In recent years, ever more electronic devices have started to exploit the advantages of organic semiconductors. The work reported in this thesis focuses on analyzing theoretically the energy level alignment of different metal/organic interfaces, necessary to tailor devices with good performance. Traditional methods based on density functional theory (DFT), are not appropriate for analyzing them because they underestimate the organic energy gap and fail to correctly describe the van der Waals forces. Since the size of these systems prohibits the use of more accurate methods, corrections to those DFT drawbacks are desirable. In this work a combination of a standard DFT calculation with the inclusion of the charging energy (U) of the molecule, calculated from first principles, is presented. Regarding the dispersion forces, incorrect long range interaction is substituted by a van der Waals potential. With these corrections, the C60, benzene, pentacene, TTF and TCNQ/Au(111) interfaces are analyzed, both for single molecules and for a monolayer. The results validate the induced density of interface states model.

Crystallography is an interdisciplinary science covering a wide area, from biology to earth sciences, mathematics and materials science. Its role is growing, owing to the contribution crystallography can offer to the understanding of such diverse fields as biological structures, high-temperature superconductors, mineral properties, and phase transitions. The book describes both the theoretical bases and applications of different areas interacting with crystallography. As with the first and second editions, it is organized as a collection of chapters written by recognized specialists, with all contributions being harmonized into a unified whole. The main text is devoted to the presentation of basics; the appendices deal with specialist aspects. In this third edition topics have been updated so as to document the present state of the art: emphasis is placed upon areas of current research.
To facilitate learning and make teaching more effective, new illustrations have been introduced. As with the second edition, a software package is included via the book's OUP web site: modern graphics will help users to better understand the basics of this science via three-dimensional images, simulation of experiments, and exercises.

The interest in the problem of surface diffusion has been steadily growing over the last fifteen years. This is clearly evident from the increase in the number of papers dealing with the problem, the development of new experimental techniques, and the specialized sessions focusing on diffusion in national and international meetings. Part of the driving force behind this increasing activity is our recently acquired ability to observe and possibly control atomic scale phenomena. It is now possible to look selectively at individual atomistic processes and to determine their relative importance during growth and reactions at surfaces. The number of researchers interested in this problem also has been growing steadily which generates the need for a good reference source to farniliarize newcomers to the problem. While the recent emphasis is on the role of diffusion during growth, there is also continuing progress on the more traditional aspects of the problem describing mass transport in an ensemble of particles. Such a description is based on the statistical mechanical analysis of a collection of particles that mutually interact and develop correlations. An average over the multitude of atomistic processes that operate under these conditions is necessary to fully describe the dynamics in the system.

The terms 'liquid crystal' or 'liquid crystal display' (LCD) are well-known in the context of flat-screen televisions, but the properties and history of liquid crystals are little understood. This book tells the story of liquid crystals, from their controversial discovery at the end of the nineteenth century, to their eventual acceptance as another state of matter to rank alongside gases, liquids and solids. As their story unfolds, the scientists involved and their works are put into illuminating broader socio-political contexts. In recent years, liquid crystals have had a major impact on the display industry, culminating in the now widely available flat-screen televisions; this development is described in detail over three chapters, and the basic science behind it is explained in simple terms accessible to a general reader. New applications of liquid crystals in materials, bio-systems, medicine and technology are also explained.
The authors' approach to the subject defines a new genre of popular science books. The historical background to the scientific discoveries is given in detail, and the personal communications between the scientists involved are explored. The book tells the story of liquid crystals, but it also shows that scientific discovery and exploitation relies on human interactions, and the social and political environments in which they work.

