Developing innovative efficient and sensitive spectroscopic and optical techniques for studying biomedically relevant molecules, structures and processes in vitro and in vivo is a field of rapidly growing interest. This symposium book covers novel and exciting approaches in biomedical spectroscopy. Several chapters deal with infrared and Raman spectroscopy. These complimentary vibrational spectroscopic techniques are capable of monitoring molecular structures as well as structural changes. Such studies are of interest for understanding diseases at a molecular level as well as for developing techniques for efficient early diagnosis based on molecular structural information. The chapters demonstrate also applications vibrational spectroscopy in proteomics and the characterization of micro organisms. The second section of the book introduces surface enhanced Raman scattering (SERS), demonstrates the application of the effect in the biomedical field and develops the concept of multifunctional nanosensors. The measurement of intrinsic optical signals from biological objects such as nerve tissue are discussed in the next section of the book. Chapters deal also with Coherent anti-Stokes Raman scattering (CARS) and fluorescence fluctuation spectroscopy. Other chapters illustrate how photons of very different energies, in the Terahertz and in the ultra violet range, can be used to retrieve molecular structural information from native biomolecules. The electrical properties of protein molecules adsorbed onto a gold substrate are studied by using a scanning Kelvin nanoprobe in a microarray format. The final chapters in the book demonstrate the powerful combination of different spectroscopic techniques for the characterization of biomolecules as well as native and engineered biomaterials. These chapters combine information from Raman and Inelastic Neutron Scattering, optical absorbance and energy dispersive X-ray analysis, positron annihilation lifetime spectroscopy (PALS), 1H NMR, and 129Xe NMR X-ray diffraction and fluorescence resonance energy transfer.

The purpose of this book is to provide an update on some of the latest research and applications in the broad field of ionic liquids. This volume spans research and development activities ranging from fundamental and experimental investigations to commercial applications. A brief history of the field is included, as well as both new developments and reviews organized in the general topical areas of applications, materials, biomass processing, and fundamental studies. This book attempts to propel the field forward by bringing together contributions from some of the foremost researchers on ionic liquids. Recent products and new large-scale processes using ionic liquids, both in operation and being announced, indicate that an exciting new chapter in this field is about to begin. The authors summarize some of the history, applications, conferences, books, databases, issues related to data quality and toxicity for researchers working in the field of ionic liquids and includes an overview for each proceeding chapter with an introduction about the authors.

This book offers a broad discussion of the concepts required to understand the thermodynamic stability of molecules and bonds and a description of the most important condensed-phase techniques that have been used to obtain that information. Above all, this book attempts to provide useful guidelines on how to choose the "best" data and how to use it to understand chemistry. Although the book assumes some basic knowledge on physical-chemistry, it has been written in a "textbook" style and most topics are addressed in a way that is accessible to advanced undergraduate students. Many examples are given throughout the text, involving a variety of molecules.
This text will provide a good starting point for those who wish to initiate in the field or simply to understand how to assess, to estimate, and to use thermochemical data. It will therefore appeal to a broad range of practicing chemists and particularly to those interested in energetics-structure-reactivity relationships.

Climate change is a major challenge facing modern society. The chemistry of air and its influence on the climate system forms the main focus of this book. Vol. 2 of Chemistry of the Climate System takes a problem-based approach to presenting global atmospheric processes, evaluating the effects of changing air compositions as well as possibilities for interference with these processes through the use of chemistry.

More than four decades have passed since surface-enhanced Raman scattering (SERS) was discovered. In today's world SERS has been established as a plasmon-based spectroscopy with ultra-high sensitivity and versatility at the forefront of the developments in plasmonics. SERS has been developing with the advances in nanoscience and nanotechnology. The "SERS world" has grown up markedly for the last 20 years or so, and recently the wider concept of, plasmon-enhanced spectroscopy was born. Plasmon-enhanced spectroscopy contains not only SERS but also tip-enhanced Raman scattering (TERS), surface-enhanced infrared absorption (SEIRA), surface-enhanced fluorescence (SEF), and more. Through these novel spectroscopies various amazing properties of plasmons have become known, providing new exciting research fields. One of the main purposes of the book is to convey the enthusiastic discussion on plasmon-enhanced spectroscopy at the symposium to the scientific community. This book reports leading-edge advances in the theory of plasmonic enhancement and application of plasmon-enhanced spectroscopy to biology, chemistry, physics, materials science, and medicine. Many books have been published about SERS, but this may be the first time that a book on a wide area of plasmon-enhanced spectroscopy has ever been published. The book consists of two volumes; the second volume discusses TERS, SEIRA, and other topics related to plasmon-enhanced spectroscopy.

