Unraveling the mystery of the negative thermal expansion of liquid water has been a challenge for scientists for centuries. Various theories have been proposed so far, but none has been able to solve this mystery. Since the thermodynamic properties of matter are determined by the interaction between particles, the mystery can be solved fundamentally if the thermodynamic physical quantities using the laws of thermodynamics and statistical mechanics are determined, the experimental results are reproduced, and the phenomena in relation to the shape of the interaction between particles are elucidated. In this sense, this book has fundamentally unraveled this mystery. In addition, it discusses the mysteries of isothermal compressibility, structural diversity, as well as liquefaction and boiling points of water in relation to the shape of the interaction between particles. It carefully explains the analysis and calculation methods so that they can be easily understood by the readers.

Polymer electronics is the science behind many important new developments in technology, such as the flexible electronic display (e-ink) and many new developments in transistor technology. Solar cells, light-emitting diodes, and transistors are all areas where plastic electronics is likely to, or is already having, a serious impact on our daily lives. With polymer transistors and light-emitting diodes now being commercialised, there is a clear need for a pedagogic text that discusses the subject in a clear and concise fashion suitable for senior undergraduate and graduate students. The content builds on what has been learnt in an elementary (core) course in solid state physics and electronic behaviour, but care has been taken to ensure that important aspects such as the synthesis of these polymers are not overlooked. The chemistry is treated in a manner appropriate to students of physics. Polymer Electronics presents a thorough discussion of the physics and chemistry behind this new and important area of science, appealing to all physical scientists with an interest in the field.

This book reflects the outcome of the 1st International Workshop on Turbulent Spray Combustion held in 2009 in Corsica (France). The focus is on reporting the progress of experimental and numerical techniques in two-phase flows, with emphasis on spray combustion. The motivation for studies in this area is that knowledge of the dominant phenomena and their interactions in such flow systems is essential for the development of predictive models and their use in combustor and gas turbine design. This necessitates the development of accurate experimental methods and numerical modelling techniques. The workshop aimed at providing an opportunity for experts and young researchers to present the state-of-the-art, discuss new developments or techniques and exchange ideas in the areas of experimentations, modelling and simulation of reactive multiphase flows. The first two papers reflect the contents of the invited lectures, given by experts in the field of turbulent spray combustion. The first concerns computational issues, while the second deals with experiments. These lectures initiated very interesting and interactive discussions among the researchers, further pursued in contributed poster presentations. Contributions 3 and 4 focus on some aspects of the impact of the interaction between fuel evaporation and combustion on spray combustion in the context of gas turbines, while the final article deals with the interaction between evaporation and turbulence.

This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell's distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.

Excellent bridge between general solid-state physics textbook and research articles packed with providing detailed explanations of the electronic, vibrational, transport, and optical properties of semiconductors

"The most striking feature of the book is its modern outlook ... provides a wonderful foundation. The most wonderful feature is its efficient style of exposition ... an excellent book." Physics Today

"Presents the theoretical derivations carefully and in detail and gives thorough discussions of the experimental results it presents. This makes it an excellent textbook both for learners and for more experienced researchers wishing to check facts. I have enjoyed reading it and strongly recommend it as a text for anyone working with semiconductors I know of no better text I am sure most semiconductor physicists will find this book useful and I recommend it to them." Contemporary Physics

Offers much new material: an extensive appendix about the important and by now well-established, deep center known as the DX center, additional problems and the solutions to over fifty of the problems at the end of the various chapters."

In this thesis chemical and epitaxial degrees of freedom are used to manipulate charge and spin ordering phenomena in two families of transition metal oxides, while taking advantage of state-of-the-art resonant x-ray scattering (RXS) methods to characterize their microscopic origin in a comprehensive manner. First, the relationship of charge density wave order to both magnetism and the "pseudogap" phenomenon is systematically examined as a function of charge-carrier doping and isovalent chemical substitution in single crystals of a copper oxide high-temperature superconductor. Then, in copper oxide thin films, an unusual three-dimensionally long-range-ordered charge density wave state is discovered, which persists to much higher temperatures than charge-ordered states in other high-temperature superconductors. By combining crystallographic and spectroscopic measurements, the origin of this phenomenon is traced to the epitaxial relationship with the underlying substrate. This discovery opens new perspectives for the investigation of charge order and its influence on the electronic properties of the cuprates. In a separate set of RXS experiments on superlattices with alternating nickel and dysprosium oxides, several temperature- and magnetic-field-induced magnetic phase transitions are discovered. These observations are explained in a model based on transfer of magnetic order and magneto-crystalline anisotropy between the Ni and Dy subsystems, thus establishing a novel model system for the interplay between transition-metal and rare-earth magnetism.

