This work studies the magnetic behavior of ZnO nanoparticles capped with different organic molecules and showing room-temperature ferromagnetism (RTFM). Of particular significance is the combination of element-specific X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) techniques, which demonstrates the intrinsic occurrence of RTFM in these systems and indicates that it is not related to the 3-D states of the metallic cation but is relayed along the conduction band of the semiconductor. The discovery of room-temperature ferromagnetism (RTFM) in semiconductors holds great promise in future spintronics technologies. Further results presented here include O K-edge XMCD studies, which demonstrate that the oxygen ions have a ferromagnetic response in these ZnO-based systems, providing the first direct support for claims regarding the appearance of oxygen ferromagnetism in oxide semiconductors at the nanoscale.

The topics discussed in this book focus on fundamental problems concerning the structural relaxation of amorphous metallic alloys, above all the possibility of studying it on the basis of viscous flow behavior and its relation to rheological anomalies, such as bend stress relaxation, thermal expansion, specific heat, density changes, and crystallization. Most relaxation studies deal with the relaxation changes of a single definite material property, and not with a wider spectrum of physical properties integrated into a common framework. This book shows that it is possible to describe these property changes on the basis of a more comprehensive theoretical understanding of their mechanism.

This book focuses on the use of bio-inspired and biomimetic methods for the fabrication and activation of nanomaterials. This includes studies concerning the binding of the biomolecules to the surface of inorganic structures, structure/function relationships of the final materials and extensive discussions on the final applications of such biomimetic materials in unique applications including energy harvesting/storage, biomedical diagnostics and materials assembly.

This book highlights the manufacturing and applications of acoustic textiles in various industries. It also includes examples from different industries in which acoustic textiles can be used to absorb noise and help reduce the impact of noise at the workplace. Given the importance of noise reduction in the working environment in several industries, the book offers a valuable guide for companies, educators and researchers involved with acoustic materials.

This book covers the recent research advances on the utilization of date palm fibers as a new source of cellulosic fibers that can be used in the reinforcement of polymer composites. It discusses the competitive mechanical, physical, and chemical properties which make date palm fibers stand out as an alternative to other fibers currently used in the natural fiber composites market. This volume will be useful to researchers working on natural fiber composites and fiber reinforced composites looking to develop green, biodegradable and sustainable components for application in automotive, marine, aerospace, construction, wind energy and consumer goods sectors.

Describes high temperature corrosion of ceramics. In addition to pure single crystals or CVD materials, typical engineering materials of various purities were also studied. The environments used to produce corrosion were selected based on the likelihood of their being encountered in practice and their severity. The ceramic materials developed corrosion resistance by being immune to the environment or by developing passivity.

This volume describes the most recent findings on the structure of ILs interpreted through cutting-edge experimental and theoretical methods. Research in the field of ionic liquids (ILs) keeps a fast and steady pace. Since these new-generation molten salts first appeared in the chemistry and physics landscape, a large number of new compounds has been synthesized. Most of them display unexpected behaviour and possess stunning properties. The coverage in this book ranges from the mesoscopic structure of ILs to their interaction with proteins. The reader will learn how diffraction techniques (small and large angle X-Ray and neutron scattering, powder methods), X-Ray absorption spectroscopies (EXAFS/XANES), optical methods (IR, RAMAN), NMR and calorimetric methods can help the study of ILs, both as neat liquids and in mixtures with other compounds. It will enable the reader to choose the best method to suit their experimental needs. A detailed survey of theoretical methods, both quantum-chemical and classical, and of their predictive power will accompany the exposition of experimental ones. This book is a must read for postgraduate students, for post-docs, and for researchers who are interested in understanding the structural properties of ILs.

This book presents theoretical and experimental investigations of mechanical behavior of solids under shock loading and highlights a multi-scale exchange process of energy and momentum between meso and macroscopic hierarchy. It also widely covers experimental approaches for the multi-scale response of solids to impacts including uniaxial strain conditions and high-velocity penetration processes. The content comprises two parts. The first part overviews modeling and theory of dynamically deformed solids from the multi-scale point of view. The second part describes experimental characterization of shock-induced solids and experimental probing of mesostructured and mesoscale dynamic processes in solids. The theory presented in the first part is then verified as it is compared with i) experiments of shock loading into different kinds of solids and ii) probed microstructure of post-shocked specimens by scanning electron microscopy, transmission electron microscopy and optical microscopy. The text is written on the basis of author's lectures at universities and thus is concisely described for postgraduate students. It is also useful for researchers who work on the theory of multi-scale mechanics of solids and engineers who work on testing materials under dynamic loading.