More than four decades have passed since surface-enhanced Raman scattering (SERS) was discovered. In today's world SERS has been established as a plasmon-based spectroscopy with ultra-high sensitivity and versatility at the forefront of the developments in plasmonics. SERS has been developing with the advances in nanoscience and nanotechnology. The "SERS world" has grown up markedly for the last 20 years or so, and recently the wider concept of, plasmon-enhanced spectroscopy was born. Plasmon-enhanced spectroscopy contains not only SERS but also tip-enhanced Raman scattering (TERS), surface-enhanced infrared absorption (SEIRA), surface-enhanced fluorescence (SEF), and more. Through these novel spectroscopies various amazing properties of plasmons have become known, providing new exciting research fields. One of the main purposes of the book is to convey the enthusiastic discussion on plasmon-enhanced spectroscopy at the symposium to the scientific community. This book reports leading-edge advances in the theory of plasmonic enhancement and application of plasmon-enhanced spectroscopy to biology, chemistry, physics, materials science, and medicine. Many books have been published about SERS, but this may be the first time that a book on a wide area of plasmon-enhanced spectroscopy has ever been published. The book consists of two volumes; the first volume contains the introductory review by George Schatz followed by eight chapters, which are mainly concerned with SERS.

Polymer-Based Nanoscale Materials for Surface Coatings presents the latest advances and emerging technologies in polymer-based nanomaterials for coatings, focusing on novel materials, characterization techniques, and cutting-edge applications. Sections present the fundamentals of surface preparation and nanocoatings, linking materials and properties, explaining the correlation between morphology, surface phenomena, and surface protection mechanism, and covering theory, modeling and simulation. Other presented topics cover characterization methods, with an emphasis on the latest developments in techniques and approaches. Aging and lifecycle assessment of coated surfaces and coatings are also discussed. Final sections explore advanced applications across a range of fields, including intelligent coatings for biomedical implants, self-healing coatings, syper-hydrophobicity, electroluminescence, sustainable edible coatings, marine antifouling, corrosion resistance, and photocatalytic coatings.

Polymers in Electronics: Optoelectronic Properties, Design, Fabrication, and Applications brings together the fundamentals and latest advances in polymeric materials for electronic device applications, supporting researchers, scientists and advanced students, and approaching the topic from a range of disciplines. The book begins by introducing polymeric materials, their dielectric, optical, and thermal properties, and the essential principles and techniques for polymers as applied to electronics. This is followed by detailed coverage of the key steps in the preparation of polymeric materials for opto-electronic devices, including fabrication methods, materials design, rheology, encapsulation, and conductive polymer mechanisms. The final part of the book focuses on the latest developments in advanced devices, covering the areas of photovoltaics, transistors, light-emitting diodes, and stretchable electronics. In addition, it explains mechanisms, design, fabrication techniques, and end applications. This is a highly valuable resource for researchers, advanced students, engineers and R&D professionals from a range of disciplines.

Circularity of Plastics: Sustainability, Emerging Materials, and Valorization of Waste Plastic takes an innovative, interdisciplinary approach to circularity and sustainability in plastics, with an emphasis on plastic waste and end-of-life treatment and options for recycling, re-use, valorization and development of biomass-based polymers. The book introduces key concepts of sustainable materials, the circular economy, and lifecycle assessment, and discusses challenges in the valorization of waste. Other sections cover the upcycling of waste plastic into new materials and fuels, with dedicated chapters exploring state-of-the-art techniques for conversion to new sustainable polymers, fuel, fine chemicals and carbon nanomaterials. Emerging technologies used to produce functional polymers from renewable feedstocks, including CO2, biomass, natural polymers, polylactic acid (PLA), and polyhydroxyalkanoate-based materials (PHAs) are then explored, with a final chapter focusing on applications of sustainable materials, challenges, and future perspectives. This is a valuable resource for researchers, scientists, engineers, R&D professionals, and advanced students from a range of disciplines and backgrounds, with an interest in sustainable materials, circularity in plastics, and polymer waste and valorization.

