Handbook of Material Weathering, Sixth Edition, is an essential guide to the effects of weathering on polymers and industrial products, presenting theory, stress factors, methods of weathering and testing and the effects of additives and environmental stress cracking. The book provides graphical illustrations and numerical data to examine the weathering of major polymers and industrial products, including mechanisms of degradation, effect of thermal processes, and characteristic changes in properties. The book also discusses recycling, corrosion and weathering, and the weathering of stone. This sixth edition updates this seminal work with recent developments and the latest data. Polymers and industrial plastics products are widely used in environments where they are vulnerable to the effects of weathering. Weathering stress factors can lead to deterioration or even complete failure. Material durability is therefore vital, and products for outdoor usage or actinic exposure are designed so that the effects of artificial and natural weathering are minimized. This book is an important reference source for those involved in studying material durability, producing materials for outdoor use and actinic exposure, research chemists in the photochemistry field, chemists and material scientists designing new materials, users of manufactured products, those who control the quality of manufactured products and students who want to apply their knowledge to real materials.

Heat resistant layers are meant to withstand high temperatures while also protecting against all types of corrosion and oxidation. Therefore, the micro-structure and behavior of such layers is essential in understanding the functionality of these materials in order to make improvements. Production, Properties, and Applications of High Temperature Coatings is a critical academic publication which examines the methods of creation, characteristics, and behavior of materials used in heat resistant layers. Featuring coverage on a wide range of topics such as, thermal spray methods, sol-gel coatings, and surface nanoengineering, this book is geared toward students, academicians, engineers, and researchers seeking relevant research on the methodology and materials for producing effective heat resistant layers.

Nanodiamonds: Advanced Material Analysis, Properties and Applications illustrates the complementarity of specific techniques to fully characterize nanodiamonds from their diamond core (crystalline structure, defects, sp2 carbon, impurities, strain) to their surface (surface chemistry, stability of surface groups, reactivity, surface charge, colloidal properties). The relationship between physical and chemical parameters sits at the heart of what this book is about. Recent advances in the synthesis of nanodiamonds either by HPHT or detonation are covered, along with extended characterization of the core and surface of nanodiamonds, focusing on the most advanced experimental tools developed for nanoscale diagnosis. Each technique presented includes presentation of both principles and applications. This combination of advanced characterizations offers readers a better understanding of the relationship that exists between physical and chemical parameters of nanodiamonds and their properties. In particular, the role of structural defects or chemical impurities is illustrated. Toxicity of nanodiamonds for cells is also discussed, as It is an essential issue for their bioapplications. Final sections in the book cover the main promising new advances and applications of nanodiamonds, the formation of hybrids, and their use in polymer and oil composites.

This book is the first volume in a two-volume compilation on controlled/living radical polymerization. It combines all important aspects of controlled radical polymerization: from synthetic procedures, to rational selection of reaction components, to understanding of the reaction mechanisms, to materials and applications.
This book is focused on recent progress in the rapidly developing field of controlled/living radical polymerization. It is a sequel to ACS Symposium Series 685, 768, 854, 944, 1023, and 1024. Volume 1100 deals with the mechanistic aspects of controlled radical polymerization and describes the recent advances in the most important techniques, whereas Volume 1101 contains chapters on new materials prepared by controlled radical polymerization as well as applications of these materials.

Strengthening of Concrete Structures Using Fiber Reinforced Polymers (FRP): Design, Construction and Practical Applications presents a best practice guide on the structural design and strengthening of bridge structures using advanced Fiber Reinforced Polymer (FRP) composites. The book briefly covers the basic concepts of FRP materials and composite mechanics, while focusing on practical design and construction issues, including inspection and quality control, paying special attention to the differences in various design codes (US, Japan, and Europe) and recommendations. At present, several design guides from the US, Japan, and Europe are available. These guidelines are often inconsistent and do not cover all necessary design and inspection issues to the same degree of detail. This book provides a critical review and comparison of these guidelines, and then puts forward best practice recommendations, filling a significant gap in the literature, and serving as an important resource for engineers, architects, academics, and students interested in FRP materials and their structural applications. Written from a practitioner's point-of-view, it is a valuable design book for structural engineers all over the world.