Theoretical and experimental studies of phase transitions are at the forefront of modern condensed-matter physics. The seminal insight into the role played by fluctuations led to the renormalization group, an approach that has proved extremely useful in many other fields as well. This text considers a wide variety of problems in the theory of phase transitions, revealing their common features as well as their distinctions. Formal aspects are developed as required in discussions of particular systems, and theory is compared to experiment wherever possible. This book begins with a review of the classical approach, including the main aspects of a self-consistent treatment of systems with broken symmetry and a discussion of the Ginzburg-Landau functional. It then turns to a treatment of the renormalization group, discussing both Wilson's formulation based on Kadanoff's scale invariance as well as the approach using field theory. The authors then turn to a generalized approach using scale equations, which eliminates many of the problems of the other formulations. Subsequent chapters discuss applications of this approach: first to simple models; then to more realistic systems such as complex Heisenberg magnets, antiferromagnets, ferroelectrics, impure systems, and high-T(subscript c) superconductors. Finally, in the last two chapters many of these systems are analyzed within the framework of exactly solvable models. Suitable for advanced undergraduates as well as graduate students in physics, the text assumes some knowledge of statistical mechanics, but is otherwise self-contained.

This book deals with the electro-chemo-mechanical properties characteristic of and unique to solid electrode surfaces, covering interfacial electrochemistry and surface science. Electrochemical reactions such as electro-sorption, electro-deposition or film growth on a solid electrode induce changes in surface stress or film stress that lead to transformation of the surface phase or alteration of the surface film. The properties of solid electrode surfaces associated with the correlation between electrochemical and mechanical phenomena are named "electro-chemo-mechanical properties". The book first derives the surface thermodynamics of solid electrodes as fundamentals for understanding the electro-chemo-mechanical properties. It also explains the powerful techniques for investigating the electro-chemo-mechanical properties, and reviews the arguments for derivation of surface thermodynamics of solid electrodes. Further, based on current experimental findings and theories, it discusses the importance of the contribution of surface stress to the transformation of surface phases, such as surface reconstruction and underpotential deposition in addition to the stress evolution during film growth and film reduction. Moreover, the book describes the nano-mechanical properties of solid surfaces measured by nano-indentation in relation to the electro-chemo-mechanical properties. This book makes a significant contribution to the further development of numerous fields, including electrocatalysis, materials science and corrosion science.

In the past decade, the field of physics has witnessed renewed advances in physical systems without mirror (parity) symmetry. Experimentally, chiral magnetic skyrmions discovered in real materials have stirred a great deal of interest in future spintronic applications due to their nanoscale size, topological protection, and energy efficiency. Theoretically, the Hall viscosity, a new universal transport coefficient, through the progress in hydrodynamics has triggered extensive theoretical investigation in quantum Hall systems. This book provides an extensive account of skyrmion dynamics, using various analytical tools, especially the field theory Ward identity that is a first principle method using symmetries and the associated conservation equations. The identity revealed that Hall viscosity is a universal part of skyrmion motion. This book leads readers to frontline research in searching for the role of the mysterious Hall viscosity in skyrmion physics, using the interdisciplinary point of view that encompasses high-energy physics, condensed matter, and materials science. It also provides the necessary backgrounds and physical clarity for advanced undergraduates to meaningfully explore its contents through mathematical expressions conveyed in both vector and index notations.

Polymers in Solution is devoted to the static properties of flexible polymers in solution. It presents the progress made by both theory and experiment in the years up to its original publication in 1990, and remains one of the most advanced books available on this subject. Despite the variety in the chemical composition and physical properties of long polymer chains, when in solution they show a universality in their behaviour. On the experimental side, the use of photon and neutron scattering has led to a better understanding, while the use of computer simulation has also produced interesting results. This work is the result of a collaboration between a theoretician and an experimentalist, who have both worked for many years on polymer solutions.

Transition metal oxides form a series of compounds with a uniquely wide range of electronic properties. They have important applications as dielectrics, semiconductors and metals, and as materials for magnetic and optical uses. The discovery of high temperature superconductors has brought the attention of a wide scientific community to this area and has highlighted the problems involved in trying to understand transition metal oxides. The present book is not primarily about Tc superconductors, although their main properties are discussed in the final sections. The main aim is to describe the varied electronic behaviour shown by transition metal oxides, and to discuss the different types of theoretical models that have been proposed to interpret this behaviour.

