This thesis presents first observations of superconductivity in one- or two-atomic-scale thin layer materials. The thesis begins with a historical overview of superconductivity and the electronic structure of two-dimensional materials, and mentions that these key ingredients lead to the possibility of the two-dimensional superconductor with high phase-transition temperature and critical magnetic field. Thereafter, the thesis moves its focus onto the implemented experiments, in which mainly two different materials thallium-deposited silicon surfaces and metal-intercalated bilayer graphenes, are used. The study of the first material is the first experimental demonstration of both a gigantic Rashba effect and superconductivity in the materials supposed to be superconductors without spatial inversion symmetry. The study of the latter material is relevant to superconductivity in a bilayer graphene, which was a big experimental challenge for a decade, and has been first achieved by the author. The description of the generic and innovative measurement technique, highly effective in probing electric resistivity of ultra-thin materials unstable in an ambient environment, makes this thesis a valuable source for researchers not only in surface physics but also in nano-materials science and other condensed-matter physics.

This book reviews the current understanding of the mechanical, chemical and biological processes that are responsible for the degradation of a variety of implant materials. All 18 chapters will be written by internationally renowned experts to address both fundamental and practical aspects of research into the field. Different failure mechanisms such as corrosion, fatigue, and wear will be reviewed, together with experimental techniques for monitoring them, either in vitro or in vivo. Procedures for implant retrieval and analysis will be presented. A variety of biomaterials (stainless steels, titanium and its alloys, nitinol, magnesium alloys, polyethylene, biodegradable polymers, silicone gel, hydrogels, calcium phosphates) and medical devices (orthopedic and dental implants, stents, heart valves, breast implants) will be analyzed in detail. The book will serve as a broad reference source for graduate students and researchers studying biomedicine, corrosion, surface science, and electrochemistry.

This book reviews the state-of-the-art in multiscale computer modeling, in terms of both accomplishments and challenges. The information in the book is particularly useful for biomedical engineers, medical physicists and researchers in systems biology, mathematical biology, micro-biomechanics and biomaterials who are interested in how to bridge between traditional biomedical engineering work at the organ and tissue scales, and the newer arenas of cellular and molecular bioengineering.

The book introduces 'the state of the art' of pulsed laser ablation and its applications. It is based on recent theoretical and experimental studies. The book reaches from the basics to advanced topics of pulsed laser ablation. Theoretical and experimental fundamental phenomena involved in pulsed laser ablation are discussed with respect to material properties, laser wavelength, fluence and intensity regime of the light absorbed linearly or non-linearly in the target material. The energy absorbed by the electrons leads to atom/molecule excitation, ionization and/or direct chemical bond breaking and is also transferred to the lattice leading to material heating and phase transitions. Experimental non-invasive optical methods for analyzing these phenomena in real time are described. Theoretical models for pulsed laser ablation and phase transitions induced by laser beams and laser-vapour/plasma interaction during the plume expansion above the target are also presented. Calculations of the ablation speed and dimensions of the ablated micro- and nano-structures are performed. The validity and required refinement of different models in different experimental conditions is provided. The pulsed laser deposition process which bases on collecting the ablated particles on a surface is analyzed in terms of efficiency and quality of the deposited films as a function of ambient conditions, target material, laser parameters and substrate characteristics. The interaction between the incident laser and the ablation plasma is analyzed with respect to its influence on the structures of the deposited films and its capacity to generate high harmonics and single attosecond pulses which are highly desirable in pump-probe experiments.

This book presents a hybrid approach to the mechanics of thin bodies. Classical theories of rods, plates and shells with constrained shear are based on asymptotic splitting of the equations and boundary conditions of three-dimensional elasticity. The asymptotic solutions become accurate as the thickness decreases, and the three-dimensional fields of stresses and displacements can be determined. The analysis includes practically important effects of electromechanical coupling and material inhomogeneity. The extension to the geometrically nonlinear range uses the direct approach based on the principle of virtual work. Vibrations and buckling of pre-stressed structures are studied with the help of linearized incremental formulations, and direct tensor calculus rounds out the list of analytical techniques used throughout the book.

A novel theory of thin-walled rods of open profile is subsequently developed from the models of rods and shells, and traditionally applied equations are proven to be asymptotically exact. The influence of pre-stresses on the torsional stiffness is shown to be crucial for buckling analysis. Novel finite element schemes for classical rod and shell structures are presented with a comprehensive discussion regarding the theoretical basis, computational aspects and implementation details. Analytical conclusions and closed-form solutions of particular problems are validated against numerical results. The majority of the simulations were performed in the Wolfram Mathematica environment, and the compact source code is provided as a substantial and integral part of the book.