Rheology: Concepts, Methods and Applications, Third Edition provides a thorough historical and theoretical grounding in the field, and introduces rheology as the method of solving many practical problems in materials science and engineering. The book is practical and relevant for industry, but is also consistent with rheology courses in academia, making it relevant to both academics and accomplished rheologists in industry. The first four chapters discuss various aspects of theoretical rheology and, through examples from numerous studies, show how particular theories, models, or equations can be used in solving different problems. The shared experience and insight contained in these chapters assists practitioners carrying out rheological studies in generating relevant data. This helps to avert costly errors in analysis which are common when data are generated under the wrong conditions, or are incorrectly used. The fifth chapter covers methods of measurement and treatment of raw data-eight groups of methods are discussed in this chapter, providing the reader with many options for experimentation, along with guidance on where and how to use them properly. The final chapter demonstrates how to use rheological methods for different groups of products and manufacturing methods. The usefulness of chemorheological (rheokinetical) measurements is also emphasized. The chapter has a particular emphasis on real-world applications of rheology, and gives practical guidance to enable materials scientists to gather data and solve problems using these methods. This book is a systematic presentation of the subject of rheology-written by two of the foremost researchers in the field-showing the subject as an interrelated system of concepts, principal phenomena, experimental methods, and directions of their application. It also links with other branches of theoretical and applied sciences.

Defect Structure and Properties of Nanomaterials: Second and Extended Edition covers a wide range of nanomaterials including metals, alloys, ceramics, diamond, carbon nanotubes, and their composites. This new edition is fully revised and updated, covering important advances that have taken place in recent years. Nanostructured materials exhibit unique mechanical and physical properties compared with their coarse-grained counterparts, therefore these materials are currently a major focus in materials science. The production methods of nanomaterials affect the lattice defect structure (vacancies, dislocations, disclinations, stacking faults, twins, and grain boundaries) that has a major influence on their mechanical and physical properties. In this book, the production routes of nanomaterials are described in detail, and the relationships between the processing conditions and the resultant defect structure, as well as the defect-related properties (e.g. mechanical behavior, electrical resistance, diffusion, corrosion resistance, thermal stability, hydrogen storage capability, etc.) are reviewed. In particular, new processing methods of nanomaterials are described in the chapter dealing with the manufacturing procedures of nanostructured materials. New chapters on (i) the experimental methods for the study of lattice defects, (ii) the defect structure in nanodisperse particles, and (iii) the influence of lattice defects on electrical, corrosion, and diffusion properties are included, to further enhance what has become a leading reference for engineering, physics, and materials science audiences.

The world of nanomaterials is complex; there is dubiety as well as unrealistic optimism about costs, practicality, timing for the availability of, and the true capabilities of products featured in the news. The progress of the industry is being affected from the incertitude generated by the multitudinous names used, coupled with lack of clarity and standardization in the definitions for carbonaceous nanomaterials, such as graphene, graphene oxide, nanographene, nanographene flakes, nanographite flakes, graphene nanoribbons, single-layer graphene, few-layer graphene, nanographite, nanotubes, nanofibers. In this perspicuous book about the carbonaceous nanomaterial domain, the author concisely covers nomenclature, characteristics, applications, costs, and manufacturing; all with the cardinal goal to offer the reader a reality check by delineating the steps to commercialization. Along the way, he also examines the cost impact of the touted applications and the boundaries of market adoption. Through references and personal experience, the author makes a compelling case for the market readiness of a mostly neglected class of nanomaterials known as Graphitic Nanofibers. Includes varied levels of technical focus and financial analyses to appeal to a range of skills and interests.

Materials for Bone Disorders is written by a cross-disciplinary team of research scientists, engineers, and clinicians and bridges the gap between materials science and bone disorders, providing integrated coverage of biomaterials and their applications. The bioceramics, biopolymers, composites, and metallic materials used in the treatment of bone disorders are introduced, as are their interactions with cells, biomolecules, and body tissues. The main types of bone disorder and disease are covered including osteoporosis, spinal injury, load bearing joint diseases, bone cancer, and forms of cranio-maxillofacial disorders. Bone disorders are common across all ages. Various forms of bone disorders can change the lifestyle of otherwise normal and healthy people. With the development of novel materials, many forms of bone disorders are becoming manageable, allowing people to lead a fairly normal life. Specific consideration is given to areas where recent advances are enabling new treatments, such as the use of resorbable ceramics in bone tissue engineering and drug delivery, newer polymer-based implants in load-bearing contexts, and engineering biomaterials surfaces including modifying surface chemistry. Ethical and regulatory issues are also explored.

Metallic Foam Bone: Processing, Modification and Characterization and Properties examines the use of porous metals as novel bone replacement materials. With a strong focus on materials science and clinical applications, the book also examines the modification of metals to ensure their biocompatibility and efficacy in vivo. Initial chapters discuss processing and production methods of metals for tissue engineering and biomedical applications that are followed by topics on practical applications in orthopedics and dentistry. Finally, the book addresses the surface science of metallic foam and how it can be tailored for medical applications. This book is a valuable resource for materials scientists, biomedical engineers, and clinicians with an interest in innovative biomaterials for orthopedic and bone restoration.