This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

Why does a piano sound like a piano? A similar question can be asked of virtually all musical instruments. A particular note - such as middle C - can be produced by a piano, a violin, a clarinet, and many other instruments, yet it is easy for even a musically untrained listener to distinguish between these different instruments. A central quest in the study of musical instruments is to understand why the sound of the "same" note depends greatly on the instrument, and to elucidate which aspects of an instrument are most critical in producing the musical tones characteristic of the instrument. The primary goal of Physics of the Piano is to investigate these questions for the piano. The explanations in this book use a minimum of mathematics, and are intended for anyone who is interested in music and musical instruments. At the same time, there are many insights relating physics and the piano that will likely be interesting and perhaps surprising for many physicists.

The aim of this book is to present a statistical theory of wave scattering by complex systems -systems which have a chaotic classical dynamics, as in the case of microwave cavities and quantum dots, or possess quenched randomness, as in the case of disordered conductors- with emphasis on mesoscopic fluctuations. The universal character of the statistical behavior of these phenomena is incorporated in a natural way by approaching the problem from a Maximum-Entropy viewpoint -Shannon's information entropy is maximized, subject to the symmetries and constraints that are physically relevant- within the powerful, non-perturbative Theory of Random Matrices. This is a distinctive feature of the present book that greatly motivated our writing it. Another reason is that it collects in one place the material and notions -derived from the published work of the authors in collaboration with several co-workers, as well as from the work of others- which are scattered through research journals and textbooks on the subject. To make the book self-contained, we present in Chapters 2 and 3 the quantum theory of scattering, set in the context of quasi-one-dimensional, multichannel systems, thus related directly to scattering problems in mesoscopic physics. Chapter 4 discusses the linear-response theory of quantum electronic transport, adapted to the context of mesoscopic systems. These chapters, together with Chapter 5 on the Maximum-Entropy Approach and Chapter 8 on weak localization, have been written in a pedagogical style, and can be used as part of a graduate course. Chapters 6 and 7 discuss the problem of electronic transport through classically chaotic cavities and quasi-one-dimensional disordered systems. There are many exercises, most of them worked out in detail, distributed throughout the book. This should help graduate students, their teachers and the research scholars interested generally in the subject of quantum transport through disordered and chaotic systems in their preparation for it, and beyond.

Cosmology has undergone a revolution in recent years. The exciting interplay between astronomy and fundamental physics has led to dramatic revelations, including the existence of the dark matter and the dark energy that appear to dominate our cosmos. But these discoveries only reveal themselves through small effects in noisy experimental data. Dealing with such observations requires the careful application of probability and statistics.
But it is not only in the arcane world of fundamental physics that probability theory plays such an important role. It has an impact in many aspects of our everyday life, from the law courts to the lottery.
Why then do so few people understand probability? And why do so few people understand why it is so important for science? Why do so many people think that science is about absolute certainty when, at its core, it is actually dominated by uncertainty?
This book attempts to explain the basics of probability theory, and illustrate their application across the entire spectrum of science.

The second edition of this successful textbook provides an up-to-date account of the optical physics of solid state materials. The basic principles of absorption, reflection, luminescence, and light scattering are covered for a wide range of materials, including insulators, semiconductors and metals. The text starts with a review of classical optics, and then moves on to the treatment of optical transition rates by quantum theory. In addition to the traditional discussion of crystalline materials, glasses and molecular solids are also covered.
The first edition included a number of subjects that are not normally covered in standard texts, notably semiconductor quantum wells, molecular materials, vibronic solid state lasers, and nonlinear optics. The basic structure of the second edition is unchanged, but all of the chapters have been updated and improved. Futhermore, a number of important new topics have been added, including:
DT Optical control of spin
DT Quantum dots
DT Plasmonics
DT Negative refraction
DT Carbon nanostructures (graphene, nanotubes and fullerenes)
DT NV centres in diamond
The text is aimed at final year undergraduates, masters students and researchers. It is mainly written for physicists, but might also be useful for electrical engineers, materials scientists and physical chemists. The topics are written in a clear tutorial style with worked examples, chapter summaries and exercises.
To request a copy of the Solutions Manual, visit: http: //global.oup.com/uk/academic/physics/admin/solutions