In this thesis, Till Cremer investigates the bulk properties of ionic liquids (IL), the IL/vacuum interface and the IL/solid interface. For these studies the author primarily uses angle-resolved X-ray photoelectron spectroscopy under ultrahigh vacuum conditions. ILs represent a class of materials with unique physico-chemical properties. Many applications take advantage of the extremely low vapor pressure of aprotic ILs to fabricate permanent, non-volatile liquid coatings on solid materials. The author focuses on issues related to thin IL coatings, in particular concerning new catalytic concepts such as the supported ionic liquid phase (SILP) and solid catalyst with ionic liquid layer (SCILL) systems. Till Cremer presents a number of fundamental contributions to the new field of "Ionic Liquid Surface and Interface Science". Highlights are his results concerning anion/cation-interactions and the growth of ultrathin layers of ionic liquids on various substrates in the context of supported ionic liquid catalysis. His results have significantly contributed to the present level of understanding in the field and accordingly he is author and coauthor of ten publications on the topic in high-ranked journals.

In this thesis, real-time evolution of the nanopore channel growth and self-ordering process in anodic nanoporous alumina are simulated on the basis of an established kinetics model. The simulation results were in accordance with the experiments on the (i) growth sustainability of pore channels guided by pre-patterns; and (ii) substrate grain orientation dependence on self-ordering. In addition, a new fabrication method for the rapid synthesis of highly self-ordered nanoporous alumina is established, based on a systematic search for the self-ordering conditions in experiments. Lastly, it reports on a novel surface-charge induced strain in nanoporous alumina-aluminium foils, which indicates that nanoporous alumina can be used as a new type of actuating material in micro-actuator applications.

This book chronicles a few approaches to constructing biohybrid devices using photosynthetic protein complexes. Can the abundantly available solar energy be tapped to meet our rising energy demands using green and cheap active materials? Exploring nature's own tiny solar factories, the photosynthetic proteins could hold the key. Photosynthetic pigment-protein complexes found in plants and certain types of bacteria transduce sunlight into biologically useful forms of energy through a photochemical charge separation that has a 100% quantum efficiency. Getting the photoproteins to perform this efficient energy conversion reaction in a semi-artificial setup is central to developing biohybrid solar technologies, a promising green alternative to today's photovoltaics. This book looks into the existing challenges and opportunities in the field of biohybrid photovoltaics and provides a few prospective methods of enhancing the photocurrent and photovoltage in these devices. The book targets the readership of students, academics, and industrial practitioners who are interested in alternative solar technologies.

This monograph presents the latest results related to bio-mechanical systems and materials. The bio-mechanical systems with which his book is concerned are prostheses, implants, medical operation robots and muscular re-training systems. To characterize and design such systems, a multi-disciplinary approach is required which involves the classical disciplines of mechanical/materials engineering and biology and medicine. The challenge in such an approach is that views, concepts or even language are sometimes different from discipline to discipline and the interaction and communication of the scientists must be first developed and adjusted. Within the context of materials' science, the book covers the interaction of materials with mechanical systems, their description as a mechanical system or their mechanical properties.

The ICAMEST 2015 Conference covered new developments in advanced materials and engineering structural technology. Applications in civil, mechanical, industrial and material science are covered in this book. Providing high-quality, scholarly research, addressing developments, applications and implications in the field of structural health monitoring, construction safety and management, sensors and measurements. This volume contains new models for nonlinear structural analysis and applications of modeling identification. Furthermore, advanced chemical materials are discussed with applications in mechanical and civil engineering and for the maintenance of new materials. In addition, a new system of pressure regulating and water conveyance based on small and middle hydropower stations is discussed. An experimental investigation of the ultimate strength and behavior of the three types of steel tubular K-joints was presented. Furthermore, real-time and frequency linear and nonlinear modeling performance of materials of structures contents were concluded with the notion of a fully brittle material, and this approach is implemented in the book by outlining a finite-element method for the prediction of the construction performance and cracking patterns of arbitrary structural concrete forms. This book is an ideal reference for practicing engineers in material, mechanical and civil engineering and consultants (design, construction, maintenance), and can also be used as a reference for students in mechanical and civil engineering courses.

Volume 2 of Formulation Science and Technology is a survey of the different types of formulations used in the chemical industry and offers numerous real-world examples of foams, gels, latexes etc. It offers in-depth explanations for research scientists, universities, and industry practitioners looking for a complete understanding of which type formulation works best for a certain application and why.

With the development of societies fossil energy is no longer the only energy resource, and increasing attention had been paid to alternative energy. Biomass is considered to be one of the alternatives due to efficiency and low cost. This book presents biomass pyrolysis behavior for three main components: Cellulose, Hemicellulose and Lignin, and discusses the influence of mineral salts , zeolite catalysts and metal oxide on their pyrolysis.

