume of the solar system. Scores of experiments also prove that space contains electrons and positrons bound to each other by energies of a million electron volts per pair, and form a cubic lattice, named the epola.Based on the epola model of space, this book reveals the physical nature of inertia, gravitation, the spreading of electromagnetic and gravitational actions in space with the velocity of light, and derives their laws. The postulates of quantum and relativity theories are also derived and turned into explainable physical laws. Thus physics is restored as the natural science it had been before it was turned into a science of axiomatic statements and calculations.The book will appeal both to serious scientists and students as well as the general reader interested in scientific explanations of the physical world. Since as a natural science physics deals with the simplest and most basic natural phenomena, this book will be as accessible to the general public as biology books.