This book highlights a novel and holistic approach to multiscaled PVA bionanocomposite films used for electrical sensing, medical and packaging applications. With a combination of material characterization and modeling to understand the effect of nanoparticle size and shape, as well as 3D interphase properties and features such as interphase modulus and nanoscale dimensions, this book substantiates how excellent mechanical and thermal properties of these materials are achieved. Also it addresses the importance of using economical and ecofriendly bionanocomposites as potential green materials to support the goal of environmental sustainability with multifunctional properties.

This research monograph offers an introduction to advanced quantum field theoretical techniques for many-particle systems beyond perturbation theory. Several schemes for resummation of the Feynman diagrams are described. The resulting approximations are especially well suited for strongly correlated fermion and boson systems. Also considered is the crossover from BCS superconductivity to Bose--Einstein condensation in fermion systems with strong attractive interaction. In particular, a field theoretic formulation of "bosonization" is presented; it is published here for the first time. This method is applied to the fractional quantum Hall effect, to the Coulomb plasma, and to several exactly solvable models.

There is a continuing growth of interest in the computer simulation of materials at the atomic scale, using a variety of academic and commercial computer programs. In all such programs there is some physical model of the inter-atomic forces, which may be based on something as simple as a pair interaction, such as the Lennard-Jones model, or as complex as a self-consistent, all-electron solution of the quantum mechanical problem. For a student or researcher, the basis of such models is often shrouded in mystery. It is usually unclear how well founded they are, since it is hard to find a discussion of the physical assumptions that have been made in their construction. The lack of clear understanding of the scope and limitations of a given model may lead to its innocent misuse, resulting either in unfair criticism of the model or in the dissemination of nonsensical results.
In the present book, models of inter-atomic forces are derived from a common physical basis, namely the density functional theory. The interested reader will be able to follow the detailed derivation of pairwise potentials in simple metals, tight-binding models from the simplest to the most sophisticated (self-consistent) kind, and various ionic models. The book is self-contained, requiring no more background than provided by an undergraduate quantum mechanics course. It aims to furnish the reader with a critical appreciation of the broad range of models in current use, and to provide the tools for understanding other variants that are described in the literature. Some of the material is new, and some pointers are given to possible future avenues of model development.

Cloud physics is concerned with those processes which are responsible for the formation of clouds and the release of precipitation. This classic book gives a comprehensive and detailed account of experimental and theoretical research on the microphysical processes of nucleation, condensation, droplet growth, initiation and growth of snow crystals, and the mechanisms of precipitation release. As a textbook it is designed to give the student the necessary background to carry out independent work. As a reference book for the research worker, it provides an integrated account of the major developments in this field. Although written primarily for the atmospheric physicist, it contains much of interest for those in the fields of nucleation phenomena, crystal growth, and aerosol physics.

Computational Studies of Crystal Structure and Bonding, by Angelo Gavezzotti Cryo-Crystallography: Diffraction at Low Temperature and More, by Piero Macchi High-Pressure Crystallography, by Malcolm I. McMahon Chemical X-Ray Photodiffraction: Principles, Examples, and Perspectives, by Pance Naumov Powder Diffraction Crystallography of Molecular Solids, by Kenneth D. M. Harris

The new edition includes additional analytical methods in the classical theory of viscoelasticity. This leads to a new theory of finite linear viscoelasticity of incompressible isotropic materials. Anisotropic viscoplasticity is completely reformulated and extended to a general constitutive theory that covers crystal plasticity as a special case.

