During the past fifteen years there has been a dramatic increase in the number of different surfaces whose structures have been determined experimentally. For example, whereas in 1979 there were only 25 recorded adsorption structures, to date there are more than 250. This volume is therefore a timely review of the state-of-the-art in this dynamic field.

Chapter one contains a compilation of the structural data base on surfaces within a series of tables that allows direct comparison of structural parameters for related systems. Experimental structural trends amongst both clean surfaces and adsorbate systems are highlighted and discussed.

The next chapter outlines the successes of local density functional theory in predicting the relaxations and reconstructions of clean metal and semiconductor surfaces, and the behaviour of adsorbates such as hydrogen, oxygen and alkali elements on metal surfaces, thereby explaining some of the experimental trends observed within the database. These "ab initio" density functional calculations are of ground state properties at the absolute zero of temperature.

Chapter three provides an introduction to finite temperature effects in a pedagogical review of current statistical mechanical treatments of phase transitions at surfaces, many of which display the prominent role of fluctuations or non-mean field behaviour.

The final chapter discusses the relationship of the reactivity of a surface to its morphology and composition, which is particularly relevant to a fundamental understanding of catalysis.

This book presents the materials of the XIII General Meeting of the Russian Mineralogical Society. Over 190 participants prepared the result of their scientific work on mineralogy: mineral diversity and the evolution of mineral formation (S1); minerals as markers of petro- and ore genesis and new methods of their determination (S2); mineralogy and formation conditions of deposits of strategic minerals (S3); problems of applied (technological and ecological) mineralogy and geochemistry (S4); natural stone in art and architecture (S5); modern research in the field of stone and gemological studies (S6); mineralogical crystallography, crystallochemistry, and new minerals (F1); history of science, museumification, and popularization of natural science knowledge (F2). The Russian Mineralogical Society is the oldest mineralogical Society in Russia (from 1817). The Russian Mineralogical Society joins more than 1200 researchers from universities, academic and industry institutes, and production organizations in Russia's major scientific centers. The Society has 17 sections, including crystallochemistry, radiography and spectroscopy of minerals, ore mineralogy, technological mineralogy, experimental mineralogy, ecological mineralogy and geochemistry, and new mineral nomenclature classification. The main scientific and organizing event for the Russian Mineralogical members is the meeting session, organized every fourth year.

Intended for graduate students in physics and chemistry, this book touches on granular matter, protein folding, phase separating and evolution kinetics. Taking glasses as a central theme, it presents the problem of slow dynamics from several angles, a ubiquitous feature in condensed matter, mechanics and biological physics. Some of the best established workers in the field present different theoretical and experimental approaches to the subject.

Nanophase Materials is the first and, as yet, the only comprehensive book published in this new and exciting area of materials science. It gives a broad overview of the revolutionary new field of nanophase materials; a view which spans the materials, physics, and chemistry research communities at a tutorial level that is suitable for advanced undergraduates, graduate students, postdoctoral researchers, and experts or would-be experts in the science of nanostructured materials. The articles are authored by many of the world's most prominent scientists in this field. The book covers the diverse methods for synthesizing nanophase materials, a variety of subsequent processing methodologies, what is known about the structures of these materials on various length scales from atomic to macroscopic, and the properties of these unique and novel materials. The materials properties covered are mechanical, electronic, optical, and magnetic and hence span a wide range of important new opportunities for technological applications.

This book presents an analytical theory of the electronic states in ideal low dimensional systems and finite crystals based on a differential equation theory approach. It provides precise and fundamental understandings on the electronic states in ideal low-dimensional systems and finite crystals, and offers new insights into some of the basic problems in low-dimensional systems, such as the surface states and quantum confinement effects, etc., some of which are quite different from what is traditionally believed in the solid state physics community. Many previous predictions have been confirmed in subsequent investigations by other authors on various relevant problems. In this new edition, the theory is further extended to one-dimensional photonic crystals and phononic crystals, and a general theoretical formalism for investigating the existence and properties of surface states/modes in semi-infinite one-dimensional crystals is developed. In addition, there are various revisions and improvements, including using the Kronig-Penney model to illustrate the analytical theory and make it easier to understand. This book is a valuable resource for solid-state physicists and material scientists.