Since the initial predictions for the existence of Weyl fermions in condensed matter, many different experimental techniques have confirmed the existence of Weyl semimetals. Among these techniques, optical responses have shown a variety of effects associated with the existence of Weyl fermions. In chiral crystals, we find a new type of fermions protected by crystal symmetries — the chiral multifold fermions — that can be understood as a higher-spin generalization of Weyl fermions. This work provides a complete description of all chiral multifold fermions, studying their topological properties and the k·p models describing them. We compute the optical conductivity of all chiral multifold fermions and establish their optical selection rules. We find that the activation frequencies are different for each type of multifold fermion, thus constituting an experimental fingerprint for each type of multifold fermion. Building on the theoretical results obtained in the first part of our analysis, we study two chiral multifold semimetals: RhSi and CoSi. We analyze the experimental results with k·p and tight-binding models based on the crystal symmetries of the material. We trace back the features observed in the experimental optical conductivity to the existence of multifold fermions near the Fermi level and estimate the chemical potential and the scattering lifetime in both materials. Finally, we provide an overview of second-order optical responses and study the second-harmonic generation of RhSi. We find a sizeable second-harmonic response in the low-energy regime associated with optical transitions between topological bands. However, this regime is extremely challenging to access with the current experimental techniques. We conclude by providing an overview of the main results, highlighting potential avenues to further research on chiral multifold semimetals and the future of optical responses as experimental probes to characterize topological phases.

The surface modification of biomaterials plays a significant role in determining the outcome of biological-material interactions. With the appropriate modification a material's surface can be tailored to improve biocompatibility, adhesion and cell interactions. Consequently surface modification is vital in the development and design of new biomaterials and medical devices. Surface modification of biomaterials reviews both established surface modifications and those still in the early stages of research and discusses how they can be used to optimise biological interactions and enhance clinical performance. Part one begins with chapters looking at various types and techniques of surface modification including plasma polymerisation, covalent binding of poly (ethylene glycol) (PEG), heparinisation, peptide functionalisation and calcium phosphate deposition before going on to examine metal surface oxidation and biomaterial surface topography to control cellular response with particular reference to technologies, cell behaviour and biomedical applications. Part two studies the analytical techniques and applications of surface modification with chapters on analysing biomaterial surface chemistry, surface structure, morphology and topography before moving onto discuss modifying biomaterial surfaces to optimise interactions with blood, control infection, optimise interactions with soft tissues, repair and regenerate nerve cells, control stem cell growth and differentiation and to optimise interactions with bone. The distinguished editor and international team of contributors to Surface modification of biomaterials have produced a unique overview and detailed chapters on a range of surface modification techniques which will provide an excellent resource for biomaterials researchers and scientists and engineers concerned with improving the properties of biomaterials. It will also be beneficial for academics researching surface modification.

Biointegration is essential for the successful performance of implanted materials and devices within the human body. With an increasing number and wide range of implant procedures being performed, it is critical that materials scientists and engineers effectively design implant materials which will create a positive biological and mechanical response with the host tissue. Biointegration of medical implant materials provides a unique and comprehensive review of recent techniques and research into material and tissue interaction and integration. Part one discusses soft tissue biointegration with chapters on the biocompatibility of engineered stem cells, corneal tissue engineering and vascular grafts. Part two then reviews particular techniques in drug delivery including inorganic nanoparticles for targeted drug delivery and alginate based drug delivery devices. Part three covers design considerations with coverage of themes such as biocompatibility of materials and its relevance to drug delivery and tissue engineering, mechanisms of failure of medical implants during long term use and rapid prototyping in biomedical engineering. With its distinguished editor and team of international contributors, Biointegration of medical implant materials: science and design is a standard reference for medical materials scientists and engineers in industry and the academic sector.

Carbon dioxide (CO2) capture and storage (CCS) is the one advanced technology that conventional power generation cannot do without. CCS technology reduces the carbon footprint of power plants by capturing and storing the CO2 emissions from burning fossil-fuels and biomass. This volume provides a comprehensive reference on the state of the art research, development and demonstration of carbon capture technology in the power sector and in industry. It critically reviews the range of post- and pre-combustion capture and combustion-based capture processes and technology applicable to fossil-fuel power plants, as well as applications of CCS in other high carbon footprint industries.