Biopolymers: Synthesis, Properties, and Emerging Applications presents the state-of-the-art in biopolymers, bringing together detailed information on synthesis strategies, processing and cutting-edge applications. The book begins by introducing the synthesis, processing and structural and functional properties of smart biopolymers and bionanocomposites. Subsequent chapters focus on the synthesis and preparation of biopolymers with valuable properties or for specific advanced applications, including piezoelectric properties, shape memory properties, biodegradable polymer blends, synthesis and assembly of nanomaterials, synthesis of green biopolymers, and catalytic synthesis of bio-sourced polyesters and polycarbonate, as well as applications in active food packaging, water purification, biomedicine, 3D printing, and automotive. Throughout the book, there are analyses of different synthesis strategies and processing methods and their role and use in different fields of application, whilst the important challenges relating to scalable processing and shaping and micro and nano structuration are also discussed. The book also strives to balance the synthetic aspects of biopolymers with physical principles, highlighting biopolymer-based architectures including composite or hybrid conjugates, providing in-depth discussion of important examples of reaction mechanisms, and exploring potential applications of biopolymer and conjugates, ranging from physical to chemical and biological systems.

Poly(lactic-co-glycolic acid) (PLGA) Nanoparticles for Drug Delivery is a comprehensive guide to PLGA nanoparticles for targeting various diseases, covering principles, formation, characterization, applications, regulations and the latest advances. Sections introduce the fundamental aspects of PLGA nanoparticles for drug delivery, including properties, preparation methods, characterization, drug loading methods, and drug release mechanisms, along with a focus on applications. Application of PLGA nanoparticles for the treatment of cancer, inflammatory, cerebral, cardiovascular, and infectious diseases, as well as in regenerative medicine, photodynamic and photothermal therapy, and gene therapy, are all explained in detail. The final chapters explore recent advances and regulatory aspects. This book is a valuable resource for researchers and advanced students across nanomedicine, polymer science, bio-based materials, chemistry, biomedicine, biotechnology, and materials engineering, as well as for industrial scientists and R&D professionals with an interest in nanoparticles for drug delivery, pharmaceutical formulations and regulations, and development of innovative biodegradable materials.

Advanced Applications of Biobased Materials: Food, Biomedical, and Environmental Applications brings together cutting-edge developments in the preparation and application of biobased materials. The book begins by providing an overview of biobased materials, their classification, and their physical and chemical modifications. This is followed by a section covering the latest techniques in fabrication, processing and characterization. Subsequent chapters are grouped by application area, offering insights into advanced and emerging utilizations of biobased materials in food, biomedical and environmental applications. Sections cover lifecycle assessment, circular economy, sustainability, and future potential. This is a valuable resource for researchers, scientists and advanced students across polymer science, sustainable materials, biomaterials, materials chemistry, composite science, nanotechnology, biomedical engineering, and environmental science, as well a great book for engineers and R&D with an interest in biobased materials for emerging applications in the areas of biomedicine, food and the environment.

Plant Polysaccharides as Pharmaceutical Excipients explores innovative techniques and applications of plant-derived polysaccharides as pharmaceutical excipients. Plant polysaccharides are sustainable, renewable and abundantly available, offering attractive properties in terms of water solubility, swelling ability, non-toxicity and biodegradability. These qualities have resulted in extensive exploration into their applications as excipients in a variety of pharmaceutical dosage forms. This book takes a comprehensive, application-oriented approach, drawing on the very latest research that includes sources, classification and extraction methods of plant polysaccharides. Subsequent chapters focus on plant polysaccharides for individual pharmaceutical applications, enabling the reader to understand their preparation for specific targeted uses. Throughout the book, information is supported by illustrations, chemical structures, flow charts and data tables, providing a clear understanding. Finally, future perspectives and challenges are reviewed and discussed.

In-Silico Approaches to Macromolecular Chemistry helps students, researchers and industry professionals gain a clear overview of the field, giving users the knowledge needed to understand and select the most appropriate tools for conducting and analyzing computational studies. With applications across a broad range of areas, many different methods have been developed for exploring macromolecules in silico, making it difficult for researchers to select the most appropriate for their specific needs. Covering both biopolymers and synthetic polymers, this book familiarizes readers with the theoretical tools and software appropriate for such studies. In addition to providing essential background knowledge on both computational tools and macromolecules, the book presents in-depth studies of in silico macromolecule chemistry, discusses and compares these with experimental studies, and highlights the future potential for such approaches.