The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This comprehensive collection provides an unprecedented extensive bilingual dictionary on the subject of solar energy and helps users understand all the terms, abbreviations, phrases, and synonyms of solar energy and technology. Over 8000 entries also include subjects like solar infrastructures, components and other alternative energy technologies due to recent solar hybrid technology developments. See also: Vol. 2, the accompanying encyclopedia.

Nanotechnology is an interdisciplinary research field that integrates chemistry, engineering, biology, and medicine. Nanomaterials offer tremendous opportunity as well as challenges for researchers. Of course, cancer is one of the world's most common health problems, responsible for many deaths. Exploring efficient anticancer drugs could revolutionize treatment options and help manage cancer mortality. Nanomedicine plays a significant role in developing alternative and more effective treatment strategies for cancer theranostics. This book mainly focuses on the emerging trends using nanomaterials and nanocomposites as alternative anticancer material's. The book is divided into three main topic areas: how to overcome existing traditional approaches to combat cancer, applying multiple mechanisms to target the cancer cells, and how nanomaterials can be used as effective carriers. The contents highlight recent advances in interdisciplinary research on processing, morphology, structure, and properties of nanostructured materials and their applications to combat cancer.Cancer Nanotheranostics is comprehensive in that it discusses all aspects of cancer nanotechnology. Because of the vast amount of information, it was decided to split this material into two volumes. In the first volume of Cancer Nanotheranostics, we discuss the role of different nanomaterials for cancer therapy, including lipid-based nanomaterials, protein and peptide-based nanomaterials, polymer-based nanomaterials, metal-organic nanomaterials, porphyrin-based nanomaterials, metal-based nanomaterials, silica-based nanomaterials, exosome-based nanomaterials and nano-antibodies. In the second volume, we discuss the nano-based diagnosis of cancer, nano-oncology for clinical applications, nano-immunotherapy, nano-based photothermal cancer therapy, nano-erythrosomes for cancer drug delivery, regulatory perspectives of nanomaterials, limitations of cancer nanotheranostics, the safety of nano-biomaterials for cancer nanotheranostics, multifunctional nanomaterials for targeting cancer nanotheranostics, and the role of artificial intelligence in cancer nanotheranostics.

This handbook is a valuable resource for scientists, engineers, graduate students, managers, decision makers, and those who are interested in ionic liquids. Many industrial applications rely on the use of Ionic Liquid Mixtures, as in solar energy storage, waste recycling or batteries.Physicochemical Properties of Ionic Liquid Mixtures is a useful handbook that contains the following features: - the physicochemical properties and property models of mixtures containing ionic liquids - supplemented by a comprehensive database of properties listing ionic liquid systems collected from more than 800 dependable literature sources - over 60,000 data entries on 39 types of physicochemical properties for 1388 mixtures, including binary, ternary, quaternary and other mixtures.

The sea is steadily rising, presently at ~3.4 mm/y, already costing Billions in Venice, on the Thames River and in New York City, to counter sea-level-related surges. Experts anticipate an accelerated rise, and credible predictions for sea level rise by the year 2100 range from 12 inches to above 6 feet. Study of the Earth's geologic history, through ice-core samples, links sea level rise to temperature rise. Since the lifetime of carbon dioxide in the atmosphere is measured in centuries, and it has upset the balance of incoming and outgoing energy, the Earth's temperature will continue to rise, even if carbon burning ceases. Engineering the Earth's solar input appears increasingly attractive and practical as a means to lower Earth's temperature, and thus, to lower sea level. The cost of engineering the climate appears small, comparable, even, to the already-incurred costs of sea level rise represented by civil engineering projects in London, Venice and New York City. Feasible deployment of geoengineering, accompanied by some reduction in carbon burning, is predicted to lower the sea level by the order of one foot by 2100 AD, negating the expected rise, to provide an immense economic benefit. The accompanying lower global temperature would reduce the severity of extreme weather, and restore habitability to lethally hot parts of the world. This book is primarily conceived to aid and inform the educated citizen: aspects may also interest climate workers.

While nanotechnology has been a booming research field for years, the study of how it can be used alongside water engineering has not been deeply explored. By examining the ways in which nanomaterials can aid hydraulics, these tools can be used for water purification, water treatments, and a vast array of other uses that will make water engineering easier and safer. Advanced Nanomaterials for Water Engineering, Treatment, and Hydraulics is a comprehensive reference source for the latest research-based material on the use of progressive nanotechnologies for water technologies. Featuring coverage on relevant topics such as water purification, nano-metal oxides, chitosan nanoparticles, and contaminated waste water, this is an ideal reference source for engineers, students, academics, and researchers seeking innovative perspectives on the use of nanomaterials in water engineering.