Macromolecular Engineering: Design, Synthesis and Application of Polymers explores the role of macromolecular engineering in the development of polymer systems with engineered structures that offer the desired combination of properties for advanced applications. This book is organized into sections covering theory and principles, science and technology, architectures and technologies, and applications, with an emphasis on the latest advances in techniques, materials, properties, and end uses - and including recently commercialized, or soon to be commercialized, designed polymer systems. The chapters are contributed by a group of leading figures who are actively researching in the field. This is an invaluable resource for researchers and scientists interested in polymer synthesis and design, across the fields of polymer chemistry, polymer science, plastics engineering, and materials science and engineering. In industry, this book supports engineers, R&D, and scientists working on polymer design for application areas such as biomedical and healthcare, automotive and aerospace, construction and consumer goods.

This new edition has been thoroughly revised, expanded and contain some updates function of the novel results and shift of scientific interest in the topics. The book has a Foreword by Jerry L. Bona and Hongqiu Chen. The book is an introduction to nonlinear waves and soliton theory in the special environment of compact spaces such a closed curves and surfaces and other domain contours. It assumes familiarity with basic soliton theory and nonlinear dynamical systems. The first part of the book introduces the mathematical concept required for treating the manifolds considered, providing relevant notions from topology and differential geometry. An introduction to the theory of motion of curves and surfaces - as part of the emerging field of contour dynamics - is given. The second and third parts discuss the modeling of various physical solitons on compact systems, such as filaments, loops and drops made of almost incompressible materials thereby intersecting with a large number of physical disciplines from hydrodynamics to compact object astrophysics. This book is intended for graduate students and researchers in mathematics, physics and engineering.

Given the enormous interest in surface phenomena in areas ranging from materials science to applications in life science, this volume is a very timely addition to the literature. Emphasis is on surfactants mediating interfacial and molecular aggregation phenomena, and the following topics are reviewed in particular: dissolution rates, equilibrium adsorption, mixing rules, and spreading on a solid surface of surfactants, as well as the role of surfactants in mediating a range of processes, such as the fabrication of various nanomaterials. Written and edited by leading experts, this volume is dedicated to Professor Dinesh O. Shah, one of the pioneers in this field.

This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

This book provides an intuitive yet sound understanding of how structure and properties of solids may be related. The natural link is provided by the band theory approach to the electronic structure of solids. The chemically insightful concept of orbital interaction and the essential machinery of band theory are used throughout the book to build links between the crystal and electronic structure of periodic systems. In such a way, it is shown how important tools for understanding properties of solids like the density of states, the Fermi surface etc. can be qualitatively sketched and used to either understand the results of quantitative calculations or to rationalize experimental observations. Extensive use of the orbital interaction approach appears to be a very efficient way of building bridges between physically and chemically based notions to understand the structure and properties of solids.

PHEMT devices and their incorporation into advanced monolithic integrated circuits is the enabling technology for modern microwave/millimeter wave system applications. Although still in its infancy, PHEMT MIMIC technology is already finding applications in both military and commercial systems, including radar, communication and automotive technologies. The successful team in a globally competitive market is one in which the solid-state scientist, circuit designer, system engineer and technical manager are cognizant of those considerations and requirements that influence each other's function. This book provides the reader with a comprehensive review of PHEMT technology, including materials, fabrication and processing, device physics, CAD tools and modelling, monolithic integrated circuit technology and applications. Readers with a broad range of specialities in one or more of the areas of materials, processing, device physics, circuit design, system design and marketing will be introduced quickly to important basic concepts and techniques. The specialist who has specific PHEMT experience will benefit from the broad range of topics covered and the open discussion of practical issues. Finally, the publication offers an additional benefit, in that it presents a broad scope to both the researcher and manager, both of whom must be aware and educated to remain relevant in an ever-expanding technology base.

This thesis is a tour-de-force combination of analytic and computational results clarifying and resolving important questions about the nature of quantum phase transitions in one- and two-dimensional magnetic systems. The author presents a comprehensive study of a low-dimensional spin-half quantum antiferromagnet (the J-Q model) in the presence of a magnetic field in both one and two dimensions, demonstrating the causes of metamagnetism in such systems and providing direct evidence of fractionalized excitations near the deconfined quantum critical point. In addition to describing significant new research results, this thesis also provides the non-expert with a clear understanding of the nature and importance of computational physics and its role in condensed matter physics as well as the nature of phase transitions, both classical and quantum. It also contains an elegant and detailed but accessible summary of the methods used in the thesis-exact diagonalization, Monte Carlo, quantum Monte Carlo and the stochastic series expansion-that will serve as a valuable pedagogical introduction to students beginning in this field.