This 21st Century Nanoscience Handbook will be the most comprehensive, up-to-date large reference work for the field of nanoscience. Handbook of Nanophysics by the same editor published in the fall of 2010 and was embraced as the first comprehensive reference to consider both fundamental and applied aspects of nanophysics. This follow-up project has been conceived as a necessary expansion and full update that considers the significant advances made in the field since 2010. It goes well beyond the physics as warranted by recent developments in the field. This ninth volume in a ten-volume set covers industiral applications. Key Features: Provides the most comprehensive, up-to-date large reference work for the field. Chapters written by international experts in the field. Emphasises presentation and real results and applications. This handbook distinguishes itself from other works by its breadth of coverage, readability and timely topics. The intended readership is very broad, from students and instructors to engineers, physicists, chemists, biologists, biomedical researchers, industry professionals, governmental scientists, and others whose work is impacted by nanotechnology. It will be an indispensable resource in academic, government, and industry libraries worldwide. The fields impacted by nanophysics extend from materials science and engineering to biotechnology, biomedical engineering, medicine, electrical engineering, pharmaceutical science, computer technology, aerospace engineering, mechanical engineering, food science, and beyond.

This book offers concise information on the properties of polymeric materials, particularly those most relevant to physical chemistry and chemical physics. Extensive updates and revisions to each chapter include eleven new chapters on novel polymeric structures, reinforcing phases in polymers, and experiments on single polymer chains. The study of complex materials is highly interdisciplinary, and new findings are scattered among a large selection of scientific and engineering journals. This book brings together data from experts in the different disciplines contributing to the rapidly growing area of polymers and complex materials.

1. Objective and Scope Bubbles, drops and rigid particles occur everywhere in life, from valuable industrial operations like gas-liquid contracting, fluidized beds and extraction to such vital natural processes as fermentation, evaporation, and sedimentation. As we become increasingly aware of their fundamental role in industrial and biological systems, we are driven to know more about these fascinating particles. It is no surprise, therefore, that their practical and theoretical implications have aroused great interest among the scientific community and have inspired a growing number of studies and publications. Over the past ten years advances in the field of small Reynolds numbers flows and their technological and biological applications have given rise to several definitive monographs and textbooks in the area. In addition, the past three decades have witnessed enormous progress in describing quantitatively the behaviour of these particles. However, to the best of our knowledge, there are still no available books that reflect such achievements in the areas of bubble and drop deformation, hydrodynamic interactions of deformable fluid particles at low and moderate Reynolds numbers and hydrodynamic interactions of particles in oscillatory flows. Indeed, only one more book is dedicated entirely to the behaviour of bubbles, drops and rigid particles ["Bubbles, Drops and Particles" by Clift et al. (1978)] and the authors state its limitations clearly in the preface: "We treat only phenomena in which particle-particle interactions are of negligible importance. Hence, direct application of the book is limited to single-particle systems of dilute suspensions.

Background on Semimagnetic Semiconductors.- Thermodynamics and Crystal Growth of Diluted Magnetic Semiconductors.- Band Structure and Theory of Magnetic Interactions in Diluted Magnetic Semiconductors.- Transport phenomena in Semimagnetic Semiconductors.- Experimental Studies of the d-d Exchange Interactions in Diluted Magnetic Semiconductors.- Bound Magnetic Polarons in Diluted Magnetic Semiconductors.- Magnetooptic Properties of Wide Gap II1?xMnxVI Semimagnetic Semiconductors.- II-Fe-VI Semimagnetic Semiconductors.- Semimagnetic IV-VI Compound Semiconductors.- Semimagnetic Semiconductor Superlattices.- Magnetism of Fe-Based Diluted Magnetic Semiconductors.

The textbook we offer to the reader is based on a two-term course of lec tures, "Electromagnetic Response of Material Media," that the authors gave for a number of years to the final-year students of the Physics Depart ment of Moscow University. This course built on courses in quantum electronics, nonlinear optics and theoretical fundamentals of quantum radiophysics; students are as sumed to have mastered the fundamentals of quantum mechanics, laser physics and nonlinear optics. The essential core of the course, and hence of the book, is the current general theory of electromagnetic response of a nonrelativistic medium. The main aspects are presented in Chapters 1 and 2. The second part is devoted to more traditional topics which students learn in this course of lectures and also in the course "Condensed Matter Physics" for students who choose to major in radiophysics and laser physics; this course is also taught by the authors at the Physics Department. This volume was intended as a text for students and, as such, does not cite original publications. We decided to provide a list of additional recommended literature, mostly of well known, easily accessible textbooks."