The second part of Bioenergy: Principles and Technologies continues the discussion of biomass energy technologies covering fuel ethanol production, pyrolysis, biomass-based hydrogen production and fuel synthesis, biodiesel, municipal solid water treatment and microbial fuel cells. With a combination of theories, experiments and case studies, it is an essential reference for bioenergy researchers, industrial chemists and chemical engineers.

This book provides a comprehensive overview of essential topics related to conventional and advanced drying and energy technologies, especially motivated by increased industry and academic interest. The main topics discussed are: theory and applications of drying, emerging topics in drying technology, innovations and trends in drying, thermo-hydro-chemical-mechanical behaviors of porous materials in drying, and drying equipment and energy. Since the topics covered are inter-and multi-disciplinary, the book offers an excellent source of information for engineers, energy specialists, scientists, researchers, graduate students, and leaders of industrial companies. This book is divided into several chapters focusing on the engineering, science and technology applied in essential industrial processes used for raw materials and products.

Contents - 1. The Free Atom- The contribution of spectroscopy - The Rutherford-Bohr model of the atom - Modern quantum theory - The Pauli exclusion principle - The periodic system - Isotopes - 2. The Bound Atom - Band structure - The attractive and repulsive forces in binding - Stable electron configurations - Ionic bonding - Covalent bonding - Van der Waals' forces - The metallic bond - Implications of the type of bond on the structure of elements - Implications on conductivity - 3. Constitution - Crystallographic principles - The unit cell - The face centred cubic lattice - The close-packed hexagonal lattice. The body-centred cubic lattice - Twin crystals - The rhombohedral lattice - The tetragonal lattice - The structure of compounds - The silicate structure - Glasses - Carbon compounds - 4. Imperfections in Crystals - The surface - Vacant lattice sites - Interstitial atoms - Line and plane defects - Dislocations - Dislocation climb - Dislocation jogs - Imperfect dislocations - Sessile dislocations - Frank-Read sources - 5. The Vibration of Atoms and their Thermal Properties - The lattice vibration - Specific heat - Thermal expansion - Melting - Anisotropy - Thermal conductivity of insulators - Thermal shock - Thermal conductivity of good conductors - 6. Electrical, Magnetic, and Optical Properties - Electrical conductivity - Ionic conductivity - Semiconductors - Thermoelectric effects - Magnetic properties - Ferromagnetism - Antiferromagnetism and ferrimagnetism - Dielectrics - Optical properties - Other electromagnetic radiations - 7. Mechanical Properties - General aspects - Electricity - Plasticity - Resolved shear stress - The role of dislocations in plastic flow - The effect of temperature - Fracture - Creep - Fatigue - Thermal cycling - 8. Metals and Alloys - Properties of pure metals - Compatibility - Interstitial solid solution - Substitutional solid solution - Intermetallic compounds - Equilibrium and non-equilibrium - The properties of alloys - Precipitation in alloys - Complex alloys - 9. Non-metallic Materials - General - Timber - Stone, concrete, and asphalt - Plastics - Ceramics and glasses - Cermets - 10. Service Factors - General - Heterogeneity - Residual stresses - Corrosion - Radiation damage - Conclusion - Further Reading - Author Index - Subject Index - Preface - This book attempts to provide the broad background, to illustrate the basic reasons for the properties of elements, and to explain the consequences of chemical combination, alloying, and mixing. Most previous books have touched only lightly on the atom itself, but my experience in teaching engineers in the University of Manchester suggests that a greater depth of approach is welcome, perhaps because it can account for so much of the subsequent behaviour of metals.

"Morphology Genetic Materials Templated from Nature Species" provides a comprehensive and up-to-date coverage of research on bio-inspired functional materials including materials science and engineering aspects of the fabrication, properties, and applications. The book discusses bio-inspired strategies integrating biotemplate, biomineralization, and biomimesis in nature, which are adopted to fabricate functional materials with hierarchical bio-architectures and interrelated outstanding performances, as well as valuable applications in photoelectricity, photonics, photocatalysis, chemical detection, bio-imaging, and photoelectron transfer components/devices.

The book is intended for researchers and graduate students in the fields of materials science, chemistry, nanotechnology, semiconductor, biotechnology, environmental engineering, etc.

Prof. Dr. Di Zhang is currently a professor at the School of Materials Science and Engineering, Shanghai Jiao Tong University, and the director of the State Key Laboratory of Metal Matrix Composites, China.

