This thesis presents a comprehensive theoretical description of classical and quantum aspects of plasmonics in three and two dimensions, and also in transdimensional systems containing elements with different dimensionalities. It focuses on the theoretical understanding of the salient features of plasmons in nanosystems as well as on the multifaceted aspects of plasmon-enhanced light-matter interactions at the nanometer scale. Special emphasis is given to the modeling of nonclassical behavior across the transition regime bridging the classical and the quantum domains. The research presented in this dissertation provides useful tools for understanding surface plasmons in various two- and three-dimensional nanostructures, as well as quantum mechanical effects in their response and their joint impact on light-matter interactions at the extreme nanoscale. These contributions constitute novel and solid advancements in the research field of plasmonics and nanophotonics that will help guide future experimental investigations in the blossoming field of nanophotonics, and also facilitate the design of the next generation of truly nanoscale nanophotonic devices.

Density functional theory (DFT) has blossomed in the past few decades into a powerful tool that is used by experimentalists and theoreticians alike. This book highlights the extensive contributions that the DFT-based OLCAO method has made to progress in this field, and it demonstrates its competitiveness for performing ab initio calculations on large and complex models of practical systems. A brief historical account and introduction to the elements of the theory set the stage for discussions on semiconductors, insulators, crystalline metals and alloys, complex crystals, non-crystalline solids and liquids, microstructure containing systems and those containing impurities, defects, and surfaces, biomolecular systems, and the technique of ab initio core level spectroscopy calculation.

Given the enormous interest in surface phenomena in areas ranging from materials science to applications in life science, this volume is a very timely addition to the literature. Emphasis is on surfactants mediating interfacial and molecular aggregation phenomena, and the following topics are reviewed in particular: dissolution rates, equilibrium adsorption, mixing rules, and spreading on a solid surface of surfactants, as well as the role of surfactants in mediating a range of processes, such as the fabrication of various nanomaterials. Written and edited by leading experts, this volume is dedicated to Professor Dinesh O. Shah, one of the pioneers in this field.

This book provides a systematic treatment of the geometrical and transport properties of fractures, fracture networks, and fractured porous media. It is divided into two major parts. The first part deals with geometry of individual fractures and of fracture networks. The use of the dimensionless density rationalizes the results for the percolation threshold of the networks. It presents the crucial advantage of grouping the numerical data for various fracture shapes. The second part deals mainly with permeability under steady conditions of fractures, fracture networks, and fractured porous media. Again the results for various types of networks can be rationalized by means of the dimensionless density. A chapter is dedicated to two phase flow in fractured porous media.

PHEMT devices and their incorporation into advanced monolithic integrated circuits is the enabling technology for modern microwave/millimeter wave system applications. Although still in its infancy, PHEMT MIMIC technology is already finding applications in both military and commercial systems, including radar, communication and automotive technologies. The successful team in a globally competitive market is one in which the solid-state scientist, circuit designer, system engineer and technical manager are cognizant of those considerations and requirements that influence each other's function. This book provides the reader with a comprehensive review of PHEMT technology, including materials, fabrication and processing, device physics, CAD tools and modelling, monolithic integrated circuit technology and applications. Readers with a broad range of specialities in one or more of the areas of materials, processing, device physics, circuit design, system design and marketing will be introduced quickly to important basic concepts and techniques. The specialist who has specific PHEMT experience will benefit from the broad range of topics covered and the open discussion of practical issues. Finally, the publication offers an additional benefit, in that it presents a broad scope to both the researcher and manager, both of whom must be aware and educated to remain relevant in an ever-expanding technology base.

This book presents photoelectron spectroscopy as a valuable method for studying the electronic structures of various solid materials in the bulk state, on surfaces, and at buried interfaces. This second edition introduces the advanced technique of high-resolution and high-efficiency spin- and momentum-resolved photoelectron spectroscopy using a novel momentum microscope, enabling high-precision measurements down to a length scale of some tens of nanometers. The book also deals with fundamental concepts and approaches to applying this and other complementary techniques, such as inverse photoemission, photoelectron diffraction, scanning tunneling spectroscopy, as well as photon spectroscopy based on (soft) x-ray absorption and resonance inelastic (soft) x-ray scattering. This book is the ideal tool to expand readers' understanding of this marvelously versatile experimental method, as well as the electronic structures of metals and insulators.