Atomic transport in solids is a field of growing importance in solid state physics and chemistry, and one which, moreover, has important implications in several areas of materials science. This growth is due first to an increase in the understanding of the fund amentals of transport processes in solids. Of equal importance, however, have been the improvements in the last decade in the experi mental techniques available for the investigation of transport phenomena. The advances in technique have stimulated studies of a wider range of materials; and expansion of the field has been strong ly encouraged by the increasing range of applied areas where transport processes play an essential role. For example, mass transport phenomena play a critical role in the technology of fabrication of components in the electronics industry. Transport processes are involved both during the fabrication and operation of devices and with the growing trend to miniaturisation there are increasing demands on accurate control of diffusion processes. The present book (which is based on a NATO sponsored Advanced Study Institute held in 1981 at Lannion, France) aims to present a general survey of the subject, highlighting those areas where work has been especially active in recent years."

Pulse Generation and Detection: Terahertz Radiation from ElectroOptic Crystals (X.C. Zhang et al.). Photoconductive Semiconductor Switches for High Power Radiation (G.M. Loubriel). Broadband Electronic Systems and Components: Pulse Generation and Compression on a TravellingWave MMIC Schottky Diode Array (M. Dragoman et al.). Precursor of an UltraWideband Radar System (A.S. Podgorski). Antennas and Arrays: Impulse Radiating Antennas (C.E. Baum, E.G. Farr). WideBandwidth Radiation from Arrays of Endfire Tapered Slot Antennas (D.H. Schaubert). Pulse Propagation and Guidance: Ultrashort Pulse Response in Nonlinear Dispersive Media (R. Albanese et al.). Modulation and Noise in Soliton Pulse Trains (J.M. Arnold). Scattering Theory and Computation: Phase Error Control for FDTD Methods (P.G. Petropoulos). Signal Processing Techniques: Stable Pole Extraction from Scattering Data (S.U. Pillai, T.I. Shim). 49 additional articles. Index.

This book by Lev M. Blinov is ideal to guide researchers from their very first encounter with liquid crystals to the level where they can perform independent experiments on liquid crystals with a thorough understanding of their behaviour also in relation to the theoretical framework. Liquid crystals can be found everywhere around us. They are used in virtually every display device, whether it is for domestic appliances of for specialized technological instruments. Their finely tunable optical properties make them suitable also for thermo-sensing and laser technologies. There are many monographs written by prominent scholars on the subject of liquid crystals. The majority of them presents the subject in great depth, sometimes focusing on a particular research aspect, and in general they require a significant level of prior knowledge. In contrast, this books aims at an audience of advanced undergraduate and graduate students in physics, chemistry and materials science. The book consists of three parts: the first part, on structure, starts from the fundamental principles underlying the structure of liquid crystals, their rich phase behaviour and the methods used to study them; the second part, on physical properties, emphasizes the influence of anisotropy on all aspects of liquid crystals behaviour; the third, focuses on electro-optics, the most important properties from the applications standpoint. This part covers only the main effects and illustrates the underlying principles in greater detail. Professor Lev M. Blinov has had a long carrier as an experimentalist. He made major contributions in the field of ferroelectric mesophases. In 1985 he received the USSR state prize for investigations of electro-optical effects in liquid crystals for spatial light modulators. In 1999 he was awarded the Frederiks medal of the Soviet Liquid Crystal Society and in 2000 he was honoured with the G. Gray silver medal of the British Liquid Crystal Society. He has held many visiting academic positions in universities and laboratories across Europe and in Japan.

This two-volume work covers ultrafast structural and electronic dynamics of elementary processes at solid surfaces and interfaces, presenting the current status of photoinduced processes. Providing valuable introductory information for newcomers to this booming field of research, it investigates concepts and experiments, femtosecond and attosecond time-resolved methods, as well as frequency domain techniques.
The whole is rounded off by a look at future developments.