Quantum wires are artificial structures characterized by nanoscale cross sections that contain charged particles moving along a single degree of freedom. With electronic motions constrained into standing modes along with the two other spatial directions, they have been primarily investigated for their unidimensional dynamics of quantum-confined charge carriers, which eventually led to broad applications in large-scale nanoelectronics. This book is a compilation of articles that span more than 30 years of research on developing comprehensive physical models that describe the physical properties of these unidimensional semiconductor structures. The articles address the effect of quantum confinement on lattice vibrations, carrier scattering rates, and charge transport as well as present practical examples of solutions to the Boltzmann equation by analytical techniques and by numerical simulations such as the Monte Carlo method. The book also presents topics on quantum transport and spin effects in unidimensional molecular structures such as carbon nanotubes and graphene nanoribbons in terms of non-equilibrium Green’s function approaches and density functional theory.

Applications of Polymers in Drug Delivery, Second Edition, provides a comprehensive resource for anyone looking to understand how polymeric materials can be applied to current, new, and emerging drug delivery applications. Polymers play a crucial role in modulating drug delivery and have been fundamental in the successful development of many novel drug delivery systems. This book describes the development of polymeric systems, ranging from conventional dosage forms to the most recent smart systems. Regulatory and intellectual property aspects as well as the clinical applicability of polymeric drug delivery systems are also discussed. The chapters are organized by specific delivery route, offering methodical and detailed coverage throughout. This second edition has been thoroughly revised to include the latest developments in the field. This is an essential book for researchers, scientists, and advanced students, in polymer science, drug delivery, pharmacology/pharmaceuticals, materials science, tissue engineering, nanomedicine, chemistry, and biology. In industry, this book supports scientists, R&D, and other professionals, working on polymers for drug delivery applications.

Crystallography is an interdisciplinary science covering a wide area, from biology to earth sciences, mathematics and materials science. Its role is growing, owing to the contribution crystallography can offer to the understanding of such diverse fields as biological structures, high-temperature superconductors, mineral properties, and phase transitions. The book describes both the theoretical bases and applications of different areas interacting with crystallography. As with the first and second editions, it is organized as a collection of chapters written by recognized specialists, with all contributions being harmonized into a unified whole. The main text is devoted to the presentation of basics; the appendices deal with specialist aspects. In this third edition topics have been updated so as to document the present state of the art: emphasis is placed upon areas of current research.
To facilitate learning and make teaching more effective, new illustrations have been introduced. As with the second edition, a software package is included via the book's OUP web site: modern graphics will help users to better understand the basics of this science via three-dimensional images, simulation of experiments, and exercises.

The interest in the problem of surface diffusion has been steadily growing over the last fifteen years. This is clearly evident from the increase in the number of papers dealing with the problem, the development of new experimental techniques, and the specialized sessions focusing on diffusion in national and international meetings. Part of the driving force behind this increasing activity is our recently acquired ability to observe and possibly control atomic scale phenomena. It is now possible to look selectively at individual atomistic processes and to determine their relative importance during growth and reactions at surfaces. The number of researchers interested in this problem also has been growing steadily which generates the need for a good reference source to farniliarize newcomers to the problem. While the recent emphasis is on the role of diffusion during growth, there is also continuing progress on the more traditional aspects of the problem describing mass transport in an ensemble of particles. Such a description is based on the statistical mechanical analysis of a collection of particles that mutually interact and develop correlations. An average over the multitude of atomistic processes that operate under these conditions is necessary to fully describe the dynamics in the system.

In recent years, ever more electronic devices have started to exploit the advantages of organic semiconductors. The work reported in this thesis focuses on analyzing theoretically the energy level alignment of different metal/organic interfaces, necessary to tailor devices with good performance. Traditional methods based on density functional theory (DFT), are not appropriate for analyzing them because they underestimate the organic energy gap and fail to correctly describe the van der Waals forces. Since the size of these systems prohibits the use of more accurate methods, corrections to those DFT drawbacks are desirable. In this work a combination of a standard DFT calculation with the inclusion of the charging energy (U) of the molecule, calculated from first principles, is presented. Regarding the dispersion forces, incorrect long range interaction is substituted by a van der Waals potential. With these corrections, the C60, benzene, pentacene, TTF and TCNQ/Au(111) interfaces are analyzed, both for single molecules and for a monolayer. The results validate the induced density of interface states model.