This book summarizes and records the recent notable advances in diverse topics in organic crystal chemistry, which has made substantial progress along with the rapid development of a variety of analysis and measurement techniques for solid organic materials. This review book is one of the volumes that are published periodically on this theme. The previous volume, published in 2015, systematically summarized the remarkable progress in assorted topics of organic crystal chemistry using organic solids and organic-inorganic hybrid materials during the previous 5 years, and it has been widely read. The present volume also shows the progress of organic solid chemistry in the last 5 years, with contributions mainly by invited members of the Division of Organic Crystal Chemistry of the Chemical Society of Japan (CSJ), together with prominent invited authors from countries other than Japan.

This thesis is a tour-de-force combination of analytic and computational results clarifying and resolving important questions about the nature of quantum phase transitions in one- and two-dimensional magnetic systems. The author presents a comprehensive study of a low-dimensional spin-half quantum antiferromagnet (the J-Q model) in the presence of a magnetic field in both one and two dimensions, demonstrating the causes of metamagnetism in such systems and providing direct evidence of fractionalized excitations near the deconfined quantum critical point. In addition to describing significant new research results, this thesis also provides the non-expert with a clear understanding of the nature and importance of computational physics and its role in condensed matter physics as well as the nature of phase transitions, both classical and quantum. It also contains an elegant and detailed but accessible summary of the methods used in the thesis-exact diagonalization, Monte Carlo, quantum Monte Carlo and the stochastic series expansion-that will serve as a valuable pedagogical introduction to students beginning in this field.

This book provides an intuitive yet sound understanding of how structure and properties of solids may be related. The natural link is provided by the band theory approach to the electronic structure of solids. The chemically insightful concept of orbital interaction and the essential machinery of band theory are used throughout the book to build links between the crystal and electronic structure of periodic systems. In such a way, it is shown how important tools for understanding properties of solids like the density of states, the Fermi surface etc. can be qualitatively sketched and used to either understand the results of quantitative calculations or to rationalize experimental observations. Extensive use of the orbital interaction approach appears to be a very efficient way of building bridges between physically and chemically based notions to understand the structure and properties of solids.

This book reveals unique transport phenomena and functionalities in topological insulators coupled with magnetism and superconductivity. Topological insulators are a recently discovered class of materials that possess a spin-momentum-locked surface state. Their exotic spin texture makes them an exciting platform for investigating emergent phenomena, especially when coupled with magnetism or superconductivity. Focusing on the strong correlation between electricity and magnetism in magnetic topological insulators, the author presents original findings on current-direction-dependent nonreciprocal resistance, current-induced magnetization reversal and chiral edge conduction at the domain wall. In addition, he demonstrates how the coupling between superconductivity and topological surface state leads to substantial nonreciprocal resistance. The author also elucidates the origins of these phenomena and deepens readers' understanding of the topologically nontrivial electronic state. The book includes several works which are published in top journals and were selected for the President's Award by the University of Tokyo and for the Ikushi Prize, awarded to distinguished Ph.D. students in Japan.

This book gives a comprehensive introduction to the field of photovoltaic (PV) solar cells and modules. In thirteen chapters, it addresses a wide range of topics including the spectrum of light received by PV devices, the basic functioning of a solar cell, and the physical factors limiting the efficiency of solar cells. It places particular emphasis on crystalline silicon solar cells and modules, which constitute today more than 90 % of all modules sold worldwide. Describing in great detail both the manufacturing process and resulting module performance, the book also touches on the newest developments in this sector, such as Tunnel Oxide Passivated Contact (TOPCON) and heterojunction modules, while dedicating a major chapter to general questions of module design and fabrication. Overall, it presents the essential theoretical and practical concepts of PV solar cells and modules in an easy-to-understand manner and discusses current challenges facing the global research and development community.