This volume collects the contributions! to the NATO Advanced Study Institute (ASI) held in Aussois (France) by March 25 - April 5, 1991. This NATO ASI was intended to present and illustrate recent advances in computer simulation techniques applied to the study of materials science problems. Introductory lectures have been devoted to classical simulations with special reference to recent technical improvements, in view of their application to complex systems (glasses, molecular systems . . . ). Several other lectures and seminars focused on the methods of elaboration of interatomic potentials and to a critical presentation of quantum simulation techniques. On the other hand, seminars and poster sessions offered the opportunity to discuss the results of a great variety of simulation studies dealing with materials and complex systems. We hope that these proceedings will be of some help for those interested in simulations of material properties. The scientific committee advises have been of crucial importance in determining the conference program. The directors of the ASI express their gratitude to the colleagues who have participated to the committee: Y. Adda, A. Bellemans, G. BIeris, J. Castaing, C. R. A. Catlow, G. Ciccotti, J. Friedel, M. Gillan, J. P. Hansen, M. L. Klein, G. Martin, S. Nose, L. Rull-Fernandez, J. Valleau, J. Villain. The main financial support has been provided by the NATO Scientific Affairs Division and the Commission of European Communities (plan Science).

This book provides readers with a comprehensive, state-of-the-art reference to the design automation aspects of quantum computers. Given roadmaps calling for quantum computers with 2000 qubits in a few years, readers will benefit from the practical implementation aspects covered in this book. The authors discuss real hardware to the extent possible. Provides an up-to-date, single-source reference to design automation aspects of quantum computers; Presentation is not just theoretical, but substantiated with real quantum hardware; Covers multi-faceted aspects of quantum computers, providing readers with valuable information, no matter the direction in which technology moves.

"Dynamics of Soft Matter: Neutron Applications" provides an overview of neutron scattering techniques that measure temporal and spatial correlations simultaneously, at the microscopic and/or mesoscopic scale. These techniques offer answers to new questions arising at the interface of physics, chemistry, and biology. Knowledge of the dynamics at these levels is crucial to understanding the soft matter field, which includes colloids, polymers, membranes, biological macromolecules, foams, emulsions towards biological & biomimetic systems, and phenomena involving wetting, friction, adhesion, or microfluidics.

Emphasizing the complementarities of scattering techniques with other spectroscopic ones, this volume also highlights the potential gain in combining techniques such as rheology, NMR, light scattering, dielectric spectroscopy, as well as synchrotron radiation experiments. Key areas covered include polymer science, biological materials, complex fluids and surface science.

In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-d]pyridazine and dihydropyrroloazepine, which are all difficult to synthesize by other means. The isolation and characterization of the key three-fused-ring Zr/Si-containing intermediates are also described in detail. These results show that the zirconacyclobutene-silacyclobutene fused compound behaves as a "chemical transformer" upon treatment with various substrates via the "coordination-induced skeleton rearrangement" mechanism. In the second part, the author demonstrates the synthesis and isolation of a series of 2,6-diazasemibullvalenes (NSBVs) from the reaction of 1,4-dilithio-1,3-dienes and nitriles, highlighting the significant progress made for the first time in this work: (1) determination of X-ray crystal structure of a substituted 2,6-diazasemibullvalene; (2) measurement of the activation barrier of its rapid intramolecular aza-Cope rearrangement in solution; (3) exploration of several reaction types of NSBV with diverse ring-expansion products and "bowl-shape" or "cage-shape" N-containing polycyclic skeletons; (4) demonstration of the localized structure as the predominant form and the homoaromatic delocalized structure as a minor component in the equilibrium using theoretical analysis. Based on well-founded results, this work sheds new light on this controversial topic.

The study of liquids covers a wide range of scientific disciplines, primarily in physics and chemistry. As a result of this disparate activity the links between new developments in remote fields are seldom co-ordinated into a single conference. The objective of the present meeting was to gather together people with different forms of expertise. Previous ASI meetings on the liquid state have been held over an extended period and have occurred on a three-yearly basis. The first meeting in this series was on 'Structure and Dynamics of Liquids' in 1980 and was held on the island of Corsica. The next meeting on 'Molecular liquids: Dynamics and Interactions' was held in Florence in 1983 and was followed by 'Aqueous Solutions' at the Institut d'Etudes Scientifiques de Cargese in 1986. It therefore seemed a natural choice to select Cargese for the next meeting in 1989 and to choose a topic which emphasised a particular area of liquid state studies. Due to our own involvement in collaborative research we considered that 'Hydrogen-bonded liquids' would be an appropriate topic. One of its attractions, was that there was much new material coming from widely disparate investigations and it would be a convenient time to draw together the different strands. The particular interest in water was clearly central to this topic but it was thought desirable to set this development in the wider context of other systems in which hydrogen-bonding plays a significant role.