As the demands for cleaner, more efficient, reduced and zero carbon emitting transportation increase, the traditional focus of Combustion Chemistry research is stretching and adapting to help provide solutions to these contemporary issues. Combustion Chemistry and the Carbon Neutral Future: What will the Next 25 Years of Research Require? presents a guide to current research in the field and an exploration of possible future steps as we move towards cleaner, greener and reduced carbon combustion chemistry. Beginning with a discussion of engine emissions and soot, the book goes on to discuss a range of alternative fuels, including hydrogen, ammonia, small alcohols and other bio-oxygenates, natural gas, syngas and synthesized hydrocarbon fuels. Methods for predicting and improving efficiency and sustainability, such as low temperature and catalytic combustion, chemical looping, supercritical fluid combustion, and diagnostic monitoring even at high pressure, are then explored. Some novel aspects of biomass derived aviation fuels and combustion synthesis are also covered. Combining the knowledge and experience of an interdisciplinary team of experts in the field, Combustion Chemistry and the Carbon Neutral Future: What will the Next 25 Years of Research Require? is an insightful guide to current and future focus areas for combustion chemistry researchers in line with the transition to greener, cleaner technologies.

Atomically precise metal nanoclusters occupy the gap between discrete atoms and plasmonic nanomaterials, and they offer intriguing physical-chemical properties that can be rationalized in terms of their quantum size effects and discrete electronic states. The atomically precise nature of their structures lends them well to structure-property relationship elucidation, making them particularly useful for informing the rational design of nanoclusters with enhanced performance. Metal Nanocluster Chemistry: Ligand-Protected Metal Nanoclusters With Atomic Precision provides a concise introduction to the study of these useful nanoclusters. Beginning with an introduction to the fundamental concepts of, and prospects for, metal nanoclusters, the book goes on to highlight synthetic methods for controllable preparation. The subsequent chapters then highlight characterization, mechanism of size growth and structure evolution, and physical-chemical properties. Later chapters examine theoretical approaches for calculating and evaluating structures and properties. They also highlight the assembly of nanocluster building blocks and their practical applications. Drawing on the knowledge of its expert author, Metal Nanocluster Chemistry is a useful introductory guide to these exciting structures.

Mathematics for Physical Chemistry, Fifth Edition includes exercises that enable readers to test their understanding and put theory into practice. Chapters are constructed around a sequence of mathematical topics, progressing gradually into more advanced material, before discussing key mathematical skills, including the analysis of experimental data and-new to this edition-complex variables. Includes additional new content on Mathematica and its advanced applications. Drawing on the experience of its expert authors, this book is the ideal supplementary text for practicing chemists and students wanting to sharpen their mathematics skills and understanding of key mathematical concepts for applications across physical chemistry.

Atomic Clusters with Unusual Structure, Bonding and Reactivity: Theoretical Approaches, Computational Assessment and Applications reviews the latest computational tools and approaches available for accurately assessing the properties of a cluster, while also highlighting how such clusters can be adapted and utilized for the development of novel materials and applications. Sections provide an introduction to the computational methods used to obtain global minima for clusters and effectively analyze bonds, outline experimental approaches to produce clusters, discuss specific applications, and explore cluster reactivity and usage across a number of fields. Drawing on the knowledge of its expert editors and contributors, this book provides a detailed guide to ascertaining the stability, bonding and properties of atomic clusters. Atomic clusters, which exhibit unusual properties, offer huge potential as building blocks for new materials and novel applications, but understanding their properties, stability and bonding is essential in order to accurately understand, characterize and manipulate them for further use. Searching for the most stable geometry of a given cluster is difficult and becomes even more so for clusters of medium and large sizes, where the number of possible isomers sharply increase, hence this book provides a unique and comprehensive approach to the topic and available techniques and applications.