Applications of Polymers in Drug Delivery, Second Edition, provides a comprehensive resource for anyone looking to understand how polymeric materials can be applied to current, new, and emerging drug delivery applications. Polymers play a crucial role in modulating drug delivery and have been fundamental in the successful development of many novel drug delivery systems. This book describes the development of polymeric systems, ranging from conventional dosage forms to the most recent smart systems. Regulatory and intellectual property aspects as well as the clinical applicability of polymeric drug delivery systems are also discussed. The chapters are organized by specific delivery route, offering methodical and detailed coverage throughout. This second edition has been thoroughly revised to include the latest developments in the field. This is an essential book for researchers, scientists, and advanced students, in polymer science, drug delivery, pharmacology/pharmaceuticals, materials science, tissue engineering, nanomedicine, chemistry, and biology. In industry, this book supports scientists, R&D, and other professionals, working on polymers for drug delivery applications.

Existing texts on the statistical mechanics of liquids treat only spherical molecules. However, nearly all fluids of practical interest are composed of non-spherical molecules that are often dipolar or exhibit other kinds of electrostatic forces. This book describes the statistical mechanical theory of fluids of non-spherical molecules and its application to the calculation of physical properties, and is a sequel to Theory of Molecular Fluids. Volume 1: Fundamentals by C.G. Gray and K.E. Gubbins. The emphasis is on the new phenomena that arise due to the non-spherical nature of the intermolecular forces, such as new phase transitions, structural features and dielectric effects. It contains chapters on the thermodynamic properties of pure and mixed fluids, surface properties, X-ray and neutron diffraction structure factors, dielectric properties and spectroscopic properties. The book is aimed at beginning graduate students and research workers in chemistry, physics, materials science and engineering.

This book focuses on the modern development of techniques for analysis of the hierarchical structure of polymers from both the experimental and theoretical points of view. Starting with molecular and crystal symmetry, the author explains fundamental and professional methods, such as wide- and small-angle X-ray scattering, neutron diffraction, electron diffraction, FTIR and Raman spectroscopy, NMR, and synchrotron radiation. In addition, the author explains another indispensable method, computer simulation, which includes energy calculation, lattice dynamics, molecular dynamics, and quantum chemistry. These various methods are described in a systematic way so that the reader can utilize them for the purpose of 3D structure analysis of polymers. Not only such analytical knowledge but also the preparation techniques of samples necessary for these measurements and the methods of analyzing the experimental data collected in this way are given in a concrete manner. Examples are offered to help master the principles of how to clarify the static structures and dynamic structural changes in the phase transitions of various kinds of crystalline polymers that are revealed by these novel methods. The examples are quite useful for readers who want to apply these techniques in finding practical solutions to concrete problems that are encountered in their own research. The principal audience for this book is made up of young professional researchers including those working in industry, but it can also be used as an excellent reference for graduate-level students. This book is the first volume of a two-volume set with Structural Science of Crystalline Polymers: A Microscopically Viewed Structure-Property Relationship being the second volume by the same author.

This book puts forward the concept of the Diameter-Transformed Fluidized Bed (DTFB): a fluidized bed characterized by the coexistence of multiple flow regimes and reaction zones, achieved by transforming the bed into several sections of different diameters. It reviews fundamental aspects, including computational fluid dynamics simulations and industrial practices in connection with DTFB. In particular, it highlights an example concerning the development of maximizing iso-paraffins (MIP) reactors for regulating complex, fluid catalytic cracking reactions in petroleum refineries. The book is a must-have for understanding how academic and industrial researchers are now collaborating in order to develop novel catalytic processes.

In recent years, ever more electronic devices have started to exploit the advantages of organic semiconductors. The work reported in this thesis focuses on analyzing theoretically the energy level alignment of different metal/organic interfaces, necessary to tailor devices with good performance. Traditional methods based on density functional theory (DFT), are not appropriate for analyzing them because they underestimate the organic energy gap and fail to correctly describe the van der Waals forces. Since the size of these systems prohibits the use of more accurate methods, corrections to those DFT drawbacks are desirable. In this work a combination of a standard DFT calculation with the inclusion of the charging energy (U) of the molecule, calculated from first principles, is presented. Regarding the dispersion forces, incorrect long range interaction is substituted by a van der Waals potential. With these corrections, the C60, benzene, pentacene, TTF and TCNQ/Au(111) interfaces are analyzed, both for single molecules and for a monolayer. The results validate the induced density of interface states model.