This book provides a representative selection of the most relevant, innovative, and useful mathematical methods and models applied to the analysis and characterization of composites and their behaviour on micro-, meso-, and macroscale. It establishes the fundamentals for meaningful and accurate theoretical and computer modelling of these materials in the future. Although the book is primarily concerned with fibre-reinforced composites, which have ever-increasing applications in fields such as aerospace, many of the results presented can be applied to other kinds of composites. The topics covered include: scaling and homogenization procedures in composite structures, thin plate and wave solutions in anisotropic materials, laminated structures, instabilities, fracture and damage analysis of composites, and highly efficient methods for simulation of composites manufacturing. The results presented are useful in the design, fabrication, testing, and industrial applications of composite components and structures. The book is written by well-known experts in different areas of applied mathematics, physics, and composite engineering and is an essential source of reference for graduate and doctoral students, as well as researchers. It is also suitable for non-experts in composites who wish to have an overview of both the mathematical methods and models used in this area and the related open problems requiring further research.

This unique monograph covers recent theoretical and experimental results on the complex character of f electrons in materials containing lanthanides (rare earths) or actinides, such as alpha-cerium and delta-plutonium. It answers the urgent need for a general presentation of the body of experimental and theoretical results presently available in this challenging domain. Some of the fast developing applications of lanthanide and actinide materials are mentioned. Materials containing atoms with an open f shell have electronic and crystalline properties that are controlled by the localized or delocalized character of the f electrons. This book gives a theoretical discussion of the various spectroscopic methods that shed light on the character of the f electrons and on the connection between their localization and the properties of these materials. Part 1 covers the characteristics of the f electrons in atoms and solids and includes a discussion of the properties of lanthanides and actinides in connection with the f electrons. Part 2 describes the various spectroscopic methods that are used to establish the electronic distributions and energies of the states. Examples involve the determination of f electron distributions by high energy spectroscopy methods with separate treatment of the valence and core electrons. Part 3 concentrates on the theoretical treatment of electronic transitions involving f electrons and simulations of the lanthanide spectra, including comparison with the available experimental data. Part 4 discusses the localized or delocalized character of the f electrons in actinides and their compounds, including comparison (analogies & differences) between the 4f and 5f electron materials. This monograph should be of great value for researchers, academics and engineers working in the fields of high energy spectroscopy, electronic and nuclear science and technology, as well as materials involving rare earths and radio-elements.

This book focuses on molecular space chemistry, which is recognized as an important concept for the design of novel functional materials and catalysts. A wide variety of topics and ideas included in this book are based on that concept. The book showcases recent representative examples of molecular space design to create functional materials and catalysts possessing unique properties. This unique volume will be of great interest to chemists in a wide variety of research fields, including organic, inorganic, biological, polymer, and supramolecular chemistry. Readers will obtain new ideas and directions to create novel functional molecules, and those ideas will lead to innovative views of science.

This book sheds light on the shear behavior of Fiber Reinforced Concrete (FRC) elements, presenting a thorough analysis of the most important studies in the field and highlighting their shortcomings and issues that have been neglected to date. Instead of proposing a new formula, which would add to an already long list, it instead focuses on existing design codes. Based on a comparison of experimental tests, it provides a thorough analysis of these codes, describing both their reliability and weaknesses. Among other issues, the book addresses the influence of flange size on shear, and the possible inclusion of the flange factor in design formulas. Moreover, it reports in detail on tests performed on beams made of concrete of different compressive strengths, and on fiber reinforcements to study the influence on shear, including size effects. Lastly, the book presents a thorough analysis of FRC hollow core slabs. In fact, although this is an area of great interest in the current research landscape, it remains largely unexplored due to the difficulties encountered in attempting to fit transverse reinforcement in these elements.

Product reliability is the major aim of technological know-how. Uninterrupted performance of manufactured products at typical and extreme conditions of its use is the major goal of product development and the most important indicator of material quality.