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The book "Nanocosmetics and nanomedicines: new approaches for skin care" contains a summary of the most important nanocarriers for skin delivery. Although "nanocosmetics" is a subject widely commented in the academy and the beauty industry, a book covering the skin care treatments using nanotechnological approaches with cosmetics and nanomedicines is still missing, therefore the need for this publication. This book is divided in three parts: The first one (Part A) is devoted to a brief review on the main topics related to the skin delivery and to the introduction of the subject "nanocosmetics". The second part (Part B) presents different types of nanocarriers applied as skin delivery systems for cosmetics or drugs. The last part (Part C) shows a wide range of applications of nanotechnology on the skin care area as well as on dermatocosmetic and dermatological fields.

Electrocatalysts are the heart of power devices where electricity is produced via conversion of chemical into electrical energy. - pressive advances in surface science techniques and in first pr- ciples computational design are providing new avenues for signi- cant improvement of the overall efficiencies of such power dev- es, especially because of an increase in the understanding of el- trocatalytic materials and processes. For example, the devel- ment of high resolution instrumentation including various electron and ion-scattering and in-situ synchrotron spectroscopies, elect- chemical scanning tunneling microscopy, and a plethora of new developments in analytical chemistry and electrochemical te- niques, permits the detailed characterization of atomic distribution, before, during, and after a reaction takes place, giving unpre- dented information about the status of the catalyst during the re- tion, and most importantly the time evolution of the exposed ca- lytic surfaces at the atomistic level. These techniques are c- plemented by the use of ab initio methods which do not require input from experimental information, and are based on numerical solutions of the time-independent Schrodinger equation including electron-electron and electron-atom interactions. These fir- principles computational methods have reached a degree of - turity such that their use to provide guidelines for interpretation of experiments and for materials design has become a routine practice in academic and industrial communities.

In-situ scattering and diffraction measurements using synchrotron and neutron beam lines have become a viable tool to look at the non-equilibrium processing of advanced materials. This volume presents the subject from the theoretical and experimental standpoint, in order to provide a closer insight into the different synchrotron and neutron diffraction techniques as well as innovative microscopy techniques.

It addresses the following items:

- Phase detection and quantification

- In-situ welding experiments

- Stress/strain build-up

- Model development and Simulation

- Analysis tools and programming

Magnetic nanocatalysts are becoming an important tool for greener catalytic processes in chemical transformations in view of the ease of their removal from a reaction medium. This book explores assorted magnetic nanocatalysts, their deployment in synthesis, chemical transformation and their recovery and reuse. Various thematic topics embodied include magnetic nanocatalysts for S-S bond formation, N-heterocycle formation, C-heteroatom bond formation, silica-supported catalysts, multicomponent reactions, including their recyclability; another available volume emphasizes the utility of magnetic nanocatalysts in industrial appliances.

This book focuses on neuro-engineering and neural computing, a multi-disciplinary field of research attracting considerable attention from engineers, neuroscientists, microbiologists and material scientists. It explores a range of topics concerning the design and development of innovative neural and brain interfacing technologies, as well as novel information acquisition and processing algorithms to make sense of the acquired data. The book also highlights emerging trends and advances regarding the applications of neuro-engineering in real-world scenarios, such as neural prostheses, diagnosis of neural degenerative diseases, deep brain stimulation, biosensors, real neural network-inspired artificial neural networks (ANNs) and the predictive modeling of information flows in neuronal networks. The book is broadly divided into three main sections including: current trends in technological developments, neural computation techniques to make sense of the neural behavioral data, and application of these technologies/techniques in the medical domain in the treatment of neural disorders.

This book presents an approach to the design and fabrication of optical elements that are based on the use of one- or two-dimensional randomly rough surfaces to reflect or transmit light in specified ways. The reader is provided with an introduction to analytical methods for the solution of direct problems in rough surface scattering, and fabrication techniques. These can be useful in contexts outside the scope of this book. The advantages and disadvantages of this stochastic approach compared to the diffractive optics approach are discussed. Finally, experimental results that verify the predictions of the theories developed in this book are presented.
- authority of authors
- the only book on the topic
- derivations are given in detail, with many figures illustrating results

This book addresses a broad spectrum of areas in both hybrid materials and hierarchical composites, including recent development of processing technologies, structural designs, modern computer simulation techniques, and the relationships between the processing-structure-property-performance. Each topic is introduced at length with numerous and detailed examples and over 150 illustrations. In addition, the authors present a method of categorizing these materials, so that representative examples of all material classes are discussed.

This book aims to show how tribological concepts can be applied in order to improve manufacturing technology in modern industry. It can be used as a guide book for engineering students or a reference useful for academics in the fields of tribology, manufacturing, materials and mechanical engineering.