Crystallography is an interdisciplinary science covering a wide area, from biology to earth sciences, mathematics and materials science. Its role is growing, owing to the contribution crystallography can offer to the understanding of such diverse fields as biological structures, high-temperature superconductors, mineral properties, and phase transitions. The book describes both the theoretical bases and applications of different areas interacting with crystallography. As with the first and second editions, it is organized as a collection of chapters written by recognized specialists, with all contributions being harmonized into a unified whole. The main text is devoted to the presentation of basics; the appendices deal with specialist aspects. In this third edition topics have been updated so as to document the present state of the art: emphasis is placed upon areas of current research.
To facilitate learning and make teaching more effective, new illustrations have been introduced. As with the second edition, a software package is included via the book's OUP web site: modern graphics will help users to better understand the basics of this science via three-dimensional images, simulation of experiments, and exercises.

The interest in the problem of surface diffusion has been steadily growing over the last fifteen years. This is clearly evident from the increase in the number of papers dealing with the problem, the development of new experimental techniques, and the specialized sessions focusing on diffusion in national and international meetings. Part of the driving force behind this increasing activity is our recently acquired ability to observe and possibly control atomic scale phenomena. It is now possible to look selectively at individual atomistic processes and to determine their relative importance during growth and reactions at surfaces. The number of researchers interested in this problem also has been growing steadily which generates the need for a good reference source to farniliarize newcomers to the problem. While the recent emphasis is on the role of diffusion during growth, there is also continuing progress on the more traditional aspects of the problem describing mass transport in an ensemble of particles. Such a description is based on the statistical mechanical analysis of a collection of particles that mutually interact and develop correlations. An average over the multitude of atomistic processes that operate under these conditions is necessary to fully describe the dynamics in the system.

Covers the State of the Art in Superfluidity and Superconductivity Superfluid States of Matter addresses the phenomenon of superfluidity/superconductivity through an emergent, topologically protected constant of motion and covers topics developed over the past 20 years. The approach is based on the idea of separating universal classical-field superfluid properties of matter from the underlying system's "quanta." The text begins by deriving the general physical principles behind superfluidity/superconductivity within the classical-field framework and provides a deep understanding of all key aspects in terms of the dynamics and statistics of a classical-field system. It proceeds by explaining how this framework emerges in realistic quantum systems, with examples that include liquid helium, high-temperature superconductors, ultra-cold atomic bosons and fermions, and nuclear matter. The book also offers several powerful modern approaches to the subject, such as functional and path integrals. Comprised of 15 chapters, this text: Establishes the fundamental macroscopic properties of superfluids and superconductors within the paradigm of the classical matter field Deals with a single-component neutral matter field Considers fundamentals and properties of superconductors Describes new physics of superfluidity and superconductivity that arises in multicomponent systems Presents the quantum-field perspective on the conditions under which classical-field description is relevant in bosonic and fermionic systems Introduces the path integral formalism Shows how Feynman path integrals can be efficiently simulated with the worm algorithm Explains why nonsuperfluid (insulating) ground states of regular and disordered bosons occur under appropriate conditions Explores superfluid solids (supersolids) Discusses the rich dynamics of vortices and various aspects of superfluid turbulence at T 0 Provides account of BCS theory for the weakly interacting Fermi gas Highlights and analyzes the most crucial developments that has led to the current understanding of superfluidity and superconductivity Reviews the variety of superfluid and superconducting systems available today in nature and the laboratory, as well as the states that experimental realization is currently actively pursuing

Theoretical and experimental studies of phase transitions are at the forefront of modern condensed-matter physics. The seminal insight into the role played by fluctuations led to the renormalization group, an approach that has proved extremely useful in many other fields as well. This text considers a wide variety of problems in the theory of phase transitions, revealing their common features as well as their distinctions. Formal aspects are developed as required in discussions of particular systems, and theory is compared to experiment wherever possible. This book begins with a review of the classical approach, including the main aspects of a self-consistent treatment of systems with broken symmetry and a discussion of the Ginzburg-Landau functional. It then turns to a treatment of the renormalization group, discussing both Wilson's formulation based on Kadanoff's scale invariance as well as the approach using field theory. The authors then turn to a generalized approach using scale equations, which eliminates many of the problems of the other formulations. Subsequent chapters discuss applications of this approach: first to simple models; then to more realistic systems such as complex Heisenberg magnets, antiferromagnets, ferroelectrics, impure systems, and high-T(subscript c) superconductors. Finally, in the last two chapters many of these systems are analyzed within the framework of exactly solvable models. Suitable for advanced undergraduates as well as graduate students in physics, the text assumes some knowledge of statistical mechanics, but is otherwise self-contained.