Semiconductor materials have been studied intensively since the birth of silicon technology more than 50 years ago. The ability to physically and chemically t- lor their properties with precision is the key factor responsible for the electronic revolution in our society over the past few decades. Semiconductor material s- tems (like silicon and GaAs-related materials) have now matured and found well established applications in electronics, optoelectronics, and several other ?elds. Other materials such as III-Nitrides were developed later, in response to needs that the above mentioned semiconductors were unable to ful?ll. The properties of I- nitrides (AlN, GaN InN, and related alloy systems) make them an excellent choice for ef?cient light emitters in the visible as well as the UV region, UV detectors, and for a variety of electronic device such as high frequency unipolar power devices. There was a major upsurgein the research of the GaN material system around1970.

Quantum mechanical laws are well documented at the level of a single or a few atoms and are here extended to systems containing 102 to 1010 electrons - still much smaller than the usual macroscopic objects, but behaving in a manner similar to a single atom. Besides the purely theoretical interest, such systems pose a challenge to the achievement of the ultimate microelectronic applications. The present volume presents an up-to-date account of the physics, technology and expected applications of quantum effects in solid-state mesoscopic structures. Physical phenomena include the Aharonov-Bohm effect, persistent currents, Coulomb blockade and Coulomb oscillations in single electron devices, Andreev reflections and the Josephson effect in superconductor/normal/superconductor systems, shot noise suppression in microcontacts and contact resistance quantisation, and overall quantum coherence in mesoscopic and nanoscopic structures related to the emerging physics of quantum computation in the solid-state environment.

The majority of the chapters in this volume represent a series of lectures. that were given at a workshop on quantum transport in ultrasmall electron devices, held at San Miniato, Italy, in March 1987. These have, of course, been extended and updated during the period that has elapsed since the workshop was held, and have been supplemented with additional chapters devoted to the tunneling process in semiconductor quantum-well structures. The aim of this work is to review and present the current understanding in nonequilibrium quantum transport appropriate to semiconductors. Gen erally, the field of interest can be categorized as that appropriate to inhomogeneous transport in strong applied fields. These fields are most likely to be strongly varying in both space and time. Most of the literature on quantum transport in semiconductors (or in metallic systems, for that matter) is restricted to the equilibrium approach, in which spectral densities are maintained as semiclassical energy conserving delta functions, or perhaps incorporating some form of collision broadening through a Lorentzian shape, and the distribution functions are kept in the equilibrium Fermi-Dirac form. The most familiar field of nonequilibrium transport, at least for the semiconductor world, is that of hot carriers in semiconductors."

This monograph presents in detail the novel "wave" approach to finite element modeling of transient processes in solids. Strong discontinuities of stress, deformation, and velocity wave fronts as well as a finite magnitude of wave propagation speed over elements are considered. These phenomena, such as explosions, shocks, and seismic waves, involve problems with a time scale near the wave propagation time. Software packages for 1D and 2D problems yield significantly better results than classical FEA, so some FORTRAN programs with the necessary comments are given in the appendix. The book is written for researchers, lecturers, and advanced students interested in problems of numerical modeling of non-stationary dynamic processes in deformable bodies and continua, and also for engineers and researchers involved designing machines and structures, in which shock, vibro-impact, and other unsteady dynamics and waves processes play a significant role.

This volume deals with the basic knowledge and understanding of fundamental interactions of low energy electrons with molecules. It pro vides an up-to-date and comprehensive account of the fundamental in teractions of low-energy electrons with molecules of current interest in modern technology, especially the semiconductor industry. The primary electron-molecule interaction processes of elastic and in elastic electron scattering, electron-impact ionization, electron-impact dissociation, and electron attachment are discussed, and state-of-the art authoritative data on the cross sections of these processes as well as on rate and transport coefficients are provided. This fundamental knowledge has been obtained by us over the last eight years through a critical review and comprehensive assessment of "all" available data on low-energy electron collisions with plasma processing gases which we conducted at the National Institute of Standards and Technology (NIST). Data from this work were originally published in the Journal of Physical and Chemical Reference Data, and have been updated and expanded here. The fundamental electron-molecule interaction processes are discussed in Chapter 1. The cross sections and rate coefficients most often used to describe these interactions are defined in Chapter 2, where some recent advances in the methods employed for their measurement or calculation are outlined. The methodology we adopted for the critical evaluation, synthesis, and assessment of the existing data is described in Chapter 3. The critically assessed data and recommended or suggested cross sections and rate and transport coefficients for ten plasma etching gases are presented and discussed in Chapters 4, 5, and 6."