Supramolecular Coordination Complexes: Design, Synthesis, and Applications discusses the growth of the field and explores the advantages, opportunities and latest applications of supramolecular complexes. Beginning with an introduction to design principles, synthetic methods, and post-synthetic functionalization of supramolecular complexes, the book goes on to compile the different analytical and computational modeling methods used to understand the structure and functional properties of supramolecular structures. Applications of supramolecular complexes in biomedicine, sensing, catalysis and materials are then explored in detail. Drawing on the knowledge of a global team of experts, this book provides a wealth of interesting information for students and researchers working in the design, synthesis or application of such complexes.

Design and Fabrication of Large Polymer Constructions in Space is a ground-breaking study of the polymeric materials, advanced chemical processes, and cutting-edge technology required in the construction of large polymer-based structures for space, when all steps in the process are carried out in the space environment, whether in orbit, in deep space, or on the surface of a moon, asteroid, or planet. The book begins by introducing the fundamentals and requirements of large constructions and inflatable structures for space. The next section of the book focuses on the utilization of polymeric materials within the space environment, examining the effects on materials (vacuum, plasma, temperature), the possible approaches to polymerization both in space and in orbit, the preparation and structure of polymer composites, and the methods for testing materials and structures in terms of strength, defects, and aging. Three chapters then cover how these materials and techniques might be applied to specific categories of construction, including larger space habitats, supporting space structures, and ground infrastructure. Finally, the financial aspects, the consequences for human space exploitation, and the possible future developments are discussed. Using materials science to push the boundaries of construction for space exploration and exploitation, this book is a unique resource for academic researchers and advanced students across polymer science, advanced materials, chemical engineering, construction, and space engineering, as well as for researchers, scientists and engineers at space agencies, companies and laboratories, involved in developing materials or technology for use in space. This is also of great interest to anyone interested in the role of materials science in the building of large space stations, spacecraft, planetary bases, large aperture antenna, radiation and thermal shields, and repairmen sets.

Inorganic Chemistry in India, Volume 81, the latest release in the Advances in Inorganic Chemistry series, highlights new advances in the field with this new volume presenting interesting chapters on topics such as Water Oxidation and Oxygen Reduction Reactions: A Mechanistic Perspective, Redox Activity as a Tool for Bond Activations and Functionalizations, Heme/Cu-oxygen Intermediates of Amyloid beta Peptides associated with Alzheimer's Disease, N-Heterocyclic Silylene Coordinated Coinage Metal Complexes: An Itinerary of Their Utilities, Implications of strongly coupled catecholate-based anchoring functionality of a sensitizer dye molecule towards photoinduced electron transfer dynamics, and more. Additional sections cover Application of Ru(edta) complexes in biomimetic activation of small molecules: Kinetic and Mechanistic Impact, and more.

Advances in Quantum Chemical Topology Beyond QTAIM provides a complete overview of the field, starting with traditional methods and then covering key steps to the latest state-of-the-art extensions of QTAIM. The book supports researchers by compiling and reviewing key methods, comparing different algorithms, and providing computational results to show the efficacy of the approaches. Beginning with an introduction to quantum chemistry, QTAIM and key extensions, the book goes on to discuss interacting quantum atoms and related energy properties, explores partitioning methods, and compares algorithms for QTAIM. Partitioning schemes are them compared in more detail before applications are explored and future developments discussed. Drawing together the knowledge of key authorities in the area, this book provides a comprehensive, pedogeological guide to this insightful theory for all those interested in modelling, exploring and understanding molecular properties.

Plastics and Sustainability: Practical Approaches provides a broad overview of sustainability as applied to plastics, offering a range of opportunities and solutions to be applied in an academic or industrial setting. The book begins by introducing the challenges and opportunities relating to plastics and environmental sustainability. This is followed by detailed eco-profiles organized by polymer category. Subsequent chapters explore various approaches to plastics sustainability, with in-depth coverage of incineration technology for energy recovery, pyrolysis for chemical recovery, blending technology, design, packaging, circular economy, and biopolymers. Finally, international policies are summarized. The book aims to provide a broad source of information and a range of options to readers on how to evaluate and improve the sustainability of plastics, with analyses of the advantages and drawbacks of different technologies and materials. Authored by two professional engineers with substantial experience in industry and consultancy, this is a valuable resource for all those looking for a wide-ranging overview of sustainability as applied to plastics, including researchers and advanced students from a range of materials science and engineering disciplines, and engineers, manufacturers, scientists, and R&D professionals from a range of industries.