Theoretical and experimental studies of phase transitions are at the forefront of modern condensed-matter physics. The seminal insight into the role played by fluctuations led to the renormalization group, an approach that has proved extremely useful in many other fields as well. This text considers a wide variety of problems in the theory of phase transitions, revealing their common features as well as their distinctions. Formal aspects are developed as required in discussions of particular systems, and theory is compared to experiment wherever possible. This book begins with a review of the classical approach, including the main aspects of a self-consistent treatment of systems with broken symmetry and a discussion of the Ginzburg-Landau functional. It then turns to a treatment of the renormalization group, discussing both Wilson's formulation based on Kadanoff's scale invariance as well as the approach using field theory. The authors then turn to a generalized approach using scale equations, which eliminates many of the problems of the other formulations. Subsequent chapters discuss applications of this approach: first to simple models; then to more realistic systems such as complex Heisenberg magnets, antiferromagnets, ferroelectrics, impure systems, and high-T(subscript c) superconductors. Finally, in the last two chapters many of these systems are analyzed within the framework of exactly solvable models. Suitable for advanced undergraduates as well as graduate students in physics, the text assumes some knowledge of statistical mechanics, but is otherwise self-contained.

Colloid-polymer mixtures are subject of intensive research due to their wide range of applicability, for instance in coatings and food-stuffs. This thesis constitutes a fundamental investigation towards a better control over the stability of such suspensions. Through the chapters, different key parameters governing the stability of colloid-polymer mixtures are explored. How the colloid (pigment) shape and the effective polymer-colloid affinity modulate the stability of the suspension are examples of these key parameters. Despise the mostly theoretical results presented, the thesis is written in a format accessible to a broad scientific audience. Some of the equations of state presented might of direct use to experimentalists. Furthermore, new theoretical insights about colloid-polymer mixtures are put forward. These include four-phase coexistences in effective two-component, quantification of depletant partitioning at high colloidal concentrations, multiple re-entrant phase behaviour of the colloidal fluid-solid coexistence, and a condition where polymers are neither depleted nor adsorbed from/to the colloidal surface.

This book provides extensive and novel insights into transport phenomena in MnSi, paving the way for applying the topology and chirality of spin textures to the development of spintronics devices. In particular, it describes in detail the key measurements, e.g. magnetoresistance and nonlinear electronic transport, and multiple material-fabrication techniques based on molecular beam epitaxy, ion-beam microfabrication and micromagnetic simulation. The book also reviews key aspects of B20-type MnSi chiral magnets, which host magnetic skyrmions, nanoscale objects formed by helical spatial spin structures. Readers are then introduced to cutting-edge findings on the material. Furthermore, by reviewing the author's successful experiments, the book provides readers with a valuable update on the latest achievements in the measurement and fabrication of magnetic materials in spintronics.

Self-Healing Polymer-Based Systems presents all aspects of self-healing polymeric materials, offering detailed information on fundamentals, preparation methods, technology, and applications, and drawing on the latest state-of-the-art research. The book begins by introducing self-healing polymeric systems, with a thorough explanation of underlying concepts, challenges, mechanisms, kinetic and thermodynamics, and types of chemistry involved. The second part of the book studies the main categories of self-healing polymeric material, examining elastomer-based, thermoplastic-based, and thermoset-based materials in turn. This is followed by a series of chapters that examine the very latest advances, including nanoparticles, coatings, shape memory, self-healing biomaterials, ionomers, supramolecular polymers, photoinduced and thermally induced self-healing, healing efficiency, life cycle analysis, and characterization. Finally, novel applications are presented and explained. This book serves as an essential resource for academic researchers, scientists, and graduate students in the areas of polymer properties, self-healing materials, polymer science, polymer chemistry, and materials science. In industry, this book contains highly valuable information for R&D professionals, designers, and engineers, who are looking to incorporate self-healing properties in their materials, products, or components.

In the past decade, the field of physics has witnessed renewed advances in physical systems without mirror (parity) symmetry. Experimentally, chiral magnetic skyrmions discovered in real materials have stirred a great deal of interest in future spintronic applications due to their nanoscale size, topological protection, and energy efficiency. Theoretically, the Hall viscosity, a new universal transport coefficient, through the progress in hydrodynamics has triggered extensive theoretical investigation in quantum Hall systems. This book provides an extensive account of skyrmion dynamics, using various analytical tools, especially the field theory Ward identity that is a first principle method using symmetries and the associated conservation equations. The identity revealed that Hall viscosity is a universal part of skyrmion motion. This book leads readers to frontline research in searching for the role of the mysterious Hall viscosity in skyrmion physics, using the interdisciplinary point of view that encompasses high-energy physics, condensed matter, and materials science. It also provides the necessary backgrounds and physical clarity for advanced undergraduates to meaningfully explore its contents through mathematical expressions conveyed in both vector and index notations.

Computational Studies of Crystal Structure and Bonding, by Angelo Gavezzotti Cryo-Crystallography: Diffraction at Low Temperature and More, by Piero Macchi High-Pressure Crystallography, by Malcolm I. McMahon Chemical X-Ray Photodiffraction: Principles, Examples, and Perspectives, by Pance Naumov Powder Diffraction Crystallography of Molecular Solids, by Kenneth D. M. Harris