This book deals with the electro-chemo-mechanical properties characteristic of and unique to solid electrode surfaces, covering interfacial electrochemistry and surface science. Electrochemical reactions such as electro-sorption, electro-deposition or film growth on a solid electrode induce changes in surface stress or film stress that lead to transformation of the surface phase or alteration of the surface film. The properties of solid electrode surfaces associated with the correlation between electrochemical and mechanical phenomena are named "electro-chemo-mechanical properties". The book first derives the surface thermodynamics of solid electrodes as fundamentals for understanding the electro-chemo-mechanical properties. It also explains the powerful techniques for investigating the electro-chemo-mechanical properties, and reviews the arguments for derivation of surface thermodynamics of solid electrodes. Further, based on current experimental findings and theories, it discusses the importance of the contribution of surface stress to the transformation of surface phases, such as surface reconstruction and underpotential deposition in addition to the stress evolution during film growth and film reduction. Moreover, the book describes the nano-mechanical properties of solid surfaces measured by nano-indentation in relation to the electro-chemo-mechanical properties. This book makes a significant contribution to the further development of numerous fields, including electrocatalysis, materials science and corrosion science.

In the past decade, the field of physics has witnessed renewed advances in physical systems without mirror (parity) symmetry. Experimentally, chiral magnetic skyrmions discovered in real materials have stirred a great deal of interest in future spintronic applications due to their nanoscale size, topological protection, and energy efficiency. Theoretically, the Hall viscosity, a new universal transport coefficient, through the progress in hydrodynamics has triggered extensive theoretical investigation in quantum Hall systems. This book provides an extensive account of skyrmion dynamics, using various analytical tools, especially the field theory Ward identity that is a first principle method using symmetries and the associated conservation equations. The identity revealed that Hall viscosity is a universal part of skyrmion motion. This book leads readers to frontline research in searching for the role of the mysterious Hall viscosity in skyrmion physics, using the interdisciplinary point of view that encompasses high-energy physics, condensed matter, and materials science. It also provides the necessary backgrounds and physical clarity for advanced undergraduates to meaningfully explore its contents through mathematical expressions conveyed in both vector and index notations.

This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

The second edition of this successful textbook provides an up-to-date account of the optical physics of solid state materials. The basic principles of absorption, reflection, luminescence, and light scattering are covered for a wide range of materials, including insulators, semiconductors and metals. The text starts with a review of classical optics, and then moves on to the treatment of optical transition rates by quantum theory. In addition to the traditional discussion of crystalline materials, glasses and molecular solids are also covered.
The first edition included a number of subjects that are not normally covered in standard texts, notably semiconductor quantum wells, molecular materials, vibronic solid state lasers, and nonlinear optics. The basic structure of the second edition is unchanged, but all of the chapters have been updated and improved. Futhermore, a number of important new topics have been added, including:
DT Optical control of spin
DT Quantum dots
DT Plasmonics
DT Negative refraction
DT Carbon nanostructures (graphene, nanotubes and fullerenes)
DT NV centres in diamond
The text is aimed at final year undergraduates, masters students and researchers. It is mainly written for physicists, but might also be useful for electrical engineers, materials scientists and physical chemists. The topics are written in a clear tutorial style with worked examples, chapter summaries and exercises.
To request a copy of the Solutions Manual, visit: http: //global.oup.com/uk/academic/physics/admin/solutions

Primarily intended for postgraduate students and researchers in the fields of condensed matter science, chemical physics and material science, who plan to use the muon spin rotation, relaxation amd resonance (mSR) techniques, this book combines for the first time a detailed discussion of the physical information contained in the measured polarization functions with real-life examples taken from the literature.
It is divided in three main parts. The first part presents some typical results of the application of mSR and explains the basic principles involved. The second part is the core of this book. It presents a comprehensive discussion of the measured polarisation functions. In the third part we analyse in four chapters selected examples taken from the following fields: diffusion properties of muon and muonium, magnetism, superconductivity, and muonium centres in materials. The book is completed by an epilogue and eight appendices.