This book provides information on defect formation and materials damage. The following aspects of material performance are discussed:

1 Effect of composition, morphological features, and structure of different materials on material performance, durability, and resilience

2 Analysis of causes of material damage and degradation

3 Effect of processing conditions on material damage

4 Effect of combined action of different degradants on industrial products

5 Systematic analysis of existing knowledge regarding the modes of damage and morphology of

damaged material

6 Methods of analysis of material damage

7 Comparison of experiences generated in different sectors of industry regarding the most frequently encountered failures, reasons for these failures, and potential improvements preventing future damage

The name "Atlas" was selected to indicate emphasis of the book on illustration with many real examples of damaged products and discussion of causes of damage and potential for material improvements.

Special chapter contains examples of damage encountered in different groups of industrial products. Each group of materials is discussed according to the following breakdown:

1 Examples of damage typically encountered in a group under discussion

2 Results of structural analysis of degradation (e.g., image analysis, surface and bulk mapping by analytic techniques such as NMR, XPS, thermography, etc.)

3 Credit to the source of images, references, and explanations

4 Conditions under which material was degraded

5 Discussion of morphological features and observations
Data and images are provided for many material types, making this a hard-working reference guide for engineers working in a range of different market sectors.As well as providing core data, this reference explains the range of test and imaging techniques available, enabling engineers and scientists to take optimal and cost effective decisions.An essential tool for identifying material damage and implementing successful maintenance and replacement regimes.

This book presents developments of techniques for detection and analysis of two electrons resulting from the interaction of a single incident electron with a solid surface. Spin dependence in scattering of spin-polarized electrons from magnetic and non-magnetic surfaces is governed by exchange and spin-orbit effects. The effects of spin and angular electron momentum are shown through symmetry of experimental geometries: (i) normal and off normal electron incidence on a crystal surface, (ii) spin polarization directions within mirror planes of the surface, and (iii) rotation and interchange of detectors with respect to the surface normal. Symmetry considerations establish relationships between the spin asymmetry of two-electron distributions and the spin asymmetry of Spectral Density Function of the sample, hence providing information on the spin-dependent sample electronic structure. Detailed energy and angular distributions of electron pairs carry information on the electron-electron interaction and electron correlation inside the solid. The "exchange - correlation hole" associated with Coulomb and exchange electron correlation in solids can be visualized using spin-polarized two-electron spectroscopy. Also spin entanglement of electron pairs can be probed. A description of correlated electron pairs generation from surfaces using other types of incident particles, such as photons, ions, positrons is also presented.

This book gathers the best peer-reviewed papers presented at the Italian Concrete Days national conference, held in Lecco, Italy, on June 14-15, 2018. The conference topics encompass the aspects of design, execution, rehabilitation and control of concrete structures, with particular reference to theory and modeling, applications and realizations, materials and investigations, technology and construction techniques. The contributions amply demonstrate that today's structural concrete applications concern not only new constructions, but more and more rehabilitation, conservation, strengthening and seismic upgrading of existing premises, and that requirements cover new aspects within the frame of sustainability, including environmental friendliness, durability, adaptability and reuse of works and / or materials. As such the book represents an invaluable, up-to-the-minute tool, providing an essential overview of structural concrete, as well as all new materials with cementitious matrices.

This thesis combines advanced femtosecond laser micro/nanofabrication technologies and frontier bionic design principles to prepare diverse biomimetic micro/nanostructures to realize their functions. By studying the formation mechanism of the micro/nanostructures, the author identifies various artificial structural colors, three-dimensional micro/nanocage arrays, and fish-scale inspired microcone arrays in different processing environments. Multiple functions such as enhanced antireflection, hydrophobicity, and underwater superoleophobicity are achieved by precisely adjusting laser-machining parameters. This novel design and method have extensive potential applications in the context of new colorizing technologies, microfluidics, microsensors, and biomedicine.

This book provides an overview of multiscale approaches and homogenization procedures as well as damage evaluation and crack initiation, and addresses recent advances in the analysis and discretization of heterogeneous materials. It also highlights the state of the art in this research area with respect to different computational methods, software development and applications to engineering structures. The first part focuses on defects in composite materials including their numerical and experimental investigations; elastic as well as elastoplastic constitutive models are considered, where the modeling has been performed at macro- and micro levels. The second part is devoted to novel computational schemes applied on different scales and discusses the validation of numerical results. The third part discusses gradient enhanced modeling, in particular quasi-brittle and ductile damage, using the gradient enhanced approach. The final part addresses thermoplasticity, solid-liquid mixtures and ferroelectric models. The contents are based on the international workshop "Multiscale Modeling of Heterogeneous Structures" (MUMO 2016), held in Dubrovnik, Croatia in September 2016.