Over the last thirty years, the study of liquids containing polymers, surfactants, or colloidal particles has developed from a loose assembly of facts into a coherent discipline with substantial predictive power. These liquids expand our conception of what condensed matter can do. Such structured-fluid phenomena dominate the physical environment within living cells. This book teaches how to think of these fluids from a unified point of view showing the far-reaching effects of thermal fluctuations in producing forces and motions. Keeping mathematics to a minimum, the book seeks the simplest explanations that account for the distinctive scaling properties of these fluids. An example is the growth of viscosity of a polymer solution as the cube of the molecular weight of the constituent polymers. Another is the hydrodynamic radius of a colloidal aggregate, which remains comparable to its geometrical radius even though the density of particles in the aggregate becomes arbitrarily small. The book aims for a simplicity, unity and depth not found in previous treatments, and includes numerous figures, tables and problems. It will be an ideal textbook for teaching undergraduates in physical science how to understand soft matter, but will also be of interest to industrial scientists, who want to gain a broader understanding of soft matter systems.

This book collects together the lecture courses and seminars given at the Les Houches Summer School 2008 on Long-Range Interacting Systems. Leading scientists in different fields of mathematics and physics present their views on this fast growing and interdisciplinary field of research, by venturing upon fundamental problems of probability, transport theory, equilibrium and non-equilibrium statistical mechanics, condensed matter physics, astrophysics and cosmology, physics of plasmas, and hydrodynamics. The thermodynamic and dynamical properties of systems with long-range interactions were poorly understood until a few years ago. Substantial progress has been made only recently by realizing that the lack of additivity induced by long-range interactions does not hinder the development of a consistent thermodynamic formalism. This book reviews the state-of-the-art developments in this field and provides an essential background to future studies. All chapters are written from a pedagogical perspective, making the book accessible to masters and PhD students and all researchers wishing to enter this field.

Self-Healing Polymer-Based Systems presents all aspects of self-healing polymeric materials, offering detailed information on fundamentals, preparation methods, technology, and applications, and drawing on the latest state-of-the-art research. The book begins by introducing self-healing polymeric systems, with a thorough explanation of underlying concepts, challenges, mechanisms, kinetic and thermodynamics, and types of chemistry involved. The second part of the book studies the main categories of self-healing polymeric material, examining elastomer-based, thermoplastic-based, and thermoset-based materials in turn. This is followed by a series of chapters that examine the very latest advances, including nanoparticles, coatings, shape memory, self-healing biomaterials, ionomers, supramolecular polymers, photoinduced and thermally induced self-healing, healing efficiency, life cycle analysis, and characterization. Finally, novel applications are presented and explained. This book serves as an essential resource for academic researchers, scientists, and graduate students in the areas of polymer properties, self-healing materials, polymer science, polymer chemistry, and materials science. In industry, this book contains highly valuable information for R&D professionals, designers, and engineers, who are looking to incorporate self-healing properties in their materials, products, or components.

Statistical Mechanics is the study of systems where the number of interacting particles becomes infinite. In the last fifty years tremendous advances have been made which have required the invention of entirely new fields of mathematics such as quantum groups and affine Lie algebras. They have engendered remarkable discoveries concerning non-linear differential equations and algebraic geometry, and have produced profound insights in both condensed matter physics and quantum field theory. Unfortunately, none of these advances are taught in graduate courses in statistical mechanics.
This book is an attempt to correct this problem. It begins with theorems on the existence (and lack) of order for crystals and magnets and with the theory of critical phenomena, and continues by presenting the methods and results of fifty years of analytic and computer computations of phase transitions. It concludes with an extensive presentation of four of the most important of exactly solved problems: the Ising, 8 vertex, hard hexagon and